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(45) Date of publication and mention (51) intci.6: H05H 1/30, H05H 1 / 3 6
of the grant of the patent:
27.03.1996 Bulletin 1996/13
DO
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00
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lO Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give
o notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in
a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art.
a. 99(1) European Patent Convention).
LU
Printed by Jouve, 75001 PARIS (FR)
1 EP 0 568 920 B1 2
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3 EP 0 568 920 B1 4
nant output circuit 16 of which load coil 17 is the inductive back to the grid control circuit 13 and maintains RF power
part thereof. The generated plasma is symbolically to the load coil 17 constant accurately adjusted and sta-
shown as aflame 18b. It should be noted, however, that ble at the commanded power.
the plasma which comprises photons and ions is used Grid control circuit contains a power transistor, e.g.,
differently depending on its use in atomic emission spec- 5 an FET transistor, to which the error signal is fed. The
trometry or mass spectrometry. transistor controls the grid bias of triode vacuum tube 11
The capacitance of the oscillator resonant circuit 16 in accordance with the error signal.
is split as shown in Fig. 2 to act as a voltage divider to In order to extend the range of vacuum tube 11 of
cause a virtual ground to appear at the center of load coil an oscillator, its efficiency may be varied between ap-
17. This permits the plasma to be operated at zero or 10 proximately between 40% to 60% by varying grid current
near zero potential with its attendant advantage of elim- of vacuum tube 11 in accordance with actual output pow-
inating parasitic discharges when used in an atomic er, e.g., low efficiency for low grid current and high effi-
emission spectrometer and discharges that erode the or- ciency for high grid current.
ifice of the sampler when used in a mass spectrometer. A meter circuit 25 has an input from generator 11.
A capacitive voltage divider circuit 14 and a current is The meter circuit 25 has an output connected to compa-
transformer circuit 15 are connected between generator rator circuit 26 and analog to digital converter circuit 29
11 and radio frequency multiplier circuit 19. Radio fre- which, itself, provides an input to microprocessor 23. A
quency multiplier circuit 19 provides an input to compa- monitor circuit 27 provides a second input to comparator
rator circuit 19. Capacitive voltage divider circuit 14 pro- circuit 26 whose output is provided as an input to protec-
vides an output representative of the RF voltage output 20 tion circuit. The output of protection circuit 28 is connect-
of generator 11 to RF multiplier circuit 19 while current ed to high voltage power supply.
transformer 15 provides a signal representative of the One purpose of this arrangement is to monitor the
RF current output of generator 11 to RF multiplier circuit operating parameters of the generator 11 such as plate
19. Voltage divider circuit 14 and current transformer cir- voltage, plate current, and grid current. Thus, if one of
cuit 15 are connected so as to not interfere with the RF 25 the parameters exceeds a critical value set by monitor
power delivered to the load. circuit 27, protective circuit 28 will cause high voltage
RF voltage and current are in effect multiplied in RF power supply 12 to shut down. This feature is particularly
multiplier circuit 19 to give an output signal representa- important when determining the operating conditions of
tive of the RF power actually being delivered to the plas- the plasma by monitoring grid current. Prior to ignition of
ma 18b through the load coil 17. In one embodiment of 30 the plasma discharge, grid current is extremely high.
the present invention, RF multiplier circuit 19 contains This is so since very little power is being absorbed from
identical logarithmic response amplifiers and a summa- the load coil and most of the power provided by RF gen-
tion circuit similar to the AD834 four-quadrant multiplier erator 11 is fed back to the grid of the generator which,
as shown and described on page 6-65 of Analog Devic- as aforesaid, is essentially a triode vacuum tube. If the
es, Inc., "Linear Products Databook" 1990/91 Edition. 35 grid current remains high beyond a predetermined time,
Since the RF voltage signal and the RF current signal it may be indicative of an ignition problem. To prevent
are logarithmically amplified and then added together, damage to the circuitry and/or glass torch 18, protective
they are arithmetically equivalent to being multiplied to- circuit 28 shuts off high voltage from power supply 12 to
gether. Since the arithmetic product of RF voltage and generator 11. Similarly, the grid current may be indicative
RF current is RF power, the output signal from RF mul- 40 of a good ignition by reverting from a high pre-ignition
tiplier circuit 19 is representative of the RF power being value to a stable lower running condition. Variation in grid
delivered to the plasma through the load coil 17. current may also be indicative of a "bad" plasma that is
The signal representative of RF power is continu- one that comprises a destructive discharge. This is also
ously applied to comparator circuit 21 . A microprocessor detectable in time to shut off high voltage to the generator
23 provides a second input to comparator circuit 21 in- 45 11 before damage is incurred.
dicative of desired or commanded RF power. A digital to Dependent on the required RF power range, e.g.,
analog converter is interposed between microprocessor ignite or various running ranges, microprocessor 23 con-
23 and comparator circuit 22 to convert the digital data trols the power level output of the generator 11 by ad-
from microprocessor to analog form to be compatible justing amount of power provided by the power source
with the analog signal from RF multiplier circuit 19. so 12. This may be accomplished, e.g., by turning on one
The comparator circuit 21 provides an error signal of four triacs or similar devices that control the level of
to grid control circuit 13. This error signal is representa- actual high voltage to the plate of triode vacuum tube 11.
tive of the positive or negative deviation of actual RF Referring more particularly to Fig. 2, there is shown
power going to the load coil 17 from desired or com- the oscillator of the present invention. As can be seen, it
manded power provided by microprocessor 23. This val- 55 comprises triode vacuum tube 11 connected as a some-
ue among others is provided by a host computer having what modified Colpitts oscillator. Resonant output circuit
a keyboard entry system or the like and a display and/or 16 essentially comprises the load coil 17 connected in
printer. The signal from the comparator circuit 21 fed parallel to capacitors C-, and C2 whose juncture is con-
3
5 EP 0 568 920 B1 6
nected to the grounded cathode. The present Colpitts os- means and said oscillator means for maintain-
cillator circuit differs from the conventional circuit in that ing said RF power at a commanded level.
in the present arrangement C-, and C2 are made equal
in value to each other and reverse connected whereas 2. An inductively coupled plasma generator in accord-
in the conventional arrangement they are not equal. In 5 ance with claim 1, wherein said detector means
the present arrangement, the ratio of C2 to C3 controls comprises
grid drive power whereas in the conventional setup, the
ratio of C-| to C2 performs this function. first means connected to the output side of said
By having capacitances C-, and C2 equal in reac- oscillator means providing a voltage represent-
tances and reverse connected, the voltages across load ee1 ative of the RF voltage output of said oscillator
coil 17 are equal in magnitude but opposite in phase with means,
respect to ground. The effect of this arrangement is to
produce a virtual ground at the electrical midpoint of load second means connected to the output side of
coil 17 which enables the plasma to operate with no in- said oscillator means providing a current repre-
direct d.c. potential, i.e., at ground potential with the at- ss sentative of the RF current output of said oscil-
tendant advantage of eliminating damage to the glass lator means,
torch in atomic emission spectrography or erosive dam-
age to the sampler cone in mass spectrography. third means connected to said first and second
The microprocessor 23 obtains information on the means for effectively multiplying the outputs of
required or commanded RF power and other operational 20 said first and second means providing an output
parameter, e.g., level of plate voltage from high voltage voltage representative of actual RF power deliv-
power supply 12 from host computer 24. ered by said oscillator means to said inductive
The commanded RF power signal is provided to load means.
comparator circuit 22 via digital to analog converter 22
while the high voltage (low, medium, high or ignite) at 25 3. An inductively coupled plasma generator according
which the oscillator is to be operated is provided via to to claim 2 wherein said circuit means comprises
high voltage power supply 12 via digital input output cir-
cuit 31. comparator circuit means connected to said
There has above been described an inductively cou- third means for receiving said voltage repre-
pled plasma generator which provides novel means for 30 sentative of said actual RF power,
the accurate adjustment and stable control of RF output
power. Since the circuit measures true RMS power, it fourth means connected to said comparator cir-
takes into account the phase shift of the RF current and cuit means for providing an input to said com-
RF voltage due to a change in the load impedance parator circuit means representative of said
caused by different plasma operating conditions and the 35 commanded RF power,
tube plate impedance charge due to varying the grid bi-
as. said comparator circuit means providing an
In addition to maintaining the plasma at ground volt- error signal output representative of the differ-
age, the grid current of the vacuum tube is constantly ence between said actual RF power and said
monitored to prevent the above-mentioned damage 40 commanded RF power,
problems.
Finally, as aforesaid, the power adjustment range of control circuit means connected to said oscilla-
the generator is expanded by varying the efficiency of tor means and to said comparator circuit means
the RF generator's vacuum tube oscillator. for controlling the RF output power of said oscil-
45 lator means in accordance with said error sig-
nal.
Claims
4. An inductively coupled plasma generator in accord-
1. An inductively coupled plasma generator, compris- ance with claim 3, wherein said oscillator means
ing oscillator means for generating RF power, so comprises
load means connected to said oscillator for gen- a triode vacuum tube having a plate, cathode
erating a plasma, and grid.
detector means for measuring actual RF power 55 5. An inductively coupled plasma generator in accord-
delivered to said load means, ance with claim 4 wherein said control circuit means
comprises
circuit means connected between said load
4
7 EP 0 568 920 B1 8
a grid control circuit connected to the grid of said tube for disconnecting said power supply from
triode vacuum tube for applying said error signal said triode vacuum tube to prevent damage to
to said grid for maintaining RF output power at said glass torch.
said commanded RF power.
5
6. An inductively coupled plasma generator in accord- Patentanspriiche
ance with claim 5 wherein said grid control circuit
includes 1. Ein induktiv gekoppelter Plasmagenerator,
umfaBend
power transistor means which controls grid cur- 10
rent to vary the efficiency of said oscillator eine Oszillatoreinrichtung zum Erzeugen von
means between limits determined by com- HF-Leistung,
manded RF output power.
eine Lasteinrichtung, die mit dem genannten
7. An inductively coupled plasma generator in accord- 15 Oszillator zum Erzeugen eines Plasmas ver-
ance with claim 6 wherein said load means com- bunden ist,
prises
eine Erfassungseinrichtung zum Messen der
a glass torch, gegenwartigen HF-Leistung, die an die
20 genannte Lasteinrichtung geliefert wird,
a load coil disposed about said glass torch,
eine Schaltungseinrichtung, die zwischen die
first and second series connected capacitors genannte Lasteinrichtung und die genannte
connected in parallel to said load coil to form a Oszillatoreinrichtung zum Aufrechterhalten der
resonant circuit therewith connected between 25 genannten HF-Leistung auf einem verlangten
said plate and cathode of said triode. Wert verbindet.
8. An inductively coupled plasma generator in accord- 2. Ein induktiv gekoppelter Plasmagenerator gemaBt
ance with claim 7 wherein Anspruch 1, in dem die genannte Erfassungsein-
30 richtung umfaBt
said capacitors are of equal value and con-
nected at their juncture to ground whereby eine erste Einrichtung, die mit der Ausgangs-
plasma voltage is held a zero potential. seite der genannten Oszillatoreinrichtung ver-
bunden ist und eine fur den HF-Spannungsaus-
9. An inductively coupled plasma generator in accord- 35 gang der genannten Oszillatoreinrichtung
ance with claim 8 wherein said fourth means is a representative Spannung bereitstellt,
microprocessor programmed to provide said com-
manded RF power. eine zweite Einrichtung, die mit der Ausgangs-
seite der genannten Oszillatoreinrichtung ver-
10. An inductively coupled plasma generator according 40 bunden ist und einen fur den HF-Stromausgang
to claim 9 further comprising der genannten Oszillatoreinrichtung reprasen-
tativen Strom bereitstellt,
plate voltage supply means connected between
said plate of said triode vacuum tube and said eine dritte Einrichtung, die mit der genannten
microprocessor for changing plate voltage in 45 ersten und der zweiten Einrichtung gekoppelt
accordance with said commanded RF power. ist, urn wirksam die Ausgange der genannten
ersten und zweiten Einrichtung zu multiplizie-
11. An inductively coupled plasma generator according ren, wodurch eine Ausgangsspannung bereit-
to claim 10 wherein said first means and second gestellt wird, die fur die gegenwartige HF-Lei-
means each comprise logarithmic response ampli- so stung reprasentativ ist, die von der genannten
tiers and said third means comprises a summation Oszillatoreinrichtung an die genannte induktive
circuit. Lasteinrichtung geliefert wird.
12. An inductively coupled plasma generator according 3. Ein induktiv gekoppelter Plasmagenerator gemaB
to claim 11 further comprising 55 Anspruch 2, in dem die genannte Schaltungseinrich-
tung umfaBt
protective circuit means response to significant
changes in grid current of said triode vacuum eine Komparatorschaltungseinrichtung, die mit
5
9 EP 0 568 920 B1 10
5. Ein induktiv gekoppelter Plasmagenerator gemaB 11. Ein induktiv gekoppelter Plasmagenerator gemaB
Anspruch 4, in dem die genannte Steuerungsschal- 35 Anspruch 10, in dem die genannte erste Einrichtung
tungseinrichtung umfaBt und zweite Einrichtung jeweils logarithmisch reagie-
rende Verstarker umfassen und die genannte dritte
eine Gittersteuerungsschaltung, die mit dem Einrichtung eine Addierschaltung umfaBt.
Gitter der genannten Trioden-Vakuumrohre ver-
bunden ist, um das genannte Fehlersignal an 40 12. Ein induktiv gekoppelter Plasmagenerator gemaB
das genannte Gitter zum Aufrechterhalten der Anspruch 11, ferner umfassend
HF-Ausgangsleistung bei der verlangten
HF-Leistung anzulegen. eine Schutzschaltungseinrichtung, die auf
merkliche Anderungen beim Gitterstrom der
6. Ein induktiv gekoppelter Plasmagenerator gemaB 45 genannten Trioden-Vakuumrohre reagiert, um
Anspruch 5, in dem die genannte Gittersteuerungs- die genannte Stromversorgung von der
schaltung einschlieBt genannten Trioden-Vakuumrohre abzuschal-
ten, um eine Beschadigung des genannten
eine Leistungstransistoreinrichtung, die den Glasbrenners zu verhindern.
Gitterstrom steuert, um den Wirkungsgrad der 50
genannten Oszillatoreinrichtung zwischen
Grenzen zu verandern, die durch die verlangte Revendications
HF-Ausgangsleistung bestimmt sind.
1. Generateur de plasma a couplage inductif , compre-
7. Ein induktiv gekoppelter Plasmagenerator gemaB ss nant
Anspruch 6, in dem die genannte Lasteinrichtung
umfaBt un moyen oscillateur, pour generer de I'energie
RF,
6
11 EP 0 568 920 B1 12
un moyen de charge connecte audit oscillateur, revendication 4, dans lequel ledit moyen de circuit
pour generer un plasma, de commande comprend
un moyen detecteur, pour mesurer la puissance
RF reelle delivree audit moyen de charge, un circuit de commande de grille connecte a la
un moyen de circuit connecte entre ledit moyen s grille dudit tube triode a vide, pour appliquer
de charge et ledit moyen oscillateur, pour main- ledit signal d'erreur a ladite grille, pour maintenir
tenir ladite energie RF a une valeur comman- la puissance de sortie RF a ladite puissance RF
dee. commandee.
2. Generateur de plasma a couplage inductif selon la 10 6. Generateur de plasma a couplage inductif selon la
revendication 1, dans lequel ledit moyen detecteur revendication 5, dans lequel ledit circuit de com-
comprend mande de grille comporte
un premier moyen connecte a la sortie dudit un moyen de transistor de puissance qui com-
moyen oscillateur, fournissant une tension is mande le courant de grille pour faire varier le
representant la tension de sortie RF dudit rendement dudit moyen oscillateur entre des
moyen oscillateur, limites determinees par ladite puissance de sor-
un deuxieme moyen connecte a la sortie dudit tie RF commandee.
moyen oscillateur, fournissant un courant repre-
sentant le courant de sortie RF dudit moyen 20 7. Generateur de plasma a couplage inductif selon la
oscillateur, revendication 6, dans lequel ledit moyen de charge
un troisieme moyen connecte auxdits premier comprend
et deuxieme moyens, pour multiplier effective-
ment les sorties desdits premier et deuxieme une lampe en verre,
moyens, en fournissant une tension de sortie 25 une bobine de charge placee autour de ladite
representant la puissance RF reelle delivree par lampe en verre,
ledit moyen oscillateur audit moyen de charge un premier et un second condensateurs con-
inductive. nected en serie, connectes en parallele avec
ladite bobine de charge, pour former un circuit
3. Generateur de plasma a couplage inductif selon la 30 resonant avec celle-ci, connecte entre lesdites
revendication 2, dans lequel ledit moyen de circuit plaque et cathode de ladite triode.
comprend
8. Generateur de plasma a couplage inductif selon la
un moyen de circuit comparateur connecte revendication 7, dans lequel
audit troisieme moyen, pour recevoir ladite ten- 35
sion representant ladite tension RF reelle, lesdits condensateurs sont de valeurs egales et
un quatrieme moyen connecte audit moyen de sont connectes a la masse a leur jonction, de
circuit comparateur, pour fournir une entree facon a ce que la tension de plasma soit main-
audit moyen de circuit comparateur, represen- tenue a un potentiel nul.
tant ladite puissance RF commandee, 40
ledit moyen de circuit comparateur fournissant 9. Generateur de plasma a couplage inductif selon la
un signal d'erreur de sortie, representant la dif- revendication 8, dans lequel ledit quatrieme moyen
ference entre ladite puissance RF reelle et est un microprocesseur programme pour fournir
ladite puissance RF commandee, ladite puissance RF commandee.
un moyen de circuit de commande connecte 45
audit moyen oscillateur et audit moyen de circuit 10. Generateur de plasma a couplage inductif selon la
comparateur, pour commander la puissance de revendication 9, comprenant en outre
sortie RF dudit moyen oscillateur, en fonction
dudit signal d'erreur. un moyen d'alimentation de tension de plaque,
50 connecte entre ladite plaque dudit tube triode a
4. Generateur de plasma a couplage inductif selon la vide et ledit microprocesseur, pour faire varier
revendication 3, dans lequel ledit moyen oscillateur la tension de plaque en fonction de ladite puis-
comprend sance RF commandee.
un tube triode a vide ayant une plaque, une 55 11. Generateur de plasma a couplage inductif selon la
cathode et une grille. revendication 10, dans lequel ledit premier moyen
et ledit second moyen comprennent chacun des
5. Generateur de plasma a couplage inductif selon la amplificateurs a reponse logarithmique, et ledit troi-
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