Scribd Logo
Upload

Welcome to Scribd!

  • Cuestion 4 T 5.1

    Uploaded by

    al414631
    4 views1 page
    The document discusses electronic transitions in chemical compounds. It provides: 1) Possible electronic transitions in [Ni(en)2]2+ including energies of 11200 cm-1 and 18350 cm-1. 2) Possible electronic transitions in [VF6]3- including energies of 14800 cm-1 and 23250 cm-1 and Franck-Condon factors. 3) Calculations of Franck-Condon factors using the equation (B)=E1/E2 for the transitions.

    Original Description:

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses electronic transitions in chemical compounds. It provides: 1) Possible electronic transitions in [Ni(en)2]2+ including energies of 11200 cm-1 and 18350 cm-1. 2) Possible electronic transitions in [VF6]3- including energies of 14800 cm-1 and 23250 cm-1 and Franck-Condon factors. 3) Calculations of Franck-Condon factors using the equation (B)=E1/E2 for the transitions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    4 views1 page

    Cuestion 4 T 5.1

    Uploaded by

    al414631
    The document discusses electronic transitions in chemical compounds. It provides: 1) Possible electronic transitions in [Ni(en)2]2+ including energies of 11200 cm-1 and 18350 cm-1. 2) Possible electronic transitions in [VF6]3- including energies of 14800 cm-1 and 23250 cm-1 and Franck-Condon factors. 3) Calculations of Franck-Condon factors using the equation (B)=E1/E2 for the transitions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 1

    c) [Ni (en) , j2+

    TRANSICIONES POSIBLES :

    S
    "Azg
    Y
    3
    * Tzg 1 j E1 = 11200
    LAS PODEMOS
    VER

    3
    A Tig Azg j E2 = 18350

    Azg
    3
    A
    Tig [ j Es = 29000

    *
    E =

    (B) =

    11200=00

    11200 896
    12 5
    .
    = >Bi =

    B -
    B
    1 =0 , 60975 = 0 6103 896 cm
    =
    ,

    B2 = 895 12
    18350
    .

    20 5 . =
    ,

    12 5 .
    =

    A
    -
    A0 = 11200 cm

    E1 E2

    D) [VFg]3

    TRANSICIONES POSIBLES :

    F
    3
    * 3T29 E T19 j E1 =
    14800

    · "Tig(P) s "Tg(F)
    ↓ ; Ez =
    23250

    E (B) 1800
    *
    = = = 0, 60S

    -1

    14800
    23 . 5 =
    · B1 = 629 , 8 cm

    3
    235 = 0 , 6351 = 0 ,
    63656 B =
    629 , 1 cm't
    1
    23250 co-
    37 =
    B2 = 628, 4
    B

    23 5.
    =
    A

    10 = 14783 85 ,
    cm

    El =2

    You might also like