TEMA 7 : TERMODINÁMICA

(p(Pb) c'13]/gC
45) 1RyPb
=

100
(1,0 =

4183/gC
en -
-

Qb =
Gr
20 -
Desc (MP6 CP(PD) STPb)) Maco CPro Two
=

ess
.
· ·
= ·

Mob
.

<P)Pb) ·

ST(Pb)
M4 0 = -
=

,
<p(U, 0) ·

1T(mo)
= 1000 .

0'13 .
(32's -100) =

418(32'5 28'5) -

Q =
mL G =

m(17 =
10 .

209(0 -
( -
15)) =
313'5]
Q m
Q mGAT 10g 33323)/g 33323]
-
=
=
=
=

G = m(1T =
10 .

418(100 -

0) =

4180)
G =
mL =

10 -

22434 =

224377
G =

m(17 10 .
2109 (110 .
-

100) =
209]
=

Q707 =
30468'83
,

a ⑪
I mal 6 I .
A
② N

1 mal 6I

298SK =
To =
25C Tint= To 7f =
300 =
5731SK
Po= latm VF Py =
10 atm

Vo VF
. 98'1s=22'44L 4'69L
= 1 .
0082 =

1
:
compresión ISOTERMA- T = Te

A 0 =
-
G = -
W -
W =
-
nRTh = -
1 . 8314 29815 .
.
h 24 = 4088]
Vo 22'YY
↳ Q =
-

4088]
2 CALENTAMIENTO
:

ISOBARICO P= cte

SV =

c +
Q

w
/ w 01 ap 1H
= =

+
= =

↳ ap n(p m17 =

,
=

1 .
3762(57315 29815) -

= 103323

N I: Compl
adiateativa
A

intentar
Imal 6 1 .
Po= latm Incel G 1 . Pr= 10 atm
PF 300V 464L
2981SK =
To =

25C Vo 22 YYL
=
=

11
=

573'1SK
1 Compresión adialática Q =0 - 1 k =
=
n(r m1) ,

RY PaV Cam-Cr , m
=
R U =

↓
Cr , m
=

(p , m
-
R = 3762 -

8314 =

29306]/rmal

PVPY -
1 .
248 16 .
V2Ve =
Yo4L

Te V
*
- 298 .
2472 Yo -
T
=

493SK

SU = W = 1-29'3 1493'0s-29845) =

5710]
/

AU= Q +
W

a :

frame -> Q =

fec64s+0003)r=2mallisot+2mal)cositor-
6 S (Tz -Te) 000nS (T2 T? )
ap
=2 . +
2 .
-
=
1230 +
217 =
1447cal =

Como p=cte , Gp= &H =

1447 cal =
604846]
,
 W = -

PAV =
-
101325 .
(656 -49'2) . y
=

16617334
082
V =
M =
.

300 =
49 V =R =
.
400 = 656

AU =
G +
W = 60486] +

( 1661733)
-

=
4386877 = 1049'Scal

AU =

W+G -> Gr =

fa .
Cu

Came V =ct -> W =

0 (W =- p AV) .

Calculamos Crim :
<pim -Crim =
R -> Crim =

(pim -
R

(vim =

6'15 +000317 -
11987 =
4'163 +
000317
-
R

Gr =

fe: (46 +0003107 =

81326(7 2) -
+

06032(7 2) -
=

8326 +
217 =

=10496cal -
= 4387'3] =

AV/

1H =

AU +

VIp =
1387 +

49'2 103(135187 -
101325) =

60537
/
.

r
- 5

pV=nRT

↳
-
k =

(400
Y
300
,
=0'0492m=
7
Ye

P 135187Pa
.

=
=

00492

as
92

an) SU=0+W -> victe -> W=0 - >

JU= Qu

Q =

n ·

Cum .
17 -> Gr =
n([pm -
R)17 = 1 -

(291355 -

8314)(37315 298)-

Gr 1
=

1512] =

an) T=cte ->

SU 0 = (17 0) -> W= -

G =
-

nRTh
W =
-
1 .

8314 373'11 .

=
-

493]
 El gas expande de mode isaterma hasta
be) se v SOL
=

Como es
isatermo
IT=0 - AU=0 -> Q =
-
W

W nRTh W 1 8314
29815 3987's
= -
= -

=
. .

,
-

Vo

b2) El calienta valumen hasta 100

te

se a
gas

Como Vcte AU= Qu W=0

,
ya que

Gr = n .

(um 17 -
=

1 -

(291355 - 8'314) (37315 298)

- -
=

15812
,

7
AU de umbas procesos es de 1581'2] 92
3731SK ---- ⑧

La energia interna iniamente depende an b2

de los estado del b1
finals
iniciales

y 298k ---
/

sistenc .

i i
10L SOL 2

Gas ideal ,
manoatomics Crim=R
Po= Latm , V ,
T =
400k -> Pr <Y ,
V2 =
2 V, 72 7=
=
400k

Es proceso a isoterno ,
po
lo
que
U=0 y G--h

W =

nRTh W
nRTh -W nRTh2
-

=
-> =
- -

W = -
1 .

8314 .
400 = - 23051] ; G =
2303'n]
-
- ,

14 =
1 +

VP -
1H = AU + /17 - >
H SU =
=
G
AS
nRh nRh2 1 8'314 In 2 5767/1
=
= .
.

= =

AG =
AH-TDS ->
AG = 0-400 576 =- 2305'1]
.