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  • (L3) - (JLD 4.0) - Alkyl Halide - 20th Oct

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    This document discusses various aromatic substitution reactions including SNAr, SNi, and SNNGP reactions. It provides details on the mechanisms and important points for SNAr reactions, including that electron withdrawing substituents in the ortho or para position are required, and the incoming nucleophile must be a stronger base than the leaving group. It also discusses SN1 and SNNGP reactions mechanisms. The document aims to explain aromatic substitution reactions to a class of 12 students.

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    _[L3] - (JLD 4.0) - Alkyl halide - 20th Oct

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    This document discusses various aromatic substitution reactions including SNAr, SNi, and SNNGP reactions. It provides details on the mechanisms and important points for SNAr reactions, including that electron withdrawing substituents in the ortho or para position are required, and the incoming nucleophile must be a stronger base than the leaving group. It also discusses SN1 and SNNGP reactions mechanisms. The document aims to explain aromatic substitution reactions to a class of 12 students.

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    9 views48 pages

    (L3) - (JLD 4.0) - Alkyl Halide - 20th Oct

    Uploaded by

    dinesh.mission.iit
    This document discusses various aromatic substitution reactions including SNAr, SNi, and SNNGP reactions. It provides details on the mechanisms and important points for SNAr reactions, including that electron withdrawing substituents in the ortho or para position are required, and the incoming nucleophile must be a stronger base than the leaving group. It also discusses SN1 and SNNGP reactions mechanisms. The document aims to explain aromatic substitution reactions to a class of 12 students.

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    of 48

    12

    CLASS

    Aryl Halide
    SNAr, SNi &
    SNNGP Reaction

    Lokesh Choudhary
    Lokesh Choudhary
    IISER BHOPAL
    Top Kota Faculty
    Mentored Top Rankers JEE/NEET
    AIR-42 (CSIR NET/JRF)
    Researcher, R&D Shell

    7+ years of experience
    Bratin Mondal Amaiya Singhal

    100 %ile 100 %ile


    Comparison of SN2 & SN1 Reactions
    Comparison of SN2 & SN1 Reactions
    Comparison of SN2 & SN1 Reactions
    Comparison of SN2 & SN1 Reactions
    Comparison of SN2 & SN1 Reactions
    Comparison of SN2 & SN1 Reactions
    SNAr: Nucleophilic Aromatic Substitution

    This is the characteristic reaction of aryl halides with ortho or para electron withdrawing
    substituent.
    SNAr: Nucleophilic Aromatic Substitution

    Cl

    OH-
    SNAr: Nucleophilic Aromatic Substitution
    Mechanism for SNAr
    Important Points for SNAr
    Important Points for SNAr
    Important Points for SNAr
    Important Points for SNAr

    The electron-withdrawing substituent must be ortho or para to the site of


    nucleophilic attack
    Important Points for SNAr

    The incoming nucleophile must be a stronger base than the substituent that is being
    replaced, because the weaker of the two bases will be the one eliminated from the
    intermediate.
    Important Points for SNAr
    Write the correct reactivity order with NaOH for the following compounds.
    Which of the following compound gives fastest SN2Ar reaction ?

    A. B. C. D.
    Which of the following reaction is SN2Ar reaction ?

    A. B.

    C. D.
    Give the products in following reaction

    A. B.
    SN i Reaction (Darzen’s process)

    In the SNi mechanism (substitution nucleophilic internal), a part of the leaving


    group must be able to attack the substrate.
    SN i Reaction
    Mechanism
    SN i Reaction
    Mechanism
    SN NGP Reaction
    SN NGP Reaction

    1. Intramolecular attack of nucleophile.

    2. Presence of nucleophile and leaving group within a molecule.

    3. Nucleophile & Leaving group should be opposite side


    SN NGP Reaction
    SN NGP Reaction
    SN NGP Reaction
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