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SOCIETY OF PETROLEUM ENGINEERS OF AIME PAPER

Fidelity Union Bldg. NUMBER 1253-G


Dallas, Tex.

THIS IS A PREPRINT --- SUBJECT TO CORRECTION

Gamma Ray-Density Logging

By

Albin J. Zak and Joe Ed Smith, Junior Members AIME

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Core Laboratories Inc., Dallas, Tex.

ABSTRACT In the practical logging tool, a beam of


gamma rays is emitted into the formation. A
This paper presents a review of current small fraction of these photons find their way
methods of interpreting and applying gamma ray- back to the detector. Normally, the detector
density logs in evaluating fundamental reservoir used is a Geiger-Muller counter or scintillation
data. The basic theories and physical principles counter. Studies of other detecting devices,
underlying the techniques of density logging with such as cloud chambers and ionization chambers,
gamma rays are discussed along with some of the have shown them to be unsuitable for this purpose.
problems associated with the instrumentation of The most common gamma ~ay source for this tool is
such a tool. An effort has been made to evaluate radioactive cobalt (Co bO ). The source is Shielded
the instrument calibration techniques, and discus- from the detector with lead such that the majority
sion and figures are presented which describe the of the gamma rays counted by the detector are
effect of borehole conditions, pressure, tempera- those back-scattered from the formation.
ture, etc. The relationship of natural density,
grain density, and interstitial fluid density to Initial calibration of the instrument is made
porosity is presented. Field data illustrate how in special testholes in which the density of the
density logs can be correlated with porosity and calibrating material is carefully controlled.
grain density data. With the aid of adequate core These experiments are made in various hole sizes
analysis data, a reasonably accurate estimate of in each of several different mud densities. From
formation porosity can be obtained from density this, an adequate prediction has been established
log interpretation. The paper also offers a dis- as to the effect of borehole diameter and borehole
cussion of the limitations of the density log as a fluid density on the log response. To date, there
porosity tool. The current applications of the are no valid correction factors proposed for the
density log to geologic work are cited, and the effects due to poor borehole geometry. The rules
prospective uses and future developments are and limitations of logging speed, time-constant,
briefly explored. bed thickness, etc., that apply to conventional
radioactivity logs also apply to density logging.
SUMMARY The effects of temperature and pressure are those
effects that are imposed on the response of the
The principle of gamma ray absorption as a gamma ray counter, and the effects on the densi-
function of density was adapted to the logging of ties of the interstitial fluids.
petroleum formations through the utilization of a
phenomenon known as "back-scattering". This tech- The basic interpretation of the density log
nique uses a tool which contains both a gamma ray is fairly simple; the possible applications are
source and detector. The detector measures the numerous. The most prominent denSity log applica-
intensity of the gamma rays emitted from the tions are: (1) lithological eorrelations, (2)
source that have been back-scattered to the de- i determination of density grad:"ents for gravity
tector by the formation. After proper instrument , meter surveys, (3) determination of borehole fluid
calibration, the log response can be used to denSity for gradient surveys, (4) location of
compute the natural density of the formation. casing shoe and cement top, (5) location of casing
Since there is a definite relationship between leaks, (6) aid in the interpretation and evalua-
natural density and porosity, it is possible to tion of other logs, and (7) method of estimating
predict formation porosity from density logs. It formation porosity. Application 7 is probably
is necessary to correlate carefully density log the most important and most widely used.
data with core analysis data before the direct
correlation of density log response with porosity Maximum use of the density log nas not been
can be made. fully realized. Although there are some severe
limitations in its use, there are many cases where
References and illust!13,tion~~t,~~?f p_~_~~_.___ -,- ______________________________________________---'
2 GAMMA RAY-DENSITY LOGGING 1253-G

the density log is an effective tool, and serves recall that atoms with nuclei of the same Z but
as a valuable aid in f'ormation evaluation. different A are forms of the same element and are
called isotopes.
INTRODUCTION
Beta rays (~) are believed to be physically
Gamma ray-density logging has progressed far equivalent to electrons if the beta radiation
since its original experimental stage. Numerous has a negative charge. If the beta rays have a
major oil companies and several service companies positive charge, they are equivalent to positive-
have made significant contributions to its ad- charged electrons and are called positrons. When
vancement. Although the tool was originally con- talking about positrons, the term negatron is
ceived as an al~iliary exploration device, con- usually used instead of electron; negatrons and
tinued research and development has created new electrons are exactly the same. Beta radiations,
and improved equipment and techniques. This positrons, and negatrons all have the same rela-

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paper is an analysis of the theories, modern tive charge, either plus or minus one, and they
techniques and interpretation procedures applic- all have the same relative mass of one. (As
able to formation evaluation. shown in Table 1, a proton (p+) has a relative
charge of plus one, and a relative mass of ap-
Often, the reservoir geologist, petroleum proximately 1,836; a neutron (n) has a relative
engineer, and log analyst are not familiar with charge of zero, and a relative mass of approxi-
the basic theory and physical principles that mately 1,840.) Unless otherwise stated, the
underlie a particular logging tool. This results charge of beta radiation is always assumed to be
in the interpreter being unable, or limited in negative and equivalent to an electron. Hence,
his ability, to evaluate logs. An attempt is when a nucleus decays by beta emission, Z will
made herein to "bridge the gap" between theory increase by one unit and A will remain constant.
and application. It should be pointed out that the exact value of
mass will decrease very slightly; this is a
The purpose of this paper is to inform the necessary conclusion in order to explain the re-
user of the basis of gamma ray-density logging; lease of energy.
to describe the equipment used; present the ac-
cepted principles of interpretation; illustrate Alpha particles (0<) are equivalent to
the uses and applications; and cite the known accelerated helium atoms that have been stripped
advantages and limitations. of their electrons. Thus, the alpha particle
will have a nuclear charge of plus two and an
THEORY AND PHYSICAL PRINCIPLES atomic mass of four. Therefore, if a nucleus
decays by alpha emiSSion, Z will decrease by two
Basic Nuclear Concepts and A will decrease by four. Note that in either
beta or alpha decay, isotopes of the mother ele-
In order to fully understand the nuclear ment are not formed; the residual that is formed
processes that occur when a gamma ray-density log is always a different element. However, the
is run, it will be necessary to briefly review series disintegration of an element tr~ough both
some basic radiochemical theory and physical con- alpha and beta decay will often produce isotopes
cepts. The discussion here will not begin with
the most elementary principles; for introductory
I of the original element.

material on the subject of atomic PhYSicS the In atomic physics, it is conventional to


reader may refer to the works of Bttter,l 3 express energy in terms of elec~ron-volts. An
Fermi,25 Friedlander and Kennedy,2b Lapp and electron-volt is equal to 1.6 x 10- 12 ergs; it is
Andrews,3 1 and Semat.3 6 From the beginning, the further defined as the kinetic energy required by
inquirer must realize that gamma ray-density an electron to move through a potential difference
logging is different from conventional gamma ray- of one volt. Since the electron-volt is a rather
neutron logging. The gamma ray-density log is small unit, thousands of elect:ron-volts (Kev) ,
often referred to as the gamma-gamma log, which I and millions of electron-volts (Mev) have been
means that the source emits gamma rays and the adopted as standard units. Occasionally, units
detector counts gamma rays. This paper will of electron-volts (ev), and billions of electron-
present only that material which is related and volts (Bev) are used. Alpha particles will nor-
necessary to the understanding of gamma ray- mally exhibit energies in the range of several
density logging. Mev; beta particles have no normal energy range --
some are as low as one ev, whereas some are as
The definitions of nuclear terms presented high as ten Mev. Gamma rays have energies in the
by Faul,24 will be sufficient for this paper; the order of one Mev for naturally occurring decay.
atomic number Z, or nuclear charge as it is some- It is interesting to note that cosmic rays have
times called, is the integral number of protons energies in the order of several Bev, and are
in the nucleus of an atom. The mass number A, capable of penetrating ten to fifteen feet of
or atomic mass, is the total number of nucleons lead.
in the nucleus of an atom; a nucleon can be
either a proton or neutron. The reader will Nuclear reactions can be expressed in a
1253-G ALBIN J. ZAK AND JOE ED SMITH 3

manner similar to chemical reactions. The state- nuclear disintegration was fully accepted by the
ment must involve at least four terms: target, scientific world, its mathematical development is
(projectile, product) residual. The projectile very simple: It is observed that the1loss in
and product particles are commonly abbreviated. radioactive nuclei (-dN) that occurs during an
A classic example would be that of a lithium 7 interval (Jt) is directly proportional to the
atom* being bombarded with an energetic proton. total number of nuclei (N) that is present after
Since the proton has a positive charge, it will the time (d t ). Thus,
experience an electrostatic repulsion as it ap-
proaches the nucleus of the lithium atom; but if . . . . (1)
the proton is accelerated to a sufficiently high
energy level, it will penetrate inside the nuclear
radius where the strong, short-range attractive where ~ is a proportionality constant. By
forces are at work. At this point, the proton separation of variables,

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will disappear into the nucleus of the Li7 atom,
forming an excited nucleus. This nucleus will
then split into the product particle (0<) and the
residual nucleus (He~). Fau124 estimates that
jNdN =-1j\\\
Integrating Eq. 2 leads to:
dt:
.... (2)

the time necessary for this process is in the


order of 10-12 seconds. This reaction is written:
Li 7 + p+_o<-tHe'f or more commonly, L', 7(p +,0<) He'+.
If the projectile and product particles are the
same, the process is known as scattering. The
scattered particle (product) will always have Using algebra, Eg. 3 will simplify to: N = ce-~t
less energy than the projectile particle because where C = some constant of integration. The
some of the energy will be transferred to the constant C can be evaluated by setting t = 0,
residual nucleus as kinetic recoil energy. This such that N = C; therefore, C must be equal to
scattering process should be carefully noted No, where No is the number of radioactive nuclei
it is the cardinal principle upon which the present at t = O. Hence, the classic exponential
gamma ray-density log is based. The process will law of nuclear disintegration is normally written:
be discussed in detail after introductory mater-
ial on gamma radiation has been presented.
N . . . . (4)

One other definition must be stated before


going into the discussion of the nuclear disin- where'\. is a constant universally called the
tegration processes. It is possible to express disintegration constant. The time required for No
the probability of a projectile particle inter- to decrease to Noh is called the half-life (T)
acting with a target nucleus in terms of nuclear or decay period. By Eq.,

_~T . . . . (5)
cross sections. The cross section is said to be
large when the probability of a reaction is very I/,'\ ... I
higb, and conversely, the cross section is said T\NoJ = l'-loe
to be low when the probability of a reaction is
remote. Nuclear cross sections vary over a wide Using algebra, Eg. 5 clears to:
range; they are dependent on the type of particles
energy of particles, type of target, and type of
process. The common unit of nuclear cross section
\T = LOSe Z. .... (6)

is the barn (10- 24 cm 2 ). This concept of cross Eg. 6 then becomes:


sections will be used later to help explain
gamma ray attenuation. . (6a)

It took many years to define the nuclear where T is the half-life of the substance. Since
disintegration processes in terms of mathematical N and No are very difficult numbers to measure,
expressions. The first significant conclusion the exponential law is often expressed in terms
was that the amount of radioactivity of a pure of:
substance decreases with time according to some
parabolic or hyperbolic function. It was later
observed that radioactive decay is statistical in
nature, that it could not be predicted when any where R is the disintegration rate or nuclear
given atom would disintegrate, and that some sta- activity of the material. (Halliday28 presents
tistical hypothesis would have to be developed to adequate explanation of this paramet~r.) It
explain the process. 28 ,3 1 Although it was a long will suffice here to say that R- dN or something
time before the contemporary, exponential law of -(ff
proportional to it. The decay period (1l) is
* Superscripts above names of elements are Atomic normally found by plotting Log R vs t. From Eq. 7
Masses and not reference numbers in the it can be seen that ~ is the slope of the straight
Bibliography. line through these data, thereby allowing the
4 GAMMA RAY-DENSITY LOGGING 1253-G

calculation ofT with Eq. 6a. This technique is


important with respect to the calibration of the
~~
IDO \Cxt,()
density log. Before an instrument is put into
service, it is necessary first to calibrate the I f the period (T) is known, then,\(x), '\.(y) and
instrument response with the radioactive source, \(x+y) can be calculated. Halliday28 has given
usually Cobalt (A = 60). Then as the tool is put adequate treatments to this matter. He states
into actual use, it is necessary to know the that the type of detector is unimportant; it can
strength of the radioactive source at all times be counting alpha particles, positrons, or both -
in order to utilize the calibration curves. Since a plot of Log R vs t will always give the same
the strength of the C060 is constantly decreasing period rO.693 J. The period ~ is that
by radioactive decay, it is necessary to apply h(x+y) J \(y)
the exponential law to predict the source strength period which would occur if the alpha decay did
at any time. not occur simultaneously with the positron decay.

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An enlightening subject in the study of The reader is referred to the literature for
nuclear radiation is the radioactivity decay detailed discussions of the exact nature of alpha
series. There are numerous series; only the and beta emission. No attempt will be made to
heavy end elements of the nuclear chart have been present such information in this paper since ~
thoroughly explored in this respect. Most of the and (3 have very little direct bearing on gamma
other radioactive elements are too short-lived to ray-density logging. Gamma emission is the im-
be followed in a decay series. There are four portant process here and will be treated in
recognized heavy disintegration series~ Thorium, such a manner as to give sufficient explanation
Neptunium, Uranium-Radium, and Actinium. The of the behavior of the gamma ray-density log.
heavy end elements are best known because of their
rather long-lived radioactive members. The Gamma rays are highly penetrating radiations
Thorium series is illustrated on Fig. 1. Reac- that originate in radioactive materials; they are
tions that move from left to right occur through unaffected by electric or magnetic fields. Gamma
alpha emission, whereas reactions that move up or radiation is actually a part of the classic
down occur through some type of beta decay. Note electromagnetic spectrum -- their wavelength is
that isotopes are formed only through the com- in the order of 0.1 Angstrom Uni.t or less, an ex-
bined efforts of both alpha and beta radiation. tremely high frequency. Cosmic rays have some-
An excellent example of this would be Uranium- what shorter wavelengths and X-rays have slightly
240 decaying to Uranium-236 in three steps~ longer wavelengths. The differences between

(a) U
"2.40
--. Np
7...'l-C>

+ f- gamma rays and cosmic rays are not fully under-


stood at this time. The only known difference

N;4\) ~ 9u '?\ r-
is that cosmic rays have a higher frequency and
2 shorter wavelength which consequently explains
(b)
their higher energy level and greater penetrat-
ing power. The only difference between X-rays
(c) PUL'f() ~ U U\, ~ 0<... and gamma rays is that X-rays originate within
Before discussing gamma emission, it can be the radioactive atom, outside the nucleus; where-
pointed out here that nuclei do not change in A as gamma rays always originate from within the
or Z due to gamma radiation; however, there is a nucleus. Gamma rays and X-rays are otherwise
loss of nuclear energy. identical. Although seldom the case, it is pos-
sible to have gamma rays existing at energy
An interesting aspect of the nuclear dis- levels less than the normal X-rays energy level.
integration process is that a great many nuclei The nomenclature of gamma rays and X-rays is
decay by two or more types of radiation. An ex- purely a matter of their atomic origin. These
ample from Fig. 1 will illustrate this phenome- definitions are greatly simplified, but are ade-
non: Ac 224 will decay by alpha emission to Fr 220 quate for the purpose of this paper. Semat's
in X per cent of the disintegrations and by discussion of gamma rays and X-rays offers an
positron decay to Ra22)~ in Y per cent of the academic treatment of the subject matter. Since
disintegrations. X and Yare experimentally there is no difference in the type of inter-
determined; X + y: 100 per cent. By differen- actions that gamma rays and X-rays (of the same
tiation of Eq. 7, rt.(l£) (~~t =- ,and R-' energy level) have with matter, this paper will
use the generic term "photon" to mean either or
both.
\ tv) :: - (~:)y R- \ . Also, ' \6t- ... '<) = \l)() ~ \l\')
Interaction of Photons with Matter
. • . . (8)
According to Fan0 22 , there are four kinds
of interaction between photons and atomic par-
where ~(x), ,\(y) 'and Y\h+ y ) are the diSintegration ticles: (1) basic interaction with atomic
constants for 0<. decay, f3 decay, and the combined electrons, (2) basic interaction with particles
decay. From the given data: within the nucleus, (3) interaction with electric
1253-G ALBIN J. ZAK AND JOE ED SMITH 5
field surrounding charged particles, and (4) in- I 1.022 Mev before pair-production can occur since
teraction with meson field surrounding the nu- I this amount of energy is needed to supply the rest
cleus. It is further observed that each of these I energy. For large values of E., Ee- is
four kinds of interaction may produce three dif- I
ferent effects: photon absorption, elastic i essentially equal to E_
e +· For the values of
scattering of photon, and inelastic scattering of !
photon. Referring to the basic definition of I, Eyemmitted by Co "0 Er -Z>'Y\c2.may be shared
,
scattering, the process is called elastic if the
projectile acts upon the target as a whole, in any proportions between E e 1- and E e -. Ac-
whereas the process is termed inelastic if the cording to Halliday, the positron usually receives
projectile acts upon and produces some effect on more energy since it is accelerated by the nucleus
a constituent part of the target. There are whereas the negatron is restrained by the nucleus.
twelve possible interaction processes between The positron will eventually combine with an

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photons and matter. Some of these have never atomic electron, probably a free electron, and
been observed and exist only as physical hypothe- form two quanta of annihilation energy; i.e., the
ses. It is believed that only four of these positron-electron combination disappears and two
twelve processes have any influence on the gamma photons appear, each with the rest-mass of an
ray-density log: photoelectric absorption, pair- electron. The negatron is absorbed in a manner
production, Compton scattering, and Rayleigh described for beta particles by Faul. The pair-
scattering. In all of these processes, the inci- production effect predominates for energies
dent photon is either absorbed or scattered away greater than 2 Mev and large values of A.
by the atom or some part thereof.
The Compton effect for a single interaction
In the photoelectric process, a photon ex- is quite simple and is mathematically well defined
periences a collision with an atomic electron and A photon of moderate energy (0.5 Mev to 2.0 Mev)
immediately disappears. The electron which ab- collides with a presumably free electron. The
sorbs the photon is ejected from its orbit and incident photon is briefly absorbed, probably less
retains its own energy plus the photon energy than 10- 12 second, and is ejected into a trajec-
minus the binding energy of the electron. This tory that is usually slightly different from the
process does not occur for free electrons, and it incident path. Since the projectile and product
is reasoned that the effect is more prevalent for are identical, the process is called scattering,
the tightly bound electrons in the K-shell. Nu-
clear physicists normally treat the photoelectric commonly written, e-(') r ) e -. This scattering
effect as an interaction with the entire atom and process is normally considered to be inelastic
not with the ejected electron. Although this since a photon acts upon a constituent electron of
treatment is not exactly correct, it simplified an atom. However, some physicists like to think
the theoretical analysis of the process. Because of the target electron not only as free but also
of the higher energy level of the photon, the as being isolated. In this respect, the process
ejected electron generally flies off in the di- is elastic. The scattered photon always has less
rection of the incident photon. The process is energy than the incident photon. It can be seen
most likely to occur for gamma ray energies less that after a sufficient number of collisions, the
than 0.5 Mev and for material with large values photon is susceptible to photoelectric absorption.
of Z. The recoil electron flies off in the general
direction of the scattered photon.
In the pair-production process, an energetic
photon is absorbed in or around the nucleus of an When a photon is scattered in such a manner
atom, and an electron-positron pair is ejected that it loses only a small fraction of its inci-
from the proximity of the nucleus. If it is dent energy, the recoil energy imparted to the
assumed that there is total conservation of electron is very small. This is especially true
energy in the process, when the incident gamma ray energy is initially
low. When this situation exists, the recoil elec-
tron is sometimes absorbed by an atom or even a
whole molecule. This is a noticeable variation
from the Compton process and is known as Rayleigh
2
where Er = energy of incident photon, mc = rest scattering. Fano points out that, insofar as the
observer can tell, the scattering action of dif-
energy of each member of the pair, E e+ = energy ferent atomic electrons seems to combine coherent-
of the ejected positron and Ee,- ==- energy of the ly. Since the effects of the process are limited
ej~cted negatron. DuMond and Cohen 20 state that to low photon energies (<.0.3 Mev) and dense
mc = 0.511 Mev*. Thus, Ey must be greater than materials, it will not be discussed in detail and
will not be considered as a measurable factor in
the gamma-gamma log. There are data in the liter-
* mc 2 is defined as the electron energy equivalent ature to support this assumption. 22 ,29,37
2
where m = electron rest-mass, and c = mass -
energy equivalence; refer to DuMond and Cohen for The three prominent processes that have an
details. influence on the gamma-gamma log are illustrated
6 GAMMA RAY-DENSITY LOGGING 1253-G

0:-;~g~~ -;: :h~- p:otoelec::~c effect, the photons (-dP) that is absorbed or scattered away
photon expells an atomic electron from the K- in an additional absorber thickness (dx) is pro-
shell. In the pair-production process, the portional to P and to (dx). Therefore,
I gamma quantum vanishes, and an electron-positron
pair is produced. The photon is scattered by an - dP: k Pdx . . (n)
electron in the Compton process; the photon loses
some of its energy, and the electron is recoiled
from the atomic radius. Also, note that there is
a case where the photon passes through the atom
without having any kind of interaction. In fact,
or
I <I; --\,. ~ clx
The integration yields:
. . . . • . (12)

there is always the finite possibility that a


photon will travel through an infinite thickness
of matter without experiencing a collision with
p:: ?o e- k ): . • • . . .( 13)

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any atomic particle. Through the use of !!good For narrow, collimated, monoenergetic gamma ray
geometry!!, it is possible to construct a model beams, k is an expression of the probability of a
that will allow academic treatment of the gamma process per unit thickness of absorber. The con-
ray attenuation problem. The term !!good geome- cept of nuclear cross sections is immediately
try!! was coined by the early experimenters in suggested since the chance that a particular re-
this field, and is used to describe the ideal action will occur is usually expressed by its
conditions that are necessary to measure the com- cross section. This may be thought of as an
bined effects of Compton scattering, pair-produc- imaginary disk associated with each nucleus in
tion, and photoelectric effect of photons pene- the absorber material. Halliday suggests that
trating various absorber materials. Fig. 3, each target nucleus be imagined as having been
which will be used to develop the gamma ray at- replaced by its equivalent disk area, with the
tenuation concept, does not illustrate the !!good plane of the disk perpendicular to the incoming
geometry!! concept. However, Halliday28 and beam of photons. 28 Hence, it is seen that the
Cowan* present experiments utilizing good geome- cross section k is some function of the density
try. (~) of the absorber material:

In Fig. 3, Po is the number of photons that . . . . . . • (14)


enter the absorber and P is the number of photons
that pass through the absorber without having an At this point, the theory will be greatly simpli-
interaction. Af is the area of the absorber fied by stating that:
face, and x is the absorber thickness, such that
the product of x and Af is the bulk volume of the • . • . . . . . (15)
absorber. Each dot within the absorber medium
indicates a photoelectric, pair-production or where~ is the combined mass absorption coeffi-
Compton process. In the first two processes, the cient, or attenuation coefficient, of the three
photon is absorbed; in the latter process, the predominant interaction effects. It is immedi-
photon is not absorbed but disappears as far as ately noted tha~ is a function of both incident
the detector is concerned. The reader should be photon energy and atomic mass of the absorber
advised that Fig. 3 is a simplified schematic material. The equation of gamma ray attentuation
diagram of the experimental model, and that the is now writter":

P'"
!!good geometry!! previously mentioned is necessary -:-pel(
in actually making these experiments. It is fur-
D
1-0 e . . . (16)
ther necessary that the incident photons be mono-
energetic and collimated into narrow beams. P and P~ are normally expressed in units of Mev;
/ in cm /gmj e in gm/cm 3 , and x in cm. Numerous
The value of P will depend on the values of narrow-beam attenuation experiments have verified
Po and x. If an additional absorber thickness Eq. 16, and have measured values of~ .10,18,21,
(dx) is added, P will decrease by (-dP). If stil 29,37
another absorber thickness (dx) is added, (P-dP)
will decrease by (-dP). Thus, there is a definitE Separate theories have been worked out for
mathematical pattern observed: each of the three absorption processes. Remember
tha~ is the attenuation constant for the
P C( Pc.lX .(lOa combined effects of photoelectric absorption,
pair-production, Compton scattering, and such that:
-~~ C{ ~ .I
d)(. . (lOb)

- c\~' ex: (?- ~\» /


dx' .(lOc)
where/.. ,"p6 vVc.- are the partial attenuation co-
It is hence reasoned, that if P photons pass efficien£s due to photoelectric effect, pair-
through an absorber thickness x, the number of production, and Compton scattering~ respectively.
* See Physics Review, Vol. 74, (1948), page Baker3 has pointed out that the density of the
1841. absorber material will increase when A increases
l253-G ALBIN J. ZAK AND JOE ED SMITH 7
even though the number of atoms per uni t vOl~eTw~e-: (\ and-A' a~: the quantum wavelengths of the
remains unchanged. When density increases in I photon radiation before and after collision, ~
this manner,~ must also increase; but the in- is Planck's Constant, m the electron rest-mass,
crease in~is not directly proportional to the c the velocity of light, and~the photon scatter-
mass number. In the Compton effect~c is di- ing angle as indicated on Fig. 4. It should be
rectly proportioned to A; however, in the photo- noted that the wavelength change is not a functio
electric and pair-production processes~~ and of the wavelength. By using Eq. 21 and:
~ are proportional to some power function of \ C
the value of A. Halliday develops the defini- 1\= ~ . . . . . . (22)
tions of the three values o~ in the following II

manner:
I . . . (23)
I

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· (100)
where v is the frequency of the photon radiation,
/h =: n" (s) · (18b) and E~is the energy of the photon, the fractional
energy loss in any individual Compton collison can
/ c n,JS) =0 · (18c) be computed from:

where S is the equivalent disk area of each tar- I I Ex:


get nucleus; l\a., Ylb , and >lc.. are the number of ~ y::::' I+ E("
meZ:
(r
1- vcs-G- )
. . . . (24)
atoms, nuclei, and electrons per unit volume of
the absorber. This equation proves that the energy degradation

~
of scattered photons is quite large for energetic
Note that: hQ.'::: r}b .:: NA · (19) photons and large scattering angles. Fig. 5 is a
V\/ graph showing the results of calculations made
and nc.. =c Z-NA ~ .(20) with Eq. 24 for gamma ray energies up to 10 Mev
vV and scattering angles from 50 to 1200 . Naturally,
where NA is the number of molecules in a mole of
if -e- -= 0) E/ = E Klien and
Y
the absorber substance, ~ is the mass density,
and W the atomic weight. This definition of at- Nishima used a quantum mechanics approach to cal-
tenuation coefficient is essentially the same as culate the nuclear cross section per electron for
that previously presented. the Compton process. 33 Their basic assumption is:
the gamma ray energy is so great that all elec-
In gamma ray-density logging, the radio- trons can be considered free. The Klien-Nishima
active source emits photons with energies in the formula has been well proven by numerous experi-
order of 1.0 to 1.5 Mev. Most of the atoms that ments in this field.
constitute reservoir rocks and interstitial
fluids have nuclei of low A values; hydrogen, 'I'he theory of Compton scattering is of pri-
carbon, oxygen, silicon, calcium, magnesium, mary importance in the density log, and will be
sodium, chlorine, sulfur, etc. Hence, the most used throughout the remaining discussion. By ju-
predominent process active during a gamma-gamma dicious choice of gamma ray source and carefully
log-run is Compton scattering. Since the varia- engineered source-detector arrangement, the
tion in~is directly proportional to variations response of the gamma ray-density logging tool can
in A, P is very nearly an exponential function of be made to depend primarily on the density of the
~. (Refer to Eq. 16). The reader should note formation rock and interstitial fluids.
that P is an indication of the average density
along the traversed path, not the density at the INSTRUMENTATION OF LOGGING DEVICES
point from which the photons are scattered. If
it were not for the small amount of photoelectric Gamma Ray Detection
absorption and pair-production, a plot of Loge P
vs f would be a straight line, with (~x) as the Radiation detectors that have been used to
slope of the line. date in the gamma ray-density log are of three
general types: (1) ionization chambers; (2)
The first attempt to describe the Compton Geiger-Muller tubes; and (3) scintillation count-
effect was done with the classic diagram shown ers. Each type has its own particular advantages
on Fig. 4*. By using the relativistic laws for and disadvantages. The following discussion will
conservation of momentum and total energy, an present a very brief statement as to the princi-
equation has been derived that predicts the ples of operation of each, will highlight the
change in quantum wavelength of the photon per operational characteristics of each, and show how
Compton collision: 18 ,2l,2b they are adapted to the problem of gamma-gamma

A'_A=~(I-Cos~)
logging.
..... (2l)
The theory and operation of ionization cham-
*See A. H. Compton, Bulletin of National Research bers is adequately covered in the literature cited.
Council, Vol. ~, No. 20 (1922). 24,48,54,64 Basically, this instrument consists
1-------
8 GAMMA RAY-DENSITY LOGGING
~--~-----"-='------'1
1253-G

of a chamber containing an inert gas. Two I thin wire replaces the small tube or cylinder used
electrodes, usually in the form of concentric in the ionization chamber as an anode. Again, the
cylinders, are placed within the sealed chamber. counter chamber is filled with an inert gas but at
As photons penetrate the wall of the chamber, the much less pressure (in the order of one atmosphere
gas molecules will ionize into charged atoms. or less). There is also an electrical field set-
If an electric field is set up in the vessel, the! up across the electrodes of the Geiger counter,
ions will move toward the electrodes and cause an but the field strength is much greater than that
electric current to flow that is proportional to of the ionization chamber. As in the ionization
the degree of ionization produced by the radia- chamber, the photons that enter the chamber will
tion entering the chamber. The negative ions ionize gas molecules, but since the electric field
move toward the positive electrode, and con- is very strong, the ions are greatly accelerated
versely, positive ions toward the negative elec- as they move toward the electrodes. These highly

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trode. A single radiation entering the gas is energized ions will ionize more gas molecules as
capable of creating a large number of ions and they speed through the tube toward the electrode,
producing an electrical impulse; a succession and thereby cause a phenomenon called "ionic
of incoming radiations will produce a succes - avalanche". This avalanche of ions will produce
sion of these electrical impulses. The recorded an electric charge within the tube that is com-
electrical signal can be derived by: (1) count- pletely independent of the energy of the photon
ing the impulses in a given time period; (2) re- that caused it. The pulse height of a Geiger
cording the average current flowing through the counter signal is always the same regardless of
circuit. Should the detector time-constant be the type or energy of the radiation that caused
so small that the ions collect at the electrodes it. The Geiger counter merely counts the number
in less time than the interval between individual of these pulses in a given time, or it can measure
radiations, then the instrument is classified as the average current flowing in the external
a pulse chamber or differential ionization cham- circuit.
ber. In this type of chamber, each ionization
event will produce a pulse that is proportional With respect to gamma ray-density logging,
to the magnitude of the event. the Geiger counter is a desirable detector for
several reasons: (1) a fairly weak photon is
On the other hand, if the ionization chaw- nearly as capable of producing a pulse as a strong
ber has a very long time constant, the succession photon; (2) the magnitude of the output signal is
of impulses will overlap and the current produced of no significance -- only the number of pulses
will be averaged over the time interval. This per time interval are counted; (3) efficiency and
type of detector is termed an integrating ioniza- sensitivity are unaffected by elevated tempera-
tion chamber. It requires an expensive, high- tures; (4) zero reference is well-defined; and (5)
gain, direct current amplifier; its sensitivity it can be used in a small diameter logging tool
is sufficient only when the gas is under high quite readily. The Geiger-Muller tube is undesir-
pressure. As the chamber wall is thickened to able for gamma-gamma logging because short coun-
contain the higher pressures, the counting ef- ters will not give a sufficiently reliable signal
ficiency is drastically reduced. The ionization at practical logging speeds and it has a very poor
chamber is not very suitable for gamma ray-den- measuring efficiency -- less than one per cent of
sity logging for several reasons: (a) the meas- the photons that enter the tube cause the ionic
uring efficiency of integrating chambers is avalanche.
generally very poor; (b) short, small diameter
chambers will not give a sufficiently reliable The scintillation counter is an old instru-
signal at practical logging speeds; (c) an exact ment; nearly fifty years ago, physicists used
zero reference is almost impossible to determine; sphalerite crystals to observe the behavior of
and (d) the small, direct-current, output signal alpha particles. Of course, modern scintillation
requires an intricate and expensive system of counters are far removed from their ancestral
amplifiers, filters, rectifiers, etc. before the models. DiGiovanni, Graveson and Yoli,49
signal can be recorded. Hurley,53 Russell and Scherlatskay,67 Toelke,69
Youmans,71 and Lapp and Andrews31 present abundant
The Geiger-Muller tube was developed by Hans material on the theory, operation and applications
Geiger and Walther Muller in 1928. Since its of modern scintillation counters.
inception, excellent reviews of theory, technique,
and applications of modern Geiger-Muller tubes In Geiger-Muller tubes and ionization cham-
(commonly referred to as Geiger counters) have bers, an electric charge is freed when a radiation
been published by Brown,43 Curtiss,47 Peirson,62 particle creates an ion-pair by acting on the iner
Russell,66 and Slack.68 Lapp and Andrews31 also gas molecules. But in scintillation counters, the
present excellent introductory material in their radiation sets the electrons within a crystal in
nuclear physics textbook. motion (there is no electric field involved).
These excited electrons "bounce-around" within the
A Geiger counter is similar in many respects crystal lattice and cause minute flashes of light
to the ionization chamber. The electrode ar- to be emitted. These tiny light flashes are trans
rangement is the same except for the anode; a mitted through a lense to a photo-multiplier tube.
1253-G ALBIN J. ZAK AND JOE ED SMITH 9

The photo-multiplier has a series of thin,~ight- 'I Large volumes of literature have been writte
sensitive plates mounted in a vacuum. The plates, I that explain how these three basic gamma ray de-
or stages, of the photo-multiplier tube are nega- i tectors are adapted to practical well logging
tively charged. As a flash of light strikes the ' tools. (Refs. 38, 39, 48, 50, 52, 56, 66, and
first stage, electrons are liberated from the 68.) There is an even larger volume of informa-
metal plate. These electrons are expelled at high tion that deals with the calibration, interpreta-
velocities because of the negative charge of the tion, and application of these gamma ray logging
plate. The parabolic shape of the plate and high tools. (Refs. 40, 42, 44, 45, 51, 57, 58, 59,
kinetic energy of the electrons cause the elec- 60, 61, 63, 65, and 70.) The remaining portion
trons to strike the plate of the second stage; but of this discussion will review the specific prob-
they are immediately repelled and, in so doing, lems of adapting gamma ray detectors to gamma-
cause more electrons to be expelled from the gamma logging, the calibration of these instru-
second stage. This routine is repeated for each ments, and the interpretation of the curves re-

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stage in the tube. The electrons are finally corded by these tools.
collected at the anode near the end of the tube.
This process tremendously multiplies the number Basic Instrument Design
of electrons received at the anode as compared i
with those released from the first stage where the At this time, there are two different gamma
light flash originally fell. The authors are ray-density logging instruments available to the
familiar with a counter that has ten stages and industry: Type I, which uses a radial source and
is capable of multiplying the effect of one scin- a Geiger-Muller detector, and Type II, which uses
tillation one-half million times. a collimated source and scintillation counter.
The Type I tool is available through the Lane-
There are some very definite advantages of Wells Co., Houston, Tex.; Type II is available
scintillation counters over Geiger-Muller counters through the McCullough Tool Co., Los Angeles,
when applied to gamma ray detection: (1) The Calif. If the reader needs more details on a
counting efficiency is much higher than that of specific tool, he should write directly to the
Geiger counters. Sodium iodide crystals currently service company. It is not the purpose of this
in use have better than 90 per cent efficiency. paper to give all the details of any particular
(2) The height of the output signal is proportion- tool. They will be compared only as to type and
al to the energy of the detected photon. (3) as to the response that they give.
Sondes can be constructed that lend themselves to
logging in much thinner beds than tools utilizing Fig. 6 is a schematic drawing of the Type I
G-M counters. (4) In some logging tools, the tool. In the case of a formation logging instru-
zero reference is better defined than in G-M ment, it would be impossible to place a gamma ray
counters. (5) Scintillation counters are rela- source such that the formation would be in a
tively much less affected by cosmic ray-background direct path between the source and detector. How-
radiation. (6) Resolving time is much less than ever, this difficulty can be thwarted due to the
that of the Geiger-Muller tube. fact that most matter has the property of scatter-
ing gamma rays. With respect to the design of a
On the other hand, there are some distinct practical gamma-gamma logging tool, a strong,
disadvantages: (1) Not only is the behavior of gamma ray source can be placed below the detector
the crystal affected by temperature variations, and shielded from the intervening parts of the
but the crystal is damaged beyond restoration at instrument such that leakage radiation up the too~
temperatures above 1400 F. Hence, logging tools or up the borehole fluid, can be kept at a mini-
with scintillation counters must be insulated and mum. Photons from the source will penetrate the
refrigerated for efficient and accurate operation formation, scatter throughout the formation, and
in deep boreholes. (2) Large sodium iodide crys- be ultimately absorbed within the formation, ex-
tals are the most desirable; but the time neces- cept for a small percentage of this scattered
sary to grow such crystals is excessively long. radiation which will find its way back to the de-
Consequently, scintillation crystals are expen- tector. Insofar as the detector is concerned, the
sive. (3) The pulses generated in the photo-mul- scattered gamma rays that reach the detector
tiplier circuitry are very small compared to those appear to come from that portion of the formation
generated in the Geiger-Muller counter, thereby where the scattering occurs. ThiS, in effect,
requiring an intricate and expensive amplifier develops a gamma ray source within the formation.
component. (4) Photo-multiplier tubes create ex- By applying the information gained from the de-
traneous "noise signals" that are observed in the velopment of Eq. 16, it is seen that the Geiger
output signals. A discrimination circuit must be counter will respond to the changes in natural
employed to eliminate pulses ariSing from this formation denSity that occur between the spurious
source. (5) The scintillation crystal and photo- gamma ray source and the detector tube. As the
multiplier tube must be housed in total darkness. logging tool is moved up the hole, the Geiger-
(6) Even with the most expensive models, it is im- Muller counter responds as if a gamma ray source
pOSSible, at the present time, to manufacture were moving with the logging instrument but back
photo-multiplier tubes that operate at the same in the formation at an indeterminate, fixed dis-
noise level and same sensitivity. This compli- tance from the counter. Fig. 6 is designed to
cates the calibration roblem.
10 GAMMA RAY_::Q~~__L_OG_G_IN_G__~~~~~~~~~~~~~--=12=.,5,,-,,3'---=,G
I
illustrate most of these concepts. The source i large vertical angle of emission but also a large
material in the Type I tool is radioactive cobalt;! polar angle. There has been no previous attempt
the photons emitted from C060 are polyenergetic, II to define the resulting scattering region with
but the 1.1 Mev and 1.3 Mev gamma rays are pre- i dimensions. (2) The detector does not discrimi-
dominant. Lead is used to shield the source from I nate against the photons that it receives; it
the detector, and it appears that the efficiency I treats them all the same. A photon of 0.5 Mev
of this shielding is quite sufficient. However, energy will produce the same result as a photon of
some of the gamma rays will escape the source I 1.5 Mev. As to the depth of the effective scat-
chamber and enter the mud column. The probabilit~ tering region, for the 20 in. source-detector
that some of these photons will find their way I spacing and C060 source, it is highly probable
back to the detector through the mud is higher that gamma rays penetrating more than six in. of
than leakage across the shielding. Naturally, thel formation will experience scattering at such large
magnitude of the error imposed on the density log i values of -e- that the scattered radiation will suc-

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due to this leakage is related to the mud density,' cumb to photoelectric absorption before it reaches
hole diameter, and source-detector spacing. The the Geiger counter. This prediction is based on
authors have found that the error is significant calculations made with Eq. 24 for the 1.1 and 1.3
for mud densities less than 14 lb/gal; the error Mev photons. The Klein-Nishina formula will pre-
for muds heavier than 14 lb/gal is detectable but dict a slightly deeper scattering region.
diminishes rapidly with increasing density. The
error due to this leakage increases as borehole The Type II instrument operates with a some-
diameter increases. Since the source-detector what different physical arrangement of source and
spacing is always the same for any given instru- detector, and the response of the tool is conse-
ment, this factor in the leakage error is a con- quently different from that of the Type I tool.
stant value. Inasmuch as this inherent leakage Fig. 7 is a schematic drawing of such a logging
affects the response of the density log, the re- tool. This tool also has a bow-spring to hold the
corded amplitude on the density log curve there- instrument in close contact with the formation
fore requires a correction for both borehole wall, and a shoulder to wipe the mud cake from
diameter and density of the borehole fluid be- the borehole wall. The gamma ray source in this
fore an accurate interpretation of the gamma- tool is collimated into a narrow beam; both the
gamma log in terms of formation density can be vertical angle and polar angle are small. This
made. geometry also applies to the detector opening.
The detector and source are shielded in a manner
Some of the other features of this tool are: similar to that of the Type I sonde. As can be
strong bow-spring that holds the instrument seen from Fig. 7, the scattered photons that are
against the side of the borehole wall; shoulder accepted by the scintillation counter are those
that wipes the mud cake from the borehole wall -- that are scattered back in "one-shot" from the
the reproducibility of the density log indicates scattering region. However, some extraneous
that this is highly effective except for sands of photons will find their way into the detector
extremely high permeability; and natural gamma ray opening, but in order to do so they must undergo
activity of the formation is eliminated from the I multiple scattering, and thereby will have lost
detector by shielding the counter completely with I more energy than those received from the "one-
lead. Two small "windows", consisting of a much 'I'
shot" scattering region. Since the scintillometer
lighter material than lead, permit the moderate, has a pulse height discriminator in its circuitry,
scattered gamma rays to enter the G-M counter, but it is possible to "pick-out" particular photons
absorb the soft, natural gamma rays. and record only that effect which is due to the
Compton process that occurs in the small, well-
As a compromise between detector efficiency defined scattering region. By using the physical
and the critical relationship of source-detector arrangement depicted on Fig. 8, it is possible to
spacing to formation boundary definition, it has calculate the average scattering angle (t8, aver-
been found that the most desirable spacing from age depth of scattering (hs ), average length of
the midpoint of the detector to the source seems photon path (-y.+;t,'), and energy of the scattered
to be about 18 to 20 in. for an optimum detector photon (EY)' The only data needed for this cal-
length of ten in. When time-constant and logging culation is energy of incident photon (E (") ,
speed are considered, the reader will see the ad- source-detector spacing (b), and collimation angle
vantage of these suggested dimensions. (I). Of course, this calculation assumes mono-
energetic gamma radiation from the source. Since
Some excellent reviews have been prepared such a borehole source is impossible, it is neces-
on the Type I gamma ray-density logging tool. The sary to choose the most predominant energy level
reader will find of particular interest the works of the source photons, calculate Ey', and discri-
of Anderson,l Campbell and Wilson,5 Newton, minate the pulse height which represents E; .
Skinner, and Silverman,7 and Faul and Tittle. 6
There are several articles that have been
There are two features of this Type I tool published in recent months which describe gamma
that should be noted: (1) The source emits gamma ray-density logging tools utilizing collimated
rays in a radial pattern -- not only is there a sources and scintillometers. Of particular
12 -G ALBIN J. ZAK AND JOE ED c:=SM~IT""H,=--_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _-=l=-,l

interest is the works of Baker,3,11 Caldwell, 4, 16 I


I those of Type I. Baker 3 indicates that there are
Sippel and Hodges,9 and Caldwell and Sippel. 1 7 I no borehole diameter effects for smooth holes
I and little or no effects due to the presence of
The scintillation counter and its associated! borehole fluid. The reason for this is that the
electronic components are very intricate and delil scintillation detector and pulse height discrim-
cate. The behavior of the crystal is extremely i inator accepts and records the gamma ray energy
sensitive to temperature changes above 80 0 F, and I band that corresponds to Compton processes that
the necessity of insulating and refrigerating i occur in the predetermined scattering region.
the counter cannot be over emphasized. It is iI Fig. 8 shows how the various dimensions of the
felt that a large majority of the early sondes I physical arrangement of source and detector can
were insufficiently protected against the temper- be controlled such that Eg. 24 will allow the
atures encountered in wellbores. Photo-multi- I prediction of the scattered photon energy to be
plier tubes are difficult to calibrate with re- accepted and recorded. Although this tool great-

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spect to a common reference due to the dissimi- i ly reduces the number of back scattered photons
larity of tubes even of the same make and model. I that are accepted by the detector, its statis-
Pulse height discrimination is a relatively new I tical accuracy is comparable to the Geiger
technique as applied in gamma-gamma logging, al- I counter tool; this is because the scintillometer
though it is a standard procedure in X-ray I has a measuring efficiency about 100 times great-
analysis. I er than Geiger-Muller tubes. Caldwell and
Sippel1 7 present some interesting conclusions on
To the present time, the Type I sonde has calibration and response of the Type II tool.
been more widely used in the Mid-Continent and I Baker is optimistic enough to anticipate that a
Gulf Coast areas. Consequently, calibration I universal calibration curve will be established
curves and interpretation aids on this tool are in the near future for the Type II instrument.
readily available. The Type I tool has a Until better electronic components for the de-
limited-detail caliper that ,is run simultaneously tector system are available, it is necessary to
with the gamma-gamma curve, thus eliminating the have an individual calibration curve for each
chance of miscorrelation of "wash-outs" on the field tool.
density log.
Fig. 10 is an example of the density log
Calibration of Instrument calibration curves for the Type I sonde. Note
that the curves are for borehole diameters of
The attenuation of gamma rays using good 6, 10, 16, and 26 in.; the IRF is 300.00; and
geometry and monoenergetic, narrow, collimated, the borehole fluid density is 11.0 lb/gal. The
gamma ray beams is predicted by Eq. 16. The calibration curves are available through the
Compton process is well-defined with Eqs. 21 and logging company for values of IRF from 100 to
24, but only for a monoenergetic photon experi- 350, and for the following borehole fluid den-
encing a single scattering in one plane. The sities: air, 8.34, 11.0, 14.0, 16.0, and 18.0
complete process of gaJJllDa ray scattering and ab- lb/gal.
sorption is so complex that it is mathematically
prohibitive to attempt computing the response of Since the amplitude of any density log curve
this instrument in a borehole. Consequently, the is proportional to the response factor of the
preliminary calibrations were made in special instrument with which the log is made, it is al-
test holes of several diameters. Rocks and spe- ways necessary to calculate the instrument re-
cial concrete mixtures of known density were used sponse factor (IRF) for each log-run before any
as the scattering media. When the density log- interpretation can be made: From the log heading,
ging tools were used in the field with boreholes obtain values of source strength (6) and instru-
that had been cored, values of density derived ment factor (F). By the method illustrated on
from core analysis were correlated with density Fig. 9, determine the instrument sensitivity (bS).
measured with the gamma-gamma log. This combina- Find the instrument response factor by:
tion of data has been used to construct the basic
calibration charts necessary for density log • . (25)
interpretation. In the case of the Type I tool,
these charts (See Fig. 10) give density log de- The value of IRF is usually between 250 and 300.
flections as a function of natural rock density If the log deflections of any number of logs are
(e~) for any instrument response factor (IRF) at adjusted to a COJJllDon IRF, the curves can be com-
various values of borehole diameter (D) and pared directly with only small corrections for
borehole fluid density (~~). Campbell and borehole diameters and borehole fluid necessary.
Wilson5 have presented an excellent review of the Before interpreting for values of natural forma-
calibration of this tool, source strength and tion density, the log deflections must be cor-
sensitivity adjustments, and mud weight and hole rected by use of charts similar to Fig. 10. More
size corrections. often than not, an interpolation between curves
and between charts will be necessary. There are
The calibration curve for the Type II several methods of making such interpretations.
density log instrument is much less complex than The authors have worked out an accurate but
12 GAMMA RAY -DENBITY LOGc--=-:cG-=ING'-'-'-_ _ _ _ _ _ _ _ _ _ _ _ _ _ _l_25'--'3'---------,G
com:~~-ca-ted-tr~-p-l-e-l-·n-t-~r-p-o-l-a-t-ion-p-r-o-c-e-d-ur-~.--F-o-r- I localities as a correlation log. When a forma-
methods of statistical correlations, curve fit- I tion is known to be homogenous and non-porous, or
ting and curve interpolation, see Ref. 75, 76, i only slightly porous, the density log makes an
77,78,85,88,89. The entire interpretation isl, excellent log from which to construct cross sec-
programed on an electronic digital computer I tions and follow the general lithology of an
(IBM 650) thus minimizing the manual efforts. area.

A brief note on statistical error, sensitiv- Estimation of Porosity from Formation Density
ity, time-constant, and logging speed is in order
A very comprehensive analysis of these parameters The density log measures the average or
is presented in literature published by Lane- composite density of the formation near the bore-
Wells Co.56 Any geologist or engineer confronted hole walls. Therefore, the fluids filling the
with the analysis of radioactivity logs should pore spaces are averaged into the value of forma-

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have a thorough understanding of these factors. tion density that is determined from the density
Assuming that the reader is familiar with this log. This value of formation density shall be
subject matter, this paper will recognize a few referred to as "natural denSity" (~n)' The defi-
of the important points that apply specifically nition of "natural density" should be differenti-
to gamma ray-density logging: ated from "bulk density". The bulk density (~" )
is the composite density of the formation grains
(A) Make certain that the log quality is and the void pore spaces, whereas natural denSity
sufficient. Experience is the best formula here, accounts for the presence of fluids in the pore
but the "quality index number" makes a good rule spaces. The relationship between porOSity, grain
of thumb for the inexperienced. This number is density, fluid density, and natural denSity is
the ratio of the distance between maximum and
minimum deflections of the logged section to the ~::: eC] -€n. X 100 . . • . (26)
distance between maximum and minimum peaks on the
statistical recording. This index number should
~~ - e-f
be greater than five for safe interpretation. where e~ is the density of the individual sand
Experience in local areas may indicate that a grains, and efis the weighted average density of
much higher quality index should be expected for the fluids filling the pore spaces.
reliable interpretation.
Presented below is an account of a procedure
(B) The density logging instruments auto- used by the authors in estimating porosity for a
matically correct for lag. It is important that large, multi-zoned reservoir. In this applica-
the logging reference point on the sonde is under tion of the density log, several modifications
stood in this respect. were necessary. There were 39 wells having den-
sity logs, 16 of which also had core analyses in
(c) Normally, density logs are run at speed some of the sands. Of the available density log~
from 20 ft/min to 50 ft/min. Logging speed is an 34, or 87 per cent, were run in oil base mud,
important parameter with regard to density log with the average mud density being 10.0 lb/gal.
interpretation, and logging speed and time-con- Also, 29 wells, or more than 74 per cent of the
stant should be selected such that good log wells with density logs, had 9-1/2 in. boreholes
quality is assured. through the productive interval. Therefore, it
was decided that density log calibrations would
(D) Repeat runs should be made over the first be made based on the response of an instru-
sections of interest along zero and statistical ment run in a 9-1/2 in. hole with 10.0 lb/gal oil
checks. Instrument sensitivity should be deter- base mud. It was also decided that all deflec-
mined both before and after the log is run. tion readings would be adjusted, for convenience,
to an instrument response factor (IRF) of 300.
INTERPRETATION AND APPLICATIONS
It was first necessary to interpolate be-
Geologic Applications tween the calibration charts to get a curve for

It is anticipated that the density log will


10.0 lb/gal mud. Using Eq. 26, and = 1.00 er
gm/cc and e~ = 2.65 gm/cc as suggested by Campbell
have great utility to the geophysicist, petrole- and Wilson, initial calculations from this chart
um geologist and engineer. DenSity measurements were consistently higher than those reported by
will expedite the solution of a great number of the core analyses. This is to be expected because
geophysical problems that are common in explora- denSity log deflections are related to total poro-
tion work. Values of natural density are im- sity whereas core analyses measures effective
portant in the interpretation of gravity meter porOSity. Using core analyses data, grain densi-
surveys. Newton, Skinner, and Silverman 7 were ties were calculated from the information on the
among the first to use a density logging tool for original data sheets. Several hundred of these
this purpose. Geologists were later able to make grain densities were calculated from the core
use of the concept. It has been used in several data, and the average value for (e~) derived from
1253-G ALBIN J. UK AND JOE ED SMITH
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _-=1""'3
- I -
these calculations was 2.647 gm/cc, confirming I logging company were used to determine the mag-
the assumed value. nitude of these corrections. They were prepared
I in the form of a cross plot of borehole diameter
The influence of the type of fluid lost to - drilling fluid density - density log deflection
the formation on wells logged in oil base mud was correction factor. The curves were then stored
considered to be significant. It was assumed in the computer and calculations of porOSity were
that any infiltration that took place around the made in rapid order.
walls of the borehole would tend to increase the
oil saturation in the invaded zone. Since the No interpretations were made in some sands
density log investigates to about four to six in. because of poor borehole geometry, close prox-
behind the wellbore, it is the saturation distri- imity to the water table, insufficient bed thick-
bution within the flushed zone that is of inter- ness, etc. Generally, the interpretations made
est. Standard evaluation of the oil base core I were in close agreement with core analysis data

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fluid saturations provided a means for determin- I as is shown on the two examples of core analysis
ing So/Sw distribution within the flushed zone. porosity vs corrected density log-derived poro-
(See Ref. 82, 83, 84, 96, 97, 102, 112, 114, 119.~ sity given on Fig. 11. Such consistent agree-
Electronic digital computers were used to sort ment promotes the acceptance of the density log
and compute this information from the core analy- as an effective tool for estimating porosity.
sis data, and an average value of So/Sw = 70/30
was derived. It was then assumed that the 30 per After working with density logs from many
cent water was formation water and 70 per cent other fields; there are several conclusions the
of the total pore volume contained a mixture of authors have reached in respect to porosity
the original reservoir oil and a common diesel estimation:
fuel (drilling fluid filtrate). By using the
values of density for the water, reservoir oil, (1) The type and denSity of drilling fluid
and diesel fuel at reservoir conditions of tem- filtrate will have a very definite effect on the
perature and pressure, a composite or average interstitial fluid density (e~) within the in-
formation fluid density (ff) within the invaded vaded zone. Of course, hydrostatic head of mud
zone was computed as 0.795 gm/cc. column, formation type, formation permeability,
drilling rate, etc. will also have an effect on
By interpolating on the calibration charts ef· One approach is suggested which uses simple
for a 10.0 Ib/gal mud, the foregoing equation was flood-pot test to determine the average residual
solved using e~ = 0.795 gm/cc and a borehole oil or average irreducible water saturations.
diameter of 9-1/2 in. The results were plotted The interpreter then assumes that complete flush-
on a semi-log graph of density log derived ing to residual oil occurs within the four or six
porosity vs density log deflection in inches. At in. of formation examined by the density log.
this point, it is usually necessary to make em- Hence, if water base mud is used, he reasons that
pirical corrections to effective porosity. the interstitial fluid denSity is determined by
connate water saturation+ residual oil satura-
In a similar manner, the computations were tion + invaded filtrate saturation. Values of
repeated for density logs run in 9-1/2 in. holes pressure and temperature are easily estimated.
drilled with a 10.0 Ib/gal water base mud. These The majority of the material in Reference Group
two curves were the basis of the interpretation V will be helpful in determining an accurate
of the density logs, and the following set of value of ~f' Core analYsis data is of paramount
conditions was stipulated with respect to their importance in this respect.82,84,101,102~113
use: Preliminary reports on displacement logging are
encouraging in this respect. lll ,120 A study of
(1) Bore hole diameter = 9-1/2 in. - 1/2 in. the hydraulics of the invasion process is of
(2) Drilling fluid density = 10.0 Ib/gal - interest.97,98,112,119
0.4 Ib/gal
(3) Density log deflections corrected to (2) It is recognized that grain density has
IRF = 300 an appreciable effect on porosity interpretation
(4) Average grain density = 2.647 gm/cc and specific measurements should be made wheneve;
(5) Ef = 0.795 (oil base mud) or 0.926 possible. When cores are taken, it is inexpen-
(water base mud) sive and convenient to obtain grain denSity data.
(6) Bed thickness ~4 ft The laboratory measurement and calculation from
(7) Logging speed? 20 but.::... 50 n/min core analYSis of grain denSity is quite simple.
(8) Time constant consistent with bed thick- 93,9 4 ,99, 10 5,110
ness and logging speed
(9) Consistent borehole geometry
*The authors' experience in density log interpre-
It was evident that suitable corrections were tation include Northeast Texas, Upper Texas Gulf
necessary when the drilling fluid density and Coast, Mississippi-Alabama Gulf Coast, Southwest
borehole diameter did not fit conditions (1) and Texas, Permian Basin, South Central Oklahoma, and
(2). The calibration charts prepared by the Paradox Basin.
14 GAMMA RAY-DENS:rrY LOGGING 1253-G

I
~--~~

(3) Borehole geometry is important. detection and counting of gamma rays.


Through experience the log analyst must learn to
recognize the effects of poor borehole geometry. Group IV: Correlation of phenomenological
laws with mathematical expressions; elementary
(4) Porosity values developed from core and advanced theory of statistical correlations;
analysis data should be used in the development and methods of curve fitting and curve interpo-
of field calibration curves. The analysis should lation.
include porosity, permeability, fluid saturations,
grain density, and rock descriptions. Adequate Group V: Petrophysics of petroleum
core data must be available to construct the reservoir materials; evaluation of interstitial
field calibration curves and to check the valid- fluid properties and interstitial fluid hydrau-
ity of this correlation as the field develops. lics with respect to the quantities measured by

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the density log.
An interesting evaluation of the density log
as a porosity tool is presented by Northcote. 8 GROUP I
It is unfortunate that similar such investiga-
tions have not been published on other area of 1. Anderson, R. H.: "Applications of the
activity. The work of Andersonl highlights ef- Densilog", (Paper originally presented at the
fects of variations in grain density and inter- Oklahoma Geological Society Annual Meeting,
stitial fluid density on density log-derived Oklahoma City, Spring, 1958).
porosity. 2. "New Logging Technique Measures Density and
Porosity", World Oil (Dec., 1954) m, 7.
other Applications of Density Logging 3· Baker, P.E.: "Density Logging with Gamma
Rays", Trans •.• AIME (1957) 210, 289-294.
Gamma ray-density logging instruments are 4. Caldwell, Richard L.: "Using Nuclear Methods
finding other useful applications. Caldwell and in Oil Well Logging", Nucleonics (Dec., 1958)
Sippel1 7 give an account of a borehole fluid 16, 12, 58-65.
density tool and a cement-top locator. The for- 5· Campbell, John L. P., and Wilson, John C.:
mer device has application in locating casing "Density Logging in the Gulf Coast Area",
leaks or making gradient surveys. Sippel and Jour. Pet. Tech., (July, 1958) 10, 7, 21-25.
Hodges9 have presented a tool that is used to 6. Faul, Henry, and Tittle, C. W.: "Logging of
log LPG storage wells for the location of fluid Drill Holes by the Neutron-Gamma Method and
interfaces. McLendon59 cites a density logging Gamma Ray Scattering", Geophysics, (1951) 16,
device used to locate gas sands. Campbell and 261-276.
Wilson5 suggest that the tool may be useful in 7· Newton, G. R., Skinner, J. E., and Silver-
sulfur prospecting. The future applications of man, Daniel: "Subsurface Formation Density
the density log are prospectively unlimited; the Logging", Geophysics, (1954) 12, 3, 636 -
tool can be run in any borehole in any type of abstract. (Paper originally presented at
fluid. Its usefulness will be limited only by 24th Annual Meeting of Society of Exploration
the wellbore conditions which prevent the precise Geophysicists, St. Louis, Mo., April 12-15,
measurements of density. 195 4 ) •
8. Northcote, K. E.: "A Preliminary Investiga-
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General information concerning the interpre- 97-106.
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under Group I; more specific information on the Gamma Ray Technique Used in LPG Storage Well
theory, physical principles, instrumentation, Logging", Pet. Engr. (1958) 3Q, 4, B-u8.
and logging techniques are listed in Groups II
and III. Research workers and log analysts will GROUP II
find literature of interest in all five groups.
10. Aronson, R., and Goldstein, H.: "Status of
The five reference groups are defined as Calculations of Gamma Ray Penetration", NDA
follows: Report No. 15C-l, (1952), Nuclear Develop-
ment Associates, White Plains, N. Y.
Group I: Direct reference to interpreta- 11. Baker, P. E.: ''Neutron Capture Gamma Ray
tion and application of density logs; brief dis- Spectra of Earth Formations", Jour. Pet. Tech.
cussions of physical principles. (March, 1957) 2, 3·
12. Belcher, D. J., Herner, R. C., Cuykendall,
Group II: Theoretical aspects of the den- T. R., and Sack, H. S.: "Use of Radioactive
sity log; academic treatment of the physical laws Material to Measure Soil Moisture and Den-
governing the behavior of gamma rays. sity", AS'lM Tech. Paper No. 134 (1953)
American SOCiety of Testing Engineers,
Group III: Detailed survey of instrumen- Philadelphia, Pa., 10-22.
tation and logging techniques involving the 13. Bitter, Francis M.: Nuclear Physics (1950)
1253-G

14.
Addison-Wesley and Co., cambri~::::~. ANDI3:~E :lm~::.
ZAK
Blatt, S. M., and Weisskopf, V. F.: Theo-,
T.: "Graphs of the Compton fuer~:
Angle Relationships and the Klein-Nishina
retical Nuclear Physics, (1952) John Wiley Formula from 10 Kev to 500 Mev", National
and Sons, New York, N. Y. I Bureau of Standards Circular No. 542 (1953)
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Inelastic Scattering of 14-Mev Neutrons in 34. Occhialini, G. P. S., and Powell, C. F.:
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(1956) ~, No.4, 59. sign and Operation of Gamma Ray Surface
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I~ew Developments in Radioactive Well Log- partment Report No. 261 (July 17, 1956).
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20. DuMond, J. W. M., and Cohen, E. R.: "Least-
Squares Adjustment of the Atomic Constants", 38. Armstrong, F. E.: "A Small Diameter Transis-
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A. H.: "Scintillation Unit for Drill Hole
16 ---------- GAMMA RAY-DENSITY LOGGING
--r-- 1253-G

1:. Logging", Nucleonics (1953) ll, No.4, 34-39.1


Fearon, R. E.: "Gamma Ray Well Logging",
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Fearon, R. E., and Mardock, E. S.: "The
I

I
69·

70.
Toelke, L. W.: !!Scintillation Spectrometer
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I 51.
Quantitative Interpretation of Radioactivity I Bulk Density", Agricultural Engr. (1954) l2.,
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52. Guelke, R. J., Heydenrych, C. R., and Ander- bility Requirements for Scintillation Coun-
son, F.: !Measurement of Radioactivity and I ters Used in Radioactivity Logging", Trans.
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Development 'Jf Instruments for this Purpose!!,
Jour. of Scientific Instruments and Physics GROUP IV
in Industry (1949) 26, 150-153.

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1253-G ALBIN J. ZAK AND JOE ED SMITH 17

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GROUP V 108. Kay, W. B.: "Density of Hydrocarbon Gases

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101. Horner, William L.: "Contamination of Cores tute, 69-75.
by Drilling Fluid Can Be Estimated by Dis- 120. Winn, R. H.: "A Report on Displacement
solving Simple Chemicals in Mud", Oil Weekly Logging", Jour. Pet. Tech. (Feb., 1958) K, 2.
(1935) ]§, No·3, 29·
102. Horner, William L., and Lewis, James A.:
"Differentiation of Water in Oil Field
Cores", Prod. Monthly (Aug., 1943) 1, No.8,
45.
103. Horner, William L., and LeWis, James A.:
"Interstitial Water Saturation in the Pore
Space of Reservoirs", Oil Weekly (1936) 86,
No.6, 36.
104. Howard, W. V., and David, M. W.: "Develop-
ment of Porosity in Limestones", Bull. AAPG
56

1
PAIR -PRODUCTION~
54
PH OT 0 E L E C T RIC .!::E.!:FJ:F:..!E=-,CUT.---~ /
52
~'/'-

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a:
UJ
Gamma Ray Collimator ~e------ e-
4t~ /~
(D
::;; 50 And Gamma Ray sourcy / \ _
::>
z
/ ~/--\\e~L..'" ,,//
':: '21./ --I(" 61->.;/\
~Y I ~Ir!{~-+
Q.

( \
(
0
!

~<:~~~f--t\ V ) 1(-
>--
0
~

\~Y ---e-.----- /
-----= ~y'
Particle COMPTON SCATTERING~ 'C---_----. __ ~ __

photon e-'
MASS NUMBER, A e- electron
e+ positron DIAGRAM SHOWING THREE POSSIBLE
FIGURE I n neutron INTERACTIONS .OF GAMMA RADIATION
DISINTEGRATION CHART FOR p+ proton WITH THE SILICON+4 ATOM
THE THORIUM DECAY SERIES FIGURE 2
(AFTER HALLIDAY)

THE COMPTON EFFECT


®
e-
Erel £(1l~ hll'
GAMMA RAY DETECTOR I ~"l@
p

CD y-------.(x\:)
",r In! ~J--
~i- ..

GAMMA RAY e-'


COLLIMATOR @
FIGURE 3
SCHEMATIC OF MODEL USED
TO DETERMINE GAMMA RAY
Figure: 4 A Compton collision in which a photon of energy EtYl CD collides
ATTENUATION COEFFICIENTS
with an electron of energy E(e-l ® at ®. The scattered photon moves off at angle e
with energy Efyf @, and the electron is deflected at angle 'IV with energy E(e-)' ®.
10

> 9 /
'"
::i<
/
V
>- 8
t9 ~
0:::
W
z 7
!/
/ V
w
],/,0"
/ /'
z
0
I-
0
6

5
/ VV
~/
I
L.----

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0- 1--'2.0•

---
4
/' I---""'
0
W
# /
0:::
w
l-
I-
« 2
3

1// ' -
V
f-.---
I - - _30· -
u
U)

~
I~ V ----- 45·
60· =
-
~ ::-- 12~0
-
~
o 2 3 4 5 6 7 8 9 10

INITIAL PHOTON ENERGY, Mev

FIGURE 5
FIG URE 6
GRAPH SHOWING ENERGY SCHEMATIC OF TYPE I SONDE
LOSS OF SCATTERED PHOTONS FOR (RADIAL SOURCE AND
GEIGER - MULLER COUNTER)
VARIOUS SCATTERING ANGLES

DETECTOR REGION

REGIO N

b
b and I are known·
, b
'"'b" 2ToST
h"Z TonI
-e- " 21

,-
.! h-----I
SL SOURCE REGION
FIGURE 7
SCHEMATIC OF TYPE n SONDE
(COLLIMATED SOURCE AND
FIGURE 8
SCINTILLATION COUNTER)
GEOMETRY OF TYPE IT SONDE
10.00

FIGURE 10
L EXAMPLE OF DENSITY LOG 9.00
CALIBRATION CURVE FOR
TYPE I SONDE
8.00

V)
w
/ '- 7.00
::r:
<..>
:z

:z
,
WITH 215 STo. SOURC£

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STANDARD
NCALIBRATOR,400" 6.00 0
CALIBRATOR
(~ SEM1SIVITY,TIWE I-
AS '4.00" COMSUNT' 5 SEC <..>

--
w
-'
5.00 u...
'\ w
0
I\V
4 00
'"
0
-'
>-
l-
V)
of-- 300 :z
w
0

2.00

FIGURE 9 Instrument Response Factor = 300.00


Density of Bore Hole Fluid = II Olbs/gcl 1.00
METHOD OF DETERMINING
DENSITY LOG SENSITIVITY
FOR TYPE I SONDE
1.8 2.0 2.2 24 2.6 2.8 3.0 3.2
0

NATURAL DENSITY, ~
cc

POROSITY, %

--Pf!!~T.!.I,Q'L I)!T.!_
CORE DATA
o 2 ... ~ e ,0 ,2 14 '6 'EI 20 0 2

TABLE I

CHARACTERISTICS OF FUNDAMENTAL PARTICLES

Relative Relahve Year of


Particle Synlbol Charge Mass Discovery
Electron (Negatron) I 1896
Positron e+ + I 1932
Proton + I 1836
Neutron 1840 1932
Photon y
o PI 1901
Alpha Particle +2 7352

Beta Particle (J: (J-

FIGURE II
COMPARISON OF CORE ANALYSIS
PO RO SIT Y WITH POROSITY
DERIVED FROM DENSITY LOGS

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