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Natural Gas Industry B 7 (2020) 82e92
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Research Article
A prevention and control method for natural gas hydrate in pipe strings
during deepwater gas well production tests*,**
Li Xiangfang a, Liu Wenyuan b,*, Liu Shujie c, Hu Jinqiu b, Nan Yufeng d, Tian Tian d &
Zhou Yunjian b
a
College of Petroleum Engineering, China University of Petroleum, Beijing, 102249, China
b
College of Safety and Ocean Engineering, China University of Petroleum, Beijing, 102249, China
c
CNOOC Research Institute Co., Ltd., Beijing, 100028, China
d
PetroChina Oil & Gas Pipeline Control Center, Beijing, 100007, China
Received 17 May 2019; accepted 25 July 2019
Available online 13 February 2020
Abstract
The prevention and control of natural gas hydrate (hereinafter, “hydrate” for short) blockage during deepwater gas well production tests is
very important in ensuring the test safety. In this paper, the distribution of wellbore temperature and pressure field under different test conditions
was analyzed, and the changes of hydrate deposition and blockage degree in the pipe string in the whole process of test under different test
systems were evaluated using the hydrate generationedepositionedecomposition calculation method. On this basis, a deepwater gas well
production test method based on hydrate prevention and control was proposed. And the following research results were obtained. First, in the
process of deepwater gas well tests, the vaporeliquid phase of annular-mist flow pattern with the greatest risk of hydrate blockage is often
formed in the wellbore. Therefore, it is more reasonable to take measures to prevent hydrate blockage in the process of tests than to prevent the
formation of hydrate. Second, when the conventional four-point test method is used, it is required to set low gas production measurement points
with lower flowing temperature. In the wellbore with high temperature and low temperature, however, hydrate tends to form and deposit easily,
and a long period of test will increase the risk of test string blockage. Third, the mixed-sequence test system suitable for deepwater gas well tests
can change wellbore temperature by adjusting the sequence of measuring points without changing the production rate and duration, so as to
decompose hydrate sediment layers and reduce the maximum blockage degree of test string in the process of tests. Fourth, a three-point or two-
point test method is recommended for deepwater gas wells without sand production, stress sensitivity, retrograde condensation and water
production. Superior to the conventional four-point test method, three-point and two-point test methods can effectively reduce the risk of hydrate
deposition and blockage in the test string, and it can shorten the testing time and reduce the test cost on the premise of ensuring the accuracy of
the productivity equation. In conclusion, the research results are of help to the field test construction of deepwater gas wells.
© 2020 Sichuan Petroleum Administration. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND
license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Keywords: Deepwater gas well; Production test; Natural gas hydrate; Prevention and control method; Mixed-sequence test; Pipe blockage degree; Flow assurance
0. Introduction
*
Project supported by the National Program on Key Basic Research Project
(973 Program) “Deep-water oil and gas well completion and production tests In the past few years, significant progresses have been
optimization” (No.: 2015CB251205). achieved in the development of deep-water oil and gas fields.
**
This is the English version of the originally published article in Natural But for China, there is still a long way to go [1e3]. Production
Gas Industry (in Chinese), which can be found at http://dx.doi.org/10.3787/j.
issn.1000-0976.2019.07.008.
tests in deep-water gas wells are key techniques to capture
* Corresponding author. reservoir parameters and assess development potentials of gas
E-mail address: Wenyuan_liu@126.com (Liu WY). reservoirs. But these tests are characterized by huge technical
Peer review under responsibility of Sichuan Petroleum Administration.
https://doi.org/10.1016/j.ngib.2019.07.004
2352-8540/© 2020 Sichuan Petroleum Administration. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
(http://creativecommons.org/licenses/by-nc-nd/4.0/).
Li XF et al. / Natural Gas Industry B 7 (2020) 82e92 83
challenges, significant safety risks and high costs [4e8]. hydrate inhibitors and optimizing gas production and testing
Formation of natural gas hydrates (hereinafter, “hydrate” for time, the risks related to pipe string blockage by hydrates can
short) in pipe strings and consequential blocking in such tests be reduced, and the operation costs can be lowered. These
have been a headache for both gas well safety and test effi- results can provide necessary theoretical supports for on-site
ciency [9,10]. Massive deposition of hydrates in test strings production tests of deep-water gas wells.
may significantly narrow the flowing channel for fluids and
affect the accuracy of production tests. If the flowing space 1. Processes and methods for production tests of deep-
inside pipe strings is fully blocked by such hydrates, produc- water gas wells
tion tests may come to a stop. In extreme cases, build-up of
pressure may lead to pipe string fracturing, and eventually, 1.1. Test processes
causing huge economic loss [11e17].
Multiple techniques have been developed for production Fig. 1 shows the structure of a pipe string deployed for
tests in terms of system and process to prevent and control production tests of a deep-water gas well. With a mudline as
hydrate generation. For example, with regard to the test sys- the border, the test string can be divided into two parts. The
tem, the gas productivity in the test is enhanced to a level upper part, consisting of the components above the mudline, is
above the critical gas productivity for the generation of hy- installed inside a riser to separate it from sea water. The lower
drates [18]; though this technique can effectively eliminate the part, consisting of the components below the mudline, is
possibility of hydrate generation, it may reduce the extent of covered inside the casing to isolate it from formation. The two
acceptable gas productivity. Besides, though the technique by parts are connected via a subsea testing tree at the mudline.
which the testing time is reduced to lower the volume of hy- The part of the test string near the reservoir formation is
drate generated can reduce the risks pipe string blockage by equipped with shut-in valves, while a position of the test string
hydrates, a shorter testing time may negatively impact the below the mudline is equipped with an injection valve for
completeness and accuracy of fluid sampling, and may hinder hydrate inhibitors.
the stability of test flow [19]. With regard to well shut-in At present, the innovative “one opening þ one shut-in” test
mode, the surface shut-in is changed to downhole shut-in, so process characterized by fast cleanout, slow sampling, gentle
that the possibility of hydrate generation in borehole after productivity modulation and well shut-in for restoration is
shut-in can be eliminated; however, this technique may generally used for production tests of deep-water gas wells
enhance the complexity of relevant processes and the difficulty [25]. This process can be divided into 3 stages: cleanout flow
of equipment maintenance, ultimately leading to higher costs. after well opening, production flow, and pressure build-up
With regard to the test process, the “two openings þ two shut- after shut-in Ref. [7]. During the well opening and flow
ins” process is replaced by the “one opening þ one shut-in” stage, adjustable nozzles are usually used to control flow,
process [20,21], so as to reduce the risks related to abnormal while the flowback of fluids is recorded, the H2S and CO2
production during the second opening of a gas well induced by content in produced gas are monitored, and the sand produc-
the string blockage as a result of hydrate generation during the tion in formation is detected and controlled; the PVT samples
first shut-in; however, such a simplified process may lower the of gas are taken as required in design. During the shut-in stage,
rationality of relevant test parameters and the accuracy of the data of pressure build-up in formation are acquired to
solution for productivity equations. Currently, hydrate in- calculate the reservoir parameters.
hibitors are still the preference for preventing hydrates during
production tests [22e24]. To minimize the formation of hy- 1.2. Test methods
drates in test strings, a large or excessive volume of hydrate
inhibitors may be added during production tests; as a result, A production test starts with the reduction of gas produc-
both operation time and costs can be very high. tion after cleanout and flowback in condition of high gas
As a matter of fact, there are differences between flow production. Under the “one opening þ one shut-in” test pro-
barrier in test strings and pipe string blockage due to hydrate cess, samples are taken at a low gas productivity during the
generation during production tests. Accordingly, the authors earlier stage of production test to take fluid samples accurately.
analyzed the distribution of temperature-pressure fields in Sampling includes downhole sampling and separator sam-
wellbore under different test conditions. In addition, the hy- pling, which may be unsuccessful at a high gas flow rate.
drate generation-deposition and decomposition calculation Besides, steady flow is mandatory for sampling. In practices,
methods were used to highlight the degrees of hydrate steady flow can be achieved in 2e4 h after opening of a gas
blockage in pipe strings during the entire testing process under well with high productivity, but more than 8 h for a well with
different systems. On the basis of available production test low productivity in low-permeability gas reservoir. For sepa-
techniques for gas wells, the production test systems with rator sampling, approximately 1 h is required to take one
mixed sequence and variable measuring points were developed group of samples [7]. Generally, a low gas production stage is
specifically for deep-water gas wells. The study results show accompanied with relatively low fluid temperature in the
that the mixed-sequence and variable measuring points test wellbore. Such a low temperature may accelerate the genera-
systems can dramatically reduce the blockage degrees of hy- tion of hydrates, which eventually leads to flow barrier in the
drate in test strings. By coupling with a suitable volume of wellbore.
84 Li XF et al. / Natural Gas Industry B 7 (2020) 82e92
After the sampling stage, it is necessary to determine the temperature and pressure for hydrate generation are available,
well production with variable gas productivity. Specifically, hydrates may evolve in a process of gen-
the test production is evaluated and the deliverability erationegrowthedepositioeblockage under a prolonged
equation is built. The pressure build-up test is conducted to period. Eventually, hydrate films on pipe wall and grain de-
acquire reservoir parameters. To ensure successful sam- posits will narrow the diameter of the pipe string, or even
pling, separator sampling can be performed in this stage to totally block the pipe. Therefore, the distribution of wellbore
prepare back-up samples. In these tests, steady flow is pressure and temperature in different test systems should be
required under different gas productivities [7]. According to analyzed and assessed to figure out the countermeasures to
prevailing standards, no fewer than 4 measuring points are inhibit hydrate deposition and blockage.
required for production tests. Besides the low gas produc-
tivity identified for the sampling stage, 3 different gas pro- 2. Wellbore temperatureepressure field distribution and
ductivities are required; steady flow is required for each of hydrate generationedeposition and decomposition for
the gas productivity. In other words, the stage with flows at deep-water gas wells
variable rates may last a relatively long time, which is
determined predominantly by reservoir porosity and 2.1. Distribution of temperatureepressure fields in
permeability. wellbore
Usually, tests can be performed in a normal or reversed
sequence. The gas productivity changes from low to high for During production tests of deep-water gas wells, changes in
the former, while from high to low for the latter. Since a gas gas production may directly affect the distribution of tem-
well has basically an identical time span to reach and maintain perature and pressure fields within the test string. In the case of
steady flow, neither sequence will present impacts on time a relatively low wateregas ratio (WGR), the gas/liquid phases
spans of relevant tests. in the string may present an annular-mist flow pattern; a part
As clarified in the above section for test methods, the of water phase goes up along the pipe wall in the form of
testing time under each group of gas productivity is expected liquid film, while the other part may be carried by gas core
to last a few hours or even longer. In the low-rate flow process flowing at a high rate in the pipe in the form of liquid drops.
during the production flow stage, the wellbore may have re- Under the annular-mist flow pattern, temperature and pressure
gions with hydrate generated due to its high-pressure and low- are of great importance for generationedeposition and
temperature conditions. In some cases, such regions can be up decomposition of hydrates. Accordingly, different testing gas
to several thousand meters long [26]. Once the necessary volumes correspond to the various distribution patterns of
Li XF et al. / Natural Gas Industry B 7 (2020) 82e92 85
Fig. 2. Distribution of temperature fields in wellbore under different gas tested Fig. 3. Distribution of pressure fields in wellbore under different gas tested
production rates. production rates.
temperatureepressure fields, thereby leading to the differences 2.2. Generationedeposition and decomposition of
in risks of pipe blockage by hydrates. hydrates
We may take a deep-water gas well A (a vertical well) in
South China Sea as an example, with its basic parameters High pressure and low temperature may facilitate hydrate
shown in Table 1. By using the available methods for calcu- generation. Natural gas with specific composition corresponds
lating the temperatureepressure fields in wellbore during with its specific phase equilibrium curve of hydrate. Gases
production tests of deep-water gas wells [27,28], the distri- with different compositions have a similar correlation between
bution of temperatureepressure fields in wellbore under the hydrate phase equilibrium curve and temperature/pressure.
different gas productivities can be determined. Fig. 4 shows the hydrate phase equilibrium curve of gas with
It can be seen in Fig. 2 and Fig. 3 that the flowing pressure certain compositions. Areas with hydrate generation are
in wellbore decreases with the increasing gas productivities, distributed on the left side of the curve. During the production
but from bottom hole to wellhead, the overall pressure drop test of the deep-water gas well, an area in the test string with
doesn't change greatly with the gas productivity. The distri- sustained conditions for hydrate generation may experience
bution of flowing temperature within the pipe string varies continuous generation and deposition of hydrates; as a result,
significantly under different gas productivities. Generally, the the pipe diameter is reduced constantly until the string is
smaller the gas productivity, the lower the overall wellbore completely blocked. Of course. in actual tests, flow time at
temperature. Around the mudline, the wellbore temperature each gas productivity is limited. As the gas productivity in-
drops obviously. When the temperature drops to below the creases, the temperature and pressure within the pipe string
temperature for hydrate generation, hydrates begin to occur; migrate to the right side of the hydrate phase equilibrium
continuous generation of hydrates may eventually lead to curve. Then, no more hydrate generation can be observed, and
blockage of the pipe string. Thus, it is highly probable that a the existing hydrate will decompose. It can be inferred that the
long-term production test at low gas productivity involves pipe flowing space of fluids within the test string varies with the
string blockage. This is a key consideration for prevention and testing time. In this study, the ratio between the reduced cross-
control of hydrates during production tests. For Well A, the sectional area of the pipe string induced by hydrate deposition
critical gas productivity at which no hydrates are generated is and the original cross-sectional area of the pipe string is
determined to be 58 104 m3/d. defined as the pipe blockage degree, so that the flow barrier
Table 1
Basic parameters of Well A.
Parameter Value Parameter Value
Well depth/m 3300 Water-depth in the area/m 1335
Formation pressure/MPa 39.5 Formation temperature/ C 95
Formation pressure gradient/[MPa$(100 m)1] 1.18 Formation temperature gradient/[ C$(100 m)1] 3.5
Sea level temperature/ C 20 Mudline temperature/ C 2.3
Test productivity/[104 m3$d1] 20e120 Test string diameter/mm 139.7
Casing diameter/mm 244.48 Riser diameter/mm 482.6
86 Li XF et al. / Natural Gas Industry B 7 (2020) 82e92
DV ' 1 n
h ¼ Kd h feq f0 A's ¼ k' V 'h ð2Þ
Dt rg
Fig. 7. Mixed-sequence test for a deep-water gas well. Note: q is the gas productivity in the test, 104 m3/d; pwf is the bottomhole flowing pressure, MPa; pR is the
formation pressure, MPa; t is the testing time, s.
q3. Clearly, the mixed-sequence test system can significantly of the zone for hydrate generation is approximately 1400 m.
reduce the risks related to hydrate blockage within the test Under high gas productivities of 80 104 m3/d and
string. 120 104 m3/d, hydrates decompose due to high flowing
In addition, changing the sequence of measuring points temperature within the borehole. Based on the distribution of
without changing the gas productivity at the measuring point temperatureepressure fields in the wellbore, the above-
has minor impacts on testing time and data acquisition under mentioned calculation techniques for generationedeposition
steady flow at the measuring points, and no extra man power and decomposition of hydrates were used to highlight the
or materials are needed and relevant operations will go pipe blockages by hydrates during the entire test processes
smooth. Accordingly, this technique is acceptable both theo- under three test systems, as shown in Fig. 8. For the purpose of
retically and practically. safe test, 30% was taken as the maximum allowable blockage
degree of pipe string in this study.
3.2. Degrees of pipe string blockage in normal, reversed In Fig. 8, the maximum blockage degree of test string under
and mixed sequence test systems normal and reversed sequence systems is up to 35.84%, well
above 30%. Under the normal sequence test system, the
Well A was analyzed to understand its pipe blockage by maximum blockage degree is observed at 9 h in the test;
hydrates during production tests. According to the design, the thereafter, hydrate decomposes gradually under relatively high
total testing time for this well is 30 h, and the test details are gas productivity, and the blockage is fully removed upon the
shown in Table 2. completion of the production test. Under the reversed
In Fig. 2, Well A has a critical gas productivity of sequence test system, the maximum blockage degree is
58 104 m3/d for hydrate generation. Under low gas pro- observed after the production flow stage; since the production
ductivities of 20 104 m3/d and 40 104 m3/d, hydrates are flow stage is followed by the shut-in and pressure build-up
generated continuously in the string, and the maximum length stage, the complicated pigging operation is required before
the well is put into production. Under the mixed sequence test
Table 2
system, generation and decomposition of hydrates occur twice,
Details of tests for Well A. with the maximum blockage degree of 26.09%, which is
Test stage Gas production Flow time/h
27.2% lower than that under the normal and reversed sequence
rate/(104 m3$d1) test systems; moreover, the problems related to flow barrier in
Flow-back and flow stage 65 6
test string are effectively reduced, thus the possibility of pipe
Production and flow stage q1 ¼ 20 5 blockage hydrates during the test is mitigated, and no negative
q2 ¼ 40 4 impact will occur on subsequent tests and production.
q3 ¼ 80 4 In summary, with regard to the elimination of pipe
q4 ¼ 120 4 blockage by hydrates, the reversed sequence test system can
Shut-in and pressure 0 7
build-up stage
be determined to be the most unfavorable, where severe
blockage may occur and hydrate deposits cannot be removed
Li XF et al. / Natural Gas Industry B 7 (2020) 82e92 89
Table 3
Degrees of pipe blockage under different gas production rates.
Measuring Flow Test Group-1 Test Group-2 Test Group-3
point time/h Gas production Pipe blockage Gas production Pipe blockage Gas production Pipe blockage
rate/(104 m3$d1) degree rate/(104 m3$d1) degree rate/(104 m3$d1) degree
q1 5 20 26.09% 25 24.13% 30 22.33%
q4 4 120 0 120 0 120 0
q2 4 40 9.43% 40 9.43% 50 4.2%
q3 4 80 0 80 0 80 0
Table 4
Degrees of pipe blockage under different flow time.
Measuring Gas production Test Group-1 Test Group-2 Test Group-3
point rate/(104 m3$d1) Flow time/h Pipe blockage Flow time/h Pipe blockage Flow time/h Pipe blockage
degree e degree degree
q1 20 5.0 26.09% 4.5 24.59% 4.0 22.63%
q4 120 4.0 0 4.0 0 4.0 0
q2 40 4.0 9.43% 4.5 10.6% 5.0 11.46%
q3 80 4.0 0 4.0 0 4.0 0
Table 5
Content of tests for Well A under the systems with variable measuring points.
Method Stage Gas production rate/(104 m3$d1) Flow time/h
Three-point test method Flowback flow stage 65 6
Production flow stage q1 ¼ 20 5
q2 ¼ 80 4
q3 ¼ 120 4
Shut-in and pressure build-up stage 0 7
Two-point test method Flowback flow stage 65 6
Production flow stage q1 ¼ 20 5
q2 ¼ 120 4
Shut-in and pressure build-up stage 0 7
Table 6
Degrees of pipe blockage under three-point test method with different gas production rates.
Measuring Flow Test Group-1 Test Group-2 Test Group-3
point time/h Gas production Pipe blockage Gas production rate/ Pipe blockage Gas production Pipe blockage
rate/(104 m3$d1) degree (104 m3$d1) degree rate/(104 m3$d1) degree
q1 5 20 26.09% 30 22.33% 40 13.54%
q2 4 80 0 80 0 80 0
q3 4 120 0 120 0 120 0
Table 7
Degrees of pipe blockage under three-point test method with different flow time.
Measuring Gas production rate/ Test Group-1 Test Group-2 Test Group-3
point (104 m3$d1) Flow time/h Pipe blockage Flow time/h Pipe blockage Flow time/h Pipe blockage
degree degree degree
q1 20 5 26.09% 4 22.63% 3 18.20%
q2 80 4 0 5 0 4 0
q3 120 4 0 4 0 4 0
Additionally, in the case of tests with variable measuring compromising the accuracy of the productivity
points, the blockage degree can be further reduced by short- equation.
ening testing time or promoting gas productivity. Tables 6 and
7 provide the blockage of a pipe string under different testing
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