MA 2. x (om ies Name: Empower Yourself AP Chemistry Empower Your Community Date: Empower Your World Period: Track and Field - inetics Practice Problems Rate Laws 1. Consider the reaction: 2NO(g) + Ox(g) > 2 NOxg) The following data were obtained from three experiments using the method of initial rates: “Initial [NO] | Initial [Oz] | Initial rate NO mol L” mol L* mol L's? Experiment | 0,010 0.010 25x10 Experiment 2 0.020 0.010 1.0.x 107 Experiment 3 0.010 0.020 5.0.x 10" a, Determine the order of the reaction for cach reactant. b. Write the rate cxvaton forthe reo \ Rate NW o, % c. Caleulate the rate constant. le (2.09 0S 5 o> eto L258 77 | Calculate the rate (in mol L's") at the instant when [NO] = 0.015 mol 1.” and [03] = 0.0050 mol L"! Bate (2rYo. es) (o eos) [Rox = Zens] 2. The reaction of tbutyl-bromide (CH:)sCBr with water is represented by the equation: (CH:):CBr + 120 > (CHs)sCOH + HBr ‘The following data were obtained from three experiments using the method of initial rates: Initial [(CHs)sCBr] | Initial [H.0] | Initial rate mol Lt mol Lt mol Ltmin* Experiment1_| 5.0x 10? 2.0 x 102 2.0 x10 Experiment 2 | 5.0x 102 40x10? 2.0 x10 Experiment 3_| 1.0 x 107 4.0 x 102 4.0 x10¢Name: Empower Yourself AP Chemistry Empower Your Community Date: Empower Your World Period: a. What is the order with respect to (CHs)sCBr? 2x10" Sew? Y (2 wer of to © fe On Sapper ay = OS as” oy xn b. Whatis'the order with respect to H20? ae qe ¢. Write the rate equation. Date “A KC DZ EBS [HOy” d. Calculate the rate constant, k, for the reaction, ° . ‘ -? Qxioe= \e — Wand Ay107 eye l Integrated Rate Laws 3. For the reaction 2A > 2B + C, the following data were collected: Time (s) JA (M) 10 8.23 x10" SceSSaseai ESSESassaszzies PEEEESESEST. NY 30. 5.52107 40 $3210 50 3.70310" 0 3.05 x10" oe 23.230)" x aysx0. & a.Determine the ratelaw Ae be = te EAS ia once he (er x ay eee (G74 10) -(e.23x\e?) a re ao ale = dead eeececeemeseaegeiaia \.22z 74s x10) 2 ¥a@ DO-\o Zs x Wf Palm > Bw =61x10$ JPatesecan | a. tj b. Calculate k. Gl OS = \c(@T4 mo D! ve Grae? Got? Xe Jicz oats! | Iculate the ¥ life of this reaction % yee CAS xo" -3, B27 ce oe 0-643 O.6FR ty te Gut par JO7e8 |Name: Empower Yourself AP Chemistry Empower Your Community Date: Empower Your World Period: d. Calculate the [A] after 70 s. \n [Ay 20-4 (gy in a * 03 x > 4. For the reaction A> product, the first two hal-umes are 5 the beginning of the reaction, [A] was 0.10M. What is the [A] at t = 80 min? Fig = 10 min 7242422272 42asrasarae BY lw oe = JB .4n8" m1) 5. The rate law for the hydrolysis of sucrose is Rate = k[CizHo2011]. After 2.57 hours at 25 °C, 0.55 M of CazHz2011 has decreased to 0.45 M. Calculate the rate constant value and units for this reaction, re (os y =~ k(2.57 Dh 4 Inlo.ssd -0.794 =~ @.57)-~ O.s4e, ~ O.2ar e-le (toy ; “ry Ee => )k= 0.0784 | 6. The rate constant for the second order decomposition of nitrogen dioxide, ~ + NO2> NO +% Oz is 3.40 Mmin*, Calculate the time, in minutes, needed to decrease the concentration from 2.00 M to 1.50 M, = (BN(L) + ).so Clots (a4suy seaeeeeaaaaete 3.4 3.4 => 0.077 mi y= é| Arrhenius Equation 7. Determine the value of k if a reaction has an activation energy of 75.5 ki/mol and Acres constant of 95.5 M's" ata temperature of 20°C. = -_ Ee \ Inlk= -2b.4 Inl& ait InA fee lll yal nk =- (75, SBoFY.,Y ( ae —_—_ are eee eae TELE LENDS» | Infis.gy pone sieid InK=-30.9% 44.5% 2-264 ‘Name: Empower Yourself AP Chemistry Empower Your Community Date: Empower Your World Period: 8, Determine the value of E,and A for the following data. Furthermore, create an Arhenius plot and show how to use it to determine E,, A, and k. ‘Temperature (1 600 650 700 750 800 a ie (2 = -is( - Us 5.15% E, tent” Kee RT? 7 7, Perea aa ara ye fer 12% in [2022 Es a i be O.Ue Bs Yaa (Gse (oo ares a =f esr oS Say 1.2 Io = @ step f HoC=CHa + Ht + C+ HaC-CHe + CF Sg step 2 H3C-CH2 + CF + H3C-CH;CI PE, a. Which is the rate determining step? . i tab Step 15 Fa is Nia) b. Is this reaction endo or exothermic? Exotermic) A's Wiser Grane See C ¢. Which chemical species are present at A? HCC Ht and Cy d. Which chemical species are present at B? Hs C- CH, anh CK . Which chemical species are present at C? Hg Cn Che C1 b 1. Which chemical species are present atD?7IE-vkvmediake & (AD an CBS Spectaces . g. What is the rate law for this reaction? a ohe = lac 20H, CH y