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Combustion of Preheated Raw Animal Fats-Diesel Fuel Blends at Diesel Engine
Combustion of Preheated Raw Animal Fats-Diesel Fuel Blends at Diesel Engine
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Abstract
Because of pollution problems, after the Mayors Summit 2016 takes place, certain European capital cities want to be free
from diesel engines automotive equipped with diesel engine by the year 2020. Also, the International Energy Agency affirms
that the per cent of bio energy must increase till the year of 2025 and estimates that biofuels can grow to as much as 30% of
the world’s road transport fuel mix by 2050. The global share of biofuel in total transport fuel would grow from 2% today
to 27% in 2050. According to a European Commission report on the Future Transport Fuels, the 2020 Red target could be
supported by vehicles fuelled by fuels based also on animal fats. The objective of the paper is directly related with these
worldwide aspects. The paper presents combustion aspects at a diesel engine fuelled by raw animal fats blended in per cent’s
of 5% and 10% with diesel fuel. For the same engine adjustments, the preheated raw animal fats use leads to the decrease
of in-cylinder pressure with 5% and 12%, depending on animal fats content. Even if the animal fat use provides the increase
in the combustion duration with 20 CAD and later achieving per cycle of the mass fraction burned, the heat release rate
decreases with 16% (at 5% animal fats) and 20% (at 10% animal fats) assuring the decreasing of the NOx emission level with
22% versus diesel fuel. The smoke opacity decreases with 22% (at 5% of animal fats in blends with diesel fuel) and with
52% at the rise of animal fats content to 10%. The novelty of the paper is assured by aspects like: an efficiently recover of
raw animal fats from the leather industry assuring an important decrease of waste stocks and of financial costs, an optimal
correlation between animal fats per cent and diesel engine combustion performance. The raw animal fats can be considered
a very good alternative biofuel for the diesel engines and can be used for fuelling without major constructive modifications
of the engine.
Keywords Raw animal fat · Diesel engine · Combustion · Heat release · Pollutant emissions · Soot
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A. Cernat et al.
fuels based or not on animal fats, Singh fuel a compression diesel engine [12]. For 30% animal fat content in diesel fuel,
ignition engine with oil fatty acid methyl ester (Mesua fer- the NOx emission levels remain unchanged comparative to
rea methyl esters (FAME)) in blend with diesel fuel and diesel fuel [12]. For higher or less per cents of animal fat in
achieve the reduction of the N Ox emission level [3]. Singh blend with diesel fuel, the pollutant emissions levels were
presents the influence of FAME in diesel fuel on thermal decreased [12]. Behçet shows that the use of biodiesel based
efficiency of the diesel engine [3]. Lapuerta uses 50–100% on animal fats leads to the N Ox concentration increase, ver-
animal fat in blends with diesel fuel and with soybean oil sus diesel fuel, for an air-cooled diesel engine [13].
to fuel a DI (Direct Injection) diesel engine [4]. The engine Generally, the raw animal fats are formed from triglyc-
efficiency remains unchanged [4]. The smoke opacity and erides of saturated monocarboxylic fatty acids with carbon
particle emissions were decreased [4]. The NOx emission even-numbered, palmitic acid (CH3(CH2)14COOH) and
was decreased for 100% animal fat, but rise for 50% animal stearic acid ( CH3(CH2)16COOH). The raw animal fat of
fat or soybean oil [4]. Lapuerta affirms that at the use of beef contains ~ 12% oxygen, so the reduction of pollutant
animal fats, with higher cetane number, the amount of fuel emissions level, especially soot, is possible. Versus diesel
burnt in the premixed fraction of the combustion process is fuel the animal fats are environmental friendly, in almost
reduced, fact that leads to the reduction of the combustion 20 days a 98% of it are totally degraded comparative to clas-
noise, soot, particle and NOx emissions levels [4]. Lapuerta sic fuels [1, 14–16]. Because at ambient conditions, the raw
also shows that at the increase in the engine load, longer animal fats are in solid state their use in raw state as fuel
combustion duration may appears [4]. Kleinovál shows the for diesel engine requires their preheating at temperatures
decrease of diesel engine power and torque at the use of ani- above 45 °C. The raw animal fat of beef is composed from
mal fat, but the performance is related also with the engine 37 mass% (mass per cent) of saturated acids, defined by
type. The smoke opacity was decreased at animal fat use 27 mass% palmitic, 7 mass% stearic and 3 mass% myristic,
only for the engine with a higher injection pressures compar- and 61 mass% of unsaturated acids constituted from oleic
ative to low pressure injection engine, based on tests carried (48 mass%), palmitoleic (11 mass%) and linoleic (2 mass%)
on a fleet of diesel automotives fuelled with fat-diesel fuel [1, 4, 14–16].
blends [5]. Sáez makes a prediction on exhaust emission at The main properties of diesel fuel and beef raw fat are
the use of animal fat as fuel for diesel engine and affirms that shown in Table 1.
lower concentration of NOx, particle number was achieved The paper presents in-cylinder combustion aspects at a
at animal fat use [6]. Rajak uses fuel based on the waste diesel engine fuelled by raw beef animal fats-diesel fuel
animal fats to fuel a single cylinder diesel engine, at full load blends. One novelty aspect of the present study versus simi-
and speed, constant injection timing [7]. Also, Rajak uses lar experimental investigations is the use of animal fats is
a Diesel-RK model for numerical analysis of some tested raw state, without chemical modifications, in order to fuel
fuels [7]. The NOx emission decreases at chicken fats (ani- a diesel engine.
mal fats) used with 31.2% [7]. The PM (Particulate Matter) This is an efficient recover solution of animal fats from
emission was reduced with 93.78% for poultry fats and the the leather industry resulting an important decrease of waste
soot emission with 89.14% [7]. Hancsók shows that the use stocks and of financial costs, especially for fuelling with ani-
of waste animal fat and of the fuels with lower carbon con- mal fats of diesel engine—electrical generators that are used
tent in combustion process will leads to the reduction of the in leather industry. The effects of preheated raw animal fats
pollutant emissions [8]. Kumar shows that the use of animal
fat in different blends with diesel fuel leads to the reduction
of the smoke, NOx and to the increase in autoignition delay Table 1 Properties of diesel fuel and raw animal fats of beef [14, 15]
[9]. Alptekin uses animal fat fuel type to fuel a DI diesel Propertiesa Diesel fuel Phillips 66 Raw animal
engine at the speed of 1400 min−1 and different engine loads fats of beef
(150–600 Nm) [10]. At animal fat fuelling, the maximum
Density/kg m−3 849.5 929
pressure increases with 1.2%, the N Ox emission is reduced
Viscosity at 40 °C/mm2 s−1 2.96 46.37
and the combustion start occurs later on cycle [10]. Barrios
Ignition point/°C 74 96
uses diesel fuel and different fuels based on six animal fats
Sulphur/mass% 0.036 0
and soybean oil to fuel a Euro 4 diesel engine during urban
Cetane number CN/− 49.2 40–45
driving cycle tests [11]. As a result, comparative to diesel
Heating value H i/MJ kg−1 42.90 38.9
fuel, the NOx emission increases, and the PM emission was
Composite/mass% 86.67 of C 73 of C
decreased [11]. Comparative to soybean fuel, the animal fat
12.96 of H2 12.3 of H2
fuel type offers lower PM emission level [11]. Shahir uses
0.33 of O2 12.5 of O2
per cents of 10–50% animal fat in blend with diesel fuel
in order to fuel a CRDI (Common Rail Direct Injection) a
According to ASTM D613
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Combustion of preheated raw animal fats‑diesel fuel blends at diesel engine
content in blends with diesel fuel on diesel engine in-cyl- blend per cent-fuel injection timing- temperature of exhaust
inder combustion are shown. Thus, another novelty aspect gases. Thus, the highest engine performance at animal fat
of the study is the optimal correlation established between use can be assured.
raw animal fats per cent and engine operating parameters in
order to assure engine high performance.
Results and discussions
19 18 17 16 15 14
13 12
11
10
1 2 3 4 5 6 7 8 9
13
A. Cernat et al.
13
Combustion of preheated raw animal fats‑diesel fuel blends at diesel engine
– 6.9
–7 39
0 2 4 6 8 10 0 2 4 6 8 10
xc/% xc/%
Fig. 6 Mass fraction burned of 5% for different xc values Fig. 9 Mass fraction burned of 90% for different xc values
8 250 100
Mass fraction burned – 10%/°CA
240 NOx/ppm 95
7.5
230 NOx/%
90
7 220
NOx/ppm
NOx/%
85
6.5 210
80
200
6 75
190
5.5 180 70
170 65
5
0 5 10
0 2 4 6 8 10
xc/% xc/%
Fig. 7 Mass fraction burned of 10% for different xc values Fig. 10 The NOx emission level for different xc values
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A. Cernat et al.
390 in blends with diesel fuel the smoke opacity decreases with
22% for xc = 5 and with 52% for xc = 10.
Exhaust gas temperature/°C
385
380
375
Conclusions
370
10 70 xc = 10;
9 60 • because of a lower heat release during the raw animal
8 50 fats combustion, the mass fraction burned (MFB) of 50
and 90% are achieved later on the cycle with 3 and 4
7 40
CAD at xc = 5 and xc = 10, respectively, in correlation
6 30 with decreasing tendency of maximum pressure and
5 20 maximum pressure rise rate; these issues lead to the
0.00 5.00 10.00 increase in the total duration of combustion with 19.5
xc/% CAD for xc = 5 and 20 CAD for xc = 10;
• the level of the NOx emission is reduced with 22% by
Fig. 12 The opacity of the smoke at different xc values the lowers gas temperature values achieved at the ani-
mal fat combustion, the decrease being proportional
combustion temperature registered for xc = 0 is higher. For with animal fats per cent in blend;
xc = 10, the decrease of fuel blend heating value leads to • at the animal fat use, due to the rise of fuels blend
the reduction of the maximum temperature during combus- oxygen content versus diesel fuel, the smoke opacity
tion in relation with the decrease of NOx emissions level. is decreased with 22% and 52% at xc = 5 and xc = 10,
Finally, comparative to diesel fuelling the N Ox emissions respectively;
level decreases with 22% at animal fats use. • the use of small per cents of preheated raw animal fats
The NOx emissions level reduction is also in correlation in blend with diesel fuel to fuel the diesel engine does
with the reduction tendency of the exhaust gas temperature, not require major design modification of the engine,
as Fig. 11 shows. Comparative to diesel fuelling, the com- only an electrical resistance in fuel reservoir being rec-
bustion of animal fats-diesel fuel blends leads to the reduc- ommended for use in order to establish the liquid state
tion of exhaust temperature with 4% for xc = 5 and with 6.7% of beef animal fat in blend with diesel fuel;
for xc = 10. • future researches will be developed to evaluate the
The smoke emission level was evaluated by the opacity effect of the animal fats use on fuelling system reli-
value, Fig. 12. ability on long-term.
The raised oxygen content of animal fats assures the
reduction of the smoke opacity, which was decreased with
24% at xc = 5% and with 52% for xc = 10% animal fat, com- Acknowledgements The authors address special thanks to AVL GmbH
Graz Austria for providing the necessary equipments. This work has
parative to diesel fuel, Fig. 12. The reduction of the smoke been funded by University Politehnica of Bucharest, through the
emission at raw animal fats-diesel fuel blends use is related “Excellence Research Grants” Program, UPB—GEX 2017. Identifier:
with the reduction of carbon content and the rise of oxygen UPB- GEX2017, Ctr. No. TR 27-17-06/2017”. Grant of the Roma-
content in the final fuels blend ones with rise of animal fat nian Ministry of Research and Innovation, CCCDI-UEFISCDI, project
number PN-III-P1-1.2-PCCDI-2017-0404, within PNCDI III. Sectoral
per cent. Thus, versus diesel fuelling at the use of animal fats
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Combustion of preheated raw animal fats‑diesel fuel blends at diesel engine
Operational Programme Human Resources Development 2007–2013 9. Kumar MS, Kerihuel A, Bellettre J, Tazerout M. Ethanol animal
of the Ministry of European Funds through the Financial Agreement fat emulsions as a diesel engine fuel—Part 2: engine test analy-
POSDRU/159/1.5/S/134398. sis. Fuel. 2006;85(17–18):2646–52. https://doi.org/10.1016/j.
fuel.2006.05.023.
10. Alptekin E, Canakci M, Ozsezen AN, Turkcan A, Sanli H.
Using waste animal fat based biodiesels–bioethanol–diesel fuel
References blends in a DI diesel engine. Fuel. 2015;157:245–54. https://doi.
org/10.1016/j.fuel.2015.04.067.
1. Future Transport Fuels. Report of the European Expert Group 11. Barrios CC, Sáez AD, Martín C, Álvarez P. Effects of animal
on Future Transport Fuels. ALBA-Fachverlag, Dusseldorf. 2011. fat based biodiesel on a TDI diesel engine performance, com-
Accessed 10 Apr 2018. bustion characteristics and particle number and size distribution
2. Lezsovits F, Könczöl S. Animal-fat investigation and combustion emissions. Fuel. 2014;117(1):618–23. https://doi.org/10.1016/j.
test. J Therm Anal Calorim. 2012;107(1):271–8. fuel.2013.09.037.
3. Singh N, Kumar H, Jha MK, Sarma AK. Complete heat balance, 12. Shahir VK, Jawahar CP, Suresh PR, Vinod V. Experimental inves-
performance, and emission evaluation of a CI engine fueled with tigation on performance and emission characteristics of a com-
Mesua ferrea methyl and ethyl ester’s blends with petrodiesel. J mon rail direct injection engine using animal fat biodiesel blends.
Therm Anal Calorim. 2015;122(2):907–16. Energy Procedia. 2017;117:283–90. https://doi.org/10.1016/j.
4. Lapuerta M, Fernández JR, Oliva F, Canoira L. Biodiesel from egypro.2017.05.133.
low-grade animal fats: diesel engine performance and emissions. 13. Behçet R, Oktay H, Çakmak A, Aydin H. Comparison of exhaust
Energy Fuels. 2009;23(1):121–9. https://doi.org/10.1021/ef800 emissions of biodiesel–diesel fuel blends produced from animal
481q. fats. Renew Sustain Energy Rev. 2015;46:157–65. https://doi.
5. KleinováI A, Vailing J. Vegetable oils and animal fats as alterna- org/10.1016/j.rser.2015.02.015.
tive fuels for diesel engines with dual fuel operation. Fuel Pro- 14. Nicolici A, Pana C, Negurescu N, Cernat A, Nutu C (2018) The
cess Technol. 2011;92(10):1980–6. https: //doi.org/10.1016/j.fupro use of animal fats in the diesel fuelled engine. In: IOP conference
c.2011.05.018. series: materials science and engineering, 444, 1–9.
6. Sáez AD, Rattá GA, Barrios CC. Prediction of exhaust emission 15. Lazaroiu G, Pană C, Mihaescu L, Cernat A, Negurescu N, Mocanu
in transient conditions of a diesel engine fueled with animal fat R, Negreanu G. Solutions for energy recovery of animal waste
using artificial neural network and symbolic regression. Energy. from leather industry. Energy Convers Manag. 2017;149:1085–95.
2018;149:675–83. https://doi.org/10.1016/j.energy.2018.02.080. 16. Gunstone F. Fatty acid and lipid chemistry. London: Blackie;
7. Rajak U, Verma TN. Effect of emission from ethylic biodiesel 1996.
of edible and non-edible vegetable oil, animal fats, waste oil and
alcohol in CI engine. Energy Convers Manag. 2018;166:704–18. Publisher’s Note Springer Nature remains neutral with regard to
https://doi.org/10.1016/j.enconman.2018.04.070. jurisdictional claims in published maps and institutional affiliations.
8. Hancsók J, Sági D, Valyon J. Diesel fuel blending components
from mixture of waste animal fat and light cycle oil from fluid
catalytic cracking. J Environ Manag. 2018;223:92–100. https://
doi.org/10.1016/j.jenvman.2018.06.011.
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