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ELEGANT STUDY FORUM

ASSIGNMENT CLASS - XII ELECTROCHEMISTRY

Q1. Ohm-1 is unit of:


(a) molar conductivity (b) equivalent conductivity (c) specific conductance (d) conductance
Q2. On increasing the dilution the specific conductance:
(a) increases (b) decreases (c) remains constant (d) none of these
Q3. Conductance (Unit-Siemens, S) is directly proportional to the area of the vessel and the concentration of solution in
it and is inversely proportional to the length of the vessel, then the unit of constant of proportionality is:
(a) S m mol-1 (b) S m2 mol-1 (c) S-2 m1 mol (d) S2 m2 mol-2
Q4. In SI unit, the correct relation between equivalent conductivity ( ), specific conductance (k) and equivalent
concentration (C) is: (C = Number of g-equivalents in 1 L solution)

(a) (b) (c) (d)

Q5. The limiting molar conductivities ( ) for NaCl, KBr and KCl are 126, 152 and 150 S cm2 mol-1 respectively. The
for NaBr (in S cm2 mol-1) is:
(a) 302 (b) 176 (c) 278 (d) 128
Q6. Among the following solutions, which has highest electrical conductivity?
(a) 0.1 M acetic acid (b) 0.1 M chloroacetic acid
(c) 0.1 M fluoroacetic acid (d) 0.1 M difluoroacetic acid
Q7. Resistance of a conductivity cell filled with a solution of an electrolyte of this solution is 1.29 Sm-1. Resistance of
the same cell filled with 0.02 M of the same solution if the electrolyte is 520 ohm. The molar conductivity of
0.02 M solution of electrolyte would be:
(a) (b)
(c) (d)
Q8. The equivalent conductance’s of two strong electrolytes at infinite dilution in H2O (where ions move freely through
a solution) at 250C are given below:
. .
What additional information/quantity one needs to calculate of an aqueous solution of acetic acid?
(a) of NaCl (b) of CH3COOK
(c) The limiting equivalent conductance of (d) of chloroacetic acid (ClCH2COOH)
Q9. The correct order of equivalent conductances of LiCl, NaCl and KCl at infinite dilution is:
(a) LiCl > NaCl > KCl (b) KCl > NaCl > LiCl (c) NaCl > KCl > LiCl (d) LiCl > KCl > NaCl
Q10. Molar conductivity ( ) of an electrolytic solution is:
(a) (b) (c) (d)

Q11. Given that , , then equivalent conductivity of cell is:

(a) 10 (b) 20
(c) 3000 (d) 100

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Q12. Which of the following solution will have maximum molar conductivity?
(a) 0.001 M (b) 0.005 M (c) 0.002 M (d) 0.004 M
Q13. Equivalent conductivity of a solution weak monobasic acid is 8.0 mho cm2 eq-1 and at infinite dilution it 400 mho
cm2eq-1. Dissociation constant of acid is:
(a) (b) (c) (d)
Q14. At 250C and at infinite dilution, molar conductivities of NaOH, NaCl and BaCl2 are and
. Molar conductivity of Ba(OH)2 (in S m2 mol-1) will be:
(a) (b) (c) (d)
Q15. At 230C, specific conductance of 0.1 N KCl solution is 0.012 ohm-1 cm-1. If resistance of cell at same temperature is
55 ohm, then cell constant will be:
(a) 0.142 cm-1 (b) 0.66 cm-1 (c) 0.918 cm-1 (d) 1.12 cm-1
Q16. The ion having highest conductance in aqueous solution is:
(a) Li+ (b) Na+ (c) K+ (d) Cs+
Q17. At 250C specific conductance of KCl solution is 0.002765 mho cm-1. If resistance of cell (with solution) is 400

ohm, then cell constant is:


(a) 0.553 cm-1 (b) 1.106 cm-1 (c) 2.212 cm-1 (d) none of these
Q18. Good conductors of electricity are:
(a) weak electrolytes (b) strong electrolytes (c) electrolytes (d) catalysts
Q19. Unit of specific conductance is:
(a) (b) (c) (d)

Q20. Which of the following reactions does not occur at cathode?


(a) (b) (c) (d)
Q21. Reaction taking place at anode is:
(a) ionization (b) reduction (c) oxidation (d) hydrolysis
Q22. In a galvanic cell, energy change which takes place is:
(a) Chemical energy Electrical energy (b) Electrical energy Chemical energy
(c) Chemical energy Internal energy (d) Internal energy Electrical energy
Q23. Which of the following reaction takes place at anode?
(a) (b)

(c) (d) None of these

Q24. Charge on one mole of electrons is:


(a) One faraday (b) 96500 coulombs (c) N x e (d) All of these
Q25. In electrolysis, oxidation occurs at:
(a) anode (b) cathode (c) both (d) depends upon native of nature of electrode
Q26. When an electric current is passed through acidified water, 112 mL of hydrogen gas is collected at NTP at cathode
in 965 second. The current passed (in ampere) is:
(a) 1.0 (b) 0.5 (c) 0.1 (d) 2.0

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Q27. H+ ions are reduced at platinum electrons before the reduction of to:
(a) Zn2+ (b) Cu2+ (c) Ag+ (d) None of these
Q28. Among Na, Hg, S, Pt and graphite which may be used as electrodes in electrolytic cells containing aqueous
solution?
(a) Na, Pt and graphite (b) Na and Hg (c) Pt and graphite only (d) Na and S only

Q29. Galvanization of iron sheets is done by:


(a) Cu (b) Zn (c) Ag (d) Sn
Q30. Mg blocks are fitted in the bottom of ships:
(a) to keep sharks away (b) to prevent reaction with water and salt
(c) to keep ship light (d) to prevent puncture from sea rocks

Q31. The most durable metal plating to safeguard iron from corrosion will be:
(a) Copper plating (b) Tin plating (c) Zinc plating (d) Nickel plating
Q32. Saturated solution of KNO3 is used in salt bridge because:
(a) speed of K+ is greater than that of (b) speed of is greater than that of
(c) speed of and both are nearly the same (d) is highly soluble in water

Q33. The reaction for the cell expressed below is,


(a) (b)
(c) (d)
Q34. Correct representation of following cell is:
(a) (b)
(c) (d)
Q35. , Negative electrode in above cell is:
(a) Cu (b) Cu2+ (c) Zn (d) Zn2+

Q36. If the half cell reaction, has a large negative reduction potential it follows that:
(a) A is readily reduced (b) A is readily oxidized (c) is readily reduced (d) is readily oxidized

Q37. The reaction is spontaneous if the cell potential is:


(a) positive (b) negative (c) zero (d) infinite

Q38. The measured potential for, does not depend upon:


(a) rise the temperature (b) rise increasing the concentration of Mg2+ ions
(c) rise making the magnesium plate bigger (d) rise purity of magnesium plate

Q39. , on increasing concentration of Cd2+, Value of will:


(1 M)
(a) increase (b) decrease (c) remain constant (d) can’t predict

Q40. For the redox change: in a cell is 1.10 V. For the cell at 250C would be:

(a) 1.07 V (b) 0.82 V (c) 2.14 V (d) 180 V

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Q41. A standard hydrogen electrode has zero electrode potential because:
(a) hydrogen is easiest to oxidize (b) its electrode potential is assumed to be zero
(c) hydrogen atom has only one electron (d) hydrogen is the lightest element
Q42. The oxidation potential of a hydrogen electrode at pH = 1 is:
(a) 0.059 volt (b) 0.00 volt (c) -0.059 volt (d) 0.59 volt
Q43. The standard EMF for the cell reaction is 1.10 V at 250C. The EMF for the cell
reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used, at 250C is:
(a) 1.10 V (b) 0.110 V (c) 1.10 V (d) 0.110 V
Q44. For an electrochemical cell , data and proves that:
(a) is spontaneous. (b) is spontaneous
(c) = 0.77 V (d) = 0.77 V

Q45. of following half cells are:


, .
For reaction, is:
(a) 0.35 V (b) 0.35 V (c) V (d) 1.17 V
Q46. For electrode reactions, and values of are 0.76 V and -0.077 V
respectively. For the reaction is:
(a) + 1.53 V (b) 1.53 V (c) 0.01 V (d) 0.01 V

Q47. For cell, (1.0 M) || / Au, (if for V and for )


is:
(a) +4.0 V (b) 1.75 V (c) 1.75 V (d) + 1.25 V
Q48. The standard reduction potential for and electrodes are and volt respectively. For
the cell reaction:
, the standard EMF is:
(a) +0.30 V (b) 0.58 V (c) + 0.58 V (d) 0.30 V
Q49. The electrode potential becomes equal to standard electrode potential when reactants and products ratio is:
(a) equal to 1 (b) greater than 1 (c) less than 1 (d) none of these
Q50. At 250C, the values are:
,
. for the reaction is:
(a) 1.10 V (b) + 1.10 V (c) 1.34 V (d) 0.76 V
Q51. Free energy change ( is related to the EMF of the cell (E) as:
(a) (b) (c) (d)

Q52. When a rod of metal A is dipped in an aqueous solution of metal B (concentration of B2+ ion being 1 M) at 250C,
the standard electrode potentials are 0.76 volt , volts, then
(a) A will dissolve gradually (b) B will deposit on A
(c) no reaction will occur (d) water will decompose into H2 and O2

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Q53. Which metal will dissolve in the following Galvanic cell ?
(a) Cu (b) Ag (c) Both (d) None of these
Q54. The electrode potential of any electrode does not depend on:
(a) the nature of metal and its ions (b) concentration of ions present in solution
(c) pressure (d) temperature

Q55. The electrode potential of an electrode depends upon:


(a) nature of metal (b) temperature of solution (c) molarity of solution (d) all of these

Q56. Following four colourless solutions of salts have been kept in different test tubes and a copper strip was dipped in
each. Which solution will turn blue in the end?
(a) Zn(NO3)2 (b) Cd(NO3)2 (c) AgNO3 (d) Pb(NO3)2
Q57. CuSO4 can not be stored in Al bottles because:
(a) Cu gets oxidized (b) Cu2+ gets reduced (c) Al gets reduced (d) CuSO4 is decomposed

Q58. Standard reduction potentials for three metallic cations X, Y and Z are +0.52, 3.03 and 1.18 respectively. The
correct order of reducing powers of corresponding metals is:
(a) Y>Z>X (b) X > Y > Z (c) Z > Y > X (d) Z > X > Y

Q59. Which one is the incorrect statement about electrochemical series?


(a) Active metals have negative reduction potentials
(b) Active non-metals have positive reduction potentials
(c) Metals above hydrogen liberate hydrogen from acids
(d) Metals below hydrogen are strong reducing agents

Q60. Fe displaces Cu from its salt because:


(a) standard reduction potential of Fe is less than atomic number of Cu
(b) standard reduction potential of Fe is less than standard reduction potential of Cu
(c) standard reduction potential of Fe is higher than standard reduction potential of Cu
(d) salts of iron are more soluble in water than salts of Cu

Q61. At 1 atm. pressure and 250C temperature, gas X was passed though 1 and 1 solutions. If order of
standard reduced potentials are Z > Y > Z, then:
(a) Y will oxidize X but not Z (b) Y will oxidize Z but not X
(c) Y will oxidize both X and Y (d) Y will reduce both X and Z
Q62. Standard electrode potentials of Zn, Ag and Cu are V, +0.80 V and 0.34 V, then:
+
(a) Ag may oxidize Zn and Cu (b) Ag may reduce Zn2+ and Cu2+
(c) Zn may reduce Ag+ and Cu2+ (d) Cu may oxidize Zn and Ag
Q63. Standard electrode potentials of four metals A, B, C and D are , , and respectively.
Among them strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q64. In ECS, decreasing order of electropositive character of metals Na, Cu, Al and Zn is:
(a) Cu, Zn, Al, Na (b) Na, Al, Zn, Cu (c) Al, Zn, Cu, Na (d) Na, Zn, Al, Cu

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Q65. The strongest reductant among the following is:
(a) (b)

(c) (d)

Q66. The correct order of chemical reactively with water according to electrochemical series is:
(a) K > Mg > Zn > Cu (b) Mg > Zn > Cu > K (c) K > Zn > Mg > Cu (d) Cu > Zn > Mg > K
Q67. Which of the following will displace Br2 from aqueous solution of ?
(a) (b) (c) (d)
Q68. Which of the following metals may not be obtained be electrolysis of their aqueous solution?
(a) Ag and Mg (b) Ag and Al (c) Mg and Al (d) Cu and Cr
Q69. In ECS, which of the following metals do not displace H2 from acids?
(a) Ba, Sr, Ca (b) Cu, Ag, Au (c) Zn, Fe, Pb (d) N, K, Mg
Q70. Standard reduction potential of following half cell reactions are given below:
,

,
Which of them is strongest reducing agent?
(a) Zn(s) (b) H2(g) (c) (d) Cr(s)
Q71. 1 mole per litre solutions of Cu(NO3)2, AgNO3, Hg2(NO3)2 and Mg(NO3)2 are electrolysed by using inert electrode.
Value of standard reduction potential are given below:
, , ,
Upon increasing voltage, the correct order of deposition of metals at cathode is:
(a) Ag, Hg, Cu, Mg (b) Cu, Hg, Ag (c) Ag, Hg, Cu (d) Mg, Cu, Hg, Ag
Q72. Let a reaction is as follows .
If standard reduction potentials of three metals M1, M2 and M3 are 0.34 V, 3.05 V and 1.66 V, then correct
order of their reducing powers will be:
(a) M1 > M 2 > M 3 (b) M3 > M2 > M1 (c) M1 > M3 > M2 (d) M2 > M3 > M1
Q73. Standard reduction electrode potentials of three metals A, B and C are 0.5 V, 3.0 V and 1.2 V respectively.
The reducing power of these metals are:
(a) B>C>A (b) A > B > C (c) C > B > A (d) A > C > B
Q74. Standard reduction potential of four metal A, B, C and D are = 2.90, , 0.74 and V respectively. The
strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q75. The strong oxidizing agent has:
(a) high value of reduction potential (b) high value of oxidation potential
(c) low value of reduction potential (d) high tendency to lose electrons
Q76. Which of the following statements is wrong?
(a) F2 is the strongest oxidizing agent as its reduction potential is high
(b) Li is the weakest reducing agent as its reduction potential is low
(c) Li is the strongest reducing agent as its oxidation potential is high
(d) ion does not show reducing property

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Q77. Out of Cu, Ag, Fe and Zn the metal which can displace all others from their salt solution is:
(a) Ag (b) Cu (c) Fe (d) Zn
Q78. Which of the following metal is easily oxidized?
(a) Cu (b) Al (c) Ag (d) Pt
Q79. Which of the following metal displaces H2 neither from acids nor from water?
(a) Al (b) Fe (c) Pb (d) Hg
Q80. Which of the following reaction is not possible?
(a) (b)
(c) (d)
Q81. Which of the following is most electropositive metal?
(i) (ii)
(iii) (iv)
(a) Fe (b) Co (c) Ca (d) Cu
Q82. Increasing order of reducing power of Al, Sr , Hg and Cu is:
(a) Al , Hg, Sr, Cu (b) Hg, Cu, Al, Sr (c) Hg, Al, Cu, Sr (d) Cu, Hg, Al, Sr
Q83. The standard reduction potentials of Li, Ba , Na and Mg at 250C are – 3.05, , and V
respectively. The strongest oxidizing agent is:
(a) Ba2+ (b) Mg2+ (c) Na+ (d) Li+
Q84. At 250C, standard oxidation potential of Li | Li+, Ba | Ba2+ , Na | Na+ and Mg | Mg2+ pairs are +3.05, +2.73, +2.71
and +2.37 V. Strongest oxidizing agent is:
(a) Mg2+ (b) Ba2+ (c) Na+ (d) Li+
Q85. Four colourless salt solutions are placed in separate test tubes and a strip of copper is dipped in each. Which
solution finally turns blue?
(a) Zn(NO3)2 (b) Cd(NO3)2 (c) AgNO3 (d) Pb(NO3)2
Q86. values at 298 K of following half reactions are given below.
(i) V (ii)
(iii) (iv)
Select the strongest reducing agent among these.
(a) Zn(s) (b) Cr(s) (c) H2(g) (d)
Q87. When a piece of copper wire is immersed in a solution of silver nitrate, the colour of the solution becomes blue.
This is due to the:
(a) oxidation of Cu (b) reduction of Cu (c) formation of a soluble complex (d) oxidation of Ag
Q88. Some reduction potentials are given below:
Al3+ / Al = 1.67 V , Mg2+ / Mg = 2.34 V , Cu2+ / Cu = 0.34 V, = 0.53 V
Which of the following is best reducing agent?
(a) Al (b) Cu (c) Mg (d) I2
Q89. Which halide ion is not oxidizing by MnO2?
(a) (b) (c) (d)

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Q90. Which of the following is best reducing agent?
(a) (b) (c) (d)

Q91. Which of the following is most powerful reducing agent?


(a) Mg (b) K (c) Na (d) Ba

Q92. The correct order of reactivity of Mg, Cu, Na and Au is:


(a) Au > Cu > Mg > Na (b) Na > Mg > Cu > Au (c) Mg > Cu > Au > Na (d) Cu > Mg > Na > Au

Q93. Standard reduction potentials of elements A, B, C and D are 2.90, + 1.50, 0.74 and 0.34 V respectively. Among
these, the strongest oxidant is:
(a) A (b) B (c) C (d) D

Q94. Which of the following oxide will be reduced by hydrogen?


(a) Na2O (b) MgO (c) Al2O3 (d) Ag2O

Q95. The standard reduction potentials of four alkali metals A, B, C and D are 3.06 , 1.63 , 0.40 and 0.80 V
respectively. Among them strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q96. An apparatus used for the measurement of quantity of electricity is known as:
(a) Calorimeter (b) Cathetometer (c) Coulometer (d) Colorimeter
Q97. The unit of electrochemical equivalent is:
(a) Grams (b) Grams/ampere (c) Grams/coulomb (d) Coulomb/gram

Q98. The number of electrons involved in the reaction when one Faraday of electricity is passed through the
electrolyte is:
(a) (b) (c) 96500 (d)
Q99. The unit of cell constant is:
(a) ohm-1 cm-1 (b) cm (c) ohm-1 cm (d) cm-1
Q100. The number of Faraday which will be required to reduce 4 g equivalents of Cu2+ to Cu metal is:
(a) 1 (b) 2 (c) 3 (d) 4
Q101. The standard electrode potentials of four electrodes A, B, C and D are -3.05, -1.66, -0.40 and 0.80 volts
respectively. The highest chemical activity will be shown by:
(a) A (b) B (c) C (d) D
Q102. The standard emf for the cell reaction is 1.10 V at 250C. The emf of the cell reaction
when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used at 250C is:
(a) 1.10 V (b) 0.110 V (c) 1.10 V (d) 0.110V
Q103. When electricity is passed through a solution of AlCl3 13.5 g of Al is discharged. The amount of charge passed is:
(a) 1.5 F (b) 0.5 F (c) 1.0 F (d) 2.0 F

Q104. If a salt bridge is removed from the two half-cells, the voltage:
(a) drops to zero (b) does not change (c) increases gradually (d) increases rapidly

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Q105. When electric current is passed through a cell having an electrolyte, the positive ions move towards the cathode
and the negative ions towards the anode. If the cathode is pulled out of the solution:
(a) the positive and negative ions will move towards the anode
(b) the positive ions will start moving towards the anode
(c) the negative ions will continue to move towards the anode, the positive ions will stop moving
(d) the positive ions and the negative ions will start moving randomly
Q106. 1 Faraday of electricity will liberate 1 g atom of the metal from:
(a) fused NaCl (b) aqueous BaCl2 (c) aqueous CuSO4 (d) aqueous AlCl3
Q107. The standard reduction electrode potential values of the elements A, B and C are +0.68, -2.50 and -0.50 V
respectively. The order of there reducing power is:
(a) A>B>C (b) A > C > B (c) C > B > A (d) B>C>A
Q108. In an electrolytic cell; flow of electrons will be:
(a) from anode to internal source (b) from cathode to internal source
(c) from cathode to anode (d) none of these
Q109. Cell reaction is spontaneous when:
(a) is negative (b) is positive (c) is negative (d) is positive
2+ 3+
Q110. The EMF of cell, Ni / Ni (1M) Au (1.0 M)/Au
( for Ni2+ / Ni, 1.5 V for Au3+/Au) is:
(a) 1.25 V (b) -1.25 V (c) 1.75 V (d) 2.00 V
Q111. The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is:
(a) LiCl > NaCl > KCl (b) KCl > NaCl > LiCl (c) NaCl > KCl > LiCl (d) LiCl > KCl > NaCl
Q112. Equivalent conductance of NaCl, HCl and C2H5COONa at infinite dilution is 126.45, 426.16 and 91 ohm-1 cm2
respectively. The equivalent conductance of C2H5COOH is:
(a) 201.28 ohm-1/cm-2 (b) 390.71 ohm-1cm-2 (c) 698.28 / ohm cm2 (d) 540.48 / ohm cm2
Q113. Saturated solution of KNO3 is used to make salt bridge because:
(a) velocity of is greater than that of (b) velocity of is greater than that of
(c) velocity of both and are nearly the same (d) KNO3 is highly soluble in water
Q114. When zinc granules is dipped into copper sulphate solution, copper is precipitated because:
(a) both copper and zinc have positive reduction potential
(b) reduction potential of copper is higher than that of zinc
(c) reduction potential of zinc is higher than that of copper
(d) both zinc and copper have negative reduction potential
Q115. When lead storage battery discharges:
(a) SO2 is evolved (b) PbSO4 is consumed (c) Lead is formed (d) H2SO4 is consumed
Q116. Rust is a mixture of:
(a) FeO and Fe(OH)3 (b) FeO and Fe(OH)2 (c) Fe3O4 and Fe(OH)3 (d) Fe2O3 and Fe(OH)3
Q117. The e.m.f of the cell Zn/Zn2+(0.01 M) Fe2+(0.001 M)/Fe at 298 K is 0.2905 volt. Then the value of equilibrium
constant for the cell reaction is:
(a) (b) (c) (d)

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Q118. For a spontaneous reaction, and respectively will be:
(a) and (b) and – (c) and (d) and
Q119. The equilibrium constant of the reaction , at 298 K
is:
(a) (b) (c) (d)
Q120. The volume of H2 gas at NTP obtained by passing 4 amperes through acidified H2O for 30 minutes is:
(a) 0.0836 L (b) 0.0432 L (c) 0.1672 L (d) 0.836 L
Q121. If and , the standard EMF of the reaction
will be:
(a) 1.653 V (b) 1.212 V (c) 0.111 V (d) 0.330 V
Q122. Electrolysis of dilute aqueous NaCl solution was carried out by passing 10 milliamperes current. The time required
to liberate 0.01 mole H2 gas at the cathode is:
(a) (b) (c) (d)
Q123. Given (i) ;(ii) . Electrode potential
for the reaction will be:
(a) 0.90 V (b) 0.30 V (c) 0.38 V (d) 0.52 V
Q124. Conductivity of 0.01 M NaCl solution is 0.00147 . What happens to this conductivity if extra 100 ml
of H2O will be added to the above solution?
(a) Increases (b) Decreases (c) Remains unchanged
(d) First increases and then decreases
Q125. A button cell used in watches functions as follows:

If half cell potentials are

The cell potential will be:


(a) 0.84 V (b) 1.34 V (c) 1.01 V (d) 0.42 V
Q126. A current strength of 9.65 amperes is passed through excess fused AlCl3 for 5 hours. How many litres of chlorine
will be liberated at STP?(F = 96500 C)
(a) 2.016 (b) 1.008 (c) 11.2 (d) 20.16
Q127. A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl pH = 10 and by passing hydrogen
gas around the platinum wire at one atm pressure. The oxidation potential of electrode would be:
(a) 0.118 V (b) 1.18 V (c) 0.059 V (d) 0.59 V
2+
Q128. The number of Faradays required to reduce one mole of Cu to metallic copper is:
(a) one (b) two (c) three (d) four
Q129. The unit of equivalent conductance is:
(a) (b) (c) (d)
Q130. The quantity of electricity required to deposit 1.15 g of sodium from molten NaCl (Na = 23, Cl = 35.5) is:
(a) 1F (b) 0.5 F (c) 0.05 F (d) 1.5 F

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Q131. A current liberates 0.50 g of hydrogen in 2 hours. The weight of copper (At. wt. = 63.5) deposited at the same time
by the same current through copper sulphate solution is:
(a) 63.5 g (b) 31.8 g (c) 15.9 g (d) 15.5 g
Q132. Electrochemical equivalent is the amount of substance which gets deposited from its solution on passing electrical
charge equal to:
(a) 96500 coulombs (b) 1 coulomb (c) 60 coulombs (d) 965 coulombs
Q133. The ionic conductance’s of Ba and
2+ -1 2 -1 2
are 127 ohm cm and 76 ohm cm respectively at infinite dilution. The
-1 2
equivalent conductance (in ohm cm ) of BaCl2 at infinite dilution will be:
(a) 139.5 (b) 203.0 (c) 279.0 (d) 101.5
Q134. The resistance of a 0.1 N solution of acetic acid is 250 ohm. When measured in a cell of cell constant1.15 cm -1.
The equivalent conductance (in ohm-1 cm2 eq-1) of 0.1 acetic acid is:
(a) 46.0 (b) 9.2 (c) 18.4 (d) 2.3
Q135. The standard emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25 0C. The
equilibrium constant of the reaction would be:
(a) (b) (c) (d)
Q136. The cell reaction is spontaneous or feasible when emf of the cell is:
(a) negative (b) positive (c) zero (d) either positive or negative

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