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(Xii) (Electro Chemistry)
(Xii) (Electro Chemistry)
Q5. The limiting molar conductivities ( ) for NaCl, KBr and KCl are 126, 152 and 150 S cm2 mol-1 respectively. The
for NaBr (in S cm2 mol-1) is:
(a) 302 (b) 176 (c) 278 (d) 128
Q6. Among the following solutions, which has highest electrical conductivity?
(a) 0.1 M acetic acid (b) 0.1 M chloroacetic acid
(c) 0.1 M fluoroacetic acid (d) 0.1 M difluoroacetic acid
Q7. Resistance of a conductivity cell filled with a solution of an electrolyte of this solution is 1.29 Sm-1. Resistance of
the same cell filled with 0.02 M of the same solution if the electrolyte is 520 ohm. The molar conductivity of
0.02 M solution of electrolyte would be:
(a) (b)
(c) (d)
Q8. The equivalent conductance’s of two strong electrolytes at infinite dilution in H2O (where ions move freely through
a solution) at 250C are given below:
. .
What additional information/quantity one needs to calculate of an aqueous solution of acetic acid?
(a) of NaCl (b) of CH3COOK
(c) The limiting equivalent conductance of (d) of chloroacetic acid (ClCH2COOH)
Q9. The correct order of equivalent conductances of LiCl, NaCl and KCl at infinite dilution is:
(a) LiCl > NaCl > KCl (b) KCl > NaCl > LiCl (c) NaCl > KCl > LiCl (d) LiCl > KCl > NaCl
Q10. Molar conductivity ( ) of an electrolytic solution is:
(a) (b) (c) (d)
(a) 10 (b) 20
(c) 3000 (d) 100
Q31. The most durable metal plating to safeguard iron from corrosion will be:
(a) Copper plating (b) Tin plating (c) Zinc plating (d) Nickel plating
Q32. Saturated solution of KNO3 is used in salt bridge because:
(a) speed of K+ is greater than that of (b) speed of is greater than that of
(c) speed of and both are nearly the same (d) is highly soluble in water
Q36. If the half cell reaction, has a large negative reduction potential it follows that:
(a) A is readily reduced (b) A is readily oxidized (c) is readily reduced (d) is readily oxidized
Q40. For the redox change: in a cell is 1.10 V. For the cell at 250C would be:
Q52. When a rod of metal A is dipped in an aqueous solution of metal B (concentration of B2+ ion being 1 M) at 250C,
the standard electrode potentials are 0.76 volt , volts, then
(a) A will dissolve gradually (b) B will deposit on A
(c) no reaction will occur (d) water will decompose into H2 and O2
Q56. Following four colourless solutions of salts have been kept in different test tubes and a copper strip was dipped in
each. Which solution will turn blue in the end?
(a) Zn(NO3)2 (b) Cd(NO3)2 (c) AgNO3 (d) Pb(NO3)2
Q57. CuSO4 can not be stored in Al bottles because:
(a) Cu gets oxidized (b) Cu2+ gets reduced (c) Al gets reduced (d) CuSO4 is decomposed
Q58. Standard reduction potentials for three metallic cations X, Y and Z are +0.52, 3.03 and 1.18 respectively. The
correct order of reducing powers of corresponding metals is:
(a) Y>Z>X (b) X > Y > Z (c) Z > Y > X (d) Z > X > Y
Q61. At 1 atm. pressure and 250C temperature, gas X was passed though 1 and 1 solutions. If order of
standard reduced potentials are Z > Y > Z, then:
(a) Y will oxidize X but not Z (b) Y will oxidize Z but not X
(c) Y will oxidize both X and Y (d) Y will reduce both X and Z
Q62. Standard electrode potentials of Zn, Ag and Cu are V, +0.80 V and 0.34 V, then:
+
(a) Ag may oxidize Zn and Cu (b) Ag may reduce Zn2+ and Cu2+
(c) Zn may reduce Ag+ and Cu2+ (d) Cu may oxidize Zn and Ag
Q63. Standard electrode potentials of four metals A, B, C and D are , , and respectively.
Among them strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q64. In ECS, decreasing order of electropositive character of metals Na, Cu, Al and Zn is:
(a) Cu, Zn, Al, Na (b) Na, Al, Zn, Cu (c) Al, Zn, Cu, Na (d) Na, Zn, Al, Cu
(c) (d)
Q66. The correct order of chemical reactively with water according to electrochemical series is:
(a) K > Mg > Zn > Cu (b) Mg > Zn > Cu > K (c) K > Zn > Mg > Cu (d) Cu > Zn > Mg > K
Q67. Which of the following will displace Br2 from aqueous solution of ?
(a) (b) (c) (d)
Q68. Which of the following metals may not be obtained be electrolysis of their aqueous solution?
(a) Ag and Mg (b) Ag and Al (c) Mg and Al (d) Cu and Cr
Q69. In ECS, which of the following metals do not displace H2 from acids?
(a) Ba, Sr, Ca (b) Cu, Ag, Au (c) Zn, Fe, Pb (d) N, K, Mg
Q70. Standard reduction potential of following half cell reactions are given below:
,
,
Which of them is strongest reducing agent?
(a) Zn(s) (b) H2(g) (c) (d) Cr(s)
Q71. 1 mole per litre solutions of Cu(NO3)2, AgNO3, Hg2(NO3)2 and Mg(NO3)2 are electrolysed by using inert electrode.
Value of standard reduction potential are given below:
, , ,
Upon increasing voltage, the correct order of deposition of metals at cathode is:
(a) Ag, Hg, Cu, Mg (b) Cu, Hg, Ag (c) Ag, Hg, Cu (d) Mg, Cu, Hg, Ag
Q72. Let a reaction is as follows .
If standard reduction potentials of three metals M1, M2 and M3 are 0.34 V, 3.05 V and 1.66 V, then correct
order of their reducing powers will be:
(a) M1 > M 2 > M 3 (b) M3 > M2 > M1 (c) M1 > M3 > M2 (d) M2 > M3 > M1
Q73. Standard reduction electrode potentials of three metals A, B and C are 0.5 V, 3.0 V and 1.2 V respectively.
The reducing power of these metals are:
(a) B>C>A (b) A > B > C (c) C > B > A (d) A > C > B
Q74. Standard reduction potential of four metal A, B, C and D are = 2.90, , 0.74 and V respectively. The
strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q75. The strong oxidizing agent has:
(a) high value of reduction potential (b) high value of oxidation potential
(c) low value of reduction potential (d) high tendency to lose electrons
Q76. Which of the following statements is wrong?
(a) F2 is the strongest oxidizing agent as its reduction potential is high
(b) Li is the weakest reducing agent as its reduction potential is low
(c) Li is the strongest reducing agent as its oxidation potential is high
(d) ion does not show reducing property
Q93. Standard reduction potentials of elements A, B, C and D are 2.90, + 1.50, 0.74 and 0.34 V respectively. Among
these, the strongest oxidant is:
(a) A (b) B (c) C (d) D
Q95. The standard reduction potentials of four alkali metals A, B, C and D are 3.06 , 1.63 , 0.40 and 0.80 V
respectively. Among them strongest reducing agent is:
(a) A (b) B (c) C (d) D
Q96. An apparatus used for the measurement of quantity of electricity is known as:
(a) Calorimeter (b) Cathetometer (c) Coulometer (d) Colorimeter
Q97. The unit of electrochemical equivalent is:
(a) Grams (b) Grams/ampere (c) Grams/coulomb (d) Coulomb/gram
Q98. The number of electrons involved in the reaction when one Faraday of electricity is passed through the
electrolyte is:
(a) (b) (c) 96500 (d)
Q99. The unit of cell constant is:
(a) ohm-1 cm-1 (b) cm (c) ohm-1 cm (d) cm-1
Q100. The number of Faraday which will be required to reduce 4 g equivalents of Cu2+ to Cu metal is:
(a) 1 (b) 2 (c) 3 (d) 4
Q101. The standard electrode potentials of four electrodes A, B, C and D are -3.05, -1.66, -0.40 and 0.80 volts
respectively. The highest chemical activity will be shown by:
(a) A (b) B (c) C (d) D
Q102. The standard emf for the cell reaction is 1.10 V at 250C. The emf of the cell reaction
when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used at 250C is:
(a) 1.10 V (b) 0.110 V (c) 1.10 V (d) 0.110V
Q103. When electricity is passed through a solution of AlCl3 13.5 g of Al is discharged. The amount of charge passed is:
(a) 1.5 F (b) 0.5 F (c) 1.0 F (d) 2.0 F
Q104. If a salt bridge is removed from the two half-cells, the voltage:
(a) drops to zero (b) does not change (c) increases gradually (d) increases rapidly