Professional Documents
Culture Documents
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
Anton Nikitin, Loren P. Roberts, Feyzi Inanc, and Margarete M. Kopal
1
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
Detectors are optimally placed with respect to weapon stockpiles continue to be reduced and the
sensitivity and precision (Gilchrist, 2008; Gilchrist, He-3 stockpile has followed suit. The U.S. stockpile
2011) in the spatially log-linear region of the neutron has been heavily depleted in recent years by the U.S.
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
distribution. Environmental corrections will vary, Department of Homeland Security’s building of large
such as lithology effects, salinity corrections portal and inspection monitors for use at home and
(Roberts, 2010), etc. Therefore, it should be obvious abroad.
to the reader that sources can’t simply be swapped for
one another without modification and full re- While the exact amount of He-3 gas remaining and
characterization of any new or existing neutron expected to be produced in the future is hard to
porosity tool. obtain from the U.S. Department of Energy (DOE),
the price of He-3 is quite illuminating. As recently as
2007, the price of He-3 was about $35 per liter. In
2010 it has been observed from $3000 to $5000 per
liter on the open market—if any significant quantity
can be found. A typical detector for oil and gas
industry use may have on the order of 1 to 2 liters.
Figure 2. Neutron flux distribution showing possible Replacing He-3 detectors with Li-6 glass scintillators
positions for PNG-based tool long and short space is attractive for many reasons. A short comparison of
detectors, as well as for AmBe-based tools. benefits and drawbacks for He-3, Li-6, and B-10
based detection systems is presented next.
The use of Li-6 glass scintillator neutron detectors for
future neutron porosity measurements is ideal as a The first item to examine is the physical process for
replacement for He-3 detectors, which must be detecting a neutron. He-3 gas is used in proportional
addressed due to the He-3 supply shortage counters to detect neutrons through the following
(Ginhoven, 2009; Kouzes, 2009). Naturally occurring reaction
He-3 abundance is only 0.000137% of all helium in
the earth. The He-3 available for industrial use has 3
He+ 01n→13H +11p Q = 0.764 MeV ,
2
largely resulted from the decay of tritium produced
for use in nuclear weapons, although some He-3 is
produced from tritium formed in heavy water nuclear where the thermal neutron (n,p) cross section is 5328
reactors. Since the end of the Cold War, nuclear b. The useful B-10 reaction is as follows with a path
2
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
to both the ground state (6% of the time) and the peaks, but the high Q value of each corresponding
excited state (94% of the time) shown to be reaction allows for simple discrimination separation
of gamma rays and neutrons. B-10 based gaseous and
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
10
B+ 01n→37 Li + 24α Q = 2.792 MeV , solid state detectors are typically of lower thermal
5
neutron efficiency due to lower operating pressures
10
5 B+ 01n→37 Li* + 24α Q = 2.310 MeV , and boron layers that are required to be on the order
of microns thick.
where the thermal neutron (n,α) cross section is 3837
b. Li-6 has the following reaction Finally, Li-6 has the lowest thermal neutron capture
cross section, but the largest Q value. Typical
6 commercially available Li-6 glass of 3 mm thickness
3 Li + 01n→13H + 24α Q = 4.78 MeV , will be >95% efficient for thermal neutron
absorption, so the lower cross section is not an issue.
where the thermal neutron (n,t) cross section is 940 b. However, the Q value is deceiving because heavy
For each reaction the Q value energy is much larger charged particles and gamma rays do not produce the
than that of a thermal or epithermal neutron, so the same amount of light through the scintillation process
kinetic energy of the incident neutron is negligible. in the glass. A gamma ray of about 1.2 – 1.5 MeV
The ability to separate gamma ray and neutron counts will produce a similar amount of light as the 4.78
is important to consider for each detector MeV reaction products. Coupled with the Li-6 being
configuration scheme, not just the Q value of the employed in a solid glass matrix rather than a gas, it
neutron reaction as compared to energy deposited by results that Li-6 detectors are sensitive to both
incident photons. This is discussed next, for each neutrons and gamma rays. Light output is also
type. relatively low, for example about 15% of NaI(Tl) for
one glass type (Applied Scintillation Technologies,
Since He-3 is employed as a low-density gas 2009), and results in inherently low spectral
detector, gamma rays mainly interact in the wall of resolution. This eliminates the possibility for dual
the detector and produce electrons that enter the gas neutron-gamma spectroscopy; rather the goal is
region. However, the low gas density provides small simply to separate accurately the gamma ray and
stopping power to these electrons. They typically hit neutron spectral components. A Li-7 (Li-6 depleted)
the opposite wall of the detector while only detector can be used to measure only the gamma ray
depositing a fraction of their energy in the gas. This component. However, well logging tools generally
results in pulses that are much smaller than that from don’t allow for placing a second detector in a position
the triton and proton of the neutron reaction and where it measures the gamma ray background of the
allows for simple discrimination. He-3 tubes with a first detector accurately.
central anode are subject to harmonic vibration that
can create noise and interfere with the neutron signal, A number of references can be found on the
unless carefully designed and constructed. Also, properties of standard Li-6 glass types (Wraight, L.
when used in a high gamma ray flux environment, A., 1965; Zetterstrom, H. O., 1966; Spowart, A. R.,
such as with a PNG, the many low-voltage pulses 1970; Spowart, A. R., 1977; Ejik, C. W. E., 2002;
from gamma rays can pile up to overlap the neutron Applied Scintillation Technologies, 2009;). Li-6
signal. Typical He-3 detectors are on the order of one manufacturing has largely been a niche market, but
inch in diameter, a few atmospheres of pressure, and it's becoming popular again due to the He-3 shortage
are >95% efficient for thermal neutrons. and new vendors with new glass mixtures are
becoming available.
B-10 is typically employed as a gas (BF3) or within a
thin solid layer. As a gas-filled detector, the gamma Processing of Li-6 Spectra
ray separation properties are the same as discussed
for He-3. As a thin layer solid, gamma rays largely The main issue to tackle with Li-6 data, once
pass through without interaction. Any electrons obtained, is how to precisely separate the neutron
produced will have a mean free path length longer counts from the photon background in wide ranging
than the much more massive reaction products and environments. Also, optimizing Li-6 detector
they tend to escape the active volume. B-10 lined construction is vital to maximize the light collection
tubes will lose about half their efficiency due to one from the neutron interactions so as to increase
side of the layer facing the detector wall, but newer separation of the neutron peak above the low-energy
geometric designs of sandwiches and straws are background. The latter item is proprietary and not
being explored. B-10 will also result in two neutron
3
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
covered in this paper, although it certainly affects the approaches is that the spectral shapes need not be
data quality obtainable. known precisely beforehand. This approach is built
upon the fact that the PNG provides high count rates
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
The basic components of a Li-6 neutron-gamma at the detectors, thus the spectral components need
spectrum are first, a low-resolution neutron peak and not be used for precise separation. Furthermore, the
second, a continuous gamma ray background. This is neutron count rates do not directly indicate porosity.
exemplified by Figure 3, and each component’s A transform of the near-to-far detector count rate
behavior is discussed next. ratio is performed to convert to limestone porosity
units. Precision is the utmost goal, because the tool
The neutron peak shape is well approximated by a calibration will eliminate minor systematic errors.
Gaussian for short scintillators, but longer Environmental corrections, such as lithology effect,
scintillators have a peak skewed to the right with a will also aid in reducing uncertainty.
high-end tail. This is caused by the increased light
absorption in longer detectors, i.e. a position sensitive Figure 3 illustrates the use of a linear background. Fit
detector has been created. Longer detectors are Point 1 is defined to be where the slope of the
required for PNG based tools since the long-space spectrum equals zero. Fit Point 2 can be defined by
detectors must be positioned farther from the source simply using a preset number of channels to the right
than AmBe based tools to maintain porosity of the peak, or as a function of the FWHM of the
sensitivity (Roberts, 2010; Gilchrist, 2011). Further, neutron peak. These two points form a linear line
the neutron peak shape is subject to change with under the neutron peak that is used to separate the
temperature as the light yield and absorption components, as shown in the figure.
properties of the glass change. Consistency of
manufactured glass batches also comes into play. Figure 4 illustrates the exponential background
method. Fit Region 1 is defined as a preset number of
The featureless gamma ray background extends channels extending to the left of the zero-slope point,
across the whole spectrum. Generally, the spectrum as found with the linear method. Fit Region 2 is
doesn’t exhibit peaks due to both the low resolution defined as a preset number of channels extending to
of the Li-6 glass and low efficiency for full-energy the right of Fit Point 2, described for the linear
deposition from high energy photons. The gamma ray method earlier. The exponential function is fit with a
background at higher energies is primarily due to least squares routine to both regions.
single event Compton scattering of much higher
energy photons then the energy deposited in the
detector. When a PNG is used, the inelastic and
capture gamma ray background present at a detector
will be larger than that of a typically smaller activity
AmBe. Consider that the relatively low energy
hydrogen capture gamma ray of 2.2 MeV, let alone
the myriad others, can be detected to the right of the
neutron peak, although the efficiency for this is low.
In order to minimize the background, the Li-6 glass
detector thickness needs to be optimized for neutron
detection, as discussed in a paper in the same
conference proceedings (Gilchrist, 2011).
4
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
Figure 6. 2D plot of Figure 5 in voltage (energy)
and time with count rate as the coloring.
the neutron count rate for the linear and exponential expected due to the higher neutron source energy
background subtraction methods overlaid on top of (longer Ls).
the raw detector spectra for the SS Li-6 detector. The
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
fifth track is the same format for the LS Li-6 detector. However, no corrections are applied to the data and
The sixth track shows the near-to-far ratio for both the PNG based Li-6 apparent limestone porosities are
linear and exponential methods. very comparable to the CN porosity in the clean
limestone depths of 1280 to 1315 ft. and 1320 to
Discussion 1330 ft.
The ratios of the linear and exponential method The response of any new PNG and Li-6 based tool
display a higher dynamic range for the former must closely emulate the response of preceding
method. Although not shown, the model and AmBe based tools. The resulting log indicates good
laboratory based ratio-to-porosity transforms exhibit correlation between the test article’s apparent neutron
the same trend of higher dynamic range for the linear porosity and a previous CN log using two different
method up to approximately 50 pu. gamma ray background subtraction methodologies.
The differences between the test article and CN data
highlight areas of improvement that need to be
addressed through porosity transforms,
environmental corrections, and possibly more
sophisticated background subtraction methods.
6
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
Improvements in Thermal Neutron Scintillation Petroleum Engineers, Paper 123593.
Detectors for Time-of-Flight Studies, Nuclear
Instruments and Methods, 33, 181-193. Ginhoven, R. V., Kouzes, R. L., Stephens, D. L.,
2009, Alternative Neutron Detector Technologies for
Zetterstrom, H. O., Schwarz, S., Stromberg, L. G., Homeland Security, PNNL-18471, Pacific Northwest
1966, Multiple Scattering of Fast Neutrons in 6Li- National Laboratory.
Glass Scintillators, Nuclear Instruments and
Methods, 42, 277-282. Kouzes, R. L., 2009, The 3He Supply Problem,
PNNL-18388, Pacific Northwest National
Spowart, A. R., 1970, Measurement of the Gamma Laboratory.
Sensitivity of Granular and Glass Neutron
Scintillators and Films, Nuclear Instruments and LANL, MCNP – A General Monte Carlo N-Particle
Methods, 82, 1-6. Transport Code – Version 5.1.40, 2009, Los Alamos
National Laboratory.
Spowart, A. R., 1977, Neutron Scintillating Glasses:
Part II, Nuclear Instruments and Methods, 140, 19- Xu, L., Schultz, W., Huiszoon, C., 2009, A
28. Comprehensive Investigation of Source Effects on
Neutron Porosity Response for Logging-While-
Mickael, M. W., Prati, E. J.,Gilchrist Jr, W. A., Drilling Measurements, paper P in 50th Annual
Koudelka, J. C., Oliver, D. W., 1994, A New Logging Symposium Transactions: Society of
Compensated Thermal Neutron Tool for Porosity Petrophysicists and Well Log Analysts.
Measurement: SPWLA 35th Annual Logging
Symposium, Paper I. Nuclear Regulatory Commission, 2010, The 2010
radiation source protection and security task force
Ejik, C. W. E., 2002, Neutron PSDs for the Next report, http://www.nrc.gov/security/byproduct/2010-
Generation of Spallation Neutron Sources, Nuclear task-force-report.pdf
Instruments and Methods in Physics Research A,
477, 383-390. Roberts, L., Kopal, M., 2010, Formation Absorption
Effects on LWD Pulsed Thermal-Neutron Porosity
Pemper, R., Sommer, A., Guo, P., Jacobi, D., Longo, Measurements, paper MM in 51st Annual Logging
J., Bliven, S., Rodriguez, E., Mendez, F., Han, X., Symposium Transactions: Society of Petrophysicists
2006, A New Pulsed Neutron Sonde for Derivation of and Well Log Analysts.
Formation Lithology and Mineralogy, Paper SPE
102770, Trans. SPE Annual Technical Conference Gilchrist Jr., W. A., Inanc, F., Roberts, L., 2011,
and Exhibition, San Antonio, TX. Nuclear Source Replacement – Promises and Pitfalls,
52nd Annual Logging Symposium Transactions:
Jacobi, D., Longo, J., Sommer, A., Pemper, R., 2007, Society of Petrophysicists and Well Log Analysts.
A Chemistry-Based Expert System for Mineral
Quantification of Sandstones, Paper 1.3.45, Trans. Baker Hughes Incorporated, 2011, LithoTrak Bulk
PETROTECH 7th International Oil & Gas Density & Neutron Porosity,
Conference and Exhibition, New Dehli, India. http://www.bakerhughes.com/products-and-
services/drilling-and-evaluation/formation-
Gilchrist Jr., W. A., 2008, Compensated Neutron Log evaluation/logging-while-drilling/lithotrak-bulk-
Response Issues – A Tutorial: SPWLA 49th Annual density-neutron-porosity
Logging Symposium, Paper S.
7
SPWLA 52nd Annual Logging Symposium, May 14-18, 2011
Downloaded from http://onepetro.org/SPWLAALS/proceedings-pdf/SPWLA11/All-SPWLA11/SPWLA-2011-III/1662479/spwla-2011-iii.pdf/1 by Shanghai Jiao Tong University, lei zhao on 26 December 2023
Anton Nikitin received his MS in Physics from
Moscow Institute of Physics and Technology,
Feyzi Inanc is a nuclear scientist at the Baker
department of General and Applied Physics, studying
Hughes Houston Technology Center. He earned a BS
consequences of the Chernobyl disaster and chemical
in metallurgical engineering followed by MS and
bonding in uranium compounds at Kurchatov
Ph.D. degrees in the nuclear engineering discipline
Institute, Moscow, Russia. He continued his
from Iowa State University in 1986 and 1989.
education in the USA and received a Ph.D. degree in
Following a postdoctoral position at the Iowa State
Applied Physics from Stanford University where he
studied different material research techniques based University, he worked as an assistant and associate
on the photon, electron and neutron interactions with professor at Marmara University from 1990 to 1995.
matter. He joined the Nuclear Center of Excellence at He later worked at Iowa State University as a
Drilling and Evaluation Research at Baker Hughes research scientist at the Center for Nondestructive
Evaluation from 1995 to 2007. He joined Baker
Houston Technology Center as scientist in March
Hughes in 2007 as a scientist. In his career, he has
2008. His main focus is the development of new
published more than 50 technical articles, had various
gamma ray and neutron detectors, pulsed neutron
software products licensed and has been granted
generator-based well logging tools and methods to
several patents with other patents pending. He
process nuclear spectroscopic data. He is a coauthor
received a distinguished service award from Marmara
of more than 15 publications in the area of
University and inventors award from Iowa State
spectroscopy, physical chemistry and material
science, including an invited talk at IEEE Nuclear University.
Science Symposium.
Figure 8. Travis County, TX test well data acquired with the 1 11/16 in. PNG test article with two Li-6 detectors.