NEET MAHA REVISION PYQs

Atomic Structure Practice Sheet

Chemistry

1. Which of the following is never true for cathode 7. Who modified Bohr's theory by introducing
rays? elliptical orbits for electron path?
(1) They possess kinetic energy (1) Hund (2) Thomson
(2) They are electromagnetic waves (3) Rutherford (4) Sommerfeld
(3) They produce heat
8. Bohr radius for the hydrogen atom (𝑛 = 1) is
(4) They produce mechanical pressure
approximately 0.530Å. The radius for the first
excited state ( 𝑛 = 2 ) is (in Å )
2. The energies 𝐸1 and 𝐸2 of two radiations are 25eV
(1) 0.13 (2) 1.06
and 50eV respectively. The relation between their
(3) 4.77 (4) 2.12
wavelengths, i.e. 𝜆1 and 𝜆2 will be
(1) 𝜆1 = 2𝜆2 (2) 𝜆1 = 4𝜆2 9. The radius of hydrogen atom in the ground state is
1
(3) 𝜆1 = 𝜆 (4) 𝜆1 = 𝜆2 0.53Å. The radius of Li2+ ion (at. no. = 3 ) in a
2 2
similar state is
3. The energy absorbed by each molecule (𝐴2 ) of a (1) 0.17Å (2) 0.53Å
substance is 4.4 × 10−19 J and bond energy per (3) 0.265Å (4) 1.06Å
molecule is 4.0 × 10−19 J. The kinetic energy of 10. When an electron of charge 𝑒 and mass 𝑚 moves
the molecule per atom will be with a velocity 𝑣 about the nuclear charge 𝑍𝑒 in
(1) 2.0 × 10−20 J (2) 2.2 × 10−18 J circular orbit of radius 𝑟, the potential energy of the
(3) 2.0 × 10−19 J (4) 4.0 × 10−20 electrons is given by
𝑍2𝑒 2 𝑍𝑒 2
(1) (2) –
4. The energy of second Bohr orbit of the hydrogen 𝑟 𝑟
𝑍𝑒 2 𝑚𝑣 2
atom is −328 kJ mol−1, hence the energy of fourth (3) (4)
𝑟 𝑟
Bohr orbit would be
(1) −41 kJ mol−1 11. If ionisation potential for hydrogen atom is 13.6eV,
(2) −1312 kJ mol−1 then ionisation potential for He+ will be
(3) −164 kJ mol−1 (1) 54.4eV (2) 6.8eV
(4) −82 kJ mol−1 (3) 13.6eV (4) 24.5eV

5. The frequency of radiation emitted when the 12. The energy of an electron in the nth Bohr orbit of
electron falls from 𝑛 = 4 to 𝑛 = 1 in a hydrogen hydrogen atom is
atom will be (Given ionisation energy of H = 13.6 13.6
(1) − 4 eV (2) − 3 eV
2.18 × 10−18 Jatom−1 and ℎ = 6.625 × 10−34 Js) n n
(1) 1.54 × 1015 s−1 13.6 13.6
(3) − 2 eV (4) − eV
(2) 1.03 × 1015 s−1 n n
(3) 3.08 × 1015 s−1
13. Which of the following statements do not form a
(4) 2.00 × 1015 s−1 part of Bohr's model of hydrogen atom?
(1) Energy of the electrons in the orbits are
6. In hydrogen atom, energy of first excited state is quantised
−3.4eV. Then, KE of same orbit of hydrogen atom (2) The electron in the orbit nearest the nucleus
is has the lowest energy
(1) +3.4eV (3) −13.6eV (3) Electrons revolve in different orbits around
(2) +6.8eV (4) +13.6eV the nucleus
(4) The position and velocity of electrons in the
orbit cannot be determined simultaneously
14. If 𝑟 is the radius of the first orbit, the radius of 𝑛th 22. Calculate the energy in joule corresponding to light
orbit of H-atom is given by of wavelength 45 nm (Planck's constant, ℎ =
(1) 𝑟𝑛2 (2) 𝑟𝑛 6.63 × 10−34 Js; speed of light, 𝑐 = 3 ×
(3) r/n (4) 𝑟 2 𝑛2 108 ms −1 ).
(1) 6.67 × 1015
15. The spectrum of helium is expected to be similar to (3) 4.42 × 10−15
that of (2) 6.67 × 1011
(1) H (2) Na (4) 4.42 × 10−18
+
(3) Li (4) He+
23. The value of Planck's constant is 6.63 × 10−34 Js.
16. A particular station of All India Radio, New Delhi, The speed of light is 3 × 1017 nm s −1 . Which
broadcasts on a frequency of 1,368kHz (kilohertz). value is closest to the wavelength in nanometer of
The wavelength of the electromagnetic radiation a quantum of light with frequency of 6 × 1015 s−1
emitted by the transmitter is ?
[Speed of light, 𝑐 = 3.0 × 108 ms−1] (1) 10 (2) 25
(1) 219.3 m (2) 219.2 m (3) 50 (4) 75
(3) 2192 m (4) 21.92 cm
24. The measurement of the electron position is
17. In hydrogen atom, the de-Broglie wavelength of an associated with an uncertainty in momentum,
electron in the second Bohr orbit is which is equal to 1 × 10−18 g cm s−1 . The
[Given that, Bohr radius, 𝑎0 = 52.9pm]
uncertainty in electron velocity is (mass of an
(1) 211.6pm (2) 211.6𝜋pm
electron is 9 × 10−28 g )
(3) 52.9𝜋pm (4) 105.8pm
(1) 1 × 109 cm s−1
18. Which one is the wrong statement? (2) 1 × 106 cm s−1
ℎ (3) 1 × 105 cm s−1
(1) de-Broglie's wavelength is given by 𝜆 = 𝑚𝑣,
(4) 1 × 1011 cm s −1
where
𝑚 = mass of the particle,
25. If uncertainty in position and momentum are equal,
𝑣 = group velocity of the particle
ℎ then uncertainty in velocity is
(2) The uncertainty principle is Δ𝐸 × Δ𝑡 ≥ 4𝜋 1 ℎ ℎ
(3) Half-filled and fully filled orbitals have (1) √ (2) √2𝜋
2𝑚 𝜋
greater stability due to greater exchange 1 ℎ ℎ
energy, greater symmetry and more balanced (3) √ (4) √𝜋
𝑚 𝜋
arrangement
(4) The energy of 2𝑠-orbital is less than the energy
26. Given, the mass of electron is 9.11 × 10−31 kg.
of 2𝑝-orbital in case of hydrogen like atoms
Planck's constant is 6.626 × 10−34 Js, the
19. How many electrons can fit in the orbital for which uncertainty involved in the measurement of
𝑛 = 3 and 𝑙 = 1 velocity within a distance of 0.1 A is
(1) 2 (2) 6
(3) 10 (4) 14 (1) 5.79 × 106 ms−1
(2) 5.79 × 107 ms−1
20. The number of 𝑑-electrons in Fe2+ (Z = 26) is not (3) 5.79 × 108 ms−1
equal to the number of electrons in which one of (4) 5.79 × 105 ms−1
the following?
(1) s-electrons in 𝑀𝑔(𝑍 = 12)
(2) p-electrons in Cl(𝑍 = 17) 27. The value of Planck's constant is 6.63 × 10−34 Js.
(3) 𝑑-electrons in Fe(𝑍 = 26) The velocity of light is 3.0 × 108 ms−1. Which
(4) p-electrons in Ne(𝑍 = 10) value is closest to the wavelength in nanometers of
21. The angular momentum of electrons in d orbital is a quantum of light with frequency of 8 × 1015 s−1
equal to ?
(1) 6 (1) 4 × 101
(2) 2
(2) 3 × 107
(3) 2 × 10−25
(3) 2 3
(4) 0 (4) 5 × 10−18
28. The energy of photon is given as : Δ𝐸 /atom = 34. In the photoelectron emission, the energy of the
3.03 × 10−19 J𝑎𝑡𝑜𝑚−1, then the wavelength (𝜆) emitted electron is
of the photon is (Given, ℎ (Planck's constant) = (1) greater than the incident photon
6.63 × 10−34 Js, c (velocity of light) = 3.00 × (2) same as that of the incident photon
108 ms −1 ) (3) smaller than the incident photon
(1) 6.56 nm (2) 65.6 nm (4) proportional to the intensity of incident photon
(3) 656 nm (4) 0.656 nm
35. The electron was shown experimentally to have
29. The de-Broglie wavelength of a particle with mass wave properties by
1 g and velocity 100 m/s is (1) de-Broglie
(2) N Bohr
(1) 6.63 × 10−33 m
(3) Davisson and Germer
(2) 6.63 × 10−34 m (4) Schrödinger
(3) 6.63 × 10−35 m
(4) 6.65 × 10−36 m 36. The number of angular nodes and radial nodes in 3
s orbital are
30. The uncertainty in momentum of an electron is (1) 0 and 2 , respectively
1 × 10−5 kg m/s. The uncertainty in its position (2) 1 and 0 , respectively
will be (Given, ℎ = 6.62 × 10−34 kg m2 /s ) (3) 3 and 0 , respectively
(1) 1.05 × 10−28 m (4) 0 and 1 , respectively
(2) 1.05 × 10−26 m
(3) 5.27 × 10−30 m 37. 4𝑑, 5𝑝, 5𝑓 and 6𝑝-orbitals are arranged in the order
of decreasing energy. The correct option is
(4) 5.25 × 10−28 m
(1) 6𝑝 > 5𝑓 > 5𝑝 > 4𝑑
(2) 5𝑝 > 5𝑓 > 4𝑑 > 5𝑝
31. The position of both, an electron and a helium atom (3) 5𝑓 > 6𝑝 > 4𝑑 > 5𝑝
is known within 1.0 mm. Further the momentum (4) 5𝑓 > 6𝑝 > 5𝑝 > 4𝑑
of the electron is known within 5.0 ×
10−26 kg ms−1 . The minimum uncertainty in the 38. Orbital having 3 angular nodes and 3 total nodes is
measurement of the momentum of the helium atom (1) 5𝑝 (2) 3𝑑
(3) 4𝑓 (4) 6𝑑
is
(1) 50 kg ms −1 39. Which one is a wrong statement?
(2) 80 kg ms −1 (1) The electronic configuration of N-atom is
(3) 80 × 10−25 kg ms−1
(4) 5.0 × 10−26 kg ms −1
(2) An orbital is designated by three quantum
32. The momentum of a particle having a de-Broglie numbers while an electron in an atom is
wavelength of 10−17 m is designated by four quantum numbers
(Given, ℎ = 6.625 × 10−34 Js ) (3) Total orbital angular momentum of electron in
(1) 3.3125 × 10−7 kg m s−1 's' orbital is equal to zero
(4) The value of mfor𝑧2 is zero
(2) 26.5 × 10−7 kg m s −1
(3) 6.625 × 10−17 kg m s−1 40. Two electrons occupying the same orbital are
(4) 13.25 × 10−17 kg m s−1 distinguished by
(1) Magnetic quantum number
33. Uncertainty in position of an electron (mass of an (2) Azimuthal quantum number
electron is = 9.1 × 10−28 g) moving with a (3) Spin quantum number
velocity of 3 × 104 cm/s accurate upto 0.001% (4) Principal quantum number
ℎ
will be (use in uncertainty expression where ℎ = 41. Which is the correct order of increasing energy of
4𝜋
−27 he listed orbitals in the atom of titanium?
6.626 × 10 erg s)
(1) 1.93 cm (2) 3.84 cm (1) 3𝑠4𝑠3𝑝3𝑑 (2) 4𝑠3𝑠3𝑝3𝑑
(3) 3𝑠3𝑝3𝑑4𝑠 (4) 3𝑠3𝑝4𝑠3𝑑
(3) 5.76 cm (4) 7.68 cm
 (3) (ii), (iv)and(v)
42. What is the maximum numbers of electrons that (4) (i)and (iii)
can be associated with the following set of quantum 49. The orientation of an atomic orbital is governed by
numbers? (1) azimuthal quantum number
𝑛 = 3, 𝑙 = 1 and 𝑚 = −1 (2) spin quantum number
(3) magnetic quantum number
(1) 10 (2) 6
(4) principal quantum number
(3) 4 (4) 2

43. Maximum number of electrons in a subshell with 50. The following quantum numbers are possible for
𝐼 = 3 and 𝑛 = 4 is how many orbital(s) 𝑛 = 3, 𝑙 = 2 and 𝑚 = +2 ?
(1) 14 (2) 16 (1) 1 (2) 2
(3) 10 (4) 12 (3) 3 (4) 4

44. The correct set of four quantum numbers for the 51. Which of the following configuration is correct for
valence electron of rubidium atom (at. no. = 37 )
is iron?
1 1 (1) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑5
(1) 5,1,1, + 2 (2) 6,0,0, + 2
1 1 (2) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 2 , 3𝑑5
(3) 5,0,0, + 2 (4) 5,1,0, + 2
(3) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 2 , 3𝑑7
(4) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑6 , 4𝑠 2
45. If 𝑛 = 6, the correct sequence for filling of
electrons will be
(1) ns ⟶ (𝑛 − 1)𝑑 ⟶ (𝑛 − 2)𝑓 ⟶ 𝑛𝑝 52. The electronic configuration of gadolinium (at. no,
(2) ns ⟶ (𝑛 − 2)𝑓 ⟶ 𝑛𝑝 ⟶ (𝑛 − 1)𝑑 = 64 ) is
(3) ns ⟶ 𝑛𝑝 ⟶ (𝑛 − 1)𝑑 ⟶ (𝑛 − 2)𝑓 (1) [𝑋𝑒]4𝑓 8 , 5𝑑9 , 6𝑠 2
(4) ns ⟶ (𝑛 − 2)𝑓 ⟶ (𝑛 − 1)𝑑 ⟶ 𝑛𝜌 (2) [𝑋𝑒]4𝑓 7 , 5𝑑1 , 6𝑠 2
(3) [Xe]4f 6 , 5𝑑2 , 6 s 2
46. Which of the following is not permissible
arrangement of electrons in an atom? (4) [Xe]4𝑓 3 , 5𝑑5 , 6𝑠 2
1
(1) 𝑛 = 4, 𝑙 = 0, 𝑚 = 0, 𝑠 = − 2
53. The orbitals are called degenerate when
1
(2) 𝑛 = 5, 𝑙 = 3, 𝑚 = 0, 𝑠 = +2 (1) they have the same wave functions
1 (2) they have the same wave functions but
(3) 𝑛 = 3, 𝑙 = 2, 𝑚 = −3, 𝑠 = − 2
(4) 𝑛 = 3, 𝑙 = 2, 𝑚 = −2, 𝑠 = −1/2 different energies
(3) they have different wave functions but same
47. Maximum number of electrons in a subshell of an energy
atom is determined by the following (4) they have the same energy
(1) 41 + 2 (2) 21 + 1
(3) 41 − 2 (4) 2𝑛2 1
54. If an electron has spin quantum number + 2 and
48. Consider the following sets of quantum numbers. magnetic quantum number -1 , it cannot be present
in
𝑛 1 𝑚 s (1) d-orbital (2) f-orbital
(3) p-orbital (4) s-orbital
(i) 3 0 0 +1/2
(ii) 2 2 1 +1/2 55. For which one of the following sets of four
quantum numbers, an electron will have the highest
(iii) 4 3 -2 −1/2 energy?
n l m s
(iv) 1 0 -1 −1/2 (1) 3 2 1 1/2
(v) 3 2 3 +1/2 (2) 4 2 –1 1/2
(3) 4 1 0 -1/2
Which of the following sets of quantum number is (4) 5 0 0 –1/2
not possible?
(1) (iii), (iii)and (iv) 56 Electronic configuration of calcium atom can be
(2) (i) (ii) (iii)and(iv) written as
 (1) [Ne]4𝑝2 (2) [Ar]4 s 2 61. The total number of electrons that can be
2
(3) [Ne]4 s (4) [Kr]4p2 accommodated in all the orbitals having principal
57. The electronic configuration of Cu(at. no. = 29) is
58. quantum number 2 and azimuthal quantum number
(1) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝8 , 4𝑠 2 , 3𝑑9 1 are
(2) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑10 , 4𝑠1 (1) 2 (2) 4
(3) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 2 4𝑝6,5𝑠 2 5𝑝1 (3) 6 (4) 8
(4) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 2 4𝑝6 , 3𝑑3
62. The maximum number of electrons in a subshell is
58. The order of filling of electrons in the orbitals of an given by the expression
atom will be (1) 4𝑙 − 2
(1) 3𝑑, 4𝑠, 40,4𝑑, 5 s (2) 4𝑙 + 2
(2) 4𝑠, 3𝑑, 4𝑝, 5𝑠, 4𝑑 (3) 2𝑙 + 2
(3) 5𝑠, 4𝑝, 3𝑑, 4𝑑, 5𝑠 (4) 2𝑛2
(4) 3𝑑, 4𝑝, 4𝑠, 4𝑑, 5 s
63. Number of unpaired electrons in N 2+ is/are
59. For azimuthal quantum number 𝑙 = 3, the (1) 2 (2) 0
maximum number of electrons will be (3) 1 (4) 3
(1) 2 (2) 6
(3) 0 (4) 14 64. The number of spherical nodes in 3p-orbital is/are
(1) one (2) three
60. In a given atom no two electrons can have the same (3) two (4) None of the above
values of all the four quantum numbers. This is
called
(1) Hund's rule
(2) Aufbau principle
(3) Uncertainty principle
(4) Pauli's exclusion principle
 Answer Key
1. (2) 34. (3)
2. (1) 35. (3)
3. (1) 36. (1)
4. (4) 37. (4)
5. (3) 38. (3)
6. (1) 39. (1)
7. (4) 40. (3)
8. (4) 41. (4)
9. (1) 42. (4)
10. (2) 43. (1)
11. (1) 44. (3)
12. (3) 45. (4)
13. (4) 46. (3)
14. (1) 47. (1)
15. (3) 48. (3)
16. (1)
49. (3)
17. (2)
50. (1)
18. (4)
19. (2) 51. (4)
20. (2) 52. (2)
21. (1) 53. (4)
22. (4) 54. (4)
23. (3) 55. (2)
24. (1) 56. (2)
25. (1)
57. (2)
26. (1)
58. (2)
27. (1)
59. (4)
28. (3)
60. (4)
29. (1)
61. (3)
30. (3)
62. (2)
31. (4)
63. (3)
32. (3)
64. (1)
33. (1)
 Hint and Solution
1. (2)
Cathode rays are not electromagnetic wave because 6. (1)
they do not have electric and magnetic components ∵ Total energy (𝐸𝑛 ) = KE + PE
perpendicular to each other. 1 𝑍𝑒 2
In first excited state = 2 𝑚𝑣 2 + [− 𝑟 ]
2. (1) 1 𝑍𝑒 2 𝑍𝑒 2
=+ −
𝐸1 = 25eV, 𝐸2 = 50eV 2 𝑟 𝑟
ℎ𝑐 ℎ𝑐 Energy of first excited state is 3.4eV
𝐸1 = and 𝐸2 = 1 𝑍𝑒 2
𝜆1 𝜆2 −3.4eV = −
E1  2 25  2 2 𝑟
or = ; or = 1 𝑍𝑒 2
E 2 1 50 1 ∴ KE = = +3.4eV
2 𝑟
or 1 = 2 2
7. (4)
3. (1) Sommerfeld modified Bohr's theory. According to
Kinetic energy (KE) of molecule him electrons move in elliptical orbits in addition
= energy absorbed by molecule to circular orbits.
– bond energy per molecule
= (4.4 × 10−19 ) − (4.0 × 10−19 )J 8. (4)
= 0.4 × 10−19 J 𝑟 ∝ 𝑛2 /𝑍
KE per atorn where, 𝑛 = number of orbit
0.4×10−19 𝑍 = atomic number
= 2
J = 2.0 × 10−20 J ∵ 𝑟1 ∝ 𝑛12
𝑟2 ∝ 𝑟22 (𝑍 = 1 for 𝐻-atom )
4. (4) 𝑟1 𝑛12
The energy of second Bohr orbit of hydrogen atom So. 𝑟2
= 𝑛22
(𝐸2 ) is −328 kJ mol−1 0.530 12
=
1312 𝑟2 22
𝐸𝑛 = − 𝑛2 kJ mol−1
∴ 𝑟2 = 0.530 × 4 = 2.120Å
1312
∴ 𝐸2 = − 2 kJ mol−1
2 9. (1)
If 𝑛 = 4 We know that 𝑟𝑛 (Hlike)
1312
∴ 𝐸4 = − 42 kJ mol−1 𝑟𝑛 (𝐻 − atom ) × 𝑛2
=
= −82 kJ mol−1 𝑍
For ground state, 𝑛 = 1
5. (3) 0.53Å × (1)2
(𝐿𝑖 2+ )
lonisation energy of H ∴ 𝑟𝑛 =
3
= 2.18 × 10−18 Jatom−1
∴ 𝐸1 ( Energy of Ist orbit of 𝐻-atom)
= −2.18 × 10−18 Jatom−1 10. (2)
−2.18 × 10−18 Potential energy = work done
∴ 𝐸𝑛 = Jatom−1 𝑟
𝑍𝑒 2 𝑑𝑟 𝑍𝑒 2
𝑛2 =∫ − = −
𝑍 = 1 for H-atom ∞ 𝑟2 𝑟
Δ𝐸 = 𝐸4 − 𝐸1 11. (1)
−2.18 × 10−18 −2.18 × 10−18 For hydrogen atom 𝑍 = 1
= −
42 12 2𝜋2 𝑚𝑒 4
1 1 ∴ lonisation energy, 𝐸𝐻 = 𝑛2 ℎ 2
= −2.18 × 10−18 × [ 2 − 2 ]
4 1
15 For He+ ion. (He+ = 1 s1 )
−18
Δ𝐸 = −2.18 × 10 ×−
16 so, (He+ = H) ionisation energy,
= +2.0437 × 10−18 Jatom−1
Δ𝐸 2𝜋 2 𝑚𝑒 4 𝑍 2
∴ v= 𝐸𝐻𝑒 =
h 𝑛2 ℎ2
2.0437 × 10−18 Jatom−1 Eq(i)/Eq(ii), we get
=
6.625 × 10−34 Js
= 3.084 × 1015 s–1 atm–1 𝐸He∗ = 𝐸𝐻 × 𝑍 2 = 13.6 × 4 = 54.4eV
12. (3) 17. (2)
Energy of an electron in an orbit. According to Bohr.
2𝜋 2 𝑚𝑒 4 𝑧 2 1311.8𝑧 2 𝑛ℎ
𝐸𝑛 = − = − kJ mol−1 𝑚𝑣𝑟 =
𝜋 2 𝑛2 𝑛2 2𝜋
21.8×10−12 𝑍2 𝑛ℎ ℎ
𝐸𝑛 = − erg atom −1 2𝜋𝑟 = 𝑚𝑣 = 𝑛𝜆 ...(i) [∵ 𝜆 = 𝑚𝑣]
𝑛2
21.8 × 10−19 𝑧 2 where, 𝑟 = radius,
𝐸𝑛 = − Jatom−1 𝜆 = wavelength
𝑛2
13.6𝑍2 −13.6 𝑛 = number of orbit
𝐸𝑛 = − 𝑛2
eV ⋅ atom−1 = 𝜋2
eV atom
𝑎0 𝑛 2
∵ 𝑍 = latomic number for hydrogen atom) Also, 𝑟 = 𝑍
where, 𝑎0 = Bohr radius = 52.9pm
13. (4)
𝑍 = atomic number
The main postulates of Bohr model of atom are
On substituting the value of ' 𝑟 ′ from Eq.
(i) The electrons in an atom revolve around the
(ii) to Eq. (i), we get
nucleus only in certain selected circular paths,
2𝜋𝑛2 𝑎0
called orbits. 𝑛𝜆 =
(ii) The energy is emitted or absorbed only when 𝑍
2𝜋𝑛𝑎0
the electrons jump from one energy level to 𝜆=
𝑍
another. 𝜆 = 2𝜋 × 2 × 52.9 [∵ 𝑛 = 2𝑍 = 1]
(iii) Only those orbits are permitted in which the = 211.6𝜋pm
angular momentum of the electron is a whole
number multiple of h/2π (where, h is Planck's 18. (4)
constant) that's why only certain fixed orbits (a) According to de-Broglie's equation.
are allowed, i.e. the momentum of an electron ℎ
Wavelength (𝜆) =
is quantised. 𝑚𝑣
where, ℎ = Planck's constant. Thus, statement (a)
14. (1)
is correct.
Radius of an orbit,
(b) According to Heisenberg uncertainty
𝑛2 ℎ2
𝑟𝑛 = 4𝜋2 𝑚𝑒 2 𝑍 principle, the uncertainties of position (Δ𝑥)
0.529𝑛2 and momentum (𝑝 = 𝑚Δ𝑣) are related as
= 𝐴
𝑍 ℎ
Δ𝑥 ⋅ Δ𝑝 ≥ 4𝜋
For H-atom, Z = 1
ℎ
If 𝑟1 = 𝑟 or, Δ𝑥 ⋅ 𝑚Δ𝑣 ≥ 4𝜋
(according to question 𝑟1 = 𝑟 ) ℎ
Δ𝑥. 𝑚 ⋅ Δ𝑎 ⋅ Δ𝑡 ≥ 4𝜋
𝑟×𝑛2
∴ 𝑟𝑛 = 1
= 𝑟𝑛2 Δ𝑣
[ Δ𝑡 = Δ𝑎, 𝑎 = acceleration ]
15. (3) ℎ
or, Δ𝑥 ⋅ 𝐹 ⋅ Δ𝑡 ≥ 4𝜋 [∵ 𝐹 = 𝑚 ⋅ Δ𝑎]
The spectrum of an atom depends on the number of ℎ
electrons present in it. Here, helium has two or, Δ𝐸 ⋅ Δ𝑡 ≥ 4𝜋
electrons, so the spectrum of Li+ (𝑍 = 3) is similar [∵ Δ𝐸 = 𝐹 ⋅ Δ𝑥, 𝐸 = energy ]
to that of helium because both Heand Li+have two Thus, statement (b) is correct.
electrons. (c) The half and fully fllled orbitais have
greater stability due to greater exchange
16. (1) energy, greater symmetry and more balanced
Frequency of electromagnetic radiation v arrangement. Thus statement (c) is correct.
= 1368kHz (d) For a single electronic species like 𝐻. energy
= 1368 × 103 s −1 depends on value of 𝑛 and does not depend
Speed of light, 𝑐 = 3 × 108 ms−1 onl. Hence energy of 2𝑠-orbital. and 2𝑝-
Wavelength of electromagnetic orbital is equal in case of hydrogen like
𝑐
radiation, 𝜆 = 𝑣 species.
3×108 ms−1 Therefore, statement (d) is incorrect.
𝜆= = 219.3 m
1368×103 s−1
19. (2) 24. (1)
According to Hund's rule of maximum multiplicity, Given. Δ𝑝 = 1 × 10−18 g cm s−1
An orbital can accommodate a maximum number (uncertainty in momentum)
of 2 electrons of exactly opposite spin. Hence, Mass = 9 × 10−28 g
Δ𝑝 = 𝑚Δ𝑣
option (a) is correct. −18
1 × 10 = 9 × 10−28 × Δ𝑣
Caution Remember, maximum number of
Δ𝑣 = 1 × 109 cm s −1
electrons in an orbital do not depend upon the
quantum numbers as given in the question. 25. (1)
According to Heisenberg's uncertainty principle
ℎ
20. (2) Δ𝑥 ⋅ Δ𝑝 =
4𝜋
Electronic configuration of Fe2+ is [Ar]3𝑑6 4 s0 . Given, Δ𝑥 = Δ𝑝(Δ𝑥 = uncertainty in position)
∴ Number of electrons = 6 ℎ
(Δ𝑝)2 = 4𝜋 (Δ𝑝 = 𝑚 × Δ𝑣)
Mg − 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 (6s electrons) ℎ
𝑚2 Δ𝑣 2 = 4𝜋 𝑚 = mass
It matches with the 6𝑑 electrons of Fe2+
Cl − 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝5 (11pelectrons) ℎ 1 ℎ
Δ𝑣 2 = ⇒ Δ𝑣 = √
It does not match with the 6𝑑 electrons of Fe2+ 𝑚2 4𝜋 2𝑚 𝜋
Fe − [Ar]3𝑑6 4𝑠 2 (6d electrons) (Δ𝑣 = uncertainty in velocity)
It matches with the 6𝑑 electrons of Fe2+ . Ne −
26. (1)
1𝑠 2 2𝑠 2 2𝑝6 (6pelectrons) It matches with the 6𝑑 By Heisenberg's uncertainty principle Δ𝑥 × Δ𝑝𝑥 ≥
electrons of Fe2+ . Hence, CI has 11 pelectrons ℎ ℎ ℎ
4𝜋
or Δ𝑥 × Δ(𝑚𝑣𝑥 ) ≥ 4𝜋 Δ𝑥 × Δ𝑣𝑥 ≥ 4𝜋𝑚
which does not matches in number with 6d
Δ𝑝 = uncertainty in momentum
electrons of Fe2+ . Δ𝑥 = uncertainty in position
Δ𝑣 = uncertainty in velocity
𝑚 = mass of particle
21. (1) Given that,
Angular momentum of electron in 𝑑-orbital is Δ𝑥 = 0.1Å = 0.1 × 10−10 m
ℎ 𝑚 = 9.11 × 10−31 kg
= √(1 + 1) ; for d-orbital, , 1 = 2
2𝜋 ℎ = Planck's constant = 6.626 × 10−34 Js
ℎ = √6ℎ 𝜋 = 3.14
Thus,
22. (4) 6.626 × 10−34
Δ𝑣 × 0.1 × 10−10 =
The wavelength of light is related to its energy by 4 × 3.14 × 9.11 × 10−31
ℎ𝑐 6.626 × 10−34
the equation, 𝐸 = 𝜆 . (𝐸 = ℎ𝑣) Given, 𝜆 = Δ𝑣 = ms −1
4 × 3.14 × 9.11 × 10−31 × 0.1 × 10−10
45 nm = 45 × 10−9 m = 5.785 × 106 ms −1
[∵ 1 nm = 10−9 m] = 5.79 × 106 ms−1
6.63×10−34 Js×3×108 m s−1
Hence, 𝐸 = 45×10−9 m 27. (1)
−18
= 4.42 × 10 J 𝑐 3×108 ms s−1
Hence, the energy corresponds to light of Frequency (𝑣) = =
𝜆 8×1015 s−1
wavelength 45 nm is 4.42 × 10−18 J. = 0.375 × 10−7 m
= 3.75 × 101 nm = 4 × 101 nm
23. (3)
Given. Planck's constant, 28. (3)
ℎ = 6.63 × 10−34 Js ℎ𝑐 𝑐
According to formula, 𝐸 = 𝜆 (𝑣 = 𝜆)
Speed of light, c = 3 × 1017 nm s−1
Energy 𝐸 = ℎ𝑣
Frequency of quantam light ℎ𝑐
𝑣 = 6 × 1015 s−1 3.03 × 10−19 =
𝜆
Wavelength, 𝜆 = ? 6.63 × 10−34 × 3.0 × 108
𝑐 𝑐
We know that, 𝑣 = or 𝜆 = 𝜆=
𝜆 𝑣 3.03 × 10−19
3 × 1017 = 6.56 × 10−7 m
=
6 × 1015 = 6.56 × 10−7 × 109 nm
= 0.5 × 102 nm = 50 nm = 6.56 × 102 nm
= 656 nm
29. (1) 33. (1)
ℎ According to Heisenberg's uncertainty principle
𝑝= ℎ
𝜆
Δ𝑥 × Δ𝑣 =
(de-Broglie equation) 4𝜋𝑚
ℎ Here, Δx = uncertainty in position
𝜆= Δ𝑣 = uncertainty in velocity
𝑚𝑣
(∵ 𝑝 = 𝑚𝑣) ℎ = Planck's constant (6.626 × 10−27 Js)
𝑚 = mass of electron (9.1 × 10−28 kg)
ℎ = 6.625 × 10−34
Here, Δ𝑣 = 0.001% of 3 × 104
= 6.63 × 10−34 kg/s 0.001
6.63 × 10−34 kg m2 /s = × 3 × 104 = 0.3 cm/s
𝜆= 100
10−3 kg × 100 m/s ℎ
∴ Δ𝑥 =
= 6.63 × 10−33 m 4𝜋mΔ𝑣
6.626 × 10−27
= = 1.93 cm
30. (3) 4 × 3.14 × 9.1 × 10−28 × 0.3
According to Heisenberg's uncertainty principle 34. (3)
ℎ In the photoelectric effect, the energy of the emitted
Δ𝑝 × Δ ×≥ electron is smaller than that of the incident photon
4𝜋
because some energy of photon is used to eject the
Uncertainty in momentum electron and remaining energy is used to increase
Δ𝑝 = 1 × 10−5 kg m/s the kinetic energy of ejected electron.
6.62×10−34
1 × 10−5 × Δ𝑥 = 22 (Given) 35. (3)
4× The wave nature of an electron is proved by
7

6.62 × 10−34 × 7 Davisson and Germer experiment. In this

Δ𝑥 = experiment the scattering pattern of an electron is
1 × 10−5 × 4 × 22 similar to that of 𝑋-rays.
= 5.265 × 10−30 m
36. (1)
For 3 -orbital, 𝑛 = 3,1 = 0
31. (4) Number of radial nodes
= (𝑛 − 1 − 1) = 3 − 0 − 1 = 2
By Heisenberg's uncertainty principle
Number of angular nodes = 1 = 0.
ℎ Hence, option (1) is correct.
Δ𝑥 × Δ𝑝 ≥
4𝜋
when the position of electron and helium atom is 37. (4)
The order of energy of orbitals can be calculated
same and momentum of electron is known within a from (𝑛 + 1) rule. The lower the value of (𝑛 + 1)
range. therefore the momentum of helium atom is for an orbital, lower is its energy. If two orbitals
have same (𝑛 + 1) value, the orbital with lower
also equal to the momentum of electron, i.e. value of 𝑛 has the lower energy.
5 × 10−26 kg m s−1 (i) 6𝑝 = 6 + 1 = 7
(ii) 5𝑓 = 5 + 3 = 8
(iii) 4𝑑 = 4 + 2 = 6
32. (3) (iv) 5𝑝 = 5 + 1 = 6
According to de-Broglie relation. ∴ The order of decreasing energy will be
ℎ ℎ
𝜆= =
𝑚𝑣 𝜌 38. (3)
where, 𝜆 = wavelength Angular node (1) = 3
ℎ = Planck's constant Total node = radial node + angular node
𝑝 = momentum 3 = (𝑛 − 1 − 1) + 1
Here, ℎ = 6.625 × 10−34 Js 3=𝑛−1
𝜆 = 10−17 m ⇒ 𝑛=4
ℎ 6.625 × 10−34 ∴ Orbital having 3 angular nodes and 3 total
∴ 𝑝= = nodes is = 𝑛𝑖 = 4𝑓[∵ 1 = 3 for 𝑓 − orbital]
𝜆 10−17
−34
= 6.625 × 10 × 1017
39. (1) 47.
According to Hund's rule the pairing of electrons in
the orbitals of a particular subshell does not takes
place until all the orbitals of a subshell are singly
occupied. Moreover, the singly orbitals must have
the electrons with parallel spin. i.e. 48.
∴ Option (1) is the incorrect option.
(1)
Total number of subshells = (21 + 1)
∴ Maximum number of electrons in the subshell
= 2(21 + 1) = 41 + 2
(3)
The value of I varies from 0 to (𝑛 − 1) and the
value of 𝑚 varies from -1 to +1 through zero.
1
The value of 's' ± 2 which signifies the spin of
electron. The correct sets of quantum number are
following

40. (3) 𝑛 1 𝑚 s
Two electrons occupying the same orbital has
equal spin but the directions of their spin are 1
(ii) 2 1 1 −
opposite. Hence, spin quantum number, 𝑠, 2
(represented +1/2 and −1/2) distinguishes them.
1
(iv) 1 0 0 −
41. (4) 2
According to Aufbau rule 1
3𝑠 < 3𝑝 < 4s < 3d (v) 3 2 2 +
2
42. (4)
The orbital of the electron having 𝑛 = 3. 1 = 1 and
𝑚 = −1 is 3𝑝2 (as 𝑛𝑚 ) and an orbital can have a 49. (3)
maximum number of two electrons with opposite The orientation of an atomic orbital is governed by
magnetic quantum number.
spins. ∴ 3𝑝𝑧 orbital contains only two electrons or
only 2 electrons are associated with 𝑛 = 3,1 =
50. (1)
1, 𝑚 = −1.
1
𝑛 = 3, 𝐼 = 2, 𝑚 = +2𝑠 = ±
43. (1) 2
These values of quantum numbers are possible for only
n represents the main energy level and I represents
one of the five
the subshell.
3𝑑-orbitals as +2 value of 𝑚 is possible only for
If 𝑛 = 4 and 𝐼 = 3, the subshell is 4𝑓. Inf-subshell,
one orbital.
there are 7 orbitals and each orbital can
accommodate a maximum number of two
electrons, so maximum number of electrons in 4𝑓
subshell = 7 × 2 = 14.
51. (4)
44. (3) Firstly the electrons are filled in increasing order of
1 energy and then rearrange the subshells in
37 Rb = 36 [Kr]5 s
increasing order as
Its valence electron is 5𝑠1 . 2 2 6 2 6 6 2
𝑛=5 26 Fe = 1𝑠 , 2𝑠 2𝑝 , 3𝑠 3𝑝 3𝑑 , 4𝑠

1 = 0 (For s-orbital)
1 52. (2)
𝑚 = 0 ( As 𝑚 = −1 to +1) 𝑠 = + 2 𝐺𝑑64 = 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑10
4𝑠 2 4𝑝6 4𝑑10 4𝑓 7 , 5𝑠 2 5𝑝6 5𝑑1 , 6𝑠 2
45. (4) = [Xe]4𝑓 7 , 5𝑑1 , 6𝑠 2
6𝑠 → 4𝑓 → 5𝑑 → 6𝑝 for 𝑛 = 6
53. (4)
46. (3) The orbitals having the same energy energy but
If 𝑛 = 3, different in orientation, are called degenerate
𝐼 = 0 to (3 − 1) = 0,1.2 orbitals. e.g.3d-orbital, 𝑙 = 2, 𝑚 = −2 − 1,0, +1,
𝑚 = −1 to + 1 = −2 − 1,0, +1 + 2 +2 , i.e. there are five different orientations
1
𝑠 = ±2 represented by 𝑑𝑥𝑦 . 𝑑𝑦 2 , 𝑑𝑧𝑥 ′ 𝑑𝑥2 −𝑦2 and 𝑑𝑧2 .
Therefore, option (3) is not a permissible set of
quantum numbers.
54. (4) 59. (4)
Spatial orientation of the orbital with respect to When azimuthal quantum number is 3
standard set of cordinate axis. Magnetic quantum 𝑚 = (21 + 1)
number -1 is possible only when the azimuthal 𝑙 =3
quantum number have value 𝐼 = 1, which is 𝑚 = (2 × 3 + 1)
possible for 𝑝. 𝑑 and 𝑓-subshells but not for 𝑠- = 7 orbitals
subshell because the value of 𝐼 for 𝑠-subshell is then total values of 𝑚 = (2 × 3 + 1) = 7 orbitals.
zero.
We know that, one orbital contains two electrons.
55. (2) Hence, total number of electrons = 7 × 2 = 14.
For 𝑛 = 3,1 = 2 the subshell is 3𝑑(𝑛 + 1 = 5)
𝑛 = 4,1 = 2 the subshell is 4𝑑(𝑛 + 1 = 6) 60. (4)
𝑛 = 4,1 = 1 the subshell is 4𝑝(𝑛 + 1 = 5) According, to Pauli's exclusion principle "no two
𝑛 = 5, 𝑙 = 0, the subshell is 5𝑠(𝑛 + 𝑙 = 5) electrons in an atom can have the same values of
According to (𝑛 + 1) rule greater the (𝑛 + 1) value, all the four quantum numbers."
greater the energy that is 6 .
In 1𝑠 2
1
56. (2) for I electron 𝑛 = 1,1 = 0, 𝑚 = 0, 𝑠 = +
2
To write the electronic configuration of an atom, it for 1 electron 𝑛 = 1,
is better if we remember the atomic number of 1
noble gases and the orbitals follow the noble gas. 𝑙 = 0, 𝑚 = 0, 𝑠 = −
The atomic number of Ca is 20 and its nearest noble 2
gas is argon (Ar = 18). It means if the values of 𝑛, 1, and 𝑚 are same, then
the value of spin quantum number must be
57. (2) different, i.e. +𝑉2 and −1/2.
The electronic configuration of Cu(29) is an
exceptional case due to exchange of energy and 61. (3)
symmetrical distribution of electrons in orbital to When 𝑛 = 2 and 𝑙 = 1, then subshell is 2𝑝.
acquire more stability.
The number of orbitals in p-subshell
= (21 + 1) = (2 × 1 + 1)
=3
Total (maximum) number of electrons = 2 ×
number of orbitals
=2×3=6
58. (2) (as each orbital contains 2 electrons)
The sequence of energy level can be remembered
by the systematic diagram as shown below
62. (2)
The number of orbitals in a subshell = (21 + 1)
where, 𝐼 = azimuthal quantum number Since, each
orbital contains maximum two electrons, the
number of electrons in any subshel
= 2 × number of orbitals
= 2(21 + 1)
= 41 + 2

63. (3)
The electronic configuration of

Hence, the correct order is Hence, the number of unpaired electron in N 2+ is 1

1s, 2𝑠, 2𝑝, 3𝑠, 3𝑝, 4𝑠, 3𝑑, 4𝑝, 5𝑠, 4𝑑, 5𝑝, 4𝑓.
5𝑑, 6𝑝, 7𝑠 …..
64. (1)
The number of spherical nodes in any orbital (=
𝑛 − 1 − 1)
For 3 -orbital, 𝑛 = 3 and 𝑙 = 1
∴ Number of spherical nodes = 𝑛 − 1 − 1
=3−1−1
= 3 − 2 = 1 node

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