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OR AT 02 23 - Answers - A
OR AT 02 23 - Answers - A
So lut io ns
Q1. (B)
For perfectly reflecting mirror, the force exerted by the light of power is
For equilibrium
Power
As only 30% of the power is given to the mirror
So
Q2. (A)
Q3. (D )
From moseley's law
for line
On solving
Q4. (C)
Since is increasing in case (i), but it is not changing in case (ii). Hence, in the first
case de-Broglie wavelength will change, but it second case, it remain the same
Q5. (A)
Q6. (A)
Q7. (B)
Q8. (D )
Q9. (A)
Let
Q10. (D )
For first minima,
First secondary maxima will be at
Q11. (C)
Now
Q12. (C)
from one side
Total
Q13. (A)
Q14. (D )
leaked
Q15. (A)
Q16. (B)
- -
- -
T he heat flow through is divided into two path and . Symmetry shows that no heat
will flow through . T herefore
Also we have
Q19. (D )
In case of minimum density of liquid, sphere will be floating while completely submerged
So
On solving
Q20. (C)
Velocity at ground (means zero height) is non-zero therefore one is incorrect and velocity versus
height is non-linear therefore two is also incorrect.
\(v\frac{dv}{dh}=2g= const.
const.
Here we can see slope is very high when velocity is low therefore at Maximum height the slope
should be very large which is in option 3 and as velocity increases slope must decreases there for
option 3 is correct.
Q21. 2.00
Q22. 24
Binding energy per nucleon is
For deuteron, atomic mass,
x = 24
Q23. 9.00
Fill the empty space with and charge density.
Q24. 3.00
Put values
Q25. 12.00
Q26. 660.00
Q27. 5.00
For cyclic process. Total work done
and (as constant)
From FLOT,
(Process is cyclic)
Q28. 171.00
or
Q29. 40.00
Q30. 160.00
Q31. (C)
(All are Paramagnetic.
Q32. (D )
Q33. (A)
T he standard state of carbon is graphite, hence II, IV are not correct. Equation I forms moles
of , and not from the standard state of its constituent elements either, and therefore that is
also not correct either. So, option III is the only correct option.
Q34. (B)
Q35. (A)
Q36. (A)
For adiabatic process
According the question pressure is proportional to the cube of its absolute temperature hence
.
Q37. (C)
reacts with of
reacts with
Q38. (C)
T he electronic configuration of in and
are as follows:
in
in
in
and are strong ligands so, they induces pairing of electrons so, their complexes are
diamagnetic while, is a weak field ligand so, it does not induce the pairing of electrons so,
its complex is paramagnetic.
Q39. (A)
Mass of solvent
Molality
mol.wt.
Q40. (B)
molality
Q41. (B)
Q42. (C)
Q43. (B)
Hexose having different configuration after will give different osazone.
Q44. (B)
Q45. (C)
Note that here and are weak field ligands and hence pairing does not take place
whereas is a strong ligand
Q46. (D )
Here is in +2 oxidation state. T herefore, as it comes in the same group as it's electronic
configuration is in state. It forms inner spin complex as is a strong ligand, and has
one empty d orbital, giving hybridization which gives a square planar geometry
Q47. (B)
From the final product, we can deduce that if a carbocation is formed at the secondary carbon,
can attack the carbocation to give the markonikov product.
A markonikov reaction can be obtained by treating corresponding alkene
with HBr.
T hus, reagents required would be:
1. Conc. alc at which will bring about dehydrohalogenation.
2. HBr at brings about Markovniokov's addition such that bromine attacks the carbocation to
give the final product.
Q48. (A)
T he correct name for should have been sodium
(tetraacetatoethylenediamine) chromate(II).
T he difference here lies in the fact that the name of the ligands are written in alphabetical order
and therefore, acetate should come before ethylenediamine.
Q49. (B)
Use sequence rule or CIP rule
Q50. (C)
Q51. 60.00
of
of
of
Q52. 8.00
at equilibrium
At equilibrium
Q55. 12.00
Q56. 3.00
Q57. 40.00
In the mixture of and
only is oxidisable
moles of
Q58. 6.00
Q59. 6.00
Q60. 5.00
Q62. (C)
So,
let
Q63. (A)
Put
(i)
(ii)
(iii)
(iv)
Add all the equation we get
Q64. (C)
g(x)=2\ln^2-2\ln x-1
Q66. (C)
Q67. (B)
Let,
Let,
I.F.
Let,
Q68. (A)
sum
|sum|
Q69. (D )
Q70. (A)
Total ways
Fav. cases
Q71. (C)
Required probability
Q72. (B)
Q73. (B)
Q74. (B)
put
Q75. (C)
Image of point
Q76. (C)
(tangent at
(tangent at
(for common tangent )
Q77. (C)
We have upto
Q78. (B)
G iven relation,
Let and
Let
and
, but we can not say that , so
is not transitive.
Hence, option (B) is correct.
Q79. (B)
No. of intersection of line-line:
No. of intersection of circle-circle:
No. of intersection of line-circle:
Maximum no. of points of intersection:
Q80. (D )
Now,
Q81. 4.00
(i)
(ii)
&
Q82. 2.00
discontinuous at
Q83. 54.00
in
in
in
Q84. 2.00
Put x^3+3x+6=t^3
Q85. 3.00
Required area
square unit
Q86. 2008.00
Q87. 8.00
Q88. 126.00
(i)
Now,
(ii)
(from (i) & (ii))
So, .
Q89. 4
= = , = =
In , we have
+ =
= = = ]
=2 =2( - )
+ + = - +2
Q90. 8
Here,
Now,
G iven,
Hence .