(1001CJA102121087) Test Pattern

CLASSROOM CONTACT PROGRAMME

JEE (Advanced)
FULL SYLLABUS
(Academic Session : 2021 - 2022) 24-02-2022

JEE(Main + Advanced) : ENTHUSIAST COURSE : (SCORE-I)

ANSWER KEY PAPER-1
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8
SECTION-I
A. B,C A,B A,D A,C,D A,B,C,D A,C A,C A,B,C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 4 9 2 6 4 5 2 3
Q. 1 2
SECTION-IV  
A. A->PRT,B->PQ,C->S,D->P A->P,B->R,C->Q,D->R

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8
SECTION-I
A. B,C,D A,B,C A,C A,C,D A,B,C,D A,B,C,D B,C,D A,C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 16 5 3 5 415 19 10 6
Q. 1 2
SECTION-IV  
A. A->PR,B->RS,C->RS,D->QRT A->RT,B->RT,C->QRS,D->QRS

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8
SECTION-I
A. A B,C,D A,C,D C,D A,C,D A,B,C,D A,B,C,D B,D
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 4 2 54 8 4 2 6 100
Q. 1 2
SECTION-IV  
A. A->PR,B->Q,C->PQR,D->PQRST A->S,B->P,C->PQRST,D->RST

HINT – SHEET
PART-1 : PHYSICS 2. Ans ( A,B )
SECTION-I
For points r > R, it will act as a point charge 

1
    ⇒ E∝

1. Ans ( B,C ) r2
for r < R, E ∝ ∫ f (r) dr ∝ r2

3. Ans ( A,D )

Power radiaties by sphere = eσAT4

    

Power ∝ T4

intensity at point B = 
power radiated by sphere

4πd 2 Since, all capacitor are same,

1 ∴ V2 = 3V

I∝
d2 After K, is opened battery is out of circuit 

∴ no charge can flow through it.

1001CJA102121087 HS-1/7
 Target : JEE (Main + Advanced) 2022/24-02-2022/Paper-1
4. Ans ( A,C,D ) 8. Ans ( A,B,C )
1 1
13.6z 2 [ 2
− ] = 204

1 2n) 2
(

1 1

13.6z 2 [ −
2
] = 40.8    

n2 ( 2n)
solving, n = 2, z = 4
5. Ans ( A,B,C,D ) µ0sin90° = µsin (90° = θ)

μ0 1 R
In standing wave energy is confined between μ= ==

cos θ cos θ R−y

node & antinode.
R R 1
at y = ; μ = = 2 ; cos θ =

2 R/2 2
Node and antinode do not transfer its energy
θ = 60°

but element between node & antinode transfers R ⃗  = ^i cos 60 ∘

+ j sin 60
^ ∘

its energy to other element. i

^
√
–
3^ 1
R ⃗  = + j  ; cos θ =

6. 2 2 μ
Ans ( A,C )
1 2
CB process is isothermal
cos θ = =
2.5 5
max

3P0V1 = 2P0V0
PART-1 : PHYSICS
2V0
V1 =
SECTION-II
3
BA process is adiabatic
1. Ans ( 4 )
2(2m 1 )m 1 4m 1
PVr = constant
T1 = g= g

3m 1 3
3P0V1r = P0V0r
2(4m 2 )(2m 2 ) 8
T2 = g = m 2 g

V2 6m 2 3
Workdone = nRT ℓn ( )
V1 ℓ 2ℓ
2T1 = 2T2 ( )

3 3
7. Ans ( A,C ) T1 = 2T2

1 sec 4m 1 8
Error in ΔT =  = 0.05 sec
g = 2 × m 2 g

20 3 3
−
−
ℓ ℓ m1 = 4m2
T = 2π√  ⇒g∝

g T2 2. Ans ( 9 )
Δg 2ΔT
Δℓ
⇒ = ±( )
+
g Tℓ
Δg 2 × 0.05 0

⇒ 100 × = ±( + ) × 100 = ±5%

g 2 1

2f f
α= ; a CM =

mR m
3f 2
a POC = = A(10) cos(10)t

m
for no slipping

100 A = 3µg = 9 ⇒ A = 9 cm
HS-2/7 1001CJA102121087
 Enthusiast Course/Score-I/24-02-2022/Paper-1
3. Ans ( 2 ) 6. Ans ( 5 )
In given circuit bulb D glow brightest

200)2
(
R=

100

200
i2 = ; Power in bulb D = i22R

4R
( )
3

1 2
mgy = ky + μmgy

2
1
⇒ mg =  ky + μmg
2
4. Ans ( 6 ) 200 2
2
4R 9 (200) 900
2T cos θ ⇒P = ( ) × = = W

Capillary height h =
3 16 200 2 ( ) 16
rρg 100
−−−−
⇒ h = 59.6 mm
2 −
− 2 900
⇒ √P = √ = 5
3 3 16
here 59.6 mm is greater than the protruding
7. Ans ( 2 )
part hence water will rise in the capillary of Consider a small area (shaded strip) 

insufficient height 25 mm.

here Eself = Gravitational field due to this strip 

2T and Eext = Gravitational field due to the rest of

Now,  R = = 0.6mm
hρg spherical shell.

5. Ans ( 4 ) Ein = Gravitational field just inside the strip 

i = 3 + 4 sin(ωt +
π
)
Eout = Gravitational field just outside the strip

3 Ein = Eext – Eself = 0

π
i2 = 9 + 16sin 16 (ωt + )  

3 ⇒ Eext = Eself 

π
+ 24 sin(ωt +
3
)  <i2>
Eout = Eext + Eself = GM2  ⇒ Eext =  GM2

R 2R
= 9 + 16 [1/2] + 24 [0]

1
= 9 + 16 ( ) = 17

2
= r.m.s. value = √−−
17

    

After the shaded area has been removed there is

no Eself and only Eext. 

GM
hence, Enet = Eext =   
2R 2

1001CJA102121087 HS-3/7
 Target : JEE (Main + Advanced) 2022/24-02-2022/Paper-1
8. Ans ( 3 ) PART-2 : CHEMISTRY
SECTION-II

2. Ans ( 5 )
Given : First order kinetics

            4A   →   B  +  2C

As the collision is elastic e = 1

t = 0    p0 = 800 of Hg

P P
12 + 0 = 6 + v
t = 10  800–P            

4 2
⇒ v = 6 m/s

            800–600

Now, VCOM (before) = VCOM (after)

            = 200 mm of Hg

12m −6m + 24
⇒ =
total pr. after 10 min.

m+4 m+4
4 P P
⇒ m = kg
= 800 − P + + = 650

3 4 2
P = 600 mm of Hg

12 × 43
∴ VCOM = = 3m/s 800 −−→ 400 −−→ 200         

4
+4 t1 t1
3 / 2 / 2

PART-1 : PHYSICS 2t1/2 = 10 min

t1/ 2 = 5 min

SECTION-IV
6. Ans ( 19 )
2. Ans ( A->P,B->R,C->Q,D->R )
(a) = KO2

Δx = S2P – S1P

(b) = K2[PtCl6]

S2P increases so Δx increase

(c) = MnO 4
−

ΔV
B=  does not change
(d) = O2
d
Central maxima will shift down word so net PART-2 : CHEMISTRY
fringe pattern shift downward.
SECTION-IV
PART-2 : CHEMISTRY
1. Ans ( A->PR,B->RS,C->RS,D->QRT )
SECTION-I
3. Ans ( A,C ) (A) 

The distance between nearest neighbours is

same in both forms means '2r' is same in both +

and hence the unit cell edge length, i.e., cell (B) Me–C≡C–CH2+ ↔  CH3 –C  =C=CH2

constant, a, is different in both.

4r 4r
aα = –  and aβ =  –

√ 3 √ 2
The distance between next nearest neighbours (C) 
in both form is 'a', which is different.

Void space in BCC = 32%, FCC = 26%

In both forms, the required diameter of largest

spheres = (a – 2r) and 'a' is different
5. Ans ( A,B,C,D )
Carbyl amine test is given by 1° amine both
aliphatic and aromatic.
HS-4/7 1001CJA102121087
 Enthusiast Course/Score-I/24-02-2022/Paper-1
PART-3 : MATHEMATICS 5. Ans ( A,C,D )
1 – 1 – 1
tan −
(√ 2 − 1) < tan −
(√ 3 − 1) < tan −
1

SECTION-I
π π π
1. Ans ( A ) ⇒ 4× < α < 4× ⇒ < α<π  

8 4 2
∣ 1 x x2 ∣ 1 2 3∣ 1 – 1 1 1 1
∣
Also,  tan −
(√ 2 − 1) < tan −

2
< tan −

–  

√3
∣ ∣ ∣ ∣

y2 ∣
∣ ∣ ∣ ∣
1 y 2 3 1 ∣ = 0
π π 4π
∣ ∣ ⇒ 8× < β < 8× ⇒π<β<  
∣ ∣ ∣ ∣ 8 6 3
∣ 1 z z2 ∣ ∣ 3 1 2∣
6. Ans ( A,B,C,D )
⇒ (x – y) (y – z) (z – x) = 0

2. Ans ( B,C,D )
The curve M is a circle of radius √–2 unit with
center at (1,1,1).

Point A is (2,0,1). And, line L is tangent to the

circle M at point A.
3. Ans ( A,C,D ) Let QA, QP and QB be in A.P.

y'sinx + ycosx = xsinx

⇒ 2QP = QA + QB

⇒ 2QP – 2QA = QB – QA

⇒ y' + ycotx = x ⇒ ysinx = ∫ x sin x dx + c  

⇒ 2AP = AB

⇒ ysinx = –xcosx + sinx + c 

⇒ P is the mid-point of chord AB

π
⇒ y = 1 – xcotx    (as y ( ) = 1) 
⇒ curve C1 and C2 are identical

2
Now, y'(x) = xcosec2x – cotx
Also, Let P(h,k)

π So, xh + 2yk = h2 + 2k2

=  x sin x2 cos x 2x sin2 2x

−
=
−
> 0 ∀x ∈ (0,
2
]  

sin x 2sin x
π ⇒ –2h = h2 + 2k2

Hence, y(x) is strictly increasing in (0,  

]
⇒ x2 + 2x + 2y2 = 0 
2
4. Ans ( C,D )
8. Ans ( B,D )
hℓn |h|
(A) Since lim  does not exist.

h→0 h π
      So, f(x) is not differentiable at x = 0
f'(x) = (esinx + e–sinx)cosx > 0 ; ∀ x ∈ [0, ] 

2
1
(B) g(x) =   
⇒ f(x) ∈  [0, e − ]  

e
      Hence, g(x) is not differentiable at x = 0
π π
Also, g(x) = (1 – cosx) ∈ [0,  

]
(C) f(g(x)) = (x{x} + 1) ln(x{x} + 1); as g(x) > 0
2 2
1
      =   
⇒ f(g(x)) ∈  [0, e − ]  

e
    At x = 0
f (x) e 2 sin x − 1
Now,   

e sin x π2 (1 − cos x)
lim = lim

    RHD = 0, LHD = 1
x→0 +
f (g) x→0 +

2 e 2 sin x − 1 2 sin x x2
= lim × × = ∞  

(D) f(g(x)) =   
π x→0 2 sin x
+
x2 1 − cos x

       At x = 1
π 1
Further, range of g(f(x)) is  0
[ ,
2
(1 − cos(e −
e
))]  

       RHD = 1 ≠ LHD
π π 1
and 0 < < (1 − cos(e − ))  
2 2 e
1001CJA102121087 HS-5/7
 Target : JEE (Main + Advanced) 2022/24-02-2022/Paper-1
PART-3 : MATHEMATICS 4. Ans ( 8 )
SECTION-II Let box dimension be ℓ × ℓ × h.

1. Ans ( 4 ) So, ℓ2h = 83

1
V = (ℓ + 4)2 (h + 4) – ℓ2h – (2ℓ2 + 4ℓh) ×  × 2

2
2 × 83 84
= 2 (ℓ2 + 16ℓ + + + 32)  

ℓ ℓ2

83 83 84
= 2 (ℓ2 + 8ℓ  + 8ℓ  + + + + 32)  ⩾

ℓ ℓ ℓ2
2 × (6 × 82 + 32)

(∵ A. M . ⩾ G. M .)

The required radius remains same

if we reflect our system about the line y = x.

Further, equality holds when ℓ = 8 

←→
P G  :-
i.e.  h = 8
y = mx – 2m – m3
5. Ans ( 4 )
⇒ G(m2 + 2, 0)

4sin4x + 4sin3x + 4sin2x = sin2x + sinx + 1

⇒ r = SG = m2 + 1

⇒ 4sin2x (sin2x + sinx + 1) = sin2x + sinx + 1

Also, PG = SG

1
⇒ 4 + 4m2 = (m2 + 1)2
⇒ sin x = ±
2
⇒ m2 + 1 = 4 = r
6. Ans ( 2 )
2. Ans ( 2 )
1 1 2x
Probality of success in a single round
tan −
( )
64 x+1
7 6 ∫ dx

1 7 1 1 π2 ( 2x) 2 + ( x + 1) 2
= 1 − (( ) + C 1( ) × )  
0
2 2 2 2x
1 1
tan −
( )
15 1 64 x+1 dx
=  1 − =
= ∫

16 16 π2
1 + ( x2x
2
(x + 1) 2
n 0 +1
)
1 255 1 1
Hence, 1 − ( ) ⩾ ⇒ ⩾  
1
16 256 162 16n 32 1 2x
2

⇒n≥2
= [( tan −
( )) ]

π2 x+1
0
3. Ans ( 54 ) 32 π2
= ( − 0) = 2
0 2 π2 16
∫ g ([x]) dx + ∫ g (x) dx

7. Ans ( 6 )
3
− 0
0 2 ∑ αj
| − α i | = 6|α2 – α1| + 6|α3 – α1| + 3|α4 – α1|

=∫ x
([ ] + 1) ([x] + 2) ([x] + 3) dx + ∫ (x + 1) (x + 2) (x + 3) dx 1⩽i<j⩽6
– –
3
−

1
0
= 6 × 1 + 6 × √3 + 3 × 2 = 6 (2 + √3)  
= 0 + ∫ (t + 2) (t + 3) (t + 4) dt      (put x – 1 = t)
8. Ans ( 100 )
− 1
1 x2 → (1 + 2x + x2)50 (1 – x)100

= ∫ (9t 2 + 24) dt = 2 (3 + 24) = 54 ⇒ x2 → (x + 1)100 (1 – x)100 = (1 – x2)100

1
⇒ k = –100
−

HS-6/7 1001CJA102121087
 Enthusiast Course/Score-I/24-02-2022/Paper-1
PART-3 : MATHEMATICS 2. Ans ( A->S,B->P,C->PQRST,D->RST )
SECTION-IV

1. Ans ( A->PR,B->Q,C->PQR,D->PQRST )
(A) Required  r^ is along  

i
^
+ j
^ ^
− + i
^
j
– +
– + k^

√ 2 √ 2
(as these three vectors are mutually
perpendicular unit vectors) 
(A)    Let bsinC + csinB = α              .... (i)

–^         we have bcosC + ccosB = a    .... (ii)

√ 2j + k^
    So,  r ^ = ±
–

√ 3         (i)2 + (ii)2 :-

    (B) f(x) = |x| – |x| – 1 = –1 

        b2 + c2 + 2bc cos(B – C) = a2 + α2

10 10
    (C)   S = ∑ r
( + 1)(r 2 − r + 1) = ∑ r 3 + 1)
(
        ⇒ α2 + a2 ≤ (b + c)2

r=1 r=1
n 3
n2 − n         ⇒ α2 ≤ (b + c)2 – a2 = (b + c + a)(b + c – a)

    (D)  S n = ∑ ( + r)
r=1
2
        ⇒ α2 ≤ (2S) 2(S – a)

–
Δ 4√3
        ⇒ α2 ≤  4 =
– = 4 

tan(A/2) √ 3
        ⇒ α ≤ 2 (equality holds when B = C)

B−C b−c A
(B)   tan( ) = cot

2 b+c 2
B−C A 1
        ⇒  tan( ) tan =

2 2 2
(C)   –
5 + 1] 

∣[
∣ a ⃗  b⃗  c ⃗ ]∣∣ = |2 sin 2θ + cos 2θ − 1| ∈ [0, √

2
x−y – x+y
(D)   ( – ) = √ 2( – )

√ 2 √ 2
        Require Area

        =  2 – 1 )+ π
(√ 2 ×
1
1×1 =
π 1
 
3 –
√2 4
−
2
×
4
+
6

1001CJA102121087 HS-7/7
(1001CJA102121086) Test Pattern

CLASSROOM CONTACT PROGRAMME

JEE (Main)
FULL SYLLABUS
(Academic Session : 2021 - 2022) 24-02-2022

JEE(Main + Advanced) : ENTHUSIAST COURSE : (SCORE-I)

ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C B B B A C C A C B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D D A B C D C B A A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 4.00 16.00 4.80 10.00 0.30 42.00 10.00 6.00 35.00 2.00

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. D D D B C C D C B B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. B C D B A C D D B C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 6.00 5.00 3.00 5.00 3.00 4.00 1.33 20.00 62.50 7.50

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C C D C D B A B B C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A C C B D D A C D A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 9.50 23.33 5.00 3.99 1.50 8.50 3.75 0.00 4.00 4.00

HINT – SHEET
PART-1 : PHYSICS The sphere may be assumed to be in pure
rotation about an axis through contact point P

SECTION-I
1. Ans ( C )
E = hv = 54.4 eV
Ionization energy of given atom = 4 × 13.6 = 54.4 eV

Hence electron will become free and no spectral lines

will be observed.
2. Ans ( B )
Mass of radius 
V R 15V
VCM = ω. (R + x) = (R + ) =
R M 4π R 3 M R 14 14
= × =

2 4π 3 4π 3
R 3 8 7 3. Ans ( B )
(
3
R −
3
×
8
)

M 8M Beat frequency Δf must be less than 1 in 10s.

Mass of complete sphere M + =

⇒ Δf < 0.1 Hz

7 7
Distance of COM from O = x
∴ Difference in frequencies of the two sources
M R R
x. M = . ∴x= is less than 0.1 Hz.

7 2 14
∴ 1023.9 Hz < fstring < 1024.1 Hz
1001CJA102121086 HS-1/9
 Target : JEE (Main + Advanced) 2022/24-02-2022/Paper-2
4. Ans ( B ) 7. Ans ( C )
−−−−−−−−
IBRB + VBE = 2V
I1 + I2
As VBE is negligible
T1 = 2π√     (i)

M1 + M2
2V 2V −−−−−−−−
∴ IB = = = 20μA     
I1 + I2
RB 100 kΩ and  T2 = 2π√  (ii)

M1 − M2
Collector current, IC = β IB = 50 × 20 µA = 1000µA
= 1mA
Using (i) and (ii)

Applying Kirchhoff's voltage law to the circuit M1 T22 + T12 42 + 32 25

= = =
DEN, we get,
M2 T22 −T
1
2
4 2
− 3 2 7
ICRC + VCE = 9
8. Ans ( A )
or  1 mA + 2kΩ + VCE = 9
Charges on two capacitors are

or  VCE = 9 – 2 = 7V qA = 100 × 3 = 300 µC

and qB = 180 × 2 = 360 µC

5. Ans ( A )

After the switch S is closed let charge q flow in

the circuit as shown in the figure.

Using Kirchhoff's voltage law we can write

Peq = 2PL + Pm
360 + q 300 + q
3 1 1 1 + = 100    

⇒ P eq = 2( − 1) ( − )−
2 3
2 ∞ −30 −30/2 ⇒ 360 × 3 + 3q + 600 + 2q = 600

1 2 1 1 1 ⇒ q = –216 µC

⇒ P eq = + = ⇒− = ⇒ f eq 10
= −
30 30 10 f eq 10
∴ Final charge on the two capacitors is

               

qA′ = 300 + q = 84 μC

i.e., it will behave as concave mirror of focal

q′ = 360 + q = 144 μC
length 10cm. To form real image of same side, B

object should be placed at center of curvature. 9. Ans ( C )

6. Ans ( C ) WB = Ucapacitor + Usurface energy

1
Let x, y and z direction be as shown.
⇒ Q. V = CV 2 + 2σA

2
VA – V0  = –Ex (1m)
CV 2
⇒ = 2σA

Ex = 1 V/m
2
VB – V0 = –Ex(3m) – Ey (2m) – Ez (1m)
4σA 4σd
⇒ V2 = × d=

–6 = –3Ex – 2Ey – Ez
ε0 εr ε0 εr
−−−−
2Ey + Ez = 3
σd
∴ V = 2√
And VC – V0 = –Ex (1m) – Ey (3m) – Ez (4m)
ε0 εr
–3 = –1 – 3Ey – 4Ez ⇒ 3Ey + 4Ez = 2
10. Ans ( B )
Solving (2) and (3)
IAcos2θ = IBcos2(90 – θ)

Ey = 2 V/m
IA 1
⇒ tan 2 θ = =

Ez = –1 V/m IB 3
∴ θ = 30°
HS-2/9 1001CJA102121086
 Enthusiast Course/Score-I/24-02-2022/Paper-2
11. Ans ( D ) 16. Ans ( D )
Distribute current using series parallel method. μ ⃗ = I A⃗ 
12. Ans ( D ) 17. Ans ( C )
Q = Q 0 cos ωt
Hint (QF) (B.W) = constant
i = Q 0 ω sin ωt

18. Ans ( B )
1 1
ω= −−− I = ∈ 0 E 02 C
√ LC 2
13. Ans ( A ) 19. Ans ( A )
W = Mg(h 1 + h 2 + h 3 ) + Mg(μ 1 ℓ1 + μ 2 ℓ2 + μ 3 ℓ3 ) L.C. =  0.5 mm

100
14. Ans ( B ) ΔY Δℓ Δd
2 = + 2

V Y ℓ d
H max =
Δℓ 0.005 1
2g = =

ℓ 0.25 50
15. Ans ( C ) Δd 2 × 0.005 1
2 = =
d 0.5 50
20. Ans ( A )
23T = Kx

K
K eq =

23
PART-1 : PHYSICS
SECTION-II
1. Ans ( 4.00 )
F.B.D. of first half of rod is

Q2
U1 =

2C

C = 4π ∈ 0 a

ΔH = U1 – U2
∵ m = ρAL

1 Q2 m
ΔH = .
∴T .a

=
4π ∈ 0 4a 2
ρAL
T= . a

2
T ρℓa
⇒ =

A 2
⇒ Stress = 10,000
2. Ans ( 16.00 )
∵ i = neAvd

i
⇒ vd =  ....(1)

neA
n
∵ n′ =

Q2 4
U2 =
A r
2C ′ A′ = { ∵ r′ = }

4π∈ 0 (2a) × a 4 2
C′ = i i
(2a − a) ∴ v′d = = 16. = 16vd
n A neA
4
. e. 4
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3. Ans ( 4.80 ) 6. Ans ( 42.00 )
1 1 1 7R
= +  
Q = nC P × 30 = n × × 30

t t1 t2 2
t1 t2 24 × 6 5R
or t = = = 4.8 h and Q = n × × ΔT

t1 + t2 24 + 6 2
7R 5R
4. Ans ( 10.00 ) ∴ n× × 30 = n × × ΔT

2 2
or  ΔT = 42 K
7. Ans ( 10.00 )
Tolerance value for silver = 10%
8. Ans ( 6.00 )

a sin θ = λ

⇒ a × sin 30° = λ

⇒ a = 2λ

a = 6Å
9. Ans ( 35.00 )
At 'O'

The number of nuclei present is given by N = 0.05N0

B = t (µ – 1)

ln N /N 0
At point P
N = N 0 e λt → t = −
−

λ
dx T1 2 ln N /N 0 8.0d) ln 0.05
Δ= − t(μ − 1) = 0     
/ (

D = − = − = 34.58d = 35d
0.693 0.693
dx
⇒ = t(μ − 1)     
10. Ans ( 2.00 )
D
D Voutput 1
⇒x= t(μ − 1)
=

d Vinput 5
0.5 × 1.5 × 10 3 −
100
= × (1.4 − 1)   
⇒ Voutput = = 20 volt

3 × 10 3 − 5
= 0.1 m
20
∴I = = 2A
10
= 10 cm
PART-2 : CHEMISTRY
5. Ans ( 0.30 )
Let ε is the emissivity of the sphere then by SECTION-I
Stefan's law.
1. Ans ( D )
E = εσA (T 4 − T04 )     
I 2 + H 2 O 2 + 2 Ō H → 2I −
+ 2H 2 O + O 2
or 210 = εσA(5004 − 3004 )  ..........(i)

5. Ans ( C )
When sphere is blackened, it behaves like a
4 BF 3 + 6H 2 O → 3HBF 4 + B(OH ) 3
perfectly blackbody, so we have-
oxyacid
700 = σA(5004 − 3004 )      ......(ii)

7. Ans ( D )
Dividing equation (i) and (ii), we get
Switzer's reagent [Cu(NH3)4]SO4

ε = 0.3 IUPAC name - tetraammine copper (II) sulphate

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8. Ans ( C ) 14. Ans ( B )
n N a 2C O 3 = M × v = 0.25 × 0.5 = 0.125
Milli equivalent of Na2C2O4 = Milli equivalent
n H 2 CO 3 = M × v = 0.25 × 0.5 = 0.125
of KMnO4 reacted.

             H 2 C O 3 + N a 2 C O 3 → 2NaHC O 3
Total milli equivalent of KMnO4 – Excess milli
t = 0      0.125 mol       0.125 mol
equivalent of KMnO4 reacted with H2C2O4.

t = t         0                       0                0.25 mol

= 45 × 0.02 × 5 – 10 × 0.1 × 2 = 2.5

w
∴ 1000 × × 2 = 25

NaHCO3 is Amphiprotic salt.

134
1 Ka ∴ w = 0.1675 gm

pH = (p 1 + p K a 2 )

2 ∴ % purity of Na2C2O4 in sample 

1
= (7 + 11)
0.1675
2 = × 100 = 83.75
0.2
 = 9
PART-2 : CHEMISTRY
9. Ans ( B )
ΔS o = S CoH − 2S Ho − S Co
SECTION-II
4 2

= 186.2 – 2 × 130.6 – 6
5. Ans ( 3.00 )
= – 81 J/K
gly–1, bcac–1, pn
ΔG° = ΔH° – TΔS° = –TΔSuni

6. Ans ( 4.00 )
–75000 – 300(–81) = –300 ΔSuni

Fe, Sn, Zn, Pb

∴ ΔS uni = 169
7. Ans ( 1.33 )
10. Ans ( B )
r +
126
= = 0.58

r −
216
Ag+ will occupy octahedral void.
 Bond order = 8/6 = 1.33 
a
So r + r =

+ −

2
a
126 + 216 =

2 8. Ans ( 20.00 )
∴ a = 684 pm a 2.5
TB = = = 500 K

Rb 0.08 × 0.0625
11. Ans ( B )
PV = nRT

1000 × K
λm =
2 × V = 1 × 0.08 × 500

M
1000 × R1 Aℓ ⇒ V = 20 L
=
9. Ans ( 62.50 )
M
1 2.5
1000 × 100
×
20/4
Coagulation value

=
No. of mil lim oles of electrolyte required
0.01 = 

–1
= 500  Ω cm mol . 2 –1 V olume of colloidal solution in L
20 × 0.25
12. Ans ( C ) =
3

80 × 10 −

Sum of stoichiometric coefficient of gaseous = 62.50

n 2n
product =  + = n
3 3
13. Ans ( D )
Rate of diffusion of NH3 will be faster than
HCl.

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10. Ans ( 7.50 ) 5. Ans ( D )
Exp (1) : r = K'[B]y as [A]0 > > [B]0
R = {(a, b) : a 4 − b4 ⩾ 0}

∵ r 7 8 = 3 × t1 2 ⇒ y = 1

/ / Let (a, a) ∈ R

Exp (2) : r = K"[A]x as [A]0 << [B]0

It is satisfying the relation condition

t7/8 = 7 × t1/2 ⇒ x = 2
It will be reflexive

1 Let (a, b) ∈ R ⇒ a 4 − b4 ⩾ 0

t1 2 = = 10 K" = K[B]0

K ′′ [A]
/

0         b4 − a 4 ⩽ 0 ∴ (b, a) ∉ R

1
∴ K ′′ =
It does not satisfy the symmetric relation
10 × 3
From Exp (2) and (3) 
condition.

1 1 Let (a, b) ∈ R and (b, c) ∈ R

t1 2 = =  

K ′′ [A] 0 K [B] 0 [A] 0

/

∴ a 4 b4 0  and  b4 c4 0 ⇒ a 4 c4
− ⩾ − 0

⩾ ( − ) ⩾

10 ∴ (a, c) ∈ R

∴a= = 2.5  and b = 7 × 2.5 = 17.5

2×2
It will be transitive relation.

PART-3 : MATHEMATICS
It is reflexive and transitive but not symmetric.
SECTION-I
6. Ans ( B )
1. Ans ( C ) {( ā × b̄) × ā } × b̄ + ā × { b̄ × (ā × b̄)}

z13 − 3z 1 z
2
2
+ 3iz 2 z
2
1
− iz
3
2
= 2 + 11i = [( ā . ā ) b̄ − (ā . b̄)ā ] × b̄ + ā × [( b̄. b̄)ā − (ā . b̄) b̄]
)3
(z1 + iz2 = 2 + 11i
= (− 2 (ā . b̄)) ā × b̄

Similarly (z1 – iz2)3 = 2 – 11i

= ( 2 (ā . b̄)) b̄ × ā
Multiply (z12 + z22 )3 = 4 + 121

2 3
(z + z ) = 125

2 7. Ans ( A )
1 2
− / 1 3 0
z12 + z22 = 5 1⎛ ⎞

⎜ ∫ (+ )1 dx + ∫ 1 dx⎟

(− )
2
2. Ans ( C ) ⎝
−10 − / 1 3 ⎠

x3 + 27cot3x + 9x2cotx + 27x cot2x = π3

1 1 3 0
(x + 3cotx)3 = π3
([x]
− /

10 x
−[ ]
1 3)

2 − − /

⇒ x + 3 cot x = π
14
=
π x 3
⇒ cot x = −  (Now graph)
3 3 8. Ans ( B )
3. Ans ( D ) Let p is the statement that a positive number is
Required probability
prime and q is the statement that number has no
1
5
×
1
5
divisor other than 1 and itself.
=
1 1 1 1 1 1 1 1 1 1

Contrapositive of P → q is –q → –P

( )+ ( )+ ( )+ × + ×
5 6 5 5 5 5 5 5 5 5
6
So contrapositive of the above statement is if a
=
29 positive integer has divisors other than 1 and
4. Ans ( C ) itself then it is not prime.
Line joining intersection point of tangents and
middle point of the line joining both the points
is parallel to axis of the parabola.

4−1
Midpoint (2, 4), slope of axis = 1 ,

2+1
slope of directrix = –1
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9. Ans ( B ) 12. Ans ( C )
xdy−ydx
1 x2 + 1
1 x2 sin −
( )  is defined for

(2xdx + 2ydy) + = 0
2x
2 1 + x2
y2
x2 + 1
1⩽ ⩽ 1 ⇒ x = 1, −1

1 y −
2x
D (x 2 + y2 ) + Dtan 1 ( ) = 0
−

2 x But square root is there so x = 1 is the only point.

x 2 + y2 1 y x
Hence,  + tan = C

Now log x
| |
 is defined for x ≠ 0 and

2 x [ ]+ 1
x
c − x 2 − y2 1 y [x] + 1 > 1

= tan
−

2 x [x] > 0

c − x 2 − y2
y = x tan( ) x ⩾ 1

2
So common domain is x = 1
10. Ans ( C )
13. Ans ( C )
∵ (tanA – tanB)2 + (tanB – tanC)2 + (tanC – tanA)2 > 0

2ae = 4 ⇒ ae = 2 ⇒ a2 – b2 = a2e2 = 4

2(tan2A + tan2B + tan2C) – 2(tanA tanB + tanB. tanC + 5 1

tanC.tanA) > 0
Also, p1p2 = b2  ⇒ b2 = (
2
–)( –) ⇒ b = 1

√5 √5

3K – (tanA.tanB.tanC)2 > 0
∴ a2 = 5

K > 48 ∴ a2 + b2 = 6
11. Ans ( A ) 14. Ans ( B )
Case (I)
n
b = a + (n − 1) d, c = (a + b)

2
(a − d) (a + b) 2 (a − b)
∴  d = ⇒d=
2 − nx

a + b − x ( a2 b ) +

⇒ 2d – ndx = –2(n – 1)d

⇒x=2
f(–1) > 0,       f(1) < 0          f(2) > 0

1–a–1 > 0     1 + a – 1 < 0  4 + 2a – 1 > 0

15. Ans ( D )
a < 0             a < 0              2a > –3
Tr+1 = 25Cr(ax1/2)25–r(bx–1/3)r
3
a < 0 since 'a' integer so a = –1
25
25−r r
C r a 25 r br x
− <
2 =
−
2
−
3

Case (II)
25 − r r
or  − = 0 ⇒ 75 − 3r = 2r ⇒ r = 15

2 3
Tr+1 = 25C15(a)10(b)15

Now, a > 0, b > 0 ∴ by AM ≥ GM

10a + 15b 1/25

⩾ ( a 10 b15)

f(–2) > 0,       f(–1) < 0        f(1) > 0

25
25
4–2a–1 > 0   1 – a – 1 < 0  1 + a – 1 > 0
1
or a 10 b15 ⩽ ( )

2a < 3           a > 0              a > 0

25
3 25
a<
25 1
∴ Tr 1 = C 10 ( )
2 + (max)
25
3
0<a< , since 'a' integer so a = 1
2

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16. Ans ( D ) 19. Ans ( D )
The series can be re-written as  adj(4adjA2) = 16adj(adjA2)
4 6 8
tan −1
2
( )+ tan −1
(
13
) + tan
− 1
(
73
) + tan
− 1
(
241
)... ∞ We know adj(adjA) = |A|(n–2) (A)

Hence the general term Tr

adj(adj|A|A2) = 16 × 4 × A2 = 64A2
1 2r 20. Ans ( A )
= tan −
( )

1 − r2 + r4 Equation of chord of contact w.r.t. P

n
1 2r xh + yk = 4    ...(1)

S∞ ∑ tan )

−
= lim (
n→∞ 1 − r2 + r4 Equation of common chord    

r=1
n r(r + 1) − r(r − 1)
1
S∞ = lim ∑ tan −
( )
n→∞ 1 + (r(r + 1)) (r(r − 1))
r=1
n
1 1
S∞ = lim∑ ( tan −
rr
( ( + 1)) − tan −
r r
( .( − 1)))
n→∞
r=1
1 1
S∞ = lim (
n→∞
tan −
n n + 1) − tan
( (
−
( ))0

π π
S∞ = − 0= λ − 2)x + (3λ + 1)y = −9     ...(2)

2 2 (

17. Ans ( A ) Compare (i) and (ii)

h k 4
Since point (–1, 1) lies on 3x – 2y + 5 = 0
= =

λ−2 3λ + 1)
( −9
⇒ locus of point is line perpendicular to

⇒ 27h − 9k = 28

3x – 2y + 5 = 0 and passing through (–1, 1)

∴ 27x – 9y = 28
18. Ans ( C )
4 PART-3 : MATHEMATICS
x 4x 3
g′ (x) = 2f ′ ( ).
′ 4 3
+ f (6 − x ) (−4x )
2 2 SECTION-II
4
x
= 4x 3 (f ′ ( )− f ′ (6 − x 4 ))
1. Ans ( 9.50 )
2 1 3
f (x) = (4x + x − 1) 

g ′ (x) should be negative for decreasing nature.

4
Two cases are possible
1 x 1
= (x − ) (x 2 + + )

x4 2 2 2
(i) x3 < 0 and f ′ ( ′ 4
) − f (6 − x ) > 0

2
x4
⇒ x < 0     f ′ ( ′ 4
) > f (6 − x )

2
But f ′′ (x) so f ′ (x) is decreasing

x4

< 6 − x4

2
1
x 4 (1 + ) < 6

2
3
x4 ( ) < 6

2
x 4 < 4 ⇒ (x 2 + 2)(x 2 − 2) < 0

– – –

−√ 2 < x < √2  x ∈ (−√2, 0)

x4
(ii) x3 > 0           f ′ ( ′ 4
) − f (6 − x ) < 0

1
1
19
2 = 1− ∫ 4x 3 + x − 1) dx =
(
– – 2 32
⇒ x > 0             ⇒ x ∈ (−∞, −√2) ∪ (√2, ∞)

1/2
So x ∈ (√–2, ∞)
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2. Ans ( 23.33 ) 5. Ans ( 1.50 )
For non trivial solution

∣ a + 2t b c ∣
∣ ∣
∣ ∣
Δ=
∣
b c + 2t a ∣
= 0

∣ ∣
∣ c a b + 2t ∣
Clearly Δ is cubic in t and has 3 roots K = 3
6. Ans ( 8.50 )
PQ is parallel to normal vector
ex 2
/

sin 3x + 3.ex 2
/
cos 3x
2
x−1 y+2 z−3 I = ∫ dx

= = = λ
5 + ex /2 sin 3x
1 −1 1
Take 5 + ex/2 sin3x = t

⇒ x = λ + 1, y = –2 – λ, z = 3 + λ

2 ex 2/

Mid point lies on plane ⇒ λ =

( sin 3x + 3.ex 2 cos 3x) dx = dt

3 2
5 8 11
−−
−
70 dt x 2 sin 3x| + C

Q( ,− , ) ⇒ OQ = √
I=∫ = ln |5 + e
/

3 3 3 3 t

3. Ans ( 5.00 ) Hence λ = 5, μ = 1  and γ = 3

2
7. Ans ( 3.75 )
x1 + x2 + x3 + x4 = 15, No. of ways = 18C3 

x1 + x2 + x3 + x4 = 10, No. of ways = 13C3 

x1 + x2 + x3 + x4 = 12, No. of ways = 15C3 

Total No. of ways = 18C3.13C3.15C3 ⇒ K = 3 

8. Ans ( 0.00 )
d 2y
p = 3, q = 2
For homogeneous equation = 0   at point
dx 2
p+q=5 lying on the curve.
4. Ans ( 3.99 ) 9. Ans ( 4.00 )
Σx i Let P(α, β) then

= 10 ⇒ Σx i = 200

20 α – β + 2 = 0

Σx 2i x2 y2
− 100 = 4

20 Equation of C.O.C for  − = 1

6 2
Σx 2i = 104 × 20 = 2080
α−x β y
200 − 9 + 11 202
is  − = 1

6 2
Actual mean = =

20 20 or αx – 3βy = 6

2
2080 − 81 + 121 202 or αx – 3(α + 2)y – 6 = 0
Variance = −( )

20 20 or α(x – 3y) – 6y – 6 = 0

2120 2 ∴ x = –3, y = –1

= − (10.1)

20 |x + y| = 4
= 106 – 102.01

= 3.99 10. Ans ( 4.00 )

11
x (1 − 2
cos x) + 92 sin x
λ= lim
3

x→0 sin x
Using series λ = 2

−−−− −
√ 2 −x 4
lim
– = 2
x→2 −−
√ −
−−
x +√
−−
−√ 2 x 2
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