(7501CJA101031230011) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

REVIEW TEST
(Academic Session : 2023 - 2024)
10-09-2023

JEE(Main + Advanced) : Leader (PHASE : 1&2)

Test Type : Unit Test # 01
ANSWER KEY PAPER-2
PHYSICS
Q. 1 2 3 4 5 6
SECTION-I
A. A,B,C,D A,B,C,D A,B,C A,B C,D B,D
Q. 1 2 3 4 5 6
SECTION-II
A. 0.25 1.00 4.00 3.00 5.00 0.60

Q. 1 2 3 4 5 6
SECTION-III
A. 5 6 6 5 9 4

CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I
A. A,B,D A,B,C A,B,D A,B,C A,B,C,D A,B,D
Q. 1 2 3 4 5 6
SECTION-II
A. 26.00 4.00 324.00 20.00 3 6
Q. 1 2 3 4 5 6
SECTION-III
A. 3 0 8 2 4 4

MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I
A. A,B,D A,C B,C,D B,C A,C,D B,C,D
Q. 1 2 3 4 5 6
SECTION-II
A. 60 4 13 253 8 50
Q. 1 2 3 4 5 6
SECTION-III
A. 2 9 1 2 1 2

HINT – SHEET

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PHYSICS 2. Ans ( A,B,C,D )
SECTION-I
Obviously FBD of upper ball as tension becomes
zero it looses contant, speed of lower ball
1. Ans ( A,B,C,D ) maximize.
f01 = 50 N; f02 = 100 N
f03 = 150 N; f04 = 0 N
If the system moves with no relative motion,
then common acceleration = 2m/s2
A : f1 = 20 N

(1) V ′ sinθ = V cosθ

f2 – 20 = 20 × 2 1 1
(2) mV 2 + mV ′2 = mg(ℓ − ℓ sin θ)
2 2
V 2 + V ′2 = 2gℓ(1 − sinθ)
V 2 + V 2 cot2 θ \; = 2gℓ(1 − sinθ)
f2 = 60 N
2gℓ(1 − sin θ)
100 – 20 – f3 = 30 × 2 V =√
cos ec2 θ
= sin θ√2gℓ(1 − sin θ)

For max: d sin2 θ(1 − sin θ) = 0

f3 = 20 N dθ
(1 − sin θ)(2 sin θ cos θ) + sin2 θ (− cos θ) = 0
2 cos θ(1 − sin θ) = sin θ cos θ
2(1 − sin θ) = sin θ
2
sin θ =
3
2√ 1
V = 2gℓ.
3 3
8gℓ 8gℓ 10gℓ
=√ &V′=√ \; × √ 5 \; = √

27 27 4 27
3. Ans ( A,B,C )

2mv0 = 2mv1 + mv2

1 v2 cos 30o − v1 cos 30o v2 − v1
e= = o =
2 v0 cos 30 v0

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4. Ans ( A,B ) 6. Ans ( B,D )
Q
∫ Px dt = mvx − mux Charge flown = ( Cε + ) − Q
2
⇒ ∫ Px dt = −mωR cos θ − (−mω0 R)....(1) Q
= (Cε − )
2
∫ Py dt = mvy − muy

⇒ ∫ Py dt = mωR sin θ ....(2)

Charge on the inner surface of left plate should

be C ε
2Q
If ε = then charge flow
C
Q 3Q
R cos θ ∫ Px dt − R sin θ ∫ Py dt = Iω − Iω0 .... Cε − =
2 2
(3) Work done = (charge flown) (emf) =
r−h 2 3q 2Q 3Q2
cos θ = ; I = MR2 ( )( ) =
r 5 2 C C
On solving eqn. (1), (2) and (3), we get
PHYSICS
(I + MR2 cos θ) 5h
ω = ω0 ⇒ ω = ω0 (1 − )
SECTION-II
I + MR2 7R
From conservation of energy 1. Ans ( 0.25 )
1 2 1
mv + I(ω)2min + 0 = 0 + mgh Initially
2 2
mg 5 mg
1 10 7 10gh P1 = P0 + =
⇒ ωf = √ gh ⇒ ω0 = √ A 2 A
R 7 7R − 5h 7 Finally
Mg 3 g
P2 = P0 − = ( m − M)
A 2 A
V
P1 = P2 V
2

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2. Ans ( 1.00 ) 2. Ans ( 6 )
Mg sin θ + T sin θ = Ma Assuming temperature remains constant at 300
K
From P1V1 = P2V2
V0 V0
P1 ( 2
) P ′1 ( 2
− Ax)
=
T T

( P ′1 − P ′2 ) A = mg
V0 V0
mg − T = ma sin θ ⎡ P1 ( 2
) P2 ( 2
) ⎤

⎢ − ⎥ A = mg
solving, we get ⎢
V0
− Ax
V0
+ Ax
⎥

⎣ ⎦
2 2
(M + m) g sin θ
a= 1 1
M + msin2 θ nRT [ − ] = mg
4−x 4+x
4. Ans ( 3.00 )
(0.1)(8.3)[ 4 + x − 4 2+ x ] = mg
VC = VR ⇒ 16 − x
CV (1 − e−t/RC ) 2x
V −t/RC 3( ) = 1
= (1 − e )R 16 − x2
C R 6x = 16 – x2
t = RC ℓ n2
x2 + 6x – 16 = 0
6. Ans ( 0.60 ) x=2
distance = 4 + 2 = 6m
PHYSICS 3. Ans ( 6 )
SECTION-III

1. Ans ( 5 )
About contact point with ground
Lfinal = 0
2 5v0
Linitial =mR 2 ω0 − mv0 R ; ω0 = or 3Q
5 2R V = E(2d) = 2d
5 × v0 A × ε0
ω0 = = 5 rad/sec
2 × (0.05)

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6. Ans ( 4 ) 2. Ans ( A,B,C )
N cos θ = mg | a = g tan θ Stability order ∝ Denticity of ligands ∝ Stronger
ligand ∝ Zeff value ∝ Oxidation state.
(A) Their formation of entropy decreases in the
same order because of denticity of ligand
decreases, Hence correct order.
(B) Zeff value decreases from Ir3 ⊕ to Co3 ⊕ .
Hence correct order.
(C) Oxidation state of Cr atom decreases from +3
dy to +1. Hence correct order.
N sin θ = ma | tan θ =
dx (D) Incorrect order;
y = x2 Strength of ligand CO > NH3 > H2O
dy
= 2x = 2 × 0.2 = 0.4 Correct order:
dx
a = 10 × 0.4 = 4 m/s2 [Cu(CO)4 ]2⊕ > [Cu(NH3 )4 ]2⊕ > [Cu(H2 O)4 ]2⊕

CHEMISTRY CHEMISTRY
SECTION-I SECTION-II

1. Ans ( A,B,D ) 1. Ans ( 26.00 )

(A) Na2[Fe(CN)5(NO)] NO is +1 electronic configuration of M3+ is [Ar] d5 i.e. M
2 = x – 5 + 1 = 0 ⇒ n = +2 → Correct will have e – configuration [Ar] d6s2 so metal is
Answer. (B) Co – ordination number = 2 Fe.
hybridisation = sp 2. Ans ( 4.00 )
so geometry is linear → Correct Answer.
(C) [Fe(H2O6]3 ⊕
Fe3 ⊕ = [Ar] 3d5
H2O is weak field ligand (WFL) so, back 4. Ans ( 20.00 )
D−d
pairing does not taken place herce hybridisation α=
d(n − 1)
is sp3d2. 60
−d
2
According to question option (C) is Incorrect. 0.5 =
d(2 − 1)
(D) [Ni(CO)4] , CO is neutral d = 20

n + 0 = 0 ⇒ x = 0 Correct Answer. 5. Ans ( 3 )

Chiral molecule /species : (Not containing POS)
[I, II, III] = 3
6. Ans ( 6 )
Compound with non zero tipole. [I, II, V, VII,
IX]

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CHEMISTRY MATHEMATICS
SECTION-III SECTION-I

2. Ans ( 0 ) 1. Ans ( A,B,D )

Bond order of CO+ is 3.5 f(x) + f (
2x
) = x ...(i)
All species have bond order less than '3.5' 3
3x
3. Ans ( 8 ) x→
2
(NH4)2CO3(s) ⇌ 2NH3(g) + CO2(g) + H2O(g) 3x 3x
f( ) + f (x) = ...(ii)
2 2
2p p p
2 eq. (ii) – eq.(i)
Kp = (2p) , p.p = 64 atm
3x 2x x
p = 2 atm f( ) − f ( ) =
2 3 2
ptotal = 2p + p + p = 8 atm 2x
x→
3
4. Ans ( 2 )
f(x) − f ( 4x
9
) =
x
3
⎫
⎪
⎪
Δ rH = ( – 110.5 – 241.8) – ( – 393.5 + 0) ⎪

⎬ on adding
= 41.2 kJ/mol ÷ 20.6 = 2 4x 16x 4x ⎪
f( 9
) −f( 81
) = 27
⎪
⎭
⎪

. ⋮ ⋮
n 2 3
2 1 2 1 2 1
f(x) − n→∞
lim f (( ) x) = x ( + ( ) ⋅ + ( ) ⋅
3 3 3 3 3 3
1
⎛ 3 ⎞ 3x
f(x) − f(0) = x 4
=
⎝ 1− ⎠ 5
9
3x
f(x) =
5

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2. Ans ( A,C ) 3. Ans ( B,C,D )
(A)
n
1 As f(x) = x3 + 3x + 2 ⇒ f ' (x) = 3x2 + 3
lim ∑
n→∞ (2r − 1) (2r + 1) 1
r=1
n
And g(f(x)) = x ⇒ g'(f(x)) =
1 (2r + 1) − (2r − 1) f ′ (x)
lim
n→∞
∑
1 1
2 r=1
(2r − 1) (2r + 1) So g ′ (2) = =
n f ′ (0) 3
1 1 1
lim ∑( − ) Also h(g(g(x))) = x ⇒ h(g(x)) = f(x) ⇒ h(x) =
n→∞ 2 r=1
2r − 1 2r + 1
f(f(x))
⇒ h(0) = f(f(0)) = f(2) = 8 + 6 + 2 = 16
1 1 1 1 1 1
= lim (1 − + − ....... − )
And h(g(3)) = f(3) = 27 + 9 + 2 = 38
n→∞ 2 3 3 5 2n − 1 2n + 1
1 1 1 1 and h'(1) = f'(f(1)) ∙ f '(1) = f '(6) ∙ f '(1) = 111.6
lim (1 − ) ⇒ (1 − 0) =
n→∞ 2 2n + 1 2 2 = 666
(B)
4. Ans ( B,C )
( 3x2 ) (4x2 ) − (2x − 1) (2x + 1) (3x2 + x + 2)
lim x
g(x) = 2f ( ) + f(1 − x) and
x→∞ 4x2 (2x + 1) 2
g ′ (x) = f ′ (x/2) − f ′ (1 − x)
12x4 − (12x4 + 4x3 + 8x2 − 3x2 − x − 2) Now, g(x) is increasing if g ′ (x) ⩾ 0
lim x
x→∞ 8x3 + 4x2 f′ ( ′
) ⩾ f (1 − x)
2
[∵ f ′′ (x) < 0 i.e. f ′ (x) is decreasing]
12x4 − (12x4 + 4x3 + 8x2 − 3x2 − x − 2) x
lim
x→∞
⇒ ⩽ 1 − x ⇒ x ⩽ 2 − 2x
8x3 + 4x2 2
3
−4x − 5x + x + 2 2 2
lim ⇒ 3x ⩽ 2 ⇒ x ⩽ 2/3 ⇒ 0 ⩽ x ⩽
x→∞ 8x3 + 4x2 3
⇒ g(x) increases in 0 ≤ x ≤ 2/3
x (−4 − 5x + 12 + 23 )
3
x x −4 and g ′ (x) ⩽ 0 for decreasing
lim ⇒
x→∞ 8 x x
x3 (8 + 4x ) ⇒ f′ ( ′
) ⩽ f (1 − x) ⇒ ⩾1−x
2 2
1
⇒− ⇒ x ≥ 2/3
2
1 (n (n + 1)) ⇒ 2/3 ≤ x ≤ 1
(C) lim
n→∞
n2 2
n (1 (1 + 1n ))
2
1
lim ⇒
n→∞ 2n2 2
(n + 2) (n + 1)! + (n + 1)!
(D) lim
n→∞ (n + 2) (n + 1)! − (n + 1)!
(n + 1)! (n + 2 + 1)
lim
n→∞ (n + 1)! (n + 2 − 1)
3
n (1 + n )
n+3
lim
n→∞ n + 1
⇒ lim
n→∞
=1
1
n (1 + n
)

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5. Ans ( A,C,D ) MATHEMATICS
LMVT on f(x) in [A, B] SECTION-II
f(B) − f(A)
= f ′ (C) 1. Ans ( 60 )
B−A
sin2 B − sin2 A distance = 300 km
⇒ = 2sinC cosC = sin2C
B−A speed = 'x' km/hr
∵ A < C < B ⇒ 2A < 2C < 2B
30 ≤ x ≤ 60
⇒ sin2A < sin2C < sin2B
fuel cost = 10/ ℓ
π
( ∵ sin x is increasing in x ∈ [0, ]) x2
2 consumed at rate of ( 2+ ) ℓ/hr
2 2 600
⇒ (B – A) sin 2A < sin B – sin A < (B – A)
300
sin2B Time = hr
x
Also 2A < 2B ⇒ cos 2A > cos2B 300 1200 + x2
∴ Total cost = (200 + ( 10))
(∵ cos x is derceasing fn) x 600
Now 300 13200 + x2
= ( )
x 60
13200
f(x) = 5 ( + x)
x
−13200
6. Ans ( B,C,D ) f ′ (x) = 5 ( + 1)
x2
− (1 + x) e−x − e−x x2 − 13200
f ′ (x) > 0 ⇒ >0 =5 ( )
(1 + x)2 x2
for x < −2 increasing

∴ f(x) will be min. at x = 60 ( ∵ 30 ⩽ x ⩽ 60

)
Most economical speed is 60 km/hr

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2. Ans ( 4 ) 3. Ans ( 13 )
x = y4 dy 2x
h>0; =
dy dy 1 dx 3y 2
1 = 4y 3 ⇒ = . . . (1)
dx dx 4y 3
xy = k
dy
y+x =0
dx 1
−y 1
dy 4 1 12

dx
= x x=y ⇒y=x = 4 (
16
)

∵ Slope of normal at P = MPQ

1
1
3 1
1
12
3y 2 ∣ h2 − 2
∴ m1 m2 = −1 k = xy = ( ) ( ) ⇒ − ∣ = ⇒
16 16 2x ∣P h3 − 13
5 3 h4 (h2 − 2)3
⇒
−y
= −1 k= 1 12 − . =
4y 3 x
(
16
)
2 h3 3h3 − 1
√13

5 P (1, 1), P Q = .
2 1 3 3
⇒ 1 = 4y x k= ( )
2

5
1 = 16y 4 x2 k3 = ( 12 )

1 = 16.x. x2 25 k3 = 1

1
x3 = 16
26 k3 = 2

1
1 3 3
x = ( 16 ) (4k) = 2

6
(4k) = 4

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4. Ans ( 253 ) 5. Ans ( 8 )
(i) f (x) = 2x3 − 21 x2 + 36 x − 20 f(0 + h) − f(0)
′ 2
lim = exist
∴ f (x) = 3x − 12 x + 9 h→0 h
a cosh +bh sinh +ceh − 2h
For local max. and local min. lim exists
h→0 h3 5
f ′ (x) = 0 or 3x2 − 12x + 9 = 0 h2 h h2
a (1 − + 5! +. . .) + c (1 + h + 2!
+. . .) − 2h
or 3 x2 − 4x + 3 = 0 or x2 − 4x + 3 = 0
( )
lim
3!

or (x − 1) (x − 3) = 0, ∴ x = 1, x = 3 h→0 h2
a c
(a + c) + (c − 2)h + h2 (− + + b) + h3 ( )+. . .
f ′′ (x) = 6x − 12 2 2
lim
at x = 1, f ′′ (x) = 6 × 1 − 12 = −6 < 0 negative h→0 h3
at x = 3, f ′′ (x) = 6 × 3 − 12 = 6 > 0 positive
so a + c = 0
∴ at x = 1, f (x) has maximum,
c–2=0
a c
f (1) = 1 − 6 + 9 + 7 = 11 − + +b=0
2 2
at x = 3, f (x) has minimum, a = – 2 b = – 2, c = 2
f (3) = 27 − 54 + 27 + 7 = 7 abc = 8
(ii) f (x) = 2x3 − 21x2 + 36x − 20 6. Ans ( 50 )
f ′ (x) = 6x2 − 42x + 36 = 6 (x2 − 7x + 6) 1 1
1
= 6 (x − 1) (x − 6) ∫ f(x) (x − f(x)) dx = ∫ x2 dx
4
For local max. and local min. 0 0
′ 1
f (x) = 0 ⇒ 6 (x − 1) (x − 6) = 0 x2
∴ x = 1, 6 ⇒∫ ( − xf(x) + (f(x))2 ) dx = 0
4
f ′′ (x) = 12x − 42 = 6 (2x − 7) 0
1
∴ f ′′ (1) = 6 (2 − 7) = −30 < 0 x 2
⇒∫ ( − f (x)) dx = 0
f ′′ (6) = 6 (12 − 7) = 30 > 0 2
0
∴ at x = 1 f (x) has local max and at x = 6 x 1
∴ f(x) = & 300 & ( ) = 50
there is local min, 2 3
Local max value
3 2
= f (1) = 2(1) − 21(1) + 36 (1) − 20
= 2 − 21 + 36 − 20 = −3
Local min value
= f (6) = 2 (216) − 21 (36) + 36 (6) − 20
= 432 − 756 + 216 − 20 = −128

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MATHEMATICS 3. Ans ( 1 )
p
1 x x x
SECTION-III e q = lim exp [1 + sin
( + sin + sin − 1])
x→0 x 2 2 2
23
1. Ans ( 2 ) 1 1 1 7
= exp( + 2 + 3 ) = e 8
⎧ −1 , −2 ⩽ x ⩽ 0 2 2 2
Given that, f (x) = ⎨
⎩ 4. Ans ( 2 )
(x − 1) , 0<x⩽2
Since, x ∈ [ – 2,2]. Therefore, |x| ∈ [0,2] At x = sin θ
f (x) = sin−1 (sin 3θ)
⇒ f(|x|) = |x| – 1, ∀ x ∈ [ – 2,2]
−π
⎧ x−1 , 0⩽x⩽2 if θ ∈ ( , π )
⇒ f (|x|) = ⎨ 2 2
⎩
−x − 1 , −2 ⩽ x ⩽ 0 −3π 3π
3θ ∈ ( , )

⎧ 1 , −2 ⩽ x < 0 2 2
⎪
⎪
⎪
⎪

Also, |f (x)| = ⎨ 1−x , 0⩽x<1

⎪
⎪
⎪
⎩
⎪
x−1 , 1⩽x⩽2
Also, g(x) = f(|x|) + |f(x)|
⎧
⎪
−x , −2 ⩽ x ⩽ 0
⎪
⎪
⎪

g (x) = ⎨ 0 , 0⩽x<1
⎪
⎪
⎪
⎩
⎪
2 (x − 1) , 1 ⩽ x ⩽ 2
⎧ −1 , −2 ⩽ x ⩽ 0
⎪
⎪
⎪
⎪

∴ g ′ (x) = ⎨ 0 , 0⩽x<1
⎪
⎪
5. Ans ( 1 )
⎪
⎩
⎪
2 , 1⩽x⩽2
⇒ g(x) is not differentiable at x = 0.
Hence, g(x) is differentiable for all x ∈ (2,2) –
{0,1}
2. Ans ( 9 )
No of solution = 1
2f(x + y) + f(x − y) = 3f(x) + 3f(y) + 2xy
f(0) = 0 6. Ans ( 2 )
2f(x + h) − 2f(x) f(x) = 30 − 2x − x3
f (x) = lim
h→0 2h f ′ (x) = −2 − 3x2 < 0 = 1 f(x) is ↓
3f(x) + 3f(h) + 2xh − f(x − h) − 2f(x) f (f (f (x))) > f (f (1 − x))
f ′ (x) = lim ( )
h→0 2h ⇒ f (f(x)) < f(1 − x)
f(x) − f(x − h) 3
= lim + f ′ (0) + x ⇒ f(x) > 1 − x
h→0 2(x − (x − h)) 2
′ (x) ⇒ 30 − 2x − x3 > 1 − x
f
f ′ (x) = + x ⇒ f ′ (x) = 2x ⇒ f(x) = x2 ⇒ x3 + x − 30 < 0
2
AltIer:- ⇒ (x − 3) (x2 + 3x + 10) < 0
(1) Replace y with x ⇒ x < 3 ⇒ n ∈ (−∞, 3)
(2) Replace y with -x no. of the integral ⇒ x = 1, 2
⇒ f (−x) = x2
⇒ f (x) = x2

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