Epsilon

Ramnagar Road 5 . Agartala .Tripura (west).

CLASS 11 - CHEMISTRY
ATOMIC STRUCTURE
Time Allowed: 45 minutes Maximum Marks: 60

1. The number of radial nodes for 3p orbital is ________. [1]

a) 1 b) 2

c) 4 d) 3
2. An atom of an element contains 29 electrons and 35 neutrons. The number of protons are: [1]

a) 35 b) 32

c) 30 d) 29
3. Among the following pairs of orbitals 2s and 3s, 4d and 4f, 3d and 3p, the orbitals that will [1]
experience the larger effective nuclear charge will be:

a) 2s, 4d and 3d respectively b) 2s, 4d and 3p respectively

c) 2s, 4f and 3d respectively d) 3s, 4f and 3d respectively

4. The wave character of electrons is used in the construction of [1]

a) fluorescence microscope b) compound microscope

c) electron microscope d) light microscope

5. 2 × 108 atoms of carbon are arranged side by side. Find the radius of carbon atom if the [1]
length of this arrangement is 2.4 cm.

a) 3.0 × 10-11 m b) 6.0 × 10-11 m

c) 1.2 × 10-11 m d) 5.7 × −11

10 m

6. Give the number of electrons in the species, O2 and O+

2
. [1]

a) 16 and 8 b) 16 and 14

c) 16 and 15 d) 32 and 16
7. Photoelectric effect established that light [1]

a) behaves like particles b) behaves like magnetic fields

c) behaves like waves d) behaves like rays

8. Total number of orbitals associated with third shell will be ________. [1]

a) 4 b) 3

c) 9 d) 2
9. Radio frequency region of the electromagnetic spectrum is used for broadcasting. It is [1]

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 a) Around 106 Hz b) Around 1015 Hz

c) Around 1013 Hz d) Around 1010 Hz

10. Correct expression for all series of lines in the hydrogen spectrum is (n1 = 1, 2, 3... and n2 = n1 [1]
+ 1, n1 +2, ... , and is the wavenumber)

a) ¯v
¯
¯
= 109, 677 (
1
−
1
) b) ¯v
¯
¯
= 109, 677 (
1
−
1
)
3 2 4 2
n1 n n n
2 1 2

c) ¯v
¯
¯
= 109, 677 (
1
−
1
) d) ¯v
¯
¯
= 109, 677 (
1
−
1
)
2 2 2 3
n n n n2
1 2 1

11. An element with mass number 81 contains 31.7 % more neutrons as compared to protons. [1]
Assign the atomic symbol.

a) 81
35
Cl b) 81
35
Ag

c) 81
35
S d) 81
35
Br

12. Isobars are the atoms with [1]

a) same atomic number but different b) same mass number but different
mass number atomic number

c) same number of neutrons but d) same atomic number but different

different mass number number of neutrons
13. Quantum mechanics is a theoretical science that deals with the study of the: [1]

a) motions of the microscopic objects b) motions of the macroscopic objects

that have only particle like that do not have both observable
properties wave-like and particle like
properties

c) motions of the microscopic objects d) motions of the macroscopic objects

that have both observable wave-like that have only particle like
and particle-like properties properties
14. Lines in the hydrogen spectrum which appear in the infrared region of the electromagnetic [1]
Spectrum, then they are called as

a) Balmer series b) Hydrogen line series

c) Hydrogen series d) Paschen series

15. Spin quantum number with two spin states of the electron represented by two arrows, ↑ (spin- [1]
up) and ↓ (spin down) was introduced to account for:

a) to account for uncertainty in b) the splitting of emission lines in an

electron states electric field

c) the splitting of emission lines in d) the splitting of emission lines in a

vacuum Magnetic field
16. What transition in the hydrogen spectrum would have the same wavelength as the Balmer [1]

transition n = 4 to n = 2 of He+ spectrum?

a) n = 2 to n = 1 b) n = 6 to n = 1

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 c) n = 4 to n = 1 d) n = 4 to n = 2
17. The orbital with n = 3 and l = 2 is [1]

a) 3p b) 3d

c) 3s d) 3f
18. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal [1]
quantum numbers, l = 1 and 2 are, respectively:

a) 12 and 4 b) 16 and 4

c) 12 and 5 d) 16 and 5
19. If travelling at same speeds, which of the following matter waves have the shortest [1]
wavelength?

a) Alpha particle (He2+) b) Proton

c) Neutron d) Electron
20. de-Broglie equation is [1]
hv mv
a) λ = m
b) λ = h

h
c) λ = hmv d) λ = mv

21. In an atom of sodium with atomic number 11 and mass number 23, the number of neutrons [1]
present is:

a) equal to the number of electrons b) greater than the number of protons

c) equal to the number of protons d) less than the number of protons

22. According to the Heisenberg uncertainty principle, in dealing with milligram-sized or heavier [1]
objects:

a) there are no uncertainties at all b) the associated uncertainties are

unacceptable

c) the associated uncertainties are d) the associated uncertainties are very

hardly of any real consequence important
23. According to Pauli’s exclusion principle: [1]

a) No two electrons in an atom can b) Any two electrons in an atom can

have the same set of four quantum have the same spin numbers
numbers

c) Any two electrons in an atom can d) All electrons in an atom can have the
have the same set of four quantum same spin numbers
numbers
24. For the electrons of oxygen atom, which of the following statements is correct? [1]

a) An electron in the 2s orbital has the b) The two electrons present in the 2s
same energy as an electron in the 2p orbital have spin quantum numbers
orbital. ms but of opposite sign.

c) d)

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 Zeff for an electron in a 2s orbital is Zeff for an electron in 1s orbital is the
the same as Zeff for an electron in a same as Zeff for an electron in a 2s

2p orbital. orbital.

25. Which of the following is responsible to rule out the existence of definite paths or trajectories [1]
of electrons?

a) Hund’s rule of maximum b) Aufbau principle.

multiplicity.

c) Heisenberg’s uncertainty principle d) Pauli’s exclusion principle.

26. Television pictures result due to [1]

a) fluorescence of canal rays on the b) fluorescence of cathode rays on the

television screen television screen

c) phosphorescence of protons on the d) fluorescence of protons on the

television screen television screen

27. The energy associated with the first orbit in the hydrogen atom is -2.18 × 10-18 J/atom. What is [1]
the energy associated with the fifth orbit?

a) -7.72 × 10-20 J/atom b) -5.72 × 10-20 J/atom

c) -3.72 × 10-20 J/atom d) -8.68 × 10-20 J/atom

28. The atom with the given atomic number Z = 17, and the atomic mass A = 35.5 is [1]

a) 35
17
Al b) 35
17
Mg

c) 35
17
Cl d) 35
17
Br

29. According to Heisenberg's Uncertainty Principle, the product of the uncertainties in the [1]
position and momentum of an electron is always:

a) greater than or equal to h/ 6π b) greater than or equal to h/4π .

c) greater than or equal to h/3π d) greater than or equal to h/2π

30. Number of angular nodes for 4d orbital is ________. [1]

a) 2 b) 1

c) 3 d) 4
31. One of the following scientists was the first to discover electron [1]

a) Ernest Rutherford b) J.J. Thomson

c) James Chadwick d) Robert Hooke

32. The commonly occurring isotopes of carbon atoms are: 612C, 613C, 614C . They contain: [1]

a) 7, 8 and 9 neutrons 6 protons b) 6, 8 and 9 neutrons and 6 protons

c) 6, 7 and 9 neutrons and 6 protons d) 6, 7 and 8 neutrons and 6 protons

33. Maximum number of electrons in a subshell with l = 3 and n = 4 is _____. [1]

a) 14 b) 32

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 c) 16 d) 12
34. One of the orbitals is non-directional [1]

a) p- orbital b) f- orbital

c) s- orbital d) d- orbital
35. Isotopes are the atoms with [1]

a) same number of neutrons but b) same atomic number but different

different mass number mass number

c) same mass number but different d) same atomic number but different
atomic number number of electrons
∘

36. Find the energy of the photon which has a wavelength of 0.50 A? [1]

(Hint: h = Planck’s constant = 6.626 × 10-34 J)

a) 1.98 × 10-15 J b) 3.98 × 10-15 J

c) 2.98 × 10-15 J d) 0.98 × 10-15 J

37. Orbital angular momentum depends on ________. [1]

a) m and s b) n and m

c) l d) n and l
38. The orbital with quantum numbers n = 4, l = 3 is [1]

a) 4f b) 3d

c) 4d d) 4p
39. When an electric discharge is passed through gaseous hydrogen, the H2 molecules dissociate [1]

and the energetically excited hydrogen atoms produced emit electromagnetic radiation of
discrete frequencies. The hydrogen spectrum consists of

a) several lines named after their b) a continuous spectrum that reduces

discoverers to zero at small wavelengths

c) several series of lines named after d) a continuous spectrum that reduces

their discoverers to zero at large wavelengths
40. In the emission spectrum of hydrogen atom, the Balmer series falls in the [1]

a) Ultraviolet region b) X - ray region

c) Infra-red region d) Visible region

41. Values of e/m (charge/mass) in the categories alpha particle (α), electron (e) and protons (p) [1]
increase in the order:

a) α <e<p b) p < e < α

c) α <p<e d) e < α < p

42. Lines in the hydrogen spectrum which appear in the ultraviolet region of the electromagnetic [1]
spectrum, then they are called as:

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 a) Pfund series b) Bracket series

c) Lyman series d) Balmer series

43. The electronic configuration 1s2 2s2 2p1 belongs to [1]

a) Boron b) Carbon

c) Beryllium d) Lithium
44. Rutherford’s α–particle scattering experiment supported the discovery of: [1]

a) nucleus b) electron

c) radioactivity d) proton
45. Daltons atomic theory could not explain one of the following: [1]

a) Law of conservation of mass b) Law of constant composition

c) Discovery of sub-atomic particles d) Law of multiple Proportions

46. Which of the following statements about the electron is incorrect? [1]

a) It is a negatively charged particle. b) The mass of electron is equal to the

mass of neutron.

c) It is a constituent of cathode rays. d) It is a basic constituent of all atoms.

47. Absorption spectrum, seen as dark lines in an otherwise continuous spectrum, for the given [1]
material results from the material's (atom or molecules):

a) absorbing selected wavelengths and b) absorbing selected wavelengths

returning to normal ground state from an input of continuous
spectrum

c) absorbing all wavelengths and d) absorbing all wavelengths from an

returning to normal ground state input of continuous spectrum
48. For azimuthal quantum number (l) = 2, the values of magnetic quantum number will be: [1]

a) +2, +1, 0, -1, -2 b) s, p, d

c) 0, 1, 2 d) 2l + 1

49. Find energy of the photons which correspond to light of frequency 3 × 1015 Hz (Hint: h = [1]

Planck’s constant = 6.626 × 10-34 Js)?

a) 2.988 × 10-18 J b) 0.988 × 10-18 J

c) 1.308 × 10-18 J d) 1.988 × 10-18 J

50. The amount of energy required to remove the valence electron of an isolated gaseous atom to [1]
form a cation is called its ________.

a) Electronegativity b) Lattice Enthalpy

c) Ionization energy d) Electron affinity

51. Lines in the hydrogen spectrum which appear in the visible region of the electromagnetic [1]
Spectrum, then they are called as:

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 a) Balmer series b) Lyman series

c) Paschen series d) Bracket series

52. Bohr’s model of the atom could explain quantitatively the general features of the structure of: [1]

a) Hydrogen atom b) nitrogen atom

c) carbon atom d) oxygen atom

53. If a cation B3+ has 18 electrons, the atomic number of element B will be [1]

a) 12 b) 21

c) 24 d) 15
54. In the Thomson Model of Atom: [1]

a) electrons move in circular orbits b) electrons are embedded in a

around nucleus positively charged pudding or water
melon

c) electrons swarm like flies around d) electrons oscillate about the nucleus
nucleus
55. An atom of an element contains 29 electrons and 35 neutrons. The electronic configuration of [1]
an element

a) 1s2 2s2 2p6 3s2 3p6 4s1 3d10 b) 1s2 2s2 2p6 3s2 3p 4s2 3d6 4s2 4p2

c) 1s2 2s2 2p6 3s2 3p5 4s1 3d9 4s2 d) 1s2 2s2 2p6 3s2 3p 4s2 3d8 4s2

56. Oil drop experiment is for determining the: [1]

a) deviation of the electron. b) mass of the electron

c) number of electrons d) charge on the electrons

57. The correct expression for mass number A is: [1]

a) A = number of electrons (Z)+ number b) A = number of protons (Z)+ number

of positrons (n) of neutrons (n)

c) A = number of nucleons (Z) + number d) A = number of protons (Z)+ number

of neutrons (n) of electrons(n)
58. How many neutrons and protons are there in the 13
6
C nucleus? [1]

a) 8, 5 b) 7, 6

c) 0, 13 d) 8, 6
59. Which of the following sets of quantum numbers represent the highest energy of an electron? [1]

a) n = 3, l = 0, m = 0, s = +1/ 2 b) n = 3, l = 2, m = 1, s = +1/ 2

c) n = 4, l = 0, m = 0, s = +1/ 2 d) n = 3, l = 1, m = 1, s = +1/ 2
60. Which of the following properties of atom could be explained correctly by Thomson Model of [1]
atom?

a) Position of electrons, protons and b) Spectra of hydrogen atom.

neutrons in atom.

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c) Overall neutrality of atom. d) Stability of atom.

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