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Acdest;
CHAPTER: 14
SEMICONDUCTOR ELECTRONICS
structure at
band structure at | Energy band structure at | Energy band
Energy room temperature:
room temperature: room temperature:
Empty Conduction band
Partlally filed Conduction band
E 3eV
3ev
Ev
temperature.
Electrons are charge cariers. | Electrons and holes are | No charge carriers.
charge cariers.
Note:
1. In metals (conductors): only electrons are charge carriers.
In semiconductors: elecirons and holes are charge carriers. (Note that, no charge
carriers at OK in semiconductors).
In insulators: no charge carriers.
2. Elemental semiconductors: Ge(E =0.72eV) and Si (E = 1.l eV).
3. Compound semiconductors: examples are
Compound Inorganic: Cds, GaAs, CdSe, InP, etc.
.Compound Organic: Anthracene, doped pthalocyanines,
Compound Organic polymers: polypyrrole, polyaniline, etc.
|4. C, Si and Ge have same lattice structure. Why C is insulator while Si and Ge are
intrinsic semiconductors?
Ans: The four bonding electrons of
C, Si and Ge lie in the second, third and fourth
orbit respectively. Hence, energy needed to take out an electron (ionisation energy
rom these atoms will be least for Ge, followed by Si and highest for C. Hence
number offree electrons for conduction: in Ge and Si are significat but negligibly
small for C.
W h a t is Hole?
electronic charge (te) in
with effective positive
"electron vacancy
Ans: Hole is
valance band of semiconductor"
senmiconductors:
Ge, Si
like have four valance conduct
Pure
semiconductors
electrons are free to
atoms. So no
with nearest neighbour as insulator at
four covalent bonds Hence "pure
semiconductors behave
zero temperature).
at OK (absolute
Ge
(
Free electron
are called
semiconductors intrinsic
(free from impuitiesand crystal defects)
Pure
semiconductors. Ex:germanium(Ge), silicon (Si).
valance electrons. These electrons form
Puresemiconductors like Ge,Sinave tour
four covalent bonds withzero
nearest
negnborng atoms. So n o electrons are free to
temperaeure). Hence pure semiconductors behave as
conduct at OK (absolute
insulator at OK or at low
temperature.
are created due to breaking of
clectron hole pairs
As temperature increases, electrons and holes is a n 'intrinsic'
of charge carriers,
covalent bonds (The presence
I = Ie+ Ih
Semiconductors at T =
0K and
structure of Intrinsic
Q. Write the energy band
T OK.
E, E
anreroanc
At T OK At T OKK
Ecbottom of CB, Eytop of VB
0-hole electron
Extrinsic Semiconductors: An impure or doped semiconductor is called extrinsic
semiconductor.
Note:
1) For extrinsic semiconductors, the electron and hole concentration in a
semiconductor at thermal equilibriumis given by ne nh= n
where ne - concentration of free electrons,
n - concentration of holes,
2) Both p - type andn- type semiconductors are electrically neutral. Because, they
are obtained by adding neutral impurity atoms to neutral pure semiconductor (Si or
Ge).
Problem:
A semiconductor has equal electron and hole concentration of 8 x 10" /m. On
doping, the hole concentration increases to 4 x 10 /m.
i) Identify the new type of semiconductor obtained after doping.
ii) Find the new electron concentration.
Ans: i) p-type semiconductor.
=4x 10 /m.
ii) given n, 8 x 10° Im', na
=
-122
i
5.Ac"T
VDonor: The
impurity atom which donates free electron to pure semiconductorsis
called donor. Example: Pentavalent atoms like Arsenic (As), Phosphorous
Bisnuth (Bi), Antimony (Sb). (P),
Acceptor: The impurity atom which accepts electron from pure semiconductor is
called acceptor. Example: Trivalent atoms like Aluminium (Al), Indium
B), Gallium (Ga). (In), Boron
Mention the factors which
on
electuical conductivity of semiconductors depend:
i) For Intrinsic
semiconductor, conductivity depends only on temperaturc,
ii) For extrinsic
semiconductor, conductivity depends its
Concentration of impurity atoms.
on
temperature and
N-type semiconductors: Ge
N-type semiconductors are obtained
by adding a pentavalent impurity
(donar) atom like As, Sb, P,... to a Ge
pure semiconductor like Ge or Si.
-12.3
The phosphorous atomn has five valence clectrons. Among these, four electrons a
involved in the formation of four covalent bonds with the nearest
germanium
atoms. The fifth clcctron is free as shown in
figurc.
.Thus each phosphorous atom donates one free electron. These free electrons cause
conduction cven at 0K.
Energy band diagram,T >OK
When temperature increases (T> 0
K),electron-
pnductonbap hole pairs are produced by the
breakage of
-
figure.
Boron atom accepts one electron from
the nearest
neighboring Ge atom to
Energy band diagram, T >0K Cu
form fourth covalent bond
by
hole. Thus addition of each creating Ebottom of C8
impurity EEtop ofVB
atom (boron atom) give
These holes
rise to hole. EAacceptor leve!
cause conduction even at --EA lectron
OK. 0hole
Ey
When the temperature increases
(T> 0
K), electron- hole pairs are
produced by the breakage of
result, density of holes (na) Is grcater than covalent bonds. As a
the density of electrons (ne). Therefore,
the holes are
majority charge carriers and electrons are the
in the p-type semi conductors. minority charge cariers
For p-type
semiconductor nh>> n
124
-120-
and semiconductors:
Distinguish between n-type semiconductors p-type
N-typesemiconductors
P-type semiconductors
Holes are majority charge carriers and free Free electrons majority charge
are
side near the junction and fixed positive space - charge region on n-side near the
Junction. This develops a p.d across the junction and is called contact potential
difference or junction potential barrier. This potential barrier prevents the
further diffusion of electrons and holes across the junction.
2. Due to the positive space charge on n- side near the junction and negative space
charge on p- side near the junction, an electric field set up and it is directed from n-
side to p- side. Due to this field, electrons onp- side are drift towards n-side and
hole on n - side drift towards p- side. This results drift current, which is oppoSite
to diffusion current.
Initially, diffusion current is greater than drift current. As diffusion process
continues width of depletion region increases andhence electric field and drift current
increases. This process continues until diffusion current is equal to drift current. Thus
p-n junction is formed. At equilibrium, current in p-n junction is zero.
Depletion Region:
It is the region near the junction of the diode which is completely free from
mobile charge carriers.
Width (thickness) of depletion region is about in the order of one tenth of
micrometer um
The width of depletion region can be varied with the applied voltage.
How can you vary the width of potential barrier in a diode?
Ans: The equilibrium barrier potential can be varied by applying an external voltage V
across the diode.
What is junction potential or barrier potential?
The potential developed across p-n junction which prevents the tlow electrons
from n-region to p-region and boles from p-region to n- region is called barrier
potential or junction potential.
BIASING P-N JUNCTION (or operation of p-n junction):
The p-n junction is said to be biased, when an external voltage is applied across p-
njúnction. There are two types of biasing: 1) Forward biasing 2) Reverse biasing.
-126
Lnder
om n-
on p-
r the V
ntial
the
Fig(b)
ele e eeee
9 i e i eeee 1-V characteristic curve
pace e e ele]9 eeee
mn-
and holes
electrons
site
Figla)
ess V(volt)
ent Figlc)
When external voltage applied across forward biased
ius p-n junction,
1. The direction of the applied voltage
(V) is opposite to direction of junction
barrier potential (Vo). As a result, width of the depletion layer and the barrier
height are decreased [shown in fig b]. The effective barrier height under forward
m bias is (Vo-V).
2. Due to decrease in barrier height,the flow electrons from n-side +
of p-side and
holes from p-side n-side increases. This makes large concentration
near the junction.
gradient
3. Due to large concentration gradient the junction, large current results. The
near
total diode forward bias current is sum of hole diffusion current and electron
diffusion current. The magnitude of this current is usually in mA.
4. Thus in forward biasing:
The current is due to diffusion of majority charge carriers and it is in the
order of 10 A.
Forward bias offers very "small resistance".
The curve obtained on plotting forward bias current (1) against forward bias
voltage (V) is called forward bias characteristics curve (shown in fig c).
Note: Due to the applied voltage, clectrons from n-side cross the depletion region and
reach p-side (where they are minority carriers). Similarly, holes from p-side cross the
junction and reach the n-side (where they are minority carriers). This process under
forward bias is known as minority carrier injection.
/Reverse bías p-n junction working:
The p-n junction is said to be reverse biased, When an external voltage V is
applied across a semiconductor diode such that p-side is connected to the negative
terminal of the battery and n-side to the positive terminal of the battery.
-127
electrons
N
Fig(b)
e eeee
V,(volt)
Figla)
Figlc) (uA)
diode
mA diode
uA
Baftery Tap key
-128
Reverse Voltage | Reverse Current
Forward Voltage Forward Current
V(V) I(mA) V(V) (mA )
0.1
0.2
0.3 3
0.4
-129
S Acaserrng
AI
For diodes, the ratio of small change in voltage (AV) to the small change in
current (A)
Applications of p-n junction diode (semiconductor diodes):
1.t is used as rectifier 2.It is used as switch
Rectification: It is the process of conversion ofAC voltage into DC voltage.
Rectifier: It is a device used to convert AC voltage into DC voltage.
What property of diode is used for rectification?
Ans: p-n junction diode conducts current only ah one direction (forward direction).
This unidirectional property of diode is used fof rectification. OR The forward bias
Tesistance is low as compared to reverse bias resistance.
Types of rectifier: There are two types 1) Half wave rectifier 2) Full wave rectifier
Half Wave Rectifier:
Transformer Vin Input Ac wave form
D
tme
Vout Vout A Outgut waye fornt
dme
Half wave rectifier is a device used to convert only one half cycle of AC voltage
into DC voltage.
Explanation: The circuit diagram of half wave rectifier is as shown in figure. It
consists of transformer (step up or step down), a diode D and load resistance R. The
primary coil of transformer is connected to the AC source and the secondary coil is
connected to the diode D and load resistance R
During positive half cycle of input AC voltage (Xis positive with respect to
Y), the diode D is forward biased and it conducts. Hence the current flows
through the loadresistance RL. Thus, voltage appears across R.
During negative half cycle of input AC voltage (X is negative with respect to
Y), the diode D is reverse biased and it does not conducts. Hence no current
flows through the load resistance Rz and no voltage appears across R. Thus,
diode D conducts only positive half cycle of input AC and hence the circuit is
called half wave rectifier.
-130
T h e output voltage is unidirectional, pulsating and intermittent. This pulsating
DC may be smoothened by using filter (capacitor or inductor).
ut Ac wavg to" at Y
-- Vout Vin
-time
Vout Outpiut Wave form i
time
Working: The circuit diagram of full wave rectifier is as shown in figure. It consists
of centre tapped transformer, two diodes Di, D2 and load resistance
Rz. The primary
coil of transformer is connected to the AC source and the centre tapped secondary coil
is connected to two diodes Di, D2 and load resistance RL.
Case i) During positive half cycle of input AC voltage (the terminal X is positive with
respect to Y):
The diode D is forward biased and it conducts. Hence current flows through the
load resistance R. The diode D2 is reverse biased and it does not conduct.
Case ii) During negative half cycle of AC (the terminal X is negative with respect to
Y:
The diode D is reverse biased and it does not conduct. Diode Da is forward biased
and it conducts. Hence current flows through the load resistance R
as shown in
fig.
Thus, D, conducts positive half cycle of AC and D, conducts negative half cycle of
AC. Hence the circuit is called full wave rectifier.
The frequency of output rectified voltage is twice the frequency of input AC
voltage.
The output voltage is unidirectional and continuous but pulsating. This
pulsating DC is converted into steady DC by using filter (capacitor in parallel
to RL or inductor in series with R)
Filter Circuit: The pulsating DC is obtained during the rectification using diode can
be converted into steady DC using filters like capacitor or inductor. Filter circuit with
capacitor of high value of capacitance C in parallel with load resistance RL is as
shown in fig.
131
RS. Acnder
Input Ac wave forn1
Vin
DC component
time
time
Working: When the voltage the capacitor is rising, it gets charged. It RL =0,
across
capacitor gets charged to peak voltage rectified output. If RL # 0 (load is present),
to fall.
capacitor gets discharged through the load and the voltage across it begins
value.
Again, in next half cycle of rectified output it again gets charged to the peak
-
The rate of fall of the voltage across the capacitor depends upon the time constant
(RLC). If time constant is large (for large value of C), rate of fall is small. So voltage
across capacitor is almost equal to peak value ofrectified voltage.
Time Constant: The rate of fall of the voltage across the capacitor depends upon the
inverse product of capacitor capacitance C and the cffective resistance Rz used in the
1
circuit and is cailed the time constant. i.e. time constant=.
RC
Special Purpose (Types) p-n junction diodes:
Types of some special purpose p-n junction diodes are
1) Zener diode
2) Optoelectronic devices.
Some types of optoelectronic diodes are
-132
Hence the diode i
(visible photons). s
is released in the form of light
process, energy
called LED
Applications of LED:
1. Used in remote controls.
2. Used in calculators, radio, TV.
3. Used in burglar alarms. eL
4. Used in digital watches.
5. Used in optical communication.
shown in fig.