Q1) MCQ:

1) Use the replacement nomenclature to name:

a) 1,4-diazabenzene b) 1,4-diazacyclohexane

c) 1,4-dioxabenzene d) 1,4-diazahexane

2) The common name of:

a) 5-methyl-1H-pyrole b) 5-methyl-1H-imidazole

c) 5-methyl-1H-pyrazole d) 3-methyl-1H-pyrole

3) The minor ring for is called:

a) furan b) thiophene c) furo d) none

4) Hantzsch-Widman nomenclature of is:

a) 5H-1,3,2-Oxazathiole b) 5H-1,3,2,-Oxathiazole

c) 2H-4,5,6-Oxathiazole d) 5H-1,2,3-Oxathiazole
5) Hantzsch Widman nomenclature of is:

a) 2H-furo[2,3-b] pyran b) 2H-furo[3,2-b] pyran

c) 2H-pyrano[2,3-b] furan d) 2H-pyrano[3,2-b] furan

6) Passing a mixture of acetylene and ammonia over red hot tube gives:

a) furan b) pyrrole c) thiophene d) none of them

7) Pentose sugar can be used in the preparation of:

a) furan b) pyrrole c) thiophene d) none of them

8) 1,4-dicarbonyl compound is a starting material in the …… reaction.

a) Paal-Knorr b) Knorr c) Fiest-Benary d) Hinsberg

9) 1,4-dicarbonyl compound can be used in the preparation of:

a) furan b) pyrrole c) thiophene d) all of them

10) The synthesis of pyrrole using Hantzsch reaction involves the condensation
of:

a) α-haloketone b) β-ketoester c) ammonia d) all of them

11) Which of the following is an isocyclic organic compound:

a) A,B,C b) B,D c) C,D d) C only

e) None of the above is correct.

12)

Ⅰ- Structure (1) is:

a) CH3NH2 b) NH3 c) NH2OH d) CH3CH2NH2

Ⅱ- Structure (2) is:

Ⅲ- The condition which can be for reaction (3) is:

a) acid condition b) alkali condition c) neutral condition

Ⅳ- The reagent (5) is:

a) SO2Cl b) Cl2 c) a and b d) Cl2 ∕∆

Ⅴ- Structure (4) is:

13) Use the following structures a,b,c and d to answer questions Ⅰ-Ⅴ:

Ⅰ- Structure (a) can be named as:

a) 2-isopropylthiophene b) 5-isopropylthiophene c) 5-propylthiophene

Ⅱ- The Hantzsch-Widman nomenclature of structure (b) is:

a) 4H-Oxete b) 2H-azetete c) 2H-Oxete

Ⅲ- Structure (c) can be named as:

a) 2H-furo[2,3-b] pyran b) 2H-furo[3,2-b] pyran c) 2H-pyrano[3,2-b] furan

Ⅳ- By using the replacement nomenclature, structure (d) can be named as:

a) 1-Oxa-4-azacyclohexane b) 1-aza-4-Oxacyclohexane c) 1-Oxa-4-azahexane

Ⅴ- Structure……. is fully saturated.

a) Structure a b) Structure b c) Structure d

14)

15)

16)

17) Feist-Benary synthesis is one method for preparing:

a) Thiophene b) Pyrrole c) Furan

Q2) True or False:
1- Nitration of furan can be done using CH3COONO2. T

2- Hinsberg reaction is a method for the preparation of thiophene. T

3- The starting molecule in knorr pyrrole synthesis is 1,4-dicarbonyl
compound. F ( paal-knorr)

4- Indoles react with electrophiles through C2. F (C3)

5- Gattermann reaction used POCl3 ∕ DMF mixture. F (HCl∕HCN)

6- 1,5-dicarbonyl compound gives Pyridine in its reaction with
hydroxylamine. F (ammonia)

7- Furan can be prepared from pentose sugar. T

8- Heating a mixture of furan, ammonia and steam over alumina catalyst
gives a thiophene. F (Pyrrole)

9- The reaction of pyrrole with NBS gives tetrabromopyrrole. F

(2-bromopyrrole)

10- The reaction of pyrrole and maleic undergoes Diels-Alder reaction. F

(Michael addition)
Product of this reaction is 2-pyrrylsuccinic acid