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A covalent bond consists of the simultaneous attraction of two atomic nuclei for one or
more pairs of electrons.
Covalent bonds occur between identical atoms or between different atoms where the
difference in electronegativity is insufficient to form an ion by transfer of electrons.
A hydrogen molecule is formed from two hydrogen atoms, each of which has one
electron in the 1-s orbital.
Two hydrogen atoms are attracted to the same pair of electrons in a covalent bond.
The heat released during the formation of molecules of a compound at 298 K is the
standard enthalpy change (ΔH°) of the process.
When 1 mole of hydrogen is produced from two hydrogen atoms, ΔH° is −435 kJ
mol−1.
A hydrogen molecule is more stable than two hydrogen atoms because energy is
released during the reaction.
The reverse process, in which two bonded hydrogen atoms are pulled apart, requires
435 kJ mol-1, an amount called the bond strength of the H-H bond.
Two hydrogen nuclei are separated by a distance called the bond length.
Although there is an attractive force between the nucleus and the bonding electrons,
there are also repulsive forces between the two nuclei and between the two electrons.
Figure 1.
Figure 1.
5.
Bonding Forces in Hydrogen Molecules When a covalent bond is formed between two
hydrogen atoms, there are two sets of electrostatic repulsion (nucleus to nucleus and
electron to electron, red), but four sets of electrostatic attraction.
(green) exists.
This simple capacitive bonding model does not adequately describe chemical
bonding.
In a chlorine molecule, two chlorine atoms are attracted to the same pair of electrons.
Each chlorine atom has seven valence electrons in the third energy level, and an
additional electron is required to form an electron nucleus with the electron
configuration of argon.
Each chlorine atom contributes one electron to the bond pair shared by the two atoms.
The remaining six valence electrons of each chlorine atom do not participate in
bonding.
They are also called nonbonding electrons, lone pairs, or lone pairs.
As already mentioned, covalent bonds in Lewis structures are represented by lines.