Chemical Bonding

ALLEN® Chemical Bonding 1
7. vkf.od d{kd fl)kUr ds vuqlkj uhps nh x;h

CHEMICAL BONDING
Lih'kht esa ls fdldk vfLrRo ugha gS\
1. fuEufyf[kr esa ls dkSu ls lelajpukRed ;qXe gS?
(1) He2+ (2) He2–
2-
A. SO4 rFkk CrO24- (3) Be2 (4) O22–
B. SiCl4 rFkk TiCl4 8. B2H6 ds fy, fuEu esa ls dkSu lk lgh dFku gS\
-
C. NH3 rFkk NO 3 (1) blds fljs okys B–H vkcU/kksa esa lsrq vkca/kks
D. BCl3 rFkk BrCl3 dh vis{kk p-vfHky{k.k de gksrk gSA
(1) C rFkk D ek=k (2) A rFkk B ek=k (2) nksuksa B–H–B vkcU/k leku yEckbZ ds ugha gSaA
(3) A rFkk C ek=k (4) B rFkk C ek=k (3) lHkh B–H–B dks.k 120° ds gSaA
2. izksVhuksa dh a-gsfyDl lajpuk ds LFkkf;Ro ds fy, (4) bldk [kaM] BH3, ,d yqbl {kkj dh rjg
fuEufyf[kr esa ls fdl izdkj dh vU;ksU; fØ;k
O;ogkj djrk gSA
mÙkjnk;h gS?
9. fuEufyf[kr gSykbMksa esa ls mudh la[;k tks
(1) vk;fud vkcU/ku tyvi?kVu ds fy, vfØ; gS_______A
(2) gkbMªkstu vkcU/ku (A) BF3 (B) SiCl4 (C) PCl5 (D) SF6
(3) lla;kstd vkcU/ku 10. fuEufyf[kr Lih'kht esa ls dkSu lh esa vkca/k
(4) okMjokYl cy yEckbZ;k¡ vleku gS ?
3. fuEufyf[kr esa ls mHk;/kehZ ;kSfxdksa dh la[;k gS (1) BF4- (2) XeF4 (3) SF4 (4) SiF4
__________
11. gSykstuksa dh vkcU/k fo;kstu ,UFkSYih dk lgh Øe
(A) BeO
gS :
(B) BaO
(1) Cl2 > F2 > Br2 > I2
(C) Be(OH)2
(2) I2 > Br2 > Cl2 > F2
(D) Sr(OH)2 (3) Cl2 > Br2 > F2 > I2
–1
4. I3 vk;u dh lgh vkdfr rFkk I–I–I dks.k Øe'k% gSa (4) F2 > Cl2 > Br2 > I2
(1) fodr f=kdks.kh; leryh; 135° rFkk 90° 12. uhps nks dFku fn, x, gSaA vfHkdFku A vkSj
(2) T-tSlh vkdfr; 180° rFkk 90° dkj.k R.
(3) f=kdks.kh; leryh;; 120° vfHkdFku A : vU;ksU; f}/kzqo&f}/kzqo fØ;k;sa gh
dsoy os v&lgla;ksth vU;ksU; fØ;k;sa gSa ftuds
(4) js[kh;; 180°
node06\B0BA-BB\Kota\JEE MAIN\Jee Main-2021_Subject Topic PDF With Solution\Chemistry\Hindi\Chemical Bonding
ifj.kke Lo:i gkbMªkstu vkcU/k fojfpr gksrk gSA

5. fuEufyf[kr esa ls lgh lsV ftlesa nksuksa tksM+s
xyukad ds lgh Øe esa gSa] og gS % dkj.k R : ¶yqvksjhu lokZf/kd fo|qr&_.kkRed
(1) LiF > LiCl ; MgO > NaCl rRo gS vkSj HF esa gkbMªkstu vkcU/k lefefr; gSaA
(2) LiCl > LiF ; NaCl > MgO mijksDr dFkuksa ds lanHkZ esa uhps fn, x;s fodYiksa
(3) LiF > LiCl ; NaCl > MgO esa ls lgh mÙkj pqfu,A
(4) LiCl > LiF ; MgO > NaCl (1) A vlR; gS ijUrq R lR; gS
6. fuEufyf[kr lYQj ds vij:i esa ls (A) a lYQj (2) A rFkk R nksuksa lR; gS vkSj R lgh O;k[;k gS
(B) b-lYQj A dhA
(C) S2-:i ,sls vij:iksa dh la[;k crkbZ;s tks (3) A lR; gS ijUrq R vlR; gS
vuqpqEcdRo n'kkZrs gS ________. (4) A rFkk R nksuksa lR; gS ijUrq R lgh O;k[;k
ugh gS A dhA
H
2 Chemical Bonding ALLEN®
13. uhps nks dFku fn, x, gS% 16. lwph-I dk lwph-II ls feyku dhft,A
dFku I : o-ukbVªksQhukWy Hkki esa ok"i'khy lwph-I lwph-II
vUr%vkf.od gkbMªkstu vkcU/ku ds dkj.k gSA
¼vkWDlks vEy dk uke½ ¼'P' dh vkWDlhdj.k
dFku II : gkbMªkstu vkcU/ku ds dkj.k voLFkk½
o-ukbVªksQhukWy dk xyukad mPp gSA
(a) gkbiksQkWLQksjl vEy (i) +5
mijksDr dFkuksa ds fy, fuEufyf[kr fodYiksa esa ls
lokZf/kd mfpr mÙkj pqfu, : (b) vkWFkks±QkWLQksfjd vEy (ii) +4
(1) dFku I vlR; gS ijUrq dFku II lR; gS

(c) gkbiksQkWLQksfjd vEy (iii) +3
(2) nksuksa dFku I rFkk dFku II lR; gS

(d) vkWFkks±QkWLQksjl vEy (iv) +2
(v) +1
(3) nksuksa dFku I rFkk dFku II vlR; gSA
uhps fn, fodYiksa esa ls lgh mÙkj gS :
(4) dFku I lR; gS ijUrq dFku II vlR; gSA
(1) (a)-(v), (b)-(i), (c)-(ii), (d)-(iii)
14. uhps nks dFku fn, x, gSA ,d vfHkdFku A vkSj (2) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
nwljs dkj.k R gSA (3) (a)-(iv), (b)-(v), (c)-(ii), (d)-(iii)
vfHkdFku A : CsI3 ds lekd frd TlI3, esa] /kkrq (4) (a)-(v), (b)-(iv), (c)-(ii), (d)-(iii)
17. uhps nks] dFku A rFkk dkj.k R fn, gSaA
+1 vkWDlhdj.k voLFkk esa mifLFkr gSA
dkj.k R : Tl /kkrq ds bysDVªkuW foU;kl esa pkSng f dFku A : ty esa H–O–H cU/k dks.k 104.5o gSA
bysDVªkWu gksrs gSA dkj.k R : vkcU/k ;qXe&vkcU/k ;qXe izfrd"kZ.k dh
vis{kk] ,dkdh ;qXe&,dkdh ;qXe izfrd"kZ.k mPp
mijksDr dFkuksa ds lanHkZ esa uhps fn, x;s fodYiksa
gksrk gSA
esa ls lokZf/kd mfpr mÙkj pqfu, :
uhps fn, fodYiksa esa ls mijksDr ds fy, lgh
(1) A lgh gS ijUrq R lgh ugha gSA mÙkj gS %
(2) nksuksa A rFkk R lgh gSa vkSj R, A dh lgh (1) A vlR; gS ijUrq R lR; gSA
O;k[;k gSA (2) A rFkk R nksuksa lR; gSa ijUrq R lgh O;k[;k
(3) A lgh ugha gS ijUrq R lgh gS ugh gS A dhA
(4) nksuksa A rFkk R lgh gSa ijUrq R, A dh lgh (3) A lR; gS ijUrq R vlR; gSA
O;k[;k ugha gSA (4) A rFkk R nksuksa lR; gSa vkSj R lgh O;k[;k gS
15. lwph-I dk lwph-II ds lkFk lqesy dhft, A dhA
lwph-I lwph-II 18. C60 dh lajpuk ds fy, xyr dFku gS :
(v.kq) (vkcU/k Øe) (1) N% rFkk ik¡p lnL;h; nksuksa oy;ksa] ls N%

(a) Ne2 (i) 1 lnL;h; oy; laxfyr gksrs gSaA
(b) N2 (ii) 2 (2) izR;sd dkcZu rhu flXek vkcU/k cukrk gSA
(3) ik¡p lnL;h; oy;ksa dk laxyu dsoy N%
(c) F2 (iii) 0
lnL;h; oy;ksa ds lkFk gksrk gSA
(d) O2 (iv) 3 (4) blesa 12-N% lnL;h; oy; rFkk 24 ik¡p
uhps fn, x;s fodYiksa esa ls lgh mÙkj pqfu;s : lnL;h; oy; gksrs gSaA
(1) (a)®(iii), (b)®(iv), (c)®(i), (d)®(ii)
(2) (a)®(i), (b)®(ii), (c)®(iii), (d)®(iv)
(3) (a)®(ii), (b)®(i), (c)®(iv), (d)®(iii)
(4) (a)®(iv), (b)®(iii), (c)®(ii), (d)®(i)
H
19. ,d v.kq ds dsUæh; ijek.kq ij nks ,dkadh 27. lwph-I dks lwph-II ls feykb;s &
bysDVªkuW ;qXe gS rFkk ;g rhu ,dy vkcU/k cukrk lwph-I lwph-II

(Lih'kht) (ladfjr d{kd)
gSA v.kq dh vkdfr gS : (a) SF4 (i) sp3d2
(b) IF5 (ii) d2sp3
(1) <asdqyh (2) f=kdks.kh leryh;
(c) NO +2 (iii) sp3d
(3) T-vkdfr (4) f=kdks.kh; fijkfeMh;
20. dkSu lk fuEufyf[kr ;kSfxd yqbl {kkj ds :i esa (d) NH +4 (iv) sp3
(v) sp
dk;Z ugha dj ldrk gS\
uhps fn, fodYiksa esa ls lgh mÙkj pqfu, &
(1) NF3 (2) PCl5 (3) SF4 (4) ClF3
21. fuEufyf[kr esa tks jSf[kd Lih'kht gS]og gS : (1) (a)-( i), (b)-( ii), (c)-(v) and (d)-(iii)
(2) (a)-(ii), (b)-(i), (c)-(iv) and (d)-(v)
(1) NO2 (2) Cl2O
(3) O3 (4) N 3– (3) (a)-(iii), (b)-( i), (c)-( v) and (d)-(iv)
(4) (a)-(iv), (b)-(iii), (c)-(ii) and (d)-(v)
22. AX ,d lgla;ksth f}ijek.kqd v.kq gS tgk¡ A rFkk
X vkorZ lkj.kh dh f}rh; iafDr ds rRo gSA 28. H3C – C = CH – C º C – H esa flXek vkcU/kksa dh
vkf.od vkfcZVy fl|kUr ds vk/kkj ij AX dh H
ca/k Øe 2.5 gSA AX esa lexz bysDVªkWuksa dh dqy
la[;k _________ gSA
la[;k ______gSA
29. fuEufyf[kr esa ls ca/k Øe dk lgh Øe gS :
¼fudVre iw.kk±d esa½
23. uhps nh x;h Lih'kht esa ls mudh la[;k ftuds (1) O22- > O2+ > O2- > O2
dsUnzh; ijek.kq ij nks ,dkadh bysDVªkWu ;qXe gS] (2) O+2 > O2- > O22- > O2
____gSA (3) O+2 > O2 > O-2 > O22-
(fudVre iw.kk±d esa) (4) O2 > O-2 > O22- > O2+
SF4, BF4– , CIF3, AsF3, PCl5, BrF5, XeF4, SF6
24. t+huku dk ,d ;kSfxd A vkaf'kd tyfo?kVu ls 30. fuEufyf[kr esa og Lih'kht crkbZ;s ftlesa ,d
XeO2F2 nsrk gSA ;kSfxd A eas mifLFkr ,dkdh p vkcU/k gS vkSj ftlds dsuksfudy :iksa dh la[;k
bysDVªkuW kas ds ;qXe dh la[;k gS_______ lokZf/kd gS :
25. I-
ds dsUæh; I ijek.kq ij ,dd bysDVªkWu ;qXeksa
3 (1) SO3 (2) O2

dh la[;k gS _________A (3) SO2 (4) CO 23 -
26. NO-2 , NO2+ rFkk NH+4 dh ukbVªkstu ds ijekf.o; 31. H4P2O7, H4P2O5 rFkk H4P2O6 esa 'P' dh vkWDlhdj.k
d{kdksa dk ladj.k Øe'k% gS: voLFkk;sa Øe'k% gSa] :

(1) sp3, sp2 rFkk sp (2) sp, sp2 rFkk sp3 (1) 7, 5 rFkk 6 (2) 5, 4 rFkk 3
(3) sp3, sp rFkk sp2 (4) sp2, sp rFkk sp3
(3) 5, 3 rFkk 4 (4) 6, 4 rFkk 5
H
32. nks dFku fn, gSaA dFku A rFkk dkj.k R. 38. nks d.kksa ds chp esa yanu cyksa dh vU;ksU; ÅtkZ
dFku A : yhfFk;e gSykbM dqN lgl;ksath izdfr rx ds lekuqikrh gS] tgk¡ nks d.kksa ds chp dh nwjh
ds gksrs gSA r gSA x dk eku gS &
dkj.k R : yhfFk;e dh /kzoq hdj.k {kerk mPp gksrh gSA (1) 3 (2) –3
(3) –6 (4) 6
mijksDr dFkuksa ds fy,] uhps fn, fodYikssa esa ls
39. PCl5 ds ty vi?kVu ds QyLo:i fufeZr vafre
lokZf/kd mfpr mÙkj pqfu, :
mRikn esa fdrus vu&vk;uuh; gkbMªkstu ijek.kq
(1) A lR; gS ijUrq R vlR; gS
mifLFkr gksrs gS\
(2) A vlR; gS ijUrq R lR; gSA (1) 0 (2) 2
(3) A rFkk R nksuksa lR; gS vkSj R, A dh lgh (3) 1 (4) 3
O;k[;k ugha gSA 40. O -2 vk;u dh vkca/k dksfV ,oa pqEcdh; O;ogkj
(4) A rFkk R nksuksa lR; gS vkSj R, A dh lgh gS] Øe'k%
O;k[;k gSA (1) 1.5 ,oa vuqpqEcdh;
33. xSlh; Vªkb,sfFky ,sehu esa "–C–N–C–" vkcU/k (2) 1.5 ,oa izfrpqEcdh;
dks.k ________ fMxzh gSA (3) 2 ,oa izfrpqEcdh;
x (4) 1 ,oa vuqpqEcdh;
34. CO rFkk NOÅ dh vkcU/k dksfV es vUrj gS]
2
41. uhps nks dFku fn, gSA ,d dk uke vfHkdFku
tgk¡] x _______ gSA (fudVre iw.kkZad esa)
(A) rFkk nwljs dk dkj.k (R) gSA
35. Dyksjl vEy] Dyksfjd vEy rFkk ijDyksfjd vEy
vfHkdFku (A) : csfj;e dkcksZusV ty esa vfoys; gS
esa Cl = O vkcU/kksa dh la[;k Øe'k% gS] rFkk vR;f/kd LFkk;h gSA
(1) 3, 1 rFkk 1 (2) 4, 1 rFkk 0 dkj.k (R) : dkcksZusVksa dk rkih; LFkkf;Ro /kuk;u
(3) 1, 1 rFkk 3 (4) 1, 2 rFkk 3 ds vkdkj c<+us ij c<+rk gSA
fuEu odYiksa esa ls lokZf/kd mi;qDr mÙkj pqus &
36. O22- ds lHkh vkcU/ku vkf.od d{kdksa esa bysDVªku

W ksa
(1) nksuksa (A) ,oa (R) lgh gS ijarq (A) dh lgh
dh dqy la[;k ....... gSA ¼fudVre iw.kk±d es½a O;k[;k (R) gSA
(2) (A) lgh gS ijarq (R) lgh ugha gSA
37. AB3 ,d T-vkdfr dk varjk&gSykstu v.kq gSA A
(3) nksuksa (A) ,oa (R) lgh gS ijarq (A) dh lgh
ij bysDVªkWu ds ,dkdh ;qXeksa dh la[;k gS O;k[;k (R) ugha gSA
(4) (A) lgh ugha gS ijarq (R) lgh gSA
_______A
(fudVre iw.kkZd esa)
H
42. lwph–I dk lwph–II ls feyku dhft,A 46. vkDlkbMksa X2O (X = gSykstu) dh LFkkf;Ro dk
lwph–I lwph–II lgh Øe] fuEufyf[kr esa ls dkSu&lk ,d lgh
(Lih'kht) (dsUnzh; ijek.kq ij :i ls fu:fir djrk gS\
bysDVªkuksa ds ,dkdh (1) Br > Cl > I
(2) Br > I > Cl
;qXeksa dh la[;k)
(3) Cl > I > Br
(a) XeF2 (i) 0
(4) I > Cl > Br
(b) XeO2F2 (ii) 1
(c) XeO3F2 (iii) 2 47. vkf.od vkfcZVy fl)kUr ds vuqlkj O22- vk;u esa
(d) XeF4 (iv) 3 v;qfXer bysDVªkuksa dh la[;k gS_____A
uhps fn, fodYiksa esa ls lgh mÙkj pqfu,A
48. fn, x, fuEu vkWdlkbMksa esa ls vuqpqEcdh;
(1) (a)–(iv), (b)–(i), (c)–(ii), (d)–(iii)
vkWDlkbMksa dh la[;k gS %
(2) (a)–(iii), (b)–(iv), (c)–(ii), (d)–(i)
(3) (a)–(iii), (b)–(ii), (c)–(iv), (d)–(i) Li2O, CaO, Na2O2, KO2, MgO ,oa K2O
(4) (a)–(iv), (b)–(ii), (c)–(i), (d)–(iii) (1) 1 (2) 2 (3) 3 (4) 0
43. fuEufyf[kr v.kqvksa esa ls fdl ,d esa gSykbM ls 49. B+2 Lih'kht dk ^dsoy pØ.k* pqEcdh; vk?kw.kZ gS
________×10–2 BMA (fudVre iw.kk±d esa)
cksjku dks ,d bysDVªkWu ;qXe dk izcyre i'p~
[fn;k x;k gS : 3 = 1.73 ]
Mksus'ku izR;kf'kr gS\
(1) BCl3 (2) BF3

(3) BBr3 (4) BI3
44. fuEufyf[kr esa ls vfijSfeMh vkdfr dh Lih'kht
dh la[;k gS _______A
(A) SO3 (B) NO3-

(C) PCl3 (D) CO23-
45. CuSO4.5H2O LVkWbfd;ksehVªh ls lac) gkbMªkstu
vkcaf/kr ty ds v.kq@v.kqvksa dh la[;k gS

_______.
H
SOLUTION 5. Official Ans. by NTA (1)
Sol. L.E. µ M.P.
1. Official Ans. by NTA (2)
L.E. : LiF > LiCl, MgO > NaCl
Sol. Isostructural means same structure 6. Official Ans. by NTA (1)
O
(A) SO42– : Tetrahedral Sol. a-sulphur and b-sulphur are diamagnetic.
S –
O O
O – S2-form is paramagnetic.
O
2– : Tetrahedral 7. Official Ans. by NTA (3)
CrO4 Cr
O –
O
–
Sol. Chemical Species Bond Order
O
He +2 0.5
Cl
: Tetrahedral He -2 0.5
(B) SiCl4 Si
Cl Cl Be 2 0
Cl O22 - 1
Cl
TiCl4 : Tetrahedral According to M.O.T. If bond order of chemical
Ti
Cl Cl species is zero then that chemical species does
Cl
not exist.
(C) NH3 : Triagonal pyramidal
N 8. Official Ans. by NTA (1)
H H
H
O Sol.
NO3
–
N : Triagonal planar
–
O O
Cl · q 2 > q 1 , \ B–H (terminal) having less p-
(D) BCl3 B–Cl : Triagonal planar character as compare to bridge bond.
Cl · Both B–H–B bridge bond having same bond
Cl length.
· B–H–B bond angle is »90°
BrCl3 Cl Br : T-shape –
· BH3 is e deficient species and therefore act as
Cl lewis acid
2. Official Ans. by NTA (2) 9. Official Ans. by NTA (1)
Sol. Hydrogen bonding is responsible for the Sol. SF6 is inert towards hydrolysis
\ answere is (1)
stacking of a-helix structure of protein.
3. Official Ans. by NTA (2) Sol.

Sol. Both compounds BeO and Be(OH)2 are Species Hybridisation Bond length
BF4Q sp3 (Tetrahedral) All bond lengths equal
amphoteric in nature. XeF4 sp3 d 2 (sq. planar) All bond lengths equal
and both compounds BaO and Sr(OH)2 are axial bond length >
SF4 sp3 d(see - saw)
equitorial bond length
basic in nature. SiF4 3
sp (Tetrahedral) all bond lengths equal
I 11. Official Ans. by NTA (3)
Sol. Correct order of bond dissociation enthalpy of
!
Sol. I halogens is Cl2 > Br2 > F2 > I2.
Due to inter electronic repulsions F–F bond
I becomes weak and easily broken.
Shape : Linear, I–I–I Bond angle Þ 180°
H
Sol. Assertion is incorrect since in hydrogen Sol. (a) Hypophosphorus acid : H3PO2
bonding, Dipole–dipole interactions are non-
(+1) 3 + x + (–2)2 = 0
covalent but ion-dipole interaction can also
result in H-bond formation. Reason is correct x = +1
since F is most electronegative element & (b) Orthophosphoric acid : H3PO4
structure is (+1) 3 + x + (–2)4 = 0
F F F
H H H H x = +5
H F F
(c) Hypophosphoric acid : H4P2O6
Symmetrical H-bonds are present
13. Official Ans. by NTA (4) (+1) 4 + 2x + (–2)6 = 0
H x = +4
O O
(d) Orthophosphorous acid : H3PO3
N Intramolecular
Sol. O
H–bonding
(+1)3 + x + (–2)3 = 0
x = +3
thus it is more volatile due to intramolecular
H-bonding.
Melting point depends on packing efficiency Sol. H2O
not on H-bonding thus statement II is false
14. Official Ans. by NTA (4) O
q H
Sol. (
TlI 3 Þ Tl & I Å 1
3 ) H
CsI3 Þ ( Cs Å
&I 1
3 ) q = 104.5°
[Both have same crystalline structure is called the hybridisation of oxygen is water molecule
3
isomorphous] is sp .
T l Å(81) = [Xe54]4f14, 5d10, 6s2 So electron geometry of water molecule is
(It is correct due to present 14 f electrons in tetrahedral and the bond angle should be
TlÅ ion) 109°28" but as we know that lone pair-lone pair
15. Official Ans by NTA (1) repulsion of electrons is higher than the bond
Sol. (a) Ne2 = Total e1 = 20 pair-bond pair repulsion because lone pair is
10 - 10 occupied more space around central atom than
B.O. = =0
2 that of bond pair.
(b) N2 = Total e1 = 14 18. Official Ans. by NTA (4)
10 - 4 Sol. Structure of C60

B.O. = =3
2
(c) F2 = Total e1 = 18
10 - 8
B.O. = =1
2
(d) O2 = Total e1 = 16
10 - 6
B.O. = =2
2 It contain 20 hexagons 20 and 12 pentagons
12 so option 4 is incorrect.
H
F F
F
SF4 = S , BF4 = B
Sol. F F F
F F
F
3 Sol.
sp d hybridised As
ClF3 = Cl–F , AsF3 =
T-shaped F F
F F
Sol. Lewis base : Chemical species which has Cl F
Cl F F
capability to donate electron PCl5 = Cl–P , BrF5 = Br
Cl F F
pair. Cl
In NF3, SF4, ClF3 central atom (i.e. N, S, Cl)
F
having lone pair therefore act as lewis base. F F F F
XeF4 = Xe , SF6 = S
F F F F
In PCl5 central atom (P) does not have lone pair F
therefore does not act as lewis base. Two l.p. on central atom is = ClF3, XeF4
Sol. XeF6 + 2H2O ¾® XeO2F2 + 4HF
Sol.
(A) (Limited water)
Structure of 'A'
22. Official Ans. by NTA (15) F

Sol. AX is a covalent diatomic molecule. F F
The molecule is NO. Xe
Total no. of electrons is 15. F F
F
Total l.p. on (A) = 19
Sol. I3– :
I
: !
I
I
The number of lone pairs of electron on the
central atom is 3.
H
Sol. 2s + 1 lp
Sol. Oxidation state of P in H4P2O7, H4P2O5 and
N
O O –
\ sp2 H4P2O6 is 5, 3 & 4 respectively
Å
H4P2O7
2s + 0 lp
O=N=O 2x + 4 (+1) + 7 (–2) = 0
\ sp
H x=+5
4s + 0 H4 P2 O5
N+
H H \ sp3
H 2x + 4(+1) + 5 (–2) = 0
27. Official Ans. by NTA (3) x=+3
Sol. (a) SF4 – sp3d hybridisation H4 P2 O6
(b) IF5 – sp3d2 hybridisation
2x + 4 (+1) + 6 (–2) = 0
(c) NO +2 – sp hybridisation
x=+4
(d) NH +4 – sp3 hybridisation
Sol. Lithium due to small size has very high

Sol. Hs
polarization capability and thus increases
s
s
H s– C –s C = C–s C º C s– H covalent nature in Halides.
s s s
H H H 33. Official Ans. by NTA (108)
numbers of s bonds = 10 Sol. In gaseous triethyl amine the "–C–N–C–" bond
29. Official Ans. by NTA (3) angle is 108 degree.
Sol. O2 (16 electrons)
s1s2 , s1s*2 , s 22s , s*2 Sol. Bond order of CO = 3
2s , s 2pz
2
Bond order of NO+ = 3

p 2
2p x =p 2
2p y ,p *1
2p x =p *1
2p y ,s *
2 pz
x
Bond order of O2 Þ 2 Difference = 0 =
2
Bond order of O 2 Þ1.5
–
x=0
Bond order of O Þ1
2–
2 35. Official Ans. by NTA (4)
+
Bond order of O 2 Þ 2.5 Sol. Number of Cl = O bonds
2–
Sol. Among SO3, O2, SO2 and CO3 , only O2 and
CO32– has only one p-bond
O O– O– 36. Official Ans. by NTA (10)
C C C Sol. M. O. Configuration of O22 - ( (18e )
–
O O– O O– –
O O * *
s1s 2 s 1s 2 s2s 2 s 2s 2 s 2p 2z p2p 2x = p2p 2y
*
p 2p2x = p 2p 2y
*
Total B.M.O electrons = 10
H
Sol. Species (Number of lone pairs of electrons on
Sol. T-shaped molecule means 3 sigma bond and 2 the central atom)
lone pairs of electron on central atom. F
B
XeF2 3 Xe
B——A
F
B
38. Official Ans. by NTA (3) F
O
Sol. For london dispersion forces. XeO2F2 1 Xe
O
1 F
Eµ
r6
F
Hence x = –6 O
XeO3F2 0 Xe = O
O
Sol. PCl5 + H2O ® POCl3 + 2HCl F
H3PO4 + 3HCl
O F F
XeF4 2 Xe
In P + HCl F
F
O O
H O
H H 43. Official Ans. by NTA (2)
all hydrogens are ionisable
Sol. Type of back bonding
\ Ans is zero.
BF3 BCl BBr3 BI3
(2pp–2pp) (2pp–3pp) (2pp–4pp) (2pp–5pp)
-
Sol. O = (s1s ) (s ) (s2s ) (s ) (s2pz )
2
2 * 2
1s
2 * 2
2s
2
Therefore back bonding strength is as follows
BF3 > BCl > BBr3 > BI3
(p 2
2 px = p22 p y ) (p *2
2 px = p*1
2 py ) 44. Official Ans. by NTA (3)
10 - 7
Bond order = = 1.5
2 O O
Sol.
and paramagnetic NÅ
S
41. Official Ans. by NTA (1) O O
O –
O–
Sol. In IIA group on moving down the group size of Trigonal planar Trigonal planar
cation increases and show thermal stability of O
··
carbonate increases. C
P
Cl Cl – –
Cl O O
Pyramidal Trigonal
Hence non-pyramidal species are SO3, NO-

3
2-
and CO3 .
H
H H
–
Sol. Li2O Þ 2Li+ O2– MgO Þ Mg2+ O2–
Sol. O
H O CaO Þ Ca2+ O2– K2O Þ 2K+ O2–
H O O H
S Na2O2 Þ 2Na+ O 22 -
2+
O
Cu O
H
H O–
KO2 Þ K+ O -2
H O O
O -2 Þ Complete octet, diamagnetic
H H
O2–Þ s1s s1s s2s s2s s22px p22py ; p22p z p*2
2py ; p 2p z (dia)
2 *2 2 *2 *2
One hydrogen bonded H2O molecule

O -2 Þ s1s s1s s2s s2s s2px p2py ; p2p z p2py ; p2p z
2 *2 2 *2 2 2 2 *2 *1
46. Official Ans. by NTA (4) (para)

Sol. Stability of oxides of Halogens is
I > Cl > Br
B+2 Þ s1s s1s s2s s2s p2py ; p2pz
2 *2 2 *2 1 0
Sol.
Þ 9e–
Sol. Molecular orbital configuration of O 22 – is
µ = 1(1 + 2) = 3 BM
2 *2 2 *2
s1s (
s1s s2s s2s p2px2 = p2py2 ) (p
*2
2px = p*2
2py ) = 1.73 BM
= 1.73 × 10–2 BM
Zero unpaired electron

Chemical Bonding

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Chemical Bonding

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ALLEN® Chemical Bonding 1

7. vkf.od d{kd fl)kUr ds vuqlkj uhps nh x;h

ifj.kke Lo:i gkbMªkstu vkcU/k fojfpr gksrk gSA

(1) dFku I vlR; gS ijUrq dFku II lR; gS

(2) nksuksa dFku I rFkk dFku II lR; gS

(v.kq) (vkcU/k Øe) (1) N% rFkk ik¡p lnL;h; nksuksa oy;ksa] ls N%

bysDVªkuW ;qXe gS rFkk ;g rhu ,dy vkcU/k cukrk lwph-I lwph-II

3 (1) SO3 (2) O2

d{kdksa dk ladj.k Øe'k% gS: voLFkk;sa Øe'k% gSa] :

ds gksrs gSA r gSA x dk eku gS &

(3) A rFkk R nksuksa lR; gS vkSj R, A dh lgh (3) 1 (4) 3

36. O22- ds lHkh vkcU/ku vkf.od d{kdksa esa bysDVªku

(fudVre iw.kkZd esa)

(4) (a)–(iv), (b)–(ii), (c)–(i), (d)–(iii) (1) 1 (2) 2 (3) 3 (4) 0

(1) BCl3 (2) BF3

44. fuEufyf[kr esa ls vfijSfeMh vkdfr dh Lih'kht

(A) SO3 (B) NO3-

(C) PCl3 (D) CO23-

45. CuSO4.5H2O LVkWbfd;ksehVªh ls lac) gkbMªkstu

vkcaf/kr ty ds v.kq@v.kqvksa dh la[;k gS

3. Official Ans. by NTA (2) Sol.

10 - 4 Sol. Structure of C60

22. Official Ans. by NTA (15) F

Sol. Lithium due to small size has very high

Bond order of NO+ = 3

Total B.M.O electrons = 10

Hence non-pyramidal species are SO3, NO-

One hydrogen bonded H2O molecule

46. Official Ans. by NTA (4) (para)

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