ALLEN® Alcohol & Ether 1

ALCOHOL & ETHER 5. uhps nks dFku fn, gSa :

dFku I : C2H5OH rFkk AgCN nksuksa ukfHkdLusgh
1. lsfjd veksfu;e ukbVªsV rFkk CHCl3 / ,sYdksgkWfy;
mRié dj ldrs gSaA
KOH dk mi;ksx Øe'k% ______ rFkk ___ dFku II : vfHkfØ;k dks lHkh voLFkkvksa esa KCN
fØ;kRed lewg dks igpkuus ds fy, fd;k tkrk rFkk AgCN nksuksa ukbVªkby ukfHkdLusgh gh mRié
gSA djrs gSA
(1) ,sYdksgkWy] Q+hukWy (2) ,sehu] ,sYdksgkWy
lokZf/kd mfpr fodYi pqfu, :
(1) dFku I lR; gS ijUrq dFku II vlR; gS
(3) ,sYdksgkWy] ,sehu (4) ,sehu] Q+hukWy
(2) nksuks dFku I rFkk dFku II lR; gSA
2. uhps nks dFku fn, gSA (3) dFku I vlR; gS ijUrq dFku II lR; gSA
dFku-I : 2-esfFkyC;wVsu dk KMnO4 ds lkFk (4) nksuks dFku I rFkk dFku II vlR; gSaA
vkDlhdj.k djkus ij 2-esfFkyC;wVsu-2-vkWy nsrk gSA Official Ans. by NTA (1)
6. xzhU;kj vfHkdeZd C2H5MgBr dh C8H8O ds lkFk
dFku-II : n-,sYdsu dks lqxerk ls KMnO4 ds

®
vfHkfØ;k ds i'pkr~ ty vi?kVu ls ;kSfxd "A" izkIr
lkFk laxr ,sYdksgkWyksa esa vkDlhdr dj ldrs gSa gksrk gS tks vfr'kh?kz Y;wdkl vfHkdeZd ls vfHkfØ;k
lgh fodYi pqfu,: djds ;kSfxd B, C10H13Cl nsrk gSA ;kSfxd B gS :
(1) dFku I rFkk dFku II nksuksa lgh gS Cl
CH3
(2) dFku I rFkk dFku II nksuksa xyr gS
(3) dFku I lgh gS ijUrq dFku II xyr gS
(1) CH3 (2)
(4) dFku I xyr gS ijUrq dFku II lgh gS Cl
3. 7.8g ,sØksyhu (C3H4O) (MW = 56) dks cukus ds CH3 Cl CH3
fy,_____g 3-gkbMªkWDlhizksisuy (MW = 74) dk Cl

futZyhdj.k vko';d gS] ;fn izfr'kr yfC/k 64 (3) CH3 (4) CH3

gSA ¼fudVre iw.kk±d esa½

OH
[fn;k gS : ijekf.o; æO;eku:C : 12.0 u, H : 1.0 u,
O : 16.0 u] H3PO4
A
7. 120°C
4. 1-esFkkWDlh uS¶+FkSyhu dh gkbMªks vk;ksfMd vEy ls (eq[; mRikn)
vfHkfØ;k esa fufeZr gksus okys eq[; mRikn gSa %
(BH3)2
I – P
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H2O2/OH, H2O (eq[;

(1) rFkk CH3OH

mijksDr vfHkfØ;k ij fopkj dj mRikn P dks
OH igpkfu,:
OH CH3 OH
(2) rFkk CH3I

OH (1) (2)

(3) rFkk CH3OH

OH CH3
I OH OH

rFkk CH3I (3) (4)

(4)

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2 Alcohol & Ether ALLEN®
O 10. uhps nks dFku fn;s x;s gSaA ,d dks vfHkdFku (A)
OH
Conc.HBr
8. C–OCH3 "P" uke fn;k gS vkSj nwljs dks dkj.k (R) fn;k gSA
H3C ¼eq[; mRikn½
vfHkdFku (A): ,fFky Qsfuy bZFkj dk la'ys"k.k
mijksDr vfHkfØ;k ij fopkj dhft,A fufeZr eq[; fofy;Elu la'ys"k.k ls dj ldrs gSaA

mRikn "P" gS :- dkj.k (R): czksekscsUthu dh lksfM;e ,FkkWDlkbM ls

vfHkfØ;k ,fFky Qsfuy bZFkj nsrh gSA
O
Br mijksDr dFkuksa ds lanHkZ esa uhps fn, x;s fodYiksa
C–OCH3
(1) esa ls lgh mÙkj pqfu,A
CH3
(1) (A) rFkk (R) nksuksa lgh gSa vkSj (R) lgh
O
O;k[;k gS (A) dhA
C–OCH3
(2) (A) lR; gS ijUrq (R) vlR; gSA

®
(2) CH3
Br (3) (A) vlR; gS ijUrq (R) lR; gSA

O (4) (A) rFkk (R) nksuksa lgh gSa vkSj (R) lgh
OBr
C–OCH3 O;k[;k ugha gS (A) dhA
(3)
CH3 11. fuEufyf[kr esa ls dkSu lk ,d nh x;h vfHkfØ;k
O dk eq[; mRikn gS\
Br
C–Br CH3
(4)
CH3 NC O
(i) 2CH3MgBr
(ii) H3O+ eq[; mRikn
OH CH3
Conc. (iii) H2SO4, heat

9. H2SO4
+
D O CH3
A B CH3
(1) CH3
mijksDr vfHkfØ;k ij fopkj dj lgh dFku pqfu, CH3
CH3
(1) vEyh; ek/;e esa vfHkfØ;k laHko ugha gSA
NC CH3
(2)
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(2) nksuksa ;kSfxd A rFkk B leku ek=kk ls fufeZr

CH3
gksrs gSaA CH3
NC CH3
(3) ;kSfxd A eq[; mRikn gksxkA (3)
CH3
(4) ;kSfxd B eq[; mRikn gksxkA CH3
O
CH3
(4) CH3
CH3

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 ALLEN® Alcohol & Ether 3
SOLUTION 8. Official Ans. by NTA (2)
1. Official Ans. by NTA (3) Sol.
Sol. Ceric ammonium nitrate for alcohol and
CHCl3/KOH is carbyl amine test for primary
amines
2. Official Ans. by NTA (3)
Sol. Alkane are very less reactive, tertiary hydrogen
can oxidise to alcohal with KMnO4.
H KMnO4 OH

2-methyl-butane
3. Official Ans. by NTA (16)
H2
D
9. Official Ans. by NTA (3)
C

®
Sol. (HO)H2C CHO ¾64%
¾ ¾
® C3H4O + H2O Sol.
x x 7.8
mol ´ 0.64 =
74 74 56
x = 16.10
; 16.00
4. Official Ans. by NTA (2)
O – CH3 OH
HI
Sol. + CH3–I

Mechanism
H
O – CH3 O – CH3

H I
(SN2 )

OH

+ CH3–I
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10. Official Ans. by NTA (2)

5. Official Ans. by NTA (1)
O–Na+ O–Et
6. Official Ans. by NTA (3)
7. Official Ans. by NTA (4) Sol. + Et –Br
Sol.
OH Sodium Phenoxide Ethyl Phenyl ether

H3PO dehedration of alcohol by E1 Rxn

D Br

H.B.O
+ Et –O–Na+ X
OH
H-attached at more hindard
site while OH attached at less Partial double bond character
hindard site in H.BO. Reaction

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4 Alcohol & Ether ALLEN®
11. Official Ans. by NTA (1)
Sol.

CH 1dÅd
O 2CH3MgBr

CH3
CH3
Å 1 CH3 1 Å
BrMgN=C OMgBr
CH3
CH3
Å
H3O
CH3
CH3
C OH

®
O CH3
CH3
H2SO4 D–H2O

CH3 CH3
CH3
O
CH3

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