A 0 CHAPTER Alcohols, Phenols and Ethers fons (MCQs) will help you prepare in CUT Examinations. AAA WE ALCOHOLS, PHENOLS AND ETHERS ay Se ae ‘ALCOHOLS wero) [oi Aye ‘anie) ~ chon] Fouad) Geer aso L. (ana Methanol |» eecane |, Tertiary = Alkenes ony n-t-ol _ (CH,),COH = Carbonyl compounds te 2.Metnyopar-2-01 1 ado of aenydes, ketones, ESE 2d Vinyie carboxylic acids and ester naa ai tion =| (Tass) Gee) -| [Sion ‘Benzenol Ethenol C,H,CH,OH { aes ten aca oa Smmaica er | [WORRY rimary | cHOCH, «86 «| || CH,CH,CH,OH maT HOH Propan- ales Preperies Methoxy methane i pans) * Boiling Points Fa 0H * slit ‘Unsymmetrical Ether Propane, ‘Secondary jd Dipcis omer Chemical Properties: CHOC,H, «=< 1.2,3tiol ——(CH,),cHOH Actity Estefan fea ieaal ee mh Some Commercially re Onan ‘Aromatic Ether Important Alcohols. orator, aigiong SyocH, taal are (weno verona ‘Nomenclature Physical Properties Chemical Properties: Preparation from: “= Boiling point + Recon romati substulon + Halarnes | + Solubility, * eaction ‘+ Benzene sulphonic acid * Dipole moment Reimertiemann (ense 202) * Diazoniom sats ge sia + cumene cers _ —_¥ ¥ ¥ 7 7 Nomenclature) (Sirctures)! "Use of Ethers Preparation irom: Physical Properties) | Chemical Properties & ‘"Danjraion of cohol |C'Bolig pot | Cleavage ef 0 bond (s Solent wan Mechanism = Sau wath HI HBr | Exmencororeemss) Cltetonenets (lmcteunteneetata ‘Aromatic Ethers: ‘Cleavage by Hi and HBr ‘+ Electrophilc substiution: () Halogenation, (I) Friedel-Crafts Alkylation, (ji) Friedel-Crafts Acylation, (jw) Nitration224 agecher ewteh® Chemistry—12 TOPICS COVERED Classification, Nomenclature of Alcohols, Phenols and Ethers Alcohols: Alcohols are formed when a hydrogen atom in hydrocarbon is replaced by—OH with general formula C\H,, ,,-OH. - Monohydric alcohol: Alcohol having one alcoholic group €.g., CH,OH (methanol) C,H,OH (ethanol) they have sp hybridised °C’ attached to OH group. ‘dric alcohol: Alcohols having two —OH groups 8. CH,OH—CH,OH (Ethane-1, 2-diol). . Trihydric alcohols: Alcohols having three OH groups €g, HOCH, —CH(OH)CH,OH (Propane-1 2 3-tril). Primary alcohol: The OH group is attached to primary carbon, e.g., CH,—CH,—CH,—OH. Secondary alcohol: Alcohol in which—OH group is attached to secondary carbon e.g., CH, —CH(OH)—CH, (Propan-2-ol) Tertiary alcohol: Alcohol in which—OH group is attached to 3° carbon e.g. (CH,),C—OH (2-Methyl propan-2-ol). Allylic alcohol: —OH group is attached to sp® hybridised carbon adjacent to carbon-carbon double bond that is to allylic carbon e.g., ou CH,=CH—CH,OH(1°) CH,=CH—CH—CH,2°) Prop-2en-t-ol But cH,coon eeaee Ethyl ethanoate Ethanol m0, Beesole'actd ydroboration-oxidation , OBI cucrcron }Y cu,cx,cr,re——cH-cr—ce es . Fare , Z ce cron icin jeasi ae 40] 1,80, cu,—cn—cn, ie cH,—cu=c—cr,on 5 cr,—c—cn—Lat ore os ee co ICBSE 2023} CH;—CH—CH, CH,;—C—CH, it 2Propanol (spray! alto) 2-Propanone (Acetone)228 Fagecher wiek® Chemistry—I2 cicero, Sr CHE —CHH,HAE L i Z or ° pase ot pone 2ome Phenols a So, S0% p05, sen, 2) + NaOH O cordance ne so i eZ nee NC ou $0,Ne — +H,0 | Benzee danacium choide | {cbse 2023) | CH, os ‘Asiole eer) cue —O—OH OH (tesborybenzeoe) | How A i +0, + — + CH,COCH,Usefu! °, 4,0 ia JCOCH Lue rote] oy Consene Poesol [CBSE Sample Paper 20171 T a (2-Pheayl propane) meus 50 or OH ONa OH ee za ses_| o Na i a a Cy | , ICSE: 2020] eotonobenzene Paw ‘Solan ¥acont oe enn 2017) y “ ou ONa ijro/or | cuss K se +H,0 cH, I 2Niwophenat Scotian enone ce Gnizophenel) {beth 2019) sa cH Satieyidehyde @rydroxy benzaldehyde) TCRSE. 2023, 20; AL 2016, 17()1 -bromotenol [Foran 207Alcohols, Phenols and Ethers 229 QCOCH, inet 2017 PH on ‘COOH coon fe ee Lo tpmwonncoa] | mon s ae Salicylic acid Dein 2016) | Son {en 20171 [cose 200% Chennal 201%: (Kolbe's reaction) © tf Prefard 2023) “JCMS 2055, tu} Se cust 20381 ococn, OH | rricdet-crans oH ‘Aiton cucoa | AS | ‘cucr, NOH i | aa, Phenyl chante Passo otrcat {CBSE 2020 for Bing Methyl pheno Hy : p-Cresol (Methyl phenol) {Det 2019) ne on ON, No, yer cone. No, | 7 NeW ca : : Gy iaa \ 7 eric acid) lest 23, Pac | OT p.pydroxy azo benzne (OTREE de) No, 70 for Bing} reuse 2025) HL HH OH HL HL S0,H cocn, cone. 1,50,| -7> | cucoct ‘uel peter eo lea Dhydronyenzene Paso! 2-Hydroxy acetophenone SO,H sulphonic acid cocn, 4iydroxybenzene hydroxy sulphone ack acetophenone ‘OCH, Gi | Acetylation cut Z™) lencone ae S — tense 2020 Tohicne Q Passel Phenyl ethanoate {CSE 2023, 20() for Blin} on ° Feel, Zo Violet colour <—=* —} [C CHSE: 2023, 20; Deh 201% Phenol J cacnnat 2019: ok: Pretoard ‘P-BenzoguinoneEthers. sn th 80, | ak Willan On CHOC, ‘aymilionls Aihony ete Hoc, Meitiay ethane CMON CHL & wii anocania Aromatic Ethers Wittiammson Syatheste on ONa och, Ms, + NaOH —> + chy ———| aircon? Soxtium ptenovie ‘Anole Hest 2028, 21% atl 209] |My on och, be + CH,Br Phenol Anisole C,IJONa + CNL SH,ONa + CHE och, i 2-Thomoanisole ocn, , Br 4-Bromo anisole ocu, NO, + 2.Nitto anisole NO, 4.Nitr anisoleAlcohols, Phenols and Ethers 239 ocH, och, cocn, och, on Spot] HCI+ _tiiseder”) mw “xa, | — + CHL 1ense 20201 2-Methoxy acetophenone OCH, st 2m, | Anioe Phevo! 4:Methony acetophenone ae or |-—"— + CH,Br (cuse 20231 OCH, ocH, OCH, | Friedel-Crafts OCH, OcH, a alkylation 1H, - 0nc:H,50, a Pah 2-Methoxy benzene Anisote 2-Methyt anisole S0,H sulphone aia (setoxy (1-Methony-2methy! sy bese vena ‘benzene)—4Methoxy anisole “Onto ed tFecgn 201% Chenna 2009 q tial, — CH,—C—CH, Fegeenon” CHy Rca, es cH,—CH-CH, ‘Acsione Prop 2-0 ropene ICBSE 2020), CH,OH CHC boas capnene 222. caycazon «mec HL Meshmoat Ethanol ‘OH Te ICBSE 2020) ‘Acidic character: 4-methyl phenol < phenol < 4-nitrophenol OH_ cose 2020) OH 1CBSE 2020)