Scholars Forum

Subject : Chemistry Paper Set : 1

Standard : 12 12 ALG NEET 24072023 Date : 30-07-2023
Total Mark : 180 Time : 1H:0M


Chemistry - Section A - MCQ

[51] Maximum solubility of alcohol in water is due to (1) −CH2 OH (2) > CHOH

(1) Covalent bond (2) Ionic bond

| (4)
(3) − C −OH
|
(3) H-bond with H2 O (4) None of the above

[52] Which of following is phenolic

(1) Phthalic acid (2) Phosphoric acid
[59] In esterification of an acid, the other reagent is
(3) Picric acid (4) Phenylacetic acid
(1) Aldehyde (2) Alcohol
[53] The boiling point of glycerol is more than propanol (3) Amine (4) Water
because of
(1) Hydrogen bonding (2) Hybridisation [60] Halogenation of which one of the following will
yield m-substituted product with respect to methyl
(3) Resonance (4) All the above group as a major product?
[54] Butane −2− ol is (1)
(1) Primary alcohol (2) Secondary alcohol
(3) Tertiary alcohol (4) Aldehyde

[55] The role of conc. H2 SO4 in the esterification pro-

cess is (2)
(1) Catalyst
(2) Dehydrating agent
(3) Hydrolysing agent
(4) Dehydrating agent and catalyst (3)
[56] Phenol is less acidic than
(1) Ethanol (2) Methanol
(3) o-nitrophenol (4) p− methylphenol
(4)
[57] Boiling point of alcohol is comparatively higher than
that corresponding alkane due to
(1) Intermolecular hydrogen bonding
(2) Intramolecular hydrogen bonding
(3) Volatile nature [61] Butanal is an example of

(4) None of these (1) Primary alcohol (2) Secondary alcohol

[58] The characteristic grouping of secondary alcohols (3) Aliphatic aldehyde (4) Aliphatic ketone
is
[62] Alcoholic fermentation is brought about by the ac-
tion of

Page No : 1
 (1) CO2 (2) O2 (1) Solid compound (2) Liquid
(3) Invertase (4) Yeast (3) Gas (4) Brown solid

[63] Picric acid is (at 25 o C) [73] Alcohols react with Grignard reagent to form
(1) A white solid (2) A colourless liquid (1) Alkanes (2) Alkenes
(3) A gas (4) A bright yellow solid (3) Alkynes (4) All of these

[64] Which of the following compound is most acidic [74] In the following reaction:
[Image]
(1) CH4 (2) C2 H6 The compounds A and B respectively are ......
(3) CH ≡ CH (4) C2 H5 OH

[65] Which of the following are isomers

(1) Methyl alcohol and dimethyl ether

(2) Ethyl alcohol and dimethyl ether (1)

(3) Acetone and acetaldehyde

(4) Propionic acid and propanone
[66] Glycerol is used in the manufacture of
(2)
(1) Dynamite (2) Varnish
(3) Paints (4) Soft drinks

[67] 23 g of N a will react with methyl alcohol to give

(3)
(1) One mole of oxygen (2) One mole of H2
(3) 1
2
mole of H2 (4) None of these

[68] Alcohols of low molecular weight are

(4)
(1) Soluble in water (2) Soluble in all solvents
(3) Insoluble in all solvents
(4) Soluble in water on
heating

[69] Dehydration of ethanol gives [75] The structural formula of cyclohexanol is

(1) Acetic acid (2) Ethane (1) (2)
(3) Ethylene (4) Acetylene

[70] Absolute alcohol is

(1) 100 % pure ethanol (2) 95 % alcohol + 5 % H2 O
(3) Ethanol + water + phe-
(4) 95 % ethanol +5 %
nol methanol
(3) (4)
[71] A migration of hydrogen with a pair of electrons is
called
(1) Alkyl shift (2) Hydride shift
(3) Hydrogen ion formation
(4) Dehydrogenation
[76] Phenol on distillation with zinc dust gives
[72] At 25 o C Ethylene glycol is a
(1) C6 H6 (2) C6 H12
(3) C6 H5 OC6 H5 (4) C6 H5 − C6 H5

Page No : 2
[77] Because of resonance the oxygen atom of −OH
group of phenol (1) Acid chloride (2) Amide
(1) Acquires positive
(2) Acquires negative (3) Ester (4) Ether
charge charge
(3) Remains uneffected (4) Liberates [82] In CH3 CH2 OH which bond dissociates heterolyti-
cally
[78] Which of the following is a simple ether (1) C − C (2) C − O
(1) CH3 OCH3 (2) C2 H5 OCH3 (3) C − H (4) O − H
(3) C6 H5 OCH3 (4) C6 H5 OC2 H5 [83] 3− pentanol is a
[79] An example of a compound with the functional (1) Primary alcohol (2) Tertiary alcohol
group ′ − O−′ is (3) Secondary alcohol (4) None of these
(1) Acetic acid (2) Methyl alcohol
[84] Which compound has hydrogen bonding
(3) Diethyl ether (4) Acetone
(1) Toluene (2) Phenol
[80] Lucas test is used for
(3) Chlorobenzene (4) Nitrobenzene
(1) Alcohols (2) Amines
[85] In CH3 CH2 OH −
→o CH2 = CH2 + H2 O; ′ X ′ is
X
(3) Diethyl ether (4) Glacial acetic acid
350 C

[81] Which of the following do not contain an acyl group (1) N aCl (2) CaCl2
(3) P2 O5 (4) Al2 O3


Chemistry - Section B - MCQ(Attemp any 10)



[86] Compound X on reaction with O3 followed by Zn/ (1) > CHOH (2)
H2 O gives formaldehyde and 2−methyl propanal as
products. The compound X is :
(1) 2−Methylbut−1−ene(2) 2−Methylbut−2−ene (3) −CH2 OH (4)
(3) Pent−2−ene (4) 3−Methylbut−1−ene

[87] Fermentation is an
(1) Endothermic reaction(2) Exothermic reaction
(3) Reversible reaction (4) None of these [91] Order of reactivity of alcohols towards sodium
metal is
[88] Which compound has the highest boiling point (1) Pri > Sec > Ter (2) Pri > Sec < Ter

(1) Acetone (2) Diethyl ether (3) Pri < Sec > Ter (4) Pri < Sec < Ter

(3) Methanol (4) Ethanol [92] In reaction of alcohols with alkali metal, acid etc.
which of the following alcohol will react fastest
[89] The boiling point of alcohol are . . . . than corre-
sponding thiols (1) Secondary (2) Tertiary

(1) More (2) Same (3) Primary (4) All equal

(3) Either of these (4) Less [93] Which of the following is dihydric alcohol

[90] General formula of primary alcohol is (1) Glycerol (2) Ethylene glycol
(3) Catechol (4) Resorcinol

[94] Which of the following is tertiary alcohol

Page No : 3
 CH2 OH CH2 (1) Acetic acid
| |
(1) CH − OH CH3 − CH2 − CH2 OH (2) Sodium metal
| (2) |
CH2 OH CH2 (3) Hydrogen iodide
| (4) Acidic potassium dichromate
CH3
CH3 (4) CH3 − CH2 − OH [99] T N T has the structure
|
(1) (2)
(3) CH3 − C − OH
|
CH3

[95] The order of stability of carbonium ions is

(1) Methyl > ethyl > iso-propyl > tert-butyl (3) (4)
(2) Tert-butyl > iso-propyl > ethyl > methyl
(3) Iso-propyl > tert-butyl > ethyl > methyl
(4) Tert-butyl > ethyl > iso-propyl > methyl
[96] Cresol has
(1) Alcoholic -OH (2) Phenolic -OH
(3) -COOH (4) -CHO
[100] The compound which gives the most stable carbo-
[97] Which statement is not correct about alcohol nium ion on dehydration is

(1) Alcohol is lighter than water CH3 − CH − CH2 OH

(1) |
(2) Alcohol evaporates quickly CH3
(3) Alcohol of less no. of carbon atoms is less soluble CH3
in water than alcohol of high no. of carbon atoms |
(4) All of these (2) CH3 − C − OH
|
[98] Ethyl alcohol exhibits acidic character on reacting CH3
with
(3) CH3 − CH2 − CH2 − CH2 OH
CH3
(4) |
CH3 − CH − CH2 − CH3

Page No : 4
 Scholars Forum
Subject : Chemistry Paper Set : 1
Standard : 12 12 ALG NEET 24072023 Date : 30-07-2023
Total Mark : 180 Time : 1H:0M

Chemistry - Section A - MCQ



[51] ए ोहल क जल म अ धक वलेयता का कारण है (1) −CH2 OH (2) > CHOH

(1) सह-संयोजक ब (2) आय नक ब

| (4)
(3) − C −OH
|
(3) जल के साथ H-बंध (4) इनम से कोई नह

[52] न म से कौन फनॉ लक है

(1) थै लक अ (2) फॉ ो रक अ [59] अ के ए रीकरण म अ अ भकमक होगा
(3) प कअ (4) फे नल एसी टक अ
(1) ए हाइड (2) ए ोहल
[53] सरॉल का थनांक, ोपेनॉल से अ धक है क (3) एमीन (4) जल

(1) इसम हाइ ोजन बंध ह (2) संकरण के कारण [60] न ल खत म से कसके हैलोजनीकरण के फल प मे थल
(3) अनुनाद के कारण (4) इन सभी के कारण समूह के स म कौनसा मेटा त ायी उ ाद मु उ ाद के
प म बनेगा।
[54] ूटने −2− ऑल है (1)
(1) ाथ मक ए ोहल (2) तीयक ए ोहल
(3) तृतीयक ए ोहल (4) ए हाइड

[55] ए रीकरण व ध म सां H2 SO4 का ा काय है

(2)
(1) उ ेरक
(2) नजलीकारक
(3) जलअपघटनकारी
(4) नजलीकारक तथा उ ेरक (3)

[56] फनॉल कम अ ीय है
(1) एथेनॉल से (2) मेथेनॉल से
(3) o− नाइ ो फनॉल से (4) p− मे थल फनॉल से
(4)
[57] ए ोहल का थनांक संगत ए े न से अ धक होता है। इसका
कारण है
(1) अं त:आ क हाइ ोजन ब
(2) अ राआ क हाइ ोजन बंध [61] ूटने ल उदाहरण है
(3) वा शील भाव (1) ाथ मक ए ोहल (2) तीयक ए ोहल
(4) इनम से कोई नह (3) ए लफै टक ए हाइड (4) ए लफै टक क टोन
[58] तीयक ए ोहल क ला णक समूहता है

Page No : 5
[62] ए ोह लक क न कसक या ारा होता है [72] ए थलीन ायकॉल है (25 o C पर)
(1) CO2 (2) O2 (1) ठोस यौ गक (2) व
(3) इ टज (4) यी (3) गैस (4) भूरा ठोस

[63] प कअ (25 o C पर ) है [73] ए ोहल, गनाड अ भकमक से या कर बनाते ह

(1) ेत ठोस (2) रंगहीन व (1) ए े (2) ए
(3) गैस (4) चमक ला पीला ठोस (3) ए ाइ (4) ये सभी

[64] न म से कौनसा यौ गक सबसे अ धक अ ीय है [74] न अ भ या म B यौ गक A तथा B मश: है-

(1) CH4 (2) C2 H6
(3) CH ≡ CH (4) C2 H5 OH

[65] न म कौन समावयवी है

(1)
(1) मे थल ए ोहल तथा डाईमे थल ईथर
(2) ए थल ए ोहल तथा डाईमे थल ईथर
(3) एसीटोन एवं एसीटे हाइड
(2)
(4) ो पयो नक अ व ोपेनॉन
[66] सरॉल कसके नमाण म यु कया जाता है
(1) डायनामाइट (2) वा नश
(3) पे (4) मृदु पेय (Soft drinks) (3)

[67] 23 ाम N a, मे थल ए ोहल के साथ या करके देता है

(1) ऑ ीजन का एक मोल (2) H2 का एक मोल
(4)
(3) H2 का 1
2
मोल (4) इनम से कोई नह

[68] कम अणुभार वाले ए ोहल होते ह

(1) जल म वलेय (2) सभी वलायक म वलेय
[75] साय ोहै ेनॉल का संरचना सू है
(3) सभी वलायक म अ वलेय(4) गम करने पर जल म वलेय
(1) (2)
[69] एथेनॉल का नजलीकरण करने पर बनता है
(1) एसी टक अ (2) एथेन
(3) ए थलीन (4) एसी टलीन

[70] प रशु (Rectified) ए ोहल है

(1) 100 % शु एथेनॉल (2) 95 % ए ोहल + 5 % (3) (4)
H2 O
(3) एथेनॉल + जल + फनॉल(4) 95 % एथेनॉल + 5 %मेथेनॉल

[71] इले ॉन यु स हत हाइ ोजन के पलायन (माइ ेशन) को कहते

ह
[76] फनॉल को जक रज के साथ आस वत करने पर ा होगा
(1) ए ल श (2) हाइ ाइड श
(3) हाइ ोजन आयन नमाण (4) वहाइ ोजनीकरण

Page No : 6
 (1) C6 H6 (2) C6 H12 (1) अ ोराइड (2) एमाइड
(3) C6 H5 OC6 H5 (4) C6 H5 − C6 H5 (3) ए र (4) ईथर

[77] अनुनाद के कारण फनॉल के −OH समूह का ऑ ीजन परमाणु [82] CH3 CH2 OH म कौन-सा ब वषमांग वदलन (Het-
erolytic clevage) देता है
(1) धनावे शत हो जाता है (2) ऋणावे शत हो जाता है
(1) C − C (2) C − O
(3) अ भा वत रहता है (4) मु हो जाता है
(3) C − H (4) O − H
[78] न म से कौनसा साधारण ईथर है
[83] 3− पे ने ॉल है
(1) CH3 OCH3 (2) C2 H5 OCH3
(3) C H OCH (4) C H OC H (1) ाथ मक ए ोहल (2) तृतीयक ए ोहल
6 5 3 6 5 2 5
(3) तीयक ए ोहल (4) इनम से कोई नह
[79] न यौ गक म या क समूह − O− वाला उदाहरण है
′ ′

[84] न ल खत म से कस यौ गक म हाइ ोजन आब होते ह

(1) एसी टक अ (2) मे थल ए ोहल
(1) टॉलुईन (2) फनॉल
(3) डाईए थल ईथर (4) एसीटोन
(3) ोरोबे जीन (4) नाइ ोबे जीन
[80] ूकास परी ण कसके लये यु कया जाता है
[85] CH3 CH2 OH −
→o CH2 = CH2 + H2 O; म ′ X ′ है
X
(1) ए ोहल (2) एमीन 350 C

(3) डाईए थल ईथर (4) े शयल एसी टक अ (1) N aCl (2) CaCl2
(3) P2 O5 (4) Al2 O3
[81] 'एसायल' समूह न म नह है

Chemistry - Section B - MCQ(Attemp any 10)



[86] यौ गक X, O3 के साथ अ भ या और उसके बाद Zn/H2 O (1) > CHOH (2)

के साथ अ भ या ारा उ ाद के प म फॉम हाइड और 2−
मे थल ोपेनैल देता है। यौ गक X है।
(1) 2−मे थल ूट−1−ईन (2) 2−मे थल ूट−2−ईन (3) −CH2 OH (4)
(3) पे −2−ईन (4) 3−मे थल ूट−1−ईन

[87] क न है
(1) ऊ ाशोषी अ भ या (2) ऊ ा ेपी अ भ या
[91] सो डयम धातु के तए ोहल क याशीलता का म होता
(3) उ मणीय अ भ या (4) इनम से कोई नह है

[88] कस यौ गक का थनांक सव है (1) ाथ मक > तीयक (2)

> ाथ मक > तीयक <
तृतीयक तृतीयक
(1) एसीटोन (2) डाईए थल ईथर (3) ाथ मक < तीयक (4)
> ाथ मक < तीयक <
(3) मेथेनॉल (4) एथेनॉल तृतीयक तृतीयक

[89] ए ोहल के थनांक, संब धत थायोल से . . . . होते ह [92] ए ोहल क ारीय धातुओ ं तथा अ आ द के साथ अ भ या
म कौनसा ए ोहल सबसे अ धक ती ता से या करता है
(1) अ धक (2) समान
(1) तीयक (2) तृतीयक
(3) इनम से कोई भी (4) कम
(3) ाथ मक (4) सभी समान
[90] ाथ मक ए ोहल का सामा सू है
[93] न म से कौन डाईहाइ क ए ोहल है

Page No : 7
 [98] ए थल ए ोहल कसके साथ अ भ या करके अ ीय गुण
(1) सरॉल (2) ए थलीन ायकॉल दशाता है
(3) केटीकॉल (4) रसो सनॉल
(1) एसी टक अ
[94] एक तीयक एवं दो ाथ मक ए ोह लक समूह। (2) सो डयम धातु
CH2 OH CH2 (3) हाइ ोजन आयोडाइड
| |
(1) CH − OH CH3 − CH2 − CH2 OH (4) अ ीय पोटे शयम डाई ोमेट
| (2) |
CH2 OH CH2 [99] T N T क संरचना है
|
CH3 (1) (2)
CH3 (4) CH3 − CH2 − OH
|
(3) CH3 − C − OH
|
CH3
(3) (4)
[95] काब नयम आयन के ाय का म है

(1) मे थल > ए थल > आइसो- ो पल > तृतीयक- ू टल

(2) तृतीयक- ू टल > आइसो- ो पल > ए थल > मे थल
(3) आइसो- ो पल > तृतीयक- ू टल > ए थल > मे थल
(4) तृतीयक- ू टल > ए थल > आइसो- ो पल > मे थल
[96] सॉल के पास है [100] यौ गक जो नजलीकरण पर सवा धक ायी काब नयम आयन
(1) ए ोह लक -OH (2) फनॉ लक -OH बनाता है

(3) -COOH (4) -CHO CH3 − CH − CH2 OH

(1) |
CH3
[97] ए ोहल के स म कौनसा कथन सही नह है
CH3
(1) ए ोहल जल से ह े होते ह |
(2) CH3 − C − OH
(2) ए ोहल शी ता से वा ीकृत होते ह |
CH3
(3) कम काबन परमाणु सं ा वाले ए ोहल, अ धक काबन
(3) CH3 − CH2 − CH2 − CH2 OH
परमाणु सं ा वाले ए ोहल क अपे ा जल म कम
घुलनशील होते ह CH3
(4) |
(4) ये सभी CH3 − CH − CH2 − CH3

Page No : 8
 Scholars Forum
Subject : Che Paper Set : 1
Standard : 12 12 ALG NEET 24072023 (Answer Key) Date : 30-07-2023
Total Mark : 180 Time : 1H:0M


Chemistry - Section A - MCQ


51 - 3 52 - 3 53 - 1 54 - 2 55 - 4 56 - 3 57 - 1 58 - 2 59 - 2 60 - 3
61 - 3 62 - 4 63 - 4 64 - 4 65 - 2 66 - 1 67 - 3 68 - 2 69 - 3 70 - 1
71 - 2 72 - 2 73 - 1 74 - 3 75 - 1 76 - 1 77 - 1 78 - 1 79 - 3 80 - 1
81 - 4 82 - 4 83 - 3 84 - 2 85 - 4



Chemistry - Section B - MCQ

86 - 4 87 - 2 88 - 4 89 - 1 90 - 3 91 - 1 92 - 3 93 - 2 94 - 3 95 - 2
96 - 2 97 - 3 98 - 2 99 - 4 100 - 2

Page No : 9
 Scholars Forum
Subject : Che Paper Set : 1
Standard : 12 12 ALG NEET 24072023 (Solutions) Date : 30-07-2023
Total Mark : 180 Time : 1H:0M


Chemistry - Section A - MCQ

[51] Maximum solubility of alcohol in water is due to

Solution:[ Correct Answer : B ]
(1) Covalent bond (2) Ionic bond
(3) H-bond with H2 O (4) None of the above It's Obvious.
[55] The role of conc. H2 SO4 in the esterification pro-
Solution:[ Correct Answer : C ] cess is
(1) Catalyst
(c) Alcohol is soluble in water due to H−bonding
δ− δ+ δ− δ+ δ− δ+ (2) Dehydrating agent
O −H ·· · · · O −H ·· · · O −H
| | | (3) Hydrolysing agent
R H R
Alcohol Water (4) Dehydrating agent and catalyst
[52] Which of following is phenolic
(1) Phthalic acid (2) Phosphoric acid Solution:[ Correct Answer : D ]

(3) Picric acid (4) Phenylacetic acid It's Obvious.

[56] Phenol is less acidic than
Solution:[ Correct Answer : C ]
(1) Ethanol (2) Methanol
(3) o-nitrophenol (4) p− methylphenol

Solution:[ Correct Answer : C ]

(c) Picric acid is phenolic whileothers are non pheno-

lic.
[53] The boiling point of glycerol is more than propanol (c) Nitro group is electron with-drawing. Hence,
because of increases acidic nature.
(1) Hydrogen bonding (2) Hybridisation
[57] Boiling point of alcohol is comparatively higher than
(3) Resonance (4) All the above that corresponding alkane due to
(1) Intermolecular hydrogen bonding
Solution:[ Correct Answer : A ]
(2) Intramolecular hydrogen bonding
It's Obvious. (3) Volatile nature
[54] Butane −2− ol is (4) None of these

(1) Primary alcohol (2) Secondary alcohol Solution:[ Correct Answer : A ]

(3) Tertiary alcohol (4) Aldehyde
It's Obvious.

Page No : 10
[58] The characteristic grouping of secondary alcohols
is
(1) −CH2 OH (2) > CHOH Solution:[ Correct Answer : C ]
| (4)
(3) − C −OH
|

Electrophile will attack at ortho and para position

Solution:[ Correct Answer : B ] with respect to better electron releasing group
(ERG)
It's Obvious. ERG : −OH > −CH3
Para position with respect to −OH(+R) group and
[59] In esterification of an acid, the other reagent is it will be meta position with respect to −CH3 group.
(1) Aldehyde (2) Alcohol [61] Butanal is an example of
(3) Amine (4) Water (1) Primary alcohol (2) Secondary alcohol
(3) Aliphatic aldehyde (4) Aliphatic ketone
Solution:[ Correct Answer : B ]

It's Obvious. Solution:[ Correct Answer : C ]

[60] Halogenation of which one of the following will (c)Butanal CH3 − CH2 − CH2 − CHO, an aliphatic
yield m-substituted product with respect to methyl aldehyde.
group as a major product?
[62] Alcoholic fermentation is brought about by the ac-
(1) tion of
(1) CO2 (2) O2
(3) Invertase (4) Yeast

Solution:[ Correct Answer : D ]

(2)
Zymase
(d)Glucose −−−−→ 2C2 H5 OH + 2CO2
(From yeast)
[63] Picric acid is (at 25 o C)
(1) A white solid (2) A colourless liquid
(3)
(3) A gas (4) A bright yellow solid

Solution:[ Correct Answer : D ]

It's Obvious.
(4)
[64] Which of the following compound is most acidic
(1) CH4 (2) C2 H6
(3) CH ≡ CH (4) C2 H5 OH

Solution:[ Correct Answer : D ]

Proton donors are acids. Among given choices

the order of acidity is:
C2 H5 OH > HC ≡ CH
∴ C2 H5 OH is most acidic.
[65] Which of the following are isomers

Page No : 11
 (1) Methyl alcohol and dimethyl ether
Solution:[ Correct Answer : A ]
(2) Ethyl alcohol and dimethyl ether
(3) Acetone and acetaldehyde Ethanol is a colorless, volatile liquid with a char-
(4) Propionic acid and propanone acteristic smell. It is also highly flammable. Ethanol
is a simple alcohol with two carbon atoms and is
Solution:[ Correct Answer : B ] represented by the chemical formula CH3 CH2 OH.
Absolute alcohol is a liquid alcohol solution which
(b) C2 H5 OH and CH3 − O − CH3 are isomers. contains almost more than 99% pure alcohol (ethyl
alcohol) by weight. It is an important constituent
[66] Glycerol is used in the manufacture of of alcoholic beverages. Alcohol is prepared by the
(1) Dynamite (2) Varnish fermentation of sugar through petrochemical pro-
cesses or by yeast. The alcohol obtained through
(3) Paints (4) Soft drinks this method contains some amount of water and
it is removed by adding some dry slat. The dry salt
Solution:[ Correct Answer : A ] absorbs the water content of the ethanol solution as
it passes through and we obtain a pure alcohol, 95%
Absorbed on
(a)Glycerol −−−−→ Glyceryl trinitrate −−−−−−→ Dynamitealcohol +5% water solution is known as rectified al-
HN O3

+
Glyceryl dinitrate
Kieselguhr cohol. It is a highly concentrated solution of ethanol.
[67] 23 g of N a will react with methyl alcohol to give 95% ethanol +5% methanol is known as denatured
alcohol prepared by adding methanol to anhydrous
(1) One mole of oxygen (2) One mole of H2 ethanol. Pure alcohol prepared is denatured.
(3) 2 mole of H2
1
(4) None of these
[71] A migration of hydrogen with a pair of electrons is
called
Solution:[ Correct Answer : C ] (1) Alkyl shift (2) Hydride shift
(3) Hydrogen ion formation
(4) Dehydrogenation
(c) CH3 OH + N a → CH3 ON a + 1
H
2 2
1 mole 1 mole 1/2 mole
(23 gms)

[68] Alcohols of low molecular weight are Solution:[ Correct Answer : B ]

(1) Soluble in water (2) Soluble in all solvents A migration of hydrogen with a pair of electrons
(3) Insoluble in all solvents
(4) Soluble in water on is called hydride shift.
heating
[72] At 25 o C Ethylene glycol is a
Solution:[ Correct Answer : B ] (1) Solid compound (2) Liquid
(3) Gas (4) Brown solid
(b)Lower alcohols are soluble in all solvents.
[69] Dehydration of ethanol gives Solution:[ Correct Answer : B ]
(1) Acetic acid (2) Ethane
It's Obvious.
(3) Ethylene (4) Acetylene
[73] Alcohols react with Grignard reagent to form
Solution:[ Correct Answer : C ] (1) Alkanes (2) Alkenes
Conc. H SO (3) Alkynes (4) All of these
(c)CH3 − CH2 − OH −−−−−o−
2
−→
4
CH2 = CH2 + H2 O
170 C

[70] Absolute alcohol is Solution:[ Correct Answer : A ]

(1) 100 % pure ethanol (2) 95 % alcohol + 5 % H2 O
(3) Ethanol + water + phe-
(4) 95 % ethanol +5 %
nol methanol
(a)

Page No : 12
[74] In the following reaction:
[Image] (1) (2)
The compounds A and B respectively are ......

(1)
(3) (4)

(2)

Solution:[ Correct Answer : A ]

(3)

(4)
(a) cyclohexanol or
[76] Phenol on distillation with zinc dust gives
(1) C6 H6 (2) C6 H12
Solution:[ Correct Answer : C ]
(3) C6 H5 OC6 H5 (4) C6 H5 − C6 H5

Solution:[ Correct Answer : A ]

(a)
[77] Because of resonance the oxygen atom of −OH
group of phenol
(1) Acquires positive
(2) Acquires negative
charge charge
(3) Remains uneffected (4) Liberates
Given reaction is cumene-Peroxide method for the
preparation of phenol. Solution:[ Correct Answer : A ]
In this reaction
[75] The structural formula of cyclohexanol is

(a) Oxygen atom of −OH group acquires positive

charge.

Page No : 13
[78] Which of the following is a simple ether [82] In CH3 CH2 OH which bond dissociates heterolyti-
cally
(1) CH3 OCH3 (2) C2 H5 OCH3
(1) C − C (2) C − O
(3) C6 H5 OCH3 (4) C6 H5 OC2 H5
(3) C − H (4) O − H

Solution:[ Correct Answer : A ]

Solution:[ Correct Answer : D ]
It's Obvious. Heterolytic
(d) CH3 CH2 OH −−−−−→ CH3 CH2 O− + H +
bond fission
[79] An example of a compound with the functional
group − O− is
′ ′ [83] 3− pentanol is a
(1) Acetic acid (2) Methyl alcohol (1) Primary alcohol (2) Tertiary alcohol
(3) Diethyl ether (4) Acetone (3) Secondary alcohol (4) None of these

Solution:[ Correct Answer : C ] Solution:[ Correct Answer : C ]

Functional group' −O−represents ether. i.e. It's Obvious.

R − O − R.
Diethyl ether (C2 H5 − O − C2 H5 ) is an example of [84] Which compound has hydrogen bonding
ether. (1) Toluene (2) Phenol
[80] Lucas test is used for (3) Chlorobenzene (4) Nitrobenzene
(1) Alcohols (2) Amines
Solution:[ Correct Answer : B ]
(3) Diethyl ether (4) Glacial acetic acid

Solution:[ Correct Answer : A ]

(a) Lucas test is used for the distinction of pri-

mary secondary and tertiary alcohols.
[81] Which of the following do not contain an acyl group (b)
(1) Acid chloride (2) Amide
[85] In CH3 CH2 OH −
→o CH2 = CH2 + H2 O; ′ X ′ is
X

(3) Ester (4) Ether 350 C

(1) N aCl (2) CaCl2

Solution:[ Correct Answer : D ] (3) P2 O5 (4) Al2 O3

Acid chloride is RCOCl, Amide is RCON H2 , Es- Solution:[ Correct Answer : D ]

ter is RCOOR, and ether is ROR
Acyl group has the formula RCO−. Hence, ether do Al2 CO3 (X)
CH3 CH2 OH −−−−− −→ CH2 = CH2 + H2 O
not contain acyl group. o 350 C


Chemistry - Section B - MCQ(Attemp any 10)



[86] Compound X on reaction with O3 followed by Zn/

H2 O gives formaldehyde and 2−methyl propanal as Solution:[ Correct Answer : D ]
products. The compound X is :
(1) 2−Methylbut−1−ene(2) 2−Methylbut−2−ene
(3) Pent−2−ene (4) 3−Methylbut−1−ene

Page No : 14
[87] Fermentation is an
(1) Endothermic reaction(2) Exothermic reaction Solution:[ Correct Answer : A ]
(3) Reversible reaction (4) None of these
The reactivity of alcohols towards sodium metal
tollows the same order as the order of acidity of
Solution:[ Correct Answer : B ] alcohols. The order of acidity of alcohols is primary >
secondary > tertiary
It's Obvious. The order of reactivity of alcohols towards N a metal
[88] Which compound has the highest boiling point is also similar. The reactivity of alcohols towards
sodium follows the order primary > secondary >
(1) Acetone (2) Diethyl ether tertiary.
(3) Methanol (4) Ethanol [92] In reaction of alcohols with alkali metal, acid etc.
which of the following alcohol will react fastest
Solution:[ Correct Answer : D ] (1) Secondary (2) Tertiary

(d) Due to hydrogen bonding. (3) Primary (4) All equal

[89] The boiling point of alcohol are . . . . than corre- Solution:[ Correct Answer : C ]
sponding thiols
(1) More (2) Same (c)Order of reactivity with alkali metal (e.g.-Sodium)
(3) Either of these (4) Less follows the order 1o > 2o > 3o .
[93] Which of the following is dihydric alcohol
Solution:[ Correct Answer : A ]
(1) Glycerol (2) Ethylene glycol
In alcohol, hydrogen bonding is present between (3) Catechol (4) Resorcinol
oxygen and a hydrogen atom. Sulfur is less elec-
tronegative than oxygen and hence, forms a weaker Solution:[ Correct Answer : B ]
hydrogen bond than in alcohol.
Stronger the hydrogen bonding, higher is the boiling (b)Glycols are dihydric alcohols (having two hy-
point. Hence, the boiling point of alcohol is more droxyl groups). Ethylene glycol is the first member of
than the corresponding thiol. this series.
CH2 OH
[90] General formula of primary alcohol is
|
(1) > CHOH (2) CH2 OH
[94] Which of the following is tertiary alcohol
CH2 OH CH2
(3) −CH2 OH (4) | |
(1) CH − OH CH3 − CH2 − CH2 OH
| (2) |
CH2 OH CH2
|
CH3
CH3 (4) CH3 − CH2 − OH
|
Solution:[ Correct Answer : C ] (3) CH3 − C − OH
|
(c) −OH group is attached to primary carbon. CH3
[91] Order of reactivity of alcohols towards sodium
metal is Solution:[ Correct Answer : C ]
(1) Pri > Sec > Ter (2) Pri > Sec < Ter
It's Obvious.
(3) Pri < Sec > Ter (4) Pri < Sec < Ter
[95] The order of stability of carbonium ions is

Page No : 15
 [99] T N T has the structure
(1) Methyl > ethyl > iso-propyl > tert-butyl
(1) (2)
(2) Tert-butyl > iso-propyl > ethyl > methyl
(3) Iso-propyl > tert-butyl > ethyl > methyl
(4) Tert-butyl > ethyl > iso-propyl > methyl

Solution:[ Correct Answer : B ]

(3) (4)
CH3
|

CH3 − C+ > CH3 − C H

+
> CH3 C H2
+
>
|
CH3 2o 1o

3o
+
C H3
Methyl
Carbonium ion
[96] Cresol has Solution:[ Correct Answer : D ]
(1) Alcoholic -OH (2) Phenolic -OH
(3) -COOH (4) -CHO

Solution:[ Correct Answer : B ]

It's Obvious.
[97] Which statement is not correct about alcohol (d) 2, 4, 6 Trinitro toulene (T N T )
(1) Alcohol is lighter than water [100] The compound which gives the most stable carbo-
nium ion on dehydration is
(2) Alcohol evaporates quickly
(3) Alcohol of less no. of carbon atoms is less soluble CH3 − CH − CH2 OH
in water than alcohol of high no. of carbon atoms (1) |
CH3
(4) All of these
CH3
Solution:[ Correct Answer : C ] |
(2) CH3 − C − OH
|
(c) Alcohols having less number of carbon atoms CH3
are more soluble in water.
(3) CH3 − CH2 − CH2 − CH2 OH
[98] Ethyl alcohol exhibits acidic character on reacting
with CH3
(4) |
(1) Acetic acid CH3 − CH − CH2 − CH3
(2) Sodium metal
Solution:[ Correct Answer : B ]
(3) Hydrogen iodide
(4) Acidic potassium dichromate (b)Tertiary carbonium ion is the most stable and
it will be given by dehydration of tertiary alcohol.
Solution:[ Correct Answer : B ]

(b) 2C2 H5 OH + 2N a → 2C2 H5 ON a + H2

Page No : 16
 Scholars Forum
Subject : Che Paper Set : 1
Standard : 12 12 ALG NEET 24072023 (Solutions) Date : 30-07-2023
Total Mark : 180 Time : 1H:0M

Chemistry - Section A - MCQ



[51] ए ोहल क जल म अ धक वलेयता का कारण है

Solution:[ Correct Answer : B ]
(1) सह-संयोजक ब (2) आय नक ब
(3) जल के साथ H-बंध (4) इनम से कोई नह
[55] ए रीकरण व ध म सां H2 SO4 का ा काय है
Solution:[ Correct Answer : C ]
(1) उ ेरक
H− बंधन के कारण ए ोहल जल म वलेय है।
δ− δ+ δ− δ+ δ− δ+ (2) नजलीकारक
O −H ·· · · · O −H ·· · · O −H
| | | (3) जलअपघटनकारी
R H R
Alcohol Water
(4) नजलीकारक तथा उ ेरक
[52] न म से कौन फनॉ लक है
(1) थै लक अ (2) फॉ ो रक अ Solution:[ Correct Answer : D ]

(3) प कअ (4) फे नल एसी टक अ

Solution:[ Correct Answer : C ] [56] फनॉल कम अ ीय है

(1) एथेनॉल से (2) मेथेनॉल से
(3) o− नाइ ो फनॉल से (4) p− मे थल फनॉल से

Solution:[ Correct Answer : C ]

(प कअ ) या 2, 4, 6−
प कअ फनो लक है जब क अ फनो लक नह ह।

[53] सरॉल का थनांक, ोपेनॉल से अ धक है क नाइ ो समूह इले ॉन आकष समूह है इस लये यह अ ीय कृ त
बढ़ाता है।
(1) इसम हाइ ोजन बंध ह (2) संकरण के कारण
(3) अनुनाद के कारण (4) इन सभी के कारण [57] ए ोहल का थनांक संगत ए े न से अ धक होता है। इसका
कारण है
Solution:[ Correct Answer : A ] (1) अं त:आ क हाइ ोजन ब
(2) अ राआ क हाइ ोजन बंध
(3) वा शील भाव
[54] ूटने −2− ऑल है
(4) इनम से कोई नह
(1) ाथ मक ए ोहल (2) तीयक ए ोहल
(3) तृतीयक ए ोहल (4) ए हाइड

Page No : 17
 Solution:[ Correct Answer : A ] Solution:[ Correct Answer : C ]

Electrophile will attack at ortho and para posi-

tion with respect to better electron releasing group
[58] तीयक ए ोहल क ला णक समूहता है (ERG)
(1) −CH2 OH (2) > CHOH ERG : −OH > −CH3
Para position with respect to −OH(+R) group and
| (4) it will be meta position with respect to −CH3 group.
(3) − C −OH
|
[61] ूटने ल उदाहरण है
(1) ाथ मक ए ोहल (2) तीयक ए ोहल
(3) ए लफै टक ए हाइड (4) ए लफै टक क टोन
Solution:[ Correct Answer : B ]
Solution:[ Correct Answer : C ]

ूटने ल CH3 − CH2 − CH2 − CHO, एक ए लफै टक

[59] अ के ए रीकरण म अ अ भकमक होगा
ए हाइड है।
(1) ए हाइड (2) ए ोहल
[62] ए ोह लक क न कसक या ारा होता है
(3) एमीन (4) जल
(1) CO2 (2) O2
Solution:[ Correct Answer : B ] (3) इ टज (4) यी

Solution:[ Correct Answer : D ]

[60] न ल खत म से कसके हैलोजनीकरण के फल प मे थल Zymase
Glucose −−−−→ 2C2 H5 OH + 2CO2
समूह के स म कौनसा मेटा त ायी उ ाद मु उ ाद के (From yeast)
प म बनेगा। [63] प कअ (25 o C पर ) है
(1)
(1) ेत ठोस (2) रंगहीन व
(3) गैस (4) चमक ला पीला ठोस

Solution:[ Correct Answer : D ]

(2)

[64] न म से कौनसा यौ गक सबसे अ धक अ ीय है

(1) CH4 (2) C2 H6

(3) (3) CH ≡ CH (4) C2 H5 OH

Solution:[ Correct Answer : D ]

Proton donors are acids. Among given choices

the order of acidity is:
(4) C2 H5 OH > HC ≡ CH
∴ C2 H5 OH is most acidic.

[65] न म कौन समावयवी है

Page No : 18
 (1) मे थल ए ोहल तथा डाईमे थल ईथर
Solution:[ Correct Answer : A ]
(2) ए थल ए ोहल तथा डाईमे थल ईथर
Ethanol is a colorless, volatile liquid with a char-
(3) एसीटोन एवं एसीटे हाइड
acteristic smell. It is also highly flammable. Ethanol
(4) ो पयो नक अ व ोपेनॉन is a simple alcohol with two carbon atoms and is
represented by the chemical formula CH3 CH2 OH.
Solution:[ Correct Answer : B ] Absolute alcohol is a liquid alcohol solution which
contains almost more than 99% pure alcohol (ethyl
C2 H5 OH एवं CH3 − O − CH3 समावयवी ह। alcohol) by weight. It is an important constituent
of alcoholic beverages. Alcohol is prepared by the
[66] सरॉल कसके नमाण म यु कया जाता है fermentation of sugar through petrochemical pro-
(1) डायनामाइट (2) वा नश cesses or by yeast. The alcohol obtained through
this method contains some amount of water and
(3) पे (4) मृदु पेय (Soft drinks) it is removed by adding some dry slat. The dry salt
absorbs the water content of the ethanol solution as
Solution:[ Correct Answer : A ] it passes through and we obtain a pure alcohol, 95%
alcohol +5% water solution is known as rectified al-
Glycerol −−−−→
3
Glyceryl trinitrate −−−−−−→ Dynamite
HN O Absorbed on cohol. It is a highly concentrated solution of ethanol.
+
Glyceryl dinitrate
Kieselguhr 95% ethanol +5% methanol is known as denatured
alcohol prepared by adding methanol to anhydrous
[67] 23 ाम N a, मे थल ए ोहल के साथ या करके देता है
ethanol. Pure alcohol prepared is denatured.
(1) ऑ ीजन का एक मोल (2) H2 का एक मोल
[71] इले ॉन यु स हत हाइ ोजन के पलायन (माइ ेशन) को कहते
(3) H2 का 1
2
मोल (4) इनम से कोई नह ह
(1) ए ल श (2) हाइ ाइड श
Solution:[ Correct Answer : C ]
(3) हाइ ोजन आयन नमाण (4) वहाइ ोजनीकरण
CH3 OH + N a → CH3 ON a + 1
H
2 2
1 mole 1 mole
(23 gms)
1/2 mole Solution:[ Correct Answer : B ]
[68] कम अणुभार वाले ए ोहल होते ह
A migration of hydrogen with a pair of electrons
(1) जल म वलेय (2) सभी वलायक म वलेय is called hydride shift.
(3) सभी वलायक म अ वलेय(4) गम करने पर जल म वलेय
[72] ए थलीन ायकॉल है (25 o C पर)

Solution:[ Correct Answer : B ] (1) ठोस यौ गक (2) व

(3) गैस (4) भूरा ठोस
न ए ोहल सभी वलायक म घुलनशील ह।

[69] एथेनॉल का नजलीकरण करने पर बनता है Solution:[ Correct Answer : B ]

(1) एसी टक अ (2) एथेन

(3) ए थलीन (4) एसी टलीन
[73] ए ोहल, गनाड अ भकमक से या कर बनाते ह

Solution:[ Correct Answer : C ] (1) ए े (2) ए

Conc. H SO
(3) ए ाइ (4) ये सभी
CH3 − CH2 − OH −−−−−o−
2
−→
4
CH2 = CH2 + H2 O
170 C

[70] प रशु (Rectified) ए ोहल है Solution:[ Correct Answer : A ]

(1) 100 % शु एथेनॉल (2) 95 % ए ोहल + 5 %

H2 O
(3) एथेनॉल + जल + फनॉल(4) 95 % एथेनॉल + 5 %मेथेनॉल

Page No : 19
[74] न अ भ या म B यौ गक A तथा B मश: है-
(1) (2)

(1)

(3) (4)

(2)

Solution:[ Correct Answer : A ]

(3)

(4)

साय ोहै ेनॉल और

Solution:[ Correct Answer : C ] [76] फनॉल को जक रज के साथ आस वत करने पर ा होगा

(1) C6 H6 (2) C6 H12
(3) C6 H5 OC6 H5 (4) C6 H5 − C6 H5

Solution:[ Correct Answer : A ]

[77] अनुनाद के कारण फनॉल के −OH समूह का ऑ ीजन परमाणु

(1) धनावे शत हो जाता है (2) ऋणावे शत हो जाता है
(3) अ भा वत रहता है (4) मु हो जाता है
Given reaction is cumene-Peroxide method for the
preparation of phenol.
In this reaction Solution:[ Correct Answer : A ]

[75] साय ोहै ेनॉल का संरचना सू है

−OH समूह का ऑ ीजन परमाणु धनावेश हण करता है।

[78] न म से कौनसा साधारण ईथर है

Page No : 20
 [82] CH3 CH2 OH म कौन-सा ब वषमांग वदलन (Het-
(1) CH3 OCH3 (2) C2 H5 OCH3 erolytic clevage) देता है
(3) C6 H5 OCH3 (4) C6 H5 OC2 H5
(1) C − C (2) C − O
(3) C − H (4) O − H
Solution:[ Correct Answer : A ]

Solution:[ Correct Answer : D ]

Heterolytic
[79] न यौ गक म या क समूह ′ − O−′ वाला उदाहरण है CH3 CH2 OH −−−−−→ CH3 CH2 O− + H +
bond fission
(1) एसी टक अ (2) मे थल ए ोहल [83] 3− पे ने ॉल है
(3) डाईए थल ईथर (4) एसीटोन
(1) ाथ मक ए ोहल (2) तृतीयक ए ोहल
(3) तीयक ए ोहल (4) इनम से कोई नह
Solution:[ Correct Answer : C ]

Functional group' −O−represents ether. i.e. Solution:[ Correct Answer : C ]

R − O − R.
Diethyl ether (C2 H5 − O − C2 H5 ) is an example of
ether.
[84] न ल खत म से कस यौ गक म हाइ ोजन आब होते ह
[80] ूकास परी ण कसके लये यु कया जाता है
(1) टॉलुईन (2) फनॉल
(1) ए ोहल (2) एमीन (3) ोरोबे जीन (4) नाइ ोबे जीन
(3) डाईए थल ईथर (4) े शयल एसी टक अ
Solution:[ Correct Answer : B ]
Solution:[ Correct Answer : A ]

ूकास परी ण का उपयोग ाथ मक, तीयक एवं तृतीयक

ए ोहल के वभेदन लये कया जाता है।

[81] 'एसायल' समूह न म नह है

(1) अ ोराइड (2) एमाइड
(3) ए र (4) ईथर
[85] CH3 CH2 OH −
→o CH2 = CH2 + H2 O; म ′ X ′ है
X
350 C

Solution:[ Correct Answer : D ] (1) N aCl (2) CaCl2

(3) P2 O5 (4) Al2 O3
Acid chloride is RCOCl, Amide is RCON H2 , Es-
ter is RCOOR, and ether is ROR
Acyl group has the formula RCO−. Hence, ether do Solution:[ Correct Answer : D ]
not contain acyl group. Al2 CO3 (X)
CH3 CH2 OH −−−−−
o
−→ CH2 = CH2 + H2 O
350 C


Chemistry - Section B - MCQ(Attemp any 10)

[86] यौ गक X, O3 के साथ अ भ या और उसके बाद Zn/H2 O

के साथ अ भ या ारा उ ाद के प म फॉम हाइड और 2− Solution:[ Correct Answer : D ]
मे थल ोपेनैल देता है। यौ गक X है।
(1) 2−मे थल ूट−1−ईन (2) 2−मे थल ूट−2−ईन
(3) पे −2−ईन (4) 3−मे थल ूट−1−ईन

Page No : 21
[87] क न है
(1) ऊ ाशोषी अ भ या (2) ऊ ा ेपी अ भ या Solution:[ Correct Answer : A ]
(3) उ मणीय अ भ या (4) इनम से कोई नह
The reactivity of alcohols towards sodium metal
tollows the same order as the order of acidity of
Solution:[ Correct Answer : B ] alcohols. The order of acidity of alcohols is primary >
secondary > tertiary
The order of reactivity of alcohols towards N a metal
is also similar. The reactivity of alcohols towards
[88] कस यौ गक का थनांक सव है sodium follows the order primary > secondary >
(1) एसीटोन (2) डाईए थल ईथर tertiary.

(3) मेथेनॉल (4) एथेनॉल [92] ए ोहल क ारीय धातुओ ं तथा अ आ द के साथ अ भ या
म कौनसा ए ोहल सबसे अ धक ती ता से या करता है
Solution:[ Correct Answer : D ] (1) तीयक (2) तृतीयक
(3) ाथ मक (4) सभी समान
हाइ ोजन ब न के कारण।

[89] ए ोहल के थनांक, संब धत थायोल से . . . . होते ह Solution:[ Correct Answer : C ]

(1) अ धक (2) समान
ारीय धातुओ ं (उदाहरण सो डयम) के साथ याशीलता का
(3) इनम से कोई भी (4) कम म 1o > 2o > 3o है।

[93] न म से कौन डाईहाइ क ए ोहल है

Solution:[ Correct Answer : A ]
(1) सरॉल (2) ए थलीन ायकॉल
In alcohol, hydrogen bonding is present between
(3) केटीकॉल (4) रसो सनॉल
oxygen and a hydrogen atom. Sulfur is less elec-
tronegative than oxygen and hence, forms a weaker
hydrogen bond than in alcohol. Solution:[ Correct Answer : B ]
Stronger the hydrogen bonding, higher is the boiling
point. Hence, the boiling point of alcohol is more ायकॉल डाइहाइ क ए ोहल है ( जसम दो हाइ ॉ ल
than the corresponding thiol. समूह होते ह) ए थलीन ायकॉल इस ेणी का थम सद है।
CH2 OH
[90] ाथ मक ए ोहल का सामा सू है |
(1) > CHOH (2) CH2 OH
[94] एक तीयक एवं दो ाथ मक ए ोह लक समूह।
CH2 OH CH2
(3) −CH2 OH (4) | |
(1) CH − OH CH3 − CH2 − CH2 OH
| (2) |
CH2 OH CH2
|
CH3
CH3 (4) CH3 − CH2 − OH
|
Solution:[ Correct Answer : C ] (3) CH3 − C − OH
|
−OH समूह ाथ मक काबन से जुड़ा है। CH3

[91] सो डयम धातु के तए ोहल क याशीलता का म होता Solution:[ Correct Answer : C ]

है
(1) ाथ मक > तीयक (2)
> ाथ मक > तीयक <
तृतीयक तृतीयक
[95] काब नयम आयन के ाय का म है
(3) ाथ मक < तीयक (4)
> ाथ मक < तीयक <
तृतीयक तृतीयक

Page No : 22
 (1) मे थल > ए थल > आइसो- ो पल > तृतीयक- ू टल
Solution:[ Correct Answer : B ]
(2) तृतीयक- ू टल > आइसो- ो पल > ए थल > मे थल
2C2 H5 OH + 2N a → 2C2 H5 ON a + H2
(3) आइसो- ो पल > तृतीयक- ू टल > ए थल > मे थल
(4) तृतीयक- ू टल > ए थल > आइसो- ो पल > मे थल [99] T N T क संरचना है
(1) (2)
Solution:[ Correct Answer : B ]

CH3
|
+ + +
CH3 − C| > CH3 − C H > CH3 C H2 >
CH3 2o 1o (3) (4)
3o
+
C H3
Methyl
Carbonium ion
[96] सॉल के पास है
(1) ए ोह लक -OH (2) फनॉ लक -OH
(3) -COOH (4) -CHO
Solution:[ Correct Answer : D ]
Solution:[ Correct Answer : B ]

[97] ए ोहल के स म कौनसा कथन सही नह है

(1) ए ोहल जल से ह े होते ह

(2) ए ोहल शी ता से वा ीकृत होते ह
2, 4, 6 ाईनाइ ो टॉलुईन (T N T )
(3) कम काबन परमाणु सं ा वाले ए ोहल, अ धक काबन
परमाणु सं ा वाले ए ोहल क अपे ा जल म कम [100] यौ गक जो नजलीकरण पर सवा धक ायी काब नयम आयन
घुलनशील होते ह बनाता है

(4) ये सभी CH3 − CH − CH2 OH

(1) |
CH3
Solution:[ Correct Answer : C ]
CH3
ए ोहल जनम काबन परमाणुओ ं क सं ा कम होती है वे |
जल म अ धक वलेय होते ह। (2) CH3 − C − OH
|
[98] ए थल ए ोहल कसके साथ अ भ या करके अ ीय गुण CH3
दशाता है (3) CH3 − CH2 − CH2 − CH2 OH
(1) एसी टक अ CH3
(4) |
(2) सो डयम धातु CH3 − CH − CH2 − CH3

(3) हाइ ोजन आयोडाइड Solution:[ Correct Answer : B ]

(4) अ ीय पोटे शयम डाई ोमेट
तृतीयक काब नयम आयन सबसे अ धक ायी है और यह
तृतीयक ए ोहल के नजलीकरण ारा दया जायेगा।

Page No : 23