Go Pao o ale, oe Ammes CNH, qoup? one K Peofix~ amino , “Armies ane cleckvec by place Suppiin Un? Rivers atone Sromanta motecutee by alge ange FOP’ eer — contain Samir ae aun acstnetic. tn deutlatty 7 Novoctn > Austosmine, Hug" ~ Benadaye ~ anti tacts ad. Lane fi tion genes Pe Ne 7 p- - Zamue Famine 43 PR ni . | hoe ustosed Nikiogen. atone 4 anes C8 arivalenl es poled ails fis gp dg winatinn _ Genmety? pysanntclat: Nomenclabunre pre nam Aerie commbr anne fons Ettighamine nan proper -2-ameine cH CH: -NH, Fropropylanine N-Methyeethawamre wy -CHs ’ ‘ on Eteybometigk amanne = noche B ° meth amine NN oie or Tam ff « et anamue CH, a . . t Amine eee Benzene acMnetty2 aniline (o) NBL . o-TedutolinePreposation of amines 1. Reotuctinn op netto conpormucls ern pee (ex cor ae (or afetHe 2, Armmonobysis allege habecle® mms aN A SN diss oe NH, FE ' H > NH; +ROX 6 Cam Ge Ge G CRK i piv, oo een Ro poh nek ™ : ek e 5 { s une AnO%G 5 seactinity anannontnr * Onheh of BO pI? p.Be7 Rc PRE ® Reduction dg niites ea HL Ne “cH, -NH, This ceactiow & ea ae oe pee? eng e Nac) /G MeOH at 6 ppd om animes cont auming oe @ Reduction d amides OusALH -CH- - Povw, oa R-CH-NH#,.S : Kodbtiel phitiabrmiste syucth ests : Prepoastion ds only Pamme a °° me lt e Sten $2 EL a at ib naa e ; 1 fact 7 able Gr jee oO i cC-ONG 4 2 NH. | (© : -ona Pamme dhoctiou, 4 atwow p-c NH, th, 48N@ OL —> RNH, + Na, CB F — Auetne ge goonede cont.abn one carton. LO oe 6 Hoffman Apo rndmiale ~~ Amine 40 present bn amide - > [ower amines Ae golubte im ale een lee can fame Hy deogere bowling ane | oe ey : Se po BHO, zen een 8, ’ ote L amavis nce di ex tcl tone b Ho ch Pe amines Ee vac buble Fn 2 ara ik pr mn AES ; Bovbing pone pede B-P Pam w tis & became & p- NZ mer Lamine7 samme wher gextenkg H-bordting .* Thos iteruolecitor arvorboctinn. & mee uM Atty iu 2 amines 08 there are fiuo Choze.. | amin haw ates ake availathe 6% gonna boucl ela Extent of yeh iN an =n -e Sy pe aaa Hwee Noo Ar ycleogtrs Poa 2 amune ow a8 3 : 3.amime > Because 3’ amines have wo lydlan boul belo Che itself . $0 primary amine have te BP. Rasicitis anuines RNA tH-x = p—hnx Csa£o ~ Baste nalluye.ch, omuine a due Lo ua Lone pur RNHt+Ho = R-NH, tow 5) attrarE ut alg ko= CR-NH3J Cowl CR-NHJ 2 pkb= -409 ky ot pkal pastel byt kb pkat pasitty Atkanamme Ys amnivontr. Py © RoW: Qa pr 2p ° -pue foseebilty Pee got rt ® pul Out S Hence 15 Nie, eyabitairrs i (OD constant for ceattio moe than tho) + pe pbetic amines are Sfk0 A paactec Bae tau oan Ouit odes ails ng H Wo Legged 7 tH? zNe 7 cage Be: > our Be u «No solvents tue, ra 3 £ ¥Basuity Gf amines tn aQueoug > Ta substituted ammo niin cation gee mot ory tg election seleasing effe% f ation wetl wate molecule. Auk algo by soiiats =? The Love Aan ing ruore. dy mole cules ore moe stable - for tak amme pA the = 2) pe iH +HO <= RN! R = ty Re: +tHo = BR Accosdivg £0 1 tlers allege SOUP Achlege group be gmoll Lee CH, 7 pen OMe 1 p-Ngl ORe p---OH, f @y--OU, * y= OBL e 3 p-N-U-OK ° \ oN H 2 p poluiolion effece Hb? pie Gs. mo stere . gtobcbied. alkyl gooopl*D) olvogen bonols With. water 40 Whe with be ky volue » 3B H-bonot 2 H-bond u-bonol (7273 20 Aunt hamce fol oondirg bugger ee Ot cc haven tg we paste strength a agers NH. ro, Wo,N 7 Cols NZ CGH, NH 2 COHN 7 CH ine Vb aaron ; e ne on nittosen ON — lone paik 4 ele protonation But bn available ole 4 NH,7 (Cs, aniline Aone pot. AUOn Ante with. Ly yn 7 NA3 nitalte poe aot ene benpene hunggt NYs 7 cht 7% ae eo le 12 lL ee rNHe ~» Bash at, ordes age (eb) + CH, > NHL > iat clebocal, eck os tocalived Eng - AP 2 acts NH CPs pall kb > - > @es I = fy] treet eee . i “ fi i ech, iy Tot Bagece { NH kb> om) OQ - C fe - L—-4 Aoalized & pe Localizek Done poll Hs fone, pat NC Cy j -CH,- -NUWw kebo ole Ol 2 Cy NEL Zz Cy pli, Nps aan =a > © Eph ews c-No[eNY-CFs) Cth [-OHs “hamiobaaats! oe 1 Able sadn of own eeaaay + ann, PBK eB yu 8h FP pe e 7 agin gear tating 900 4 Aven by Fon 2? amunss amd 08{2% pection. with aioe chtoute, anhygtycles Top) « . : a cary (te ge) 63ee HOF N ase > CHy-CH,-NHL\F CHS, { og —— CH NEEL Etkamamime a B an (Pynduie) Lg Ge NH eC tal N Ettybetivanamide y I Bose de Cig Ni CHE -L —— GyHe-it — G—cH, tHE Gus C. Cos 2 a N-eth uf ettandmure. Nity =diebhyh ebharnainnl mse a ose & -N-¢-C eque HB TOM FO Cy > Gols“ GCM ! = ny dic ‘ettiovamidh aj oawrhe: Etmamnte anny Netcare Totem ee oO 5 : : oy Ste ppt é # Reaction carted ont pussoute f sg base pection Rei ee ale als in $802 *, Corb ine xeaction , : aie ek tas ancl AO MTLE promnany, enn Cee weak, p uc +3 eee 13° « egcuntde CFO 25) DL Allee 808 Or obLCny i Ne yo clea. Trorgniche, OE i. 4 Thus tes 7 caun oles ong ? anc omnes I : CON ° a a anes fect Ng ee ROK +N, ae +e.@ Aromatic amines NBL nce 1 2B2Ple nee HNO (6) wenge SS O) saee Nano, +Hce Ben enediazoutum . Aromatic auch abiphatte amines Ae custingibbed by olove Reaction ¢ suphanyl chide Hina eng 20 5. reaction wt § mnt ale a F/27/8 eamnet of amare ° © be tHe ow une Orhg yeoeats 4H ae eutpla A Ethg® aud: { selabew a2? amme , Lan a oe b . rfp vege “OF Ce pivot ce pe atole Batata et ara , hyheen a= Samme fo} te Ss omeattors t a Ko + Gus ai coteNH2 © bromination Nip, [Ho BAT Bt ~ HBR 24,6 - Tab womoanlare - 46- NAL 8 Be ” oda, censco,o MOR Hs Ba age in =? S eee. owceayt Pyptcline- C.H3C00H Anibine Ne Paronye A 2 ettasanud Cmajot) Cncatanctite) he ° actinating ofper® 06 —NH- a HCH gop 4 4- He 7 @ sex than, CAE oh Nt, Horn. because wn we ow fl cus oo Ayn? 20 2tH, tone pate oh uiteo gen B er" ey hosed. 0410 with oa got cannot aetivole penjene ting ag muck os NIL FOP : nati Ne © Nukatow nie NHe NO ia Ovo.” a no,,soe EY + EN hy) ae wo. | CUE) cstte) oie ee Kania ores 4am [he am mation 40K és mayer soem wie ofa ie a a4 f mac TH COCHs i CD Faas 01,0 sabe aca 2) uae (| NOv nfo aucune® Sulptonation @ A eh pn onew Nu,SOF. NH Ms WHE Bue. er OE) Lt HIF etn © SM SO a uM % Ne 9 00k, + HL (0) tat () Ne a ae “ Sank Aeastiniaties ‘ NeERT intext questrous amames a8 2° ae 21 Classy Hoe goto Me CCH), ao a 2 (Hs), CHN HL (ChH9 MH (amme samme C ° Lamune 3 How wie you Convene © Benzene inbs auidhine, ZN HNO [Hsoe ; (Ol 5 Si ae Benzene Nubwbempene [supuee nie +2HL0 Anulune@ Benrene unto N,N Dismettift anette : CcHs), 2CH,B4 ie we J spk Sf ste Gy see ara NyN- tee 6 obi y— tb tbo teranenibaiarmine sind 2 Nacn , Nec, -cN (wc Hye \ 4a chine c aa “vais (aati Mae cH, NH. HUNCH Hewane- |b =-d2 2 Cg HsNH © & @® cune 1 (CH) NH (CHOY Zz CHUNK CpusNHL CoH age reaction 2 Lie fotbovatig aul b ame oe ioc Ce cnet inst pdvocle. nara Cosa? Yeh > (rKs)s Ne 3 spavttepononiem nium pb. e. g O cycle with OHNE, 2 CHBN Z (CHs),NH.@ Wlaute Be teartion ab final able anilune With eKs gomethye athlon OO din & Cosharnal® pwhutcovd. pusence G poditn Ars ae gus NHL 4CHyL tNa,cos— GgHehHetl, +00, +208 * [ew T+ Nae 0% Co 42NaI GG ps NCHDSE 2 Cousens t © Na, Ce, pdt Le melgrcOy-* +Nat anliionitoe 40 a late nate. souctanes 4 dbfpeen ent LOMAS cquren pond NV. (nlacte TUPAC name F Ht ent wit a fownulo, CH 4 ralvech oil, Leprrate. N a gas on Beatin » pci caches Peopant-amene © cucu eens B cuitmctle peemebbye cana’ A, a pinvthye mebcnanie Amo’ Lear ove. | Pamine gre N, gos UNG- pune He cucH or +N +H, @ Cy G4 oP bets. Propose bonnie Ch, cHLCH puopans [- amu chy 5 che -NH i Ny CH HOF +N, theo ces, CH, puopam quame> General gfomula ALTE Aa Aaye youp XC omer 4 sane Nomenclature usoy, Ns etc NS Cle -NeN)>dlaz0 geoup » 2 Suphix c2aponum. & adced. to mame of axen& fay dan coateon fom wick Hey ORL. deviwed. me ce Ks NJ CL Benzene diazo num , 3 Ce He Nt Hou Benzene dingo num Ly OMG ate Stabibity » Pam abephotie, Pe Ques fom ums tobe wi cay onumn BAtk Rewonouce ® Methook Prepaasceeh- N Hs Noteem gute W + NaNO,+H 2 +N& + Ho ae Benz ene dioyonuime chlavdeeh galcal pups |. colourless, caystatine svbiol. bet iu CA walter - 2: opbuble tu wate aud et able Leak wth warm waler 3. Aqueous pptution ane reubal & Litine8 and conduce electricity Aneto presente Gore 4» Bonz eue diaz onium fiusobaate tg wobea msobuble and, stable at em Lempena tie h evnecol aonttion . Reouton mvobuing despmA comendech nitrogen ee requun is: OQ \ Sanam Cu, 2o len. oe +N Cathevmann ceaciou. = aa a eto CaM AS sto REY - Bt +N2 aa Oo +kI “pee + Semegs Chee peusony® 4 pephatomon! byl Ci esrshe ig +! 7 apes re SS] + CHC, 0H oe BN [7 nes +H e N, s 5 ‘G = 3 440 loam 5, +A, tHe Penk - NB Fy k. < = NaNO fy) tHBFy 7 IL Ga Pegi ya, +N, + NaBFy [i aReactan mnvohubng cetentiow of olfa20 ; : i Ccoup bag Rent, + = - | - ane HP Bempome iron Phonek - +H ° p-Agornr ayobenz one Ci ge Aye Capiz tem CNN NN Me prima o bine & cyelhodge) Sean peodiut obcoum eol Fairs botk Ate oromahie 14 ouned. th —N2N- ford ane coho lamol. useck 08 AGS