Rankers Academy JEE

FIITJEE
ALL INDIA TEST SERIES
FULL TEST – II

JEE (Main)-2024
TEST DATE: 07-01-2024

ANSWERS, HINTS & SOLUTIONS

Physics PART – A

SECTION – A

1. D
Sol. let the scooterist velocity be v. Then
1000  10  100   v  100
2000
 100v  2000  v  20 m / s
100

2. B

3. B
Sol. In the given equation [] = [b] [x];
 [b] = []/[x]. But  is mass per unit length and x is distance, therefore
[b] = ML-1/L = ML-2T0.

4. D
Sol. Point A is at rest w.r.t. motion, hence, v at A = 0. At point B there are two horizontal velocities,
hence v B = 2v

5. D
Sol. mg = 2TL  r2Ldg = 2TL   r2dg = 2T.
This relation is independent of L.

6. D

7. A
Sol. Both are diatomic gases are CP – CV = R for all gases.

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8. C
K11l2  K 22l1 K  0  2  3K  100  1
Sol.    60C
K1l2  K 2l1 K  2  3K  1

9. C
1 1 2 3C  2C
Sol.   
C C   C C C  C  C 
 1  3 
2C2  2CC  C 2  0  C  C  
 2 


10. B
Sol. R increasing with increasing temperature.
V = IR
Slope of graph = I/V = 1/R; Slope of T1 is more i.e. 1/R1 is more, hence R1 is less. This concludes
that T1 will be less than T2 as R1 is less than R2.

11. C
R1 R2 4 2 8 4
Sol. Req   parallel     
R1  R2 42 6 3

12. D
V0 100 V 100 V 100
Sol. iR    5, iL  0   10 and iC  0  5
R 20 X L 10 XC 20
2
Current, i  iR2   iC  iL   52  52  5 2 amp.

13. A
Sol. f max   mg , amax   g
2 2 2
If A is the amplitude amax  A  4 A   g
g
Therefore, A 
4 2 2

14. C
Sol. Total time taken to travel distance d is:
d d n n  d 3
 d 1 2  ; n2  3n1  neff  n2
2n1 2n2  2n1n2  neff 2

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15. B
Sol.  A1  A2    A3  A4   A12  A34
16. A
nh h
Sol. mvr  ,  ;
2 mv
1 h
2 r  ...............  i 
mv
h
 ....................  ii 
mv
2 r h  mv 1
Divide (ii) by (i),    1:1
 mv  h 1

17. B
2 1

Sol. VB  VA     2dx   3dy 
1 2 
  2  2  1  3 1  2  
   2  3  1V

18. D
Sol. In the graph given, slope of curve 2 is greater than the slope of curve 1.
P P 
 V    V    2  1
 2  1
 He   O2

19. B

20. B

SECTION – B

21. 10
Sol. Here, mA = 0.5 kg; mB = 1kg

Force on block A
T = mAg ………... (1)
Force acting on block B
F = T + mAg + (mA + mB)g ……. (2)
From (1) and (2)
F   m A g   m A g   m A g   mB g
F  3 m A g   mB g   g  3m A  mB 
 0.4  10   3  0.5  1  10N

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22. 1
ve
Sol. Given, v0 
2
GM 1 2GM

Rh 2 R
hR
When the satellite stops, K = 0
GMm  GMm  1 2
    mv
2R  R  2
v  gR

23. 300
Sol. Here the number of molecules is same. Hence,
T1  T2 200  400
Tfinal    300 K
2 2

24. 2
Sol. Magnetic induction at O due to coil Y is given by,
2
 2 I  2r 
BY  0  ............ 1
4  2r 2  d 2 3/ 2
 
Similarly, the magnetic induction at O due to coil X is given by
0 2 Ir 2
BX   ............  2 
4  r 2   d / 2 2  3/ 2
 
From eq. (1) & (2)
BY 1
=
BX 2

25. 9
Sol. Field inside the shell is zero, so potential is uniform.
kq
V= =9kilo volts
2R

26. 1
Sol. Due to balanced wheatstone bridge ABCEA BE=8Ω can be taken out.

RAC 
1  2  2  4   18  2
1  2    2  4  9
Now, ACFGHA is a balanced Wheatstone bridge, hence HC=10Ω can be taken out

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 Rankers Academy JEE 5 AITS-FT-II-PCM(Sol.)-JEE(Main)/2024

6  18 108
RAG    4.5
6  18 24

V 6.5
Hence, current i    1A
Rtotal 6.5

27. 9

28. 4

29. 2
Sol. Given that:
x  40 cos  50 t  0.02 y 
Particle velocity
dx
vp    40  50    sin  50 t  0.02 y  
dt
Putting y = 25 cm and t = 1/200 s
vp = 10 2

30. 0
Sol. All the four corners will be at the same potential.
W = q∆V = 0

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Chemistry PART – B
SECTION – A

31. A
Sol. 
 C6H5NH3  OH
C 6H5NH2  H2O 

1 0 0
1  
( Dissociation occurs in presence of NaOH and thus dissociation of C6H5NH2 will suppress)
[C6H5NH3 ][OH ] 108 x [OH ]
Kb  
[C 6H5NH2 ] [0.24]
Kw 10 14
 Kb for C6H5NH2 = 
Ka for C6H5NH3 2.4 x 105


10 14 x 0.24
 [OH ]   0.01 .
2.4 x 105 x 10 8
 NaOH = 10 2 M

32. A
 nEo   2x(0.295)  10
Sol. K = antilog 
0.059
 = antilog 
0.059   1x10
   
33. C
Sol. 14 Cl 14 OH 14
NaOH(aq). 
 OH

heat temp.
  
(  HCI)
OH

34. B
1 3
Sol. N 2  g   H 2  g   NH 3  g 
2 2
 
H 298 K   H f    H F  R   11.02  0   11.02 kcal mol 1
p

H 2   11.02 
 C p
T2  T1
H 2   11.02   1 3 
  8.38   6.96   6.89   103
773  298  2 2 
1
H 2  13.6 kcal mol

35. C
Sol. This compound has only one ionizable Cl out of given three

[Co(NH3 )4 Cl2 ]Cl  
[Co(NH3 )4 Cl2 ]  Cl


36. B
2
Sol. Cr  H 2O 6  had Cr 2 

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Cr 2  3d 4 4 s 0 (four unpaired electrons)

Fe 2  3d 6 4s 0 (in the presence of weak ligand, it also has four unpaired electrons).

37. C
Sol. OH
CHO HC
CN

(CHOH) 4 
HCN
 (CHOH) 4 
HOH


CH2OH CH 2OH
x CHOHCOOH COOH

HI
(CHOH) 4  (CH )
2 5

CH2OH CH 3
Y Z

38. B
Sol. Diazonium ion acts as an electrophile in coupling reaction. The greater the electron- withdrawing
power, the higher is the electrophilicity.

39. B
Zn(Hg)
Sol. BrCH2CH2CHO 
HCI
 BrCH2CH2CH3

40. A
Sol. O OH O OH

I2 /NaOH
CH3   ONa
H
The group gives
iodoform test O O
O



OH

If keto group is at β-position w. r. t. COOH heating causes decarboxylation

41. A
Sol. On cis-alkene there is syn addition of two-OH groups forming meso compound

42. D
Sol.
O
O Cl 111o C Cl
3
SiH3 144 0 H3Si Hybridisation of O-atom sp ,
Hybridisation of O-atom sp2 due because of less effective
to more extent of  2p  3d   2p  3d  back bonding due
back bonding to d-orbital resonance

43. D
OH  2
Sol. 

Cu 2   aq   4 NH 3 
 Cu  NH 3 4 

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

H
Cu 2   aq   4 NH 3 
 Cu  4 NH 4  No complex formation 
2 

+ +
As NH3 combines with H of acid the changes to NH4 which have no doner site.

44. B
Sol.  Zn  OH   2 H 
Zn   2 H 2 O  2
2
 Zn  OH 2   H  
Kh  ................1
 Zn  
2
 Zn   OH  
Kb  , K w   H   OH 
 Zn  OH 2 
K w2
  Kh
Kb

45. D
Sol. order of electron gain enthalpy Cl > F > O
Second electron gain enthalpy for an element is always positive.

46. A

47. D

Sol. P H 3  H   PH 4
According to Drago's rule lone pair on phosphorus resides in almost pure s-orbital, hence due to
non-directional nature, its overlapping tendency is greatly reduced in comparison to a lone pair

present in hybrid orbital, which is directional as present in N H 3 .

48. B
Non  redox
Sol. NaCl s   K 2Cr2O7  s   H 2 SO4  few drops  
reaction
 CrO2 Cl2  orange red vapours    HO
CrO2 Cl2  OH  eq .  CrO42aq.  yellowsol.  Cl   2 H 2 O

49. B
Sol. Stability order is I > II > III > IV, because I is neutral, when in II all atoms with complete octet
system while is III is more stable than IV because in case of IV oxygen is positive with incomplete
octet system.

50. B
  
Sol. For M  X  M  X , Ecell  0.44  0.33  0.11 is positive spontaneous.

SECTION – B

51. 33
Sol. ( Moles  volume at constant P and T)

 2NO2 (g)
N2O4 

Initial Moel a 0
Mole at equilibrium (a  x) 2x
Given original volume = (75/100) or existing volume at equilibrium
Or Initial volume = (75/100) x mole at equilibrium

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75
 a (a  x)
100
25
or x  a  0.33a
75
x
 Degree of dissociation,  
a
0.33a
=  0.33 or 33%
a

52. 2
Sol. The ratio constant for the first-order reaction is given by
2.303 a
k log
t ax
Now, when three-fourth of the reaction is complete,
3a
x
4
2.303 a 2.303
 t3/4= log  log 4 …(1)
k a  3a / 4 k
and when the reaction is half completed, x = a/2
2.303 a 2.303
 t1/2 = log  log2 …(2)
k aa/2 k
Dividing (1) by (2), we get
t3/4 log 4 0.6020
  2
t1/2 log 2 0.3010
Thus, the time taken for three-fourth of the reaction to be completed is double than that taken for
half of the reaction

53. 28
Sol. The energy needed to see object = 1017 J
hc
Photon energy used to see object =

6.626 x 10 34 x 3.0 x 108
=
550 x 10 9
19
= 3.61 x 10 J/Photon
17
10
 Number of photons =  27.7
3.61 x 10 19
 Minimum number of photons required to see object = 28
54. 1
1/  n 1
Sol. t1/2   a0  ; where n = order of reaction
1
t1/ 2   a0   1 3  ............1
 2
m

t1/2   a0  ............ 2 

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3
m  1  m  0.5
2
2m  1

55. 4
k2 E  T2  T1 
Sol. log   
k1 2.303  T1T2 
E  10 
log 2 
2.303  290  300 
 E  12062 cal  12 kcal

56. 9
Sol. Total energy released during combustion of
3.5 g gas = (mS) x ∆T
= 2.5 x 0.45 = 1.125 kJ
 Heat released by 1 mole of gas combustion.
28
= x 1.125 (molar mass of gas = 28)
3.5
1
= 9kJ mol

57. 3
Sol. HA 
 H  A
0.1 0 0
 1  1 0.1 1 0.1
0.1 1  
 100  100 100
 H    103  pH  3

58. 66
Sol. The redox changes are
Mn7   5e  Mn2
 C3   2C4  2e
2
 meq. of oxalate ion = meq. of KMnO4
(w/E) x 1000 = 90 x (1/20)
w 9  88 
x 1000   EC O2  
88 / 2 2  2 4
2 
wC O2 = 0.198g
2 4

 % of oxalate in sample = (0.198 x 100)/0.3 = 66%

59. 136
Sol. ∆T = 5.51  1.59 = 3.92, w = 0.186 g
1
W = 7.5g, kf = 4.9 k molality
1000 x K f x w
 T 
mxW
1000 x 4.9 x 0.186
3.92 =
m x 7.5

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 m = 136 g mol1

60. 10
Sol. 2MnO4  5C2O42  16 H   10CO2  2 Mn 2  8 H 2O
+7 +6 +8 +2
2MnO4  5C2O42
M1V1 M 2V2

2 5
0.2  V1 0.1 50

2 5
V1  10 mL

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Mathematics PART – C

SECTION – A

61. A
Sol. a2 + 7a + 1 < 0 and a2 + 8a + 4 < 0 which satisfied by 6 negative integers

62. A
Sol. Relation R is reftexive and symmetry as xRy is true then yRx is also true

63. B
3
Sol. Any number having exactly 4 factors is of the form m = p (p prime) or m = p.q (where p & q are
distinct primes)
So we have 5C2 + 2 = 12 such factors

64. B
[x]x
Sol. lim[x]  lim
x  x  x
[x]x  [x] 
= lim .lim x  lim x  as lim  1 
x  x x  x 
 x  x

n n 1
x  x 1
= lim
x  e[x]
x n  x n 1  1
= lim
x  ex
n 1
1  n
= lim x x
x  x2 xn x n 1
1  x   ..    ...
2! n! (n  1)!
n 1
1  n
= lim x x
x  1 1 1 1 x x2
   ....     ...
x n x n1 2x n2 n! (n  1)! (n  2)!
10 0 1
=   0..
1 
0  0  ..  0 
n!

65. A
Sol. The given equation is dx – x (ydx + xdy) = x 5y4 (ydx + xdy)
dx 1
  (1  x 4 y 4 )d(xy)  Inx  xy  x 5 y 5  Inc
x 5
1
xy  x5 y 5
 x  ce 5

66. B
Sol. The distance of the point (1,3) from the line 3x+4y=5 is 2. Now the value of sec2θ + 2cosec2θ is
greater than 2 hence two such lines will be possible.

67. B
Sol. Incircle and circumcircle have same centre but radius is half of that of circumcircle

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 Rankers Academy JEE 13 AITS-FT-II-PCM(Sol.)-JEE(Main)/2024

Also c =  (2g + 2f + 2) as (1, 1) lies on circumcircle

68. A
Sol. FA = 4, FB = 5
A
1 1 1
We know that 
a AF FB
20 80 F
 a=  4a  O ((a,
9 9
B 0)

69. C
b2
Sol. For the given ellipse a2 = 16. Therefore e = 1
a2
b2 16  b2
 e = 1 =
a2 4
So, the foci ellipse are (ae,0)i.e.  16  b2 ,0 
For the hyperbola e is given by
b2 81 15 5
e= 1  1  
a2 144 12 4
2
 12 5 
2 2
So, 16 – b =  x   9  b  7
 5 4

70. B
a2  1 
Sol. cos2   ,tan  tan2/3 
3 2

sin3
tan
3 
 tan   2  sin 
2  cos 
cos 3
2
 
sin3 cos3
2 2 k
sin  cos 

sin3 = k sin α ...(I)
2

cos3 2 = k cos α ...(II)

k2/3sin2/3 α + k2/3cos α = 1
2/3 2/3 1
sin α + cos α= 2/3
k
Squaring and adding (I) and (II)
3
        
k2 (sin2   cos2 )  sin6  cos6   sin2  cos2   3sin2 cos2  sin2 cos2 
2 2  2 2 2 2 2 2
2 a2 a
k = k 
4 2

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2/3
2/3 2/3 2
sin α + cos α=  
 a

71. C
Sol. Let assume that ‘A’ wins after n deuces, n [(0, )]
2 2 1 1 5
Probability of a deuce = .  . 
3 3 3 3 9
(A wins his serve then B wins his serve or A loses his serve then B also loses his serve) Now
probability of 'A' winning the game

n  21 1 2 1
 (5 / 9) .  3  3  1  (5 / 9) . 9  2
n 0

72. A
Sol. n(A)  31x31
n(B) = 41 x 21
n(C) = 11 x 11x 11
n(A  B) = 31 x 21
n(B  C) = 11 x 11
n(C  A) = 11 x 11
n(A  B  C) = 11 x 11
So n (A  B  C)
= 2381

73. A
Sol. 3 median = 2 Mean +Mode

74. D
Sol. There will be (n1 + 1) gaps created by n1 men. Now women have to be seated only in these gaps.
n1 1
Thus number of such sitting arrangements = Cn 2 (n1!)(n2!)

75. C
Sol. Since x2 y3 z4 is occurring in the expansion of (x +y +z)n , so n should be 9 only.
9!
Now A =  1260
2!x3!x4!
9! A
Coefficient of x4 y4 z =  630 
4!x4! 2

76. B
xy
Sol.  n  xy  nx  ny  0
xy
 (x  n) (y  n) = n2
2
No. of positive solutions = No. of division of n
= 7 x 9 x 13 = 819

77. D
(1  x) (1  x)ex x x
Sol. Let = I   x(1  xex )2  (xex )(1  xex )2 dx(1  xe  p,e (1  x)dx  dp)
dx 

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 Rankers Academy JEE 15 AITS-FT-II-PCM(Sol.)-JEE(Main)/2024

dp
I 
(p  1)p2
dp A B C
2
   2
(p  1)p (p  1) p p
1 = Ap2 + B(p) (p  1)  C(p  1)
For = p = 1, p = 0, and p = 1 , A = C, C = 1 and B = 1
1 dp dp (p  1) 1  xex   1 
I  dp     2  In   c  In  x  x c
(p  1) p p p p  1  xe   1  xe 

78. B
1 n  r  
Sol. lim   tan   
x  n
 r 1  3n  
r 1
 x,  dx
n n
 /3
 x  3 3 3
0 tan 3  dx   |Inset|0   In2 ( t  x / 3)

79. B
     
Sol.  a xb  b x c  c x a
   
   
  axb  2 b x c
  2

80. B

Sol. a.b  (xi  (x  1)j  k)
 . ((x  1)i  j  ak)

= x (x + 1) + x  1 + a
= X2 + 2x + a  1
We must have
 
a.b  0x R
 x2 + 2x + a  1  0x R
 4  4 (a  1) < 0
 a>2

SECTION – B

81. 2
Sol. Image of A(1, 2) in y = x will be So B is (2, 1) A (1, 2)
Image of A(1, 2) in x  2y + 1 = 0 will lie on BC.
9 2
So another point on BC is  , 
 5 5 y=x
x – 2y +
Equation of BC is 3x  y  5 = 0
B C

82. 2
2ac b 2c b  a 3c  a
Sol. a, b, c are in H.P  b =     …(i)
a c a ac ba c a
Again a, b, c are in H.P.

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2ac b 2a b  c 3a  c
b     …(ii)
a c a a c bc ac
b  a b  c 3c  a 3c  a
From (A) and (B)    2
b a b c c a ac

83. 0
Sol. The combined equation of the tangents drawn from (0,0) to
x2+y2 –2rx –2 hy + h2 = 0 is
(x2 +y2 – 2 rx – 2 hy + h2)h2 = (–rx – hy + h2)2
This equation represents a pair of perpendicular straight lines
If coefficient of x 2 + coefficient of y2 = 0 i.e. 2h2 – r2 – h2 = 0  r2 = h2 or r =  h.

84. 5
Sol. Shortest distance will take place through along the common y
normal
2 2
Equation of normal for y = 4x at (at , 2t) is A
y =  tx + 2t + 3 t
If it passes through (6, 0),
x
then t3  4t = 0 O (6,0)
 t = 0, t =  2
C
 Min distance = 20  25
= 2 5 5 5

85. 26
Sol. Shaded region is the required one.
1
 Required Area = 4x x2x2  .2  8  2 sq. units
2

86. 21
1 1 1
Sol. Hint: trace of A n1    
a11 a22 a33
 ...

 a1 b1 c1 
A 3   0 b2 c2 
 0 0 c3 
1 
 a k1 k2 
 1 
1  1 
then A   0 k3 
b2
 
0 0 1
 c3 

1  5 1 
   traceof  An  
10  n1 
1
=
10
 tr(A11 )  tr(A21 )  tr(A31 )  tr(A 41 )  tr(A 51 )

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1
=  5x 2  4 x 8  3x18  2x 32  50 
10
= 21

87. 63
6
Sol. When everyone gets a different number = C 4 . 4
6 3
When only two persons siting opposite to each other get same number = C3 . C1 .2. 2
6
When two pairs of persons sitting opposite to each other get same number C2 . 2
So = N = 630

88. 11
  
Sol. 15 |AC| = 3|AB| = 5|AD|
Given

Let |AC| =   0

 |AB| = 5 

|AD| = 3 
 ^  
Now cos BA CD  
D(d)
C(c)
    
BA .CD
=      
 b. dc   …(1)
|BA ||CD| |b||d  c|

3
   

/
Now numerator of (1) = b.c  b.d

3
/
     2
= |b||c|cos |b||d|cos 
3 3 A(a)origin 
1 1 5 2  15 2 B(b)
=  5      5  3    102
2 2 2
  
Denominator of (1) = |b||d  c|
  2 2 2  
Now |d c|  d  c  2c . d
9  2   2  2    3  1 / 2  10 2  3 2  7 2
 
 |d  c| 7
Denominator of (1) =  5   
7  5 7  2
  10 2 2
 cosBA ^CD  2

5 7 7

89. 28
 2 2 
Sol. ui  u 1 u
 2 2 
u  2i  u  4  2 u
2  2 2 2 
So,

 u 1 u   u  u  4 2 u 
= u  2 1

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90. 8
Sol. (x 4  1)  (y 4  1)  (z4  1)  0
(x 4  1)  (y4  1)  (z4  1)  0
(x 4  1)  (y 4  1)  (z4  1)  0
1 1 1
  1  1  2  1    1  1    2  3  0
1 1 
∆1 =∆2 =∆3 = 0
x  1  y 4  1  z4  1  0
4

x  1,y  1,z  1
Number of solutions is 8.

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