Professional Documents
Culture Documents
DOI 10.1007/s10163-013-0206-x
REVIEW
Abstract Due to exponential growing in urbanization and at replacement levels of 70 % in lean-mix concrete. ASTM
industrialization, byproducts from industries are becoming C 989 [1] categories three strength grades (Grade 80, 100
an increasing concern for recycling and waste manage- and 120) of slag, depending upon their respective mortar
ment. Ground granulated blast furnace slag (GGBS) is by- strengths when blended with an equal mass of Portland
product from the blast-furnaces of iron and steel industries. cement. Grades 100 and 120 are the most commonly used
GGBS is very useful in the design and development of as admixtures in concrete. Table 1 gives criteria for ASTM
high-quality cement paste/mortar and concrete. This paper C 989 [1] classification. ASTM C 989 [1] valuates the
covers the properties of GGBS, reaction mechanism, and reactivity of GGBS. Reactivity of GGBS depends upon
its effect on strength and durability properties of concrete. chemical composition, glass content, fineness of the slag,
Properties covered are sorptivity, microstructure, com- alkali concentration of the reacting system, and tempera-
pressive strength, splitting tensile strength, flexural ture variations during the early phases of hydration process.
strength, permeability, sulfate resistance, freezing and Daube and Bakker [2] suggested that chemical composition
thawing resistance, corrosion of concrete. and vitreous state determine the hydraulic properties of a
slag. Cheron and Lardinois [3] have indicated that slag
Keywords Concrete Durability properties indices between 1.65 and 1.85 are considered normal. Slag
Strength properties GGBS Sorptivity indices determine the hydraulic properties of a slag
(chemical composition and vitreous state). Hydraulic
activity index = (CaO ? 1.4 MgO ? 0.56 Al2O3)/SiO2
Introduction
Advantages of using GGBS in cement concrete
Ground granulated blast furnace slag (GGBS) is a by-
product from the blast-furnaces of iron and steel industries. There are several advantages of using GGBS in concrete,
Blast-furnaces are fed with controlled mixture of coke, including improved workability, increased strength and
iron-ore, limestone, and operated at a temperature of round durability, reduced permeability, high resistance to chlo-
1,450–1,550 °C. GGBS is used as replacement for cement, ride penetration, sulfate attack, and ASR, low heat of
and replacement percentage could be up to 85 % depend- hydration, enhancement of the life cycle of concrete
ing upon the applications. Generally 50 % is used in most structures, and reduction in maintenance and repair costs
applications. Higher replacement rates up to 85 % are used
in specialist applications such as in aggressive environ- Environmental benefits of using GGBS
ments and to reduce heat of hydration. GGBS can be used
The use of GGBS as partial cement replacements with
lower environmental burdens offers opportunities for sig-
R. Siddique (&)
nificant reductions in energy use and carbon dioxide
Department of Civil Engineering, Thapar University, Patiala,
Punjab 147004, India emissions. Proportions of up to 70 or even 80 % can be
e-mail: siddique_66@yahoo.com used with advantage in suitable situations. The use of
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7-day index, minimum Elahi et al. [4] reported the sorptivity of concrete con-
Grade 80 – – taining 50 and 70 % GGBS at the age of 44 and 91 days. It
Grade 100 75 70 was observed that sorptivity of control concrete were
Grade 120 95 90 100 m3 9 10-7/min at 44 and 91 days, respectively.
28-day index, minimum Concrete made with 50 % GGBS yielded lower value of
Grade 80 75 70 sorptivity (77.1 m3 9 10-7/min ) at 44 days compared
Grade 100 95 90 to that at 91 days (96.9 m3 9 10-7/min ) whereas there
Grade 120 115 110 was significant increase in sorptivity (120.1 m3 9 10-7/
min ) with 70 % GGBS at 44 days but considerably
reduced the sorptivity (103.8 m3 9 10-7/min ) at
Table 2 Physical properties of GGBS 91 days.
Property Tasong et al. Oner and Hui-sheng
[41] Akyuz [42] et al. [15] Microstructure
Specific gravity 2.9 2.87 2.89
Daube and Bakker [2] reported that addition of GGBS
Specific surface (m2/kg) 425–470 425 371
modifies the products and the pore structure in hardened
Bulk density (kg/m3) 1200 –
cementitious materials. Large amounts of calcium
hydroxide and large capillary pores (0.05–60 lm) were
found in OPC specimens, but only sa mall quantity of
Table 3 Chemical composition of GGBS needle-shaped ettringite existed in GGBS concrete with
capillary pores that were less than (10–50 lm), which
Composition Tasong et al. Oner and Akyuz Hui-sheng et al.
(%) [41] [42] [15] could be filled up with pozzolanic reaction products such as
low-density C–S–H gel. Basheer et al. [5] mentioned that
CaO 41.99 32.82 30.13 GGBS can be effectively used to reduce the pore size in
Al2O3 11.59 10.18 13.76 concrete. Higher GGBS content results in denser structure
SiO2 35.34 39.18 36.39 and prevents concrete from water penetration. This is
MgO 8.04 8.52 9.36 because GGBS reacts with water calcium hydroxide to
Fe2O3 0.35 2.02 2.44 form extra C–S–H gel in the paste and slows down the
MnO 0.45 – strength development at an early age. Luo et al. [6]
SO3 0.23 – 1.30 reported that coarse pores of GGBS concrete were much
fewer and the pore structure of OPC concrete was
improved greatly when 70 % GGBS was added (at
GGBS in concrete results in following environmental 60 days). However, sulfates did not improve the pore
benefits (1) saves energy; (2) reduces emission of carbon structure of GGBS as expected.
dioxide; (3) conserves natural resources. Gao et al. [7] studied the morphology of the hydration
products in concrete made with (GGBS) using SEM.
Properties of GGBS Specific surface areas of cement and GGBS were 361 and
600 m2/kg, respectively. Cement was replaced with 40 %
GGBS is a fine glassy material and its colour varies from GGBS. At the curing age of 7 days, the GGBS particle
dark to off-white depending on moisture content, chemistry surface was covered with hydration product. Binici et al.
and efficiency of granulation. Its specific gravity is less [8] made micro-structural studies of blended cements pre-
than that of cement, but is finer than cement. Its physical pared with clinker (4 %), and made with basaltic pumice
properties, reported by some authors are given in Table 2. and GGBS. Totals of 10 and 30 % of additives (pumice and
GGBS is a non-metallic product, mainly consisting of sil- GGBS) were incorporated into these blends. Cement paste
icates and alumino-silicates of calcium and other bases. and mortars were made with OPC, two types of grinding
Slag is made up of both glassy and crystalline phases. The systems (inter-grinding and separate grinding), at two
glassy nature is responsible for its cementitious properties. Blaine values (2800 ± 30 and 4800 ± 30 cm2/g). A large
In GGBS, glass content is between 85 and 90 %. The amount of needle-shaped ettringite and plate-shaped cal-
typical chemical composition of GGBS is given in Table 3. cium hydroxide were observed in the blended cement,
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indicating the formation of Portlandite (P) and CSH in Table 4 Compressive strength results [9]
OPC. The main hydration products are cotton-shaped CSH Mix code Compressive strength (MPa)
gel and a certain amount of needle-shaped ettringite.
7 days 14 days 28 days
Compressive strength OPC 39.5 45.3 53.1
55 % GGBS source 1 18.5 28.5 42.5
Wainwright and Rey [9] observed that source of the slag 55 % GGBS source 2 26.0 38.5 50.5
appeared to have little influence on strength development, 55 % GGBS source 3 22.5 36.0 50.5
and strength of OPC concrete and those containing GGBS 55 % GGBS source 4 25.0 41.5 51.5
increased with age (Table 4). Babu and Kumar [10] dem- 85 % GGBS source 1 17.5 28.0 33.5
onstrated that the slag concretes based on overall efficiency 85 % GGBS source 2 21.5 33.5 41.0
factor (k), will need an increase of 8.6 % for 50 % 85 % GGBS source 3 17.5 25.5 29.5
replacement and 19.5 % for 65 % replacement in the total 85 % GGBS source 4 19.0 26.5 32.5
cementitious materials for achieving strength equivalent to
that of normal concrete at 28 days. The efficiency factor
(k) is generally defined in terms of its strength relative to
90
control concrete. The efficiency factor (k value) is defined
as the portion of the pozzolanic material such as GGBS, 80
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70 6
Control
60
Compressive strength (MPa)
40% GGBS
30
20 2
10
0
1 10 100 0
Curing time (days) Control 40% GBS 60% GGBS 80% GGBS
Fig. 2 Effect of GGBS on compressive strength development [13] Fig. 3 Effect of GGBS on flexural strength [13]
Table 6 Compressive strength of concrete at 28 days [14] Flexural and tensile strength
Mixture Compressive strength (MPa)
Ujhelyi and Ibrahim [16] reported the results of the effect
Wet cured Dry cured of hot weather on the flexural strength of concrete made
Name 0.3 0.4 0.5 0.3 0.4 0.5
with GGBS. It was observed that (1) concretes (casting and
curing at ?42 °C) containing slag as a partial replacement
CP-350-00 75.8 63.9 53.6 72.4 63.9 52.3
of cement (up to 40 %) had higher flexural strengths than
GS-350-20 81.4 65.8 57.0 73.3 60.4 50.6
that of concretes made with Portland cement alone; and (2)
GS-350-40 81.0 67.2 55.0 72.0 57.6 46.5
flexural strength of concretes made with slag was equal (or
GS-350-60 73.3 61.8 45.1 57.2 52.6 40.4
higher) in comparison to Portland cement concrete cast and
GS-350-80 62.7 50.4 29.9 50.2 42.7 26.9
cured in high temperature. Khatib and Hibbert [13]
CP-400-00 80.7 63.9 51.4 73.1 65.6 36.9
investigated the influence of GGBS (0, 40, 60, and 80 %)
GS-400-20 81.4 66.0 52.6 69.6 63.1 37.5
on the flexural strength of concrete (Fig. 3). The flexural
GS-400-40 82.0 66.9 51.6 66.5 61.6 35.4
strength of concrete containing 60 % GGBS was notice-
GS-400-60 77.8 61.1 40.1 68.2 59.0 30.5
ably higher than the control, whereas a slight decrease at
GS-400-80 67.7 53.1 25.3 54.4 47.2 19.7
40 % and marked decrease at 80 % replacement were
CP-450-00 80.3 64.3 48.7 75.0 68.2 41.7 observed.
GS-450-20 81.8 73.5 50.4 73.2 69.1 36.3 Guo et al. [17] investigated the flexural fatigue (Table 7)
GS-450-40 83.8 66.4 49.3 76.4 61.7 35.1 of concretes made with GGBS (50 and 80 %) by mass of
GS-450-60 80.6 61.8 39.5 58.2 54.2 28.3 total cementitious material, with control concrete having
GS-450-80 66.3 46.8 27.7 56.0 42.6 17.6 460 kg/m3 of cement, aggregate-binder ratios and water-
binder ratios were 2.4 and 0.35, respectively. It was
observed that the fatigue life of 50 % GGBS concrete is the
longest and that of 0 % GGBS concrete is the shortest, with
observed that HPC with GGBS at w/b of 0.30, compressive stress levels of 0.80 or more. However, when the stress
strength reached highest value at optimum replacement of level was lower than 0.80, the fatigue life of 80 % GGBS
15 %. concrete was the longest among three mixes.
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Table 7 Average cycles of flexural fatigue life [17] 9.84 9 10-4m2/s for compressive strengths between 62.5
Stress levels Average cycles
and 91.1 MPa.
Cheng et al. [21] concluded that a higher GGBS per-
GGBS content (%) centage made structure denser and prevented concrete from
0 50 80 water penetration and resulted in lower coulombs passed in
the RCPT test. Hooton and Titherington [22] observed that
0.90 68 114 78
concretes containing ground granulated blast-furnace slag
0.85 1015 1355 620
(GGBS), silica fume (SF), or ternary blends of SF exhibited
0.80 4212 9506 5904
improved chloride penetration resistance compared to
0.75 50,433 43,679 59,971
those of plain Portland cement concretes.
0.70 413,988 469,963 565,779
0.65 2,000,801 [2 9 106 [2 9 106
Sulfate resistance
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Portland cement 34 41 53 66 68 69 97 87 0 85 74 28
60 % GGBS 17 31 48 65 69 73 106 97 62 95 75 18
70 % GGBS 13 28 49 63 66 71 105 89 90 94 77 28
60 % GGBS ? CaCO3 15 28 45 67 69 76 99 97 84 96 83 41
60 % GGBS 19 29 47 68 67 72 97 99 33 94 81 19
2 % SO3
60 % GGBS 18 32 50 62 69 75 102 99 80 94 88 50
3 % SO3
performed somewhat better, whereas the GGBS concretes exhibited less expansion than concrete incorporating 50 %
performed distinctly less well in the magnesium than the slag at corresponding ages.
sodium solution. This is what is normally observed with
GGBS concrete, which is generally more susceptible to Corrosion resistance
attack by magnesium sulfate than sodium sulfate.
Li and Roy [32] have indicated that for good-quality con-
Alkali silica reaction crete, use of GGBS is very advantageous. It not only
reduces the porosity, but also the pores become finer and
GGBS could be very effective in controlling ASR because the change in mineralogy of the cement hydrates leads to a
(1) GGBS reduces the alkalinity of the concrete, and thus reduction in the mobility of chloride ions. Mangat and
the alkali-silica ratio; (2) GGBS reduces mobility of alkalis Molloy [33] indicated that replacement of cement by up to
in the concrete; and (3) GGBS reduces free lime in con- 40 % GGBS had no significant influence on rebar corro-
crete which is regarded as an important factor for alkali sion. At 60 % GGBS, corrosion rate of reinforcement was
silica reaction. significantly reduced. Al-Amoudi et al. [34] studied the
Hogan and Meusel [28] reported that partial replacement long-term corrosion resistance of steel rebars in 5 %
of high-alkali cement with slag dramatically reduces the sodium chloride solution, and concluded that corrosion rate
likelihood of alkali aggregate reaction in concrete. of the steel rebar in GGBS containing concrete specimen
Kwon [29] investigated the influence GGBS (0, 30, 45, was between one-half and one-twelfth of those in plain
and 60 %) on the alkali-aggregate reaction of high-strength concrete specimens. Torii et al. [35] concluded that the
concrete. High-strength concrete with a cement content of resistance to chloride ion penetration of 50 % GGBS
450 kg/m3, and three types of GGBS with a fineness of concrete was almost the same as that of 10 % silica fume
4,000, 6,000, and 8,000 cm2/g were used. It was observed concrete. Jau and Tsay [36] evaluated the slag cement
that (1) the expansion coefficients were 0.20, 0.105, 0.06, subjected to seawater corrosion at various ages and con-
and 0.02 % with GGBS replacement ratio of 0, 30, 45 and cluded that slag concrete with 20–30 % substitution has the
60 %,, indicating the AAR-inhibiting effect of GGBS; and best corrosion resistance properties.
(2) fineness of GGBS had a significant effect, and differ- Yeau and Kim [37] studied the influence of GGBS on
ences were most significant when the replacement ratio the corrosion resistance of concrete made with two types of
was 30 %. The AAR-inhibiting effect was highest with a cements (ASTM Type I or ASTM Type V) and varying
fineness of 8,000 cm2/g, followed by 6,000 and 4,000 cm2/ percentages (0, 25, 40, and 55 %) of GGBS. Figure 4
g in this order. shows the results obtained from the measurements of sur-
Hester et al. [30] concluded that partial replacement of face area corroded from steel bars. It was observed that (1)
Portland cement with slag (50 %) significantly reduced the the corroded surface area (%) depend on the thickness of
expansion of the concrete, and there was no significant the concrete cover, and GGBS content; (2) corroded areas
difference in behavior irrespective of aggregate type or of steel embedded in control concrete mixtures were about
alkali load, indicating that the alkali level of the slag was is 2 times and 3 times larger than those of steel involved in
not a contributory factor at the 50 % replacement level. 40 % GGBS concrete mixture and 55 % GGBS concrete
Bouikni et al. [31] showed that continued exposure to a hot mixture, respectively; and (3) proportion of corroded areas
and humid regime resulted in increasing expansion, but the in Type I cement was lower than that of the corroded areas
concrete-containing 65 % slag replacement always in Type V cement. These results suggested that the
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Surface area of stel corroded (%) 100 Yuksel et al. [40] studied the effect of granulated blast
-- Type I cement furnace slag (GBFS), bottom ash (BA), and combination of
bar cover 1 cm .. Type V cement
80 both as partial replacement of fine aggregate on the con-
period of water crete durability. Firstly, a reference concrete was produced.
curing: 56 days
Then, three concrete series were produced replacing fine
60
aggregate by GBBS, BA and GBBS ? BA. These series
were designated as C, K, and CK, respectively. Freezing–
bar cover 2 cm
40 thawing resistance was measured by freezing and thawing
the specimens in water. Weight-loss results are shown in
20 Fig. 5. For three series, resistance to freeze–thaw increased
bar cover 3 cm
up to 20 % replacement. However, it decreased again for
0
the replacement level above 20 %. C-series (fine aggre-
0 10 20 30 40 50 60 gates were replaced by 10, 20, 30, 40 and 50 % GGBS)
Amounts of GGBs (% by binder weight) gave the best performance among the three series. For all
the series, the loss in strength was below the loss in
Fig. 4 Surface area (%) corroded from steel bars in concrete
strength value for reference concrete.
specimens [37]
7
Conclusions and summary
6
1. Use of GGBS accelerates the hydration of ordinary
Loss in strength (%)
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