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Title
Recent advances in the construction of sustainable asphalt roads with recycled plastic
Authors
Affiliations
1 Royal Melbourne Institute of Technology, Melbourne, Civil Engineering and Infrastructure,
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This article has been accepted for publication and undergone full peer review but has not been
through the copyediting, typesetting, pagination and proofreading process which may lead to
differences between this version and the Version of Record. Please cite this article as doi:
10.1002/pi.6405
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Abstract
Although various polyolefins have intermittently been used for making roads since the 1980s,
the recycling of plastic waste into roads raises new challenges related to the production,
performance and durability of plastic-modified asphalt. This review critically discusses the
microplastic pollution and contaminant leaching. Recent advances in the field are also
presented and recommendations for future work to address current research and industrial gaps
are suggested. Challenges related to the construction of plastic roads include the wide
variability in the plastic composition and its properties after recycling, which not only affect
the successful incorporation of plastic in bitumen but also impact the mechanical properties
and environmental impact of the roads. The lack of representative testing procedures prevents
an accurate understanding of the short- and long-term performance of plastic roads in real
conditions and the contribution of plastic roads to fuming and microplastics release remains
the release of PAHs and VOCs, as well as microplastics, from recycled plastic-modified asphalt
manufacturers and convince local authorities to foster the construction of plastic roads if proven
to be a sustainable practice.
Environmental concerns about plastic pollution have grown over the past decade, with a
worldwide amount of plastic released in the environment of 302 million tons (Mt) in 2015,
with only 62 Mt recycled and 15 Mt incinerated [1]. Although the best plastic waste disposal
and management practices are found in developed countries, exportation of plastic waste to
developing countries is still common since it is cost effective [2]. This plastic waste global
trade flow was abruptly reduced by China in 2017 when foreign garbage imports of 24 types
of solid trash were prohibited, including plastic materials [3]. The main objective was to stop
the annual importation of 8.8 million tons of plastic waste to the country and mitiga te
mismanagement issues and resulting environmental impacts [3]. Hence, domestic plastic waste
treatment and recycling have become a priority for many countries whose plastic waste trade
Among the 302 Mt of plastic waste produced worldwide in 2015, 141 Mt originated from
plastic packaging, such as those used for food and drinks, personal care goods or chemical and
industrial products [4]. The short lifespan of plastic packaging resulted in an excessive amount
of waste compared to plastics coming from the textile (42 Mt), healthcare and pharmaceutic a l
(37 Mt), construction (13 Mt), electronics (13 Mt) and transport (17 Mt) sectors [4]. The main
constituents of plastic waste generated globally in 2015 were poly(ethylene) PE (32 %),
poly(propylene) PP (18 %), and poly(ethylene terephthalate) PET (11 %) [1, 4], which are
heavily used in the packaging industry to produce items such as stretch films, bottles,
containers, pouches, cutlery or food trays [5]. Recycling plastic packaging waste is a complex
process due to the occurrence of multilayer packaging materials and the contamination of
plastics by food residues [6], resulting in more than 69 % of plastic packaging waste being
solution to tackle plastic pollution, not only by reducing the amount of plastic going to landfills
or being incinerated but also by improving the performance of current construction materia ls
[8, 9]. Virgin resins such as ethylene vinyl acetate (EVA) and styrene butadiene styrene (SBS)
have long been used as bitumen modifiers to successfully produce high-performance polymer-
modified asphalt pavements [10, 11]. Due to their superior mechanical and thermal properties
as well as their low cost, recycled thermoplastic resins, such as PE, PP and PET, among others,
are now considered new cost-effective road modifier materials [8, 12, 13]. Although virgin
thermoplastics have successfully been used in bituminous materials [10], the overall
sustainability, feasibility and environmental impact of using recycled plastic waste in asphalt
pavements are still under debate among the scientific community [10, 14]. Economic benefits
are indeed limited by the low cost of virgin materials and the amount of plastic that can be
incorporated in roads due to asphalt production and road performance constraints. The potential
leaching of hazardous contaminants present in plastic and the release of microplastics in the
environment must also be controlled to ensure that the sustainability of using recycled plastic
in roads is maintained.
The aim of this review is to discuss current advances and challenges in the reuse of recycled
plastic into paving materials in terms of plastic selection and compatibility with
bitumen/asphalt and to offer potential solutions to tackle issues related to the long- term
rheological and thermal behaviour, which depend on the plastic waste source [15].
melting point, degradation temperature and viscosity, can significantly vary between batches
due to the recycling processes adopted, the presence of multiple streams of plastics in PC waste,
such as PE, PP, PET, PVC, and PS, and the presence of fillers, such as carbon black, clay or
calcium carbonate [16] (Figure 1). Such residues can be found in recycled PC plastics obtained
from waste containing multilayer packaging since separating thin layers of plastics, paper and
metal is a complex process [17]. For instance, the melt flow index (MFI) of a recycled LDPE
source containing 15% fillers is 1.07 g/10 min at 190 °C and a density of 1.01 g/cm3 , whereas
the MFI of its virgin counterpart is 1.69 g/10 min at 190 °C with a density of 0.91 [18]. DSC
analysis of a comingled plastic source showed four different melting points at 108, 125, 161
and 239 °C due to the presence of LDPE, LLDPE, PP and PET in the plastic material [18].
plastics due to additive leaching or contact with other waste-containing pollutants, such as
flame retardants, phthalates or heavy metals, that can cross contaminate the plastic materia ls
during their disposal and recycling [19, 20]. Other NIAS include polymerization side products
originating from the plastic manufacturing process as well as breakdown products released
from the degradation of plastic additives during manufacturing and recycling [21]. The
presence of NIAS in PC recycled plastics is unpredictable since their concentration and nature
can significantly vary between plastic sources depending on their composition, manufactur ing
and recycling process [21]. To a lesser extent, NIAS may also be found in recycled plastics
obtained from industrial waste streams, referred to as post-industrial (PI) plastics made of only
These chemicals are concerning if the plastics are used to build roads since their exposure to
temperatures up to 180 °C during the production of bitumen can trigger the desorption of these
Figure 1. a) FTIR analysis of a recycled post-consumer plastic, b) DSC analysis of the same
recycled post-consumer plastic and c) variation in elastic modulus and MFI for different grades
and applications of HDPE, LDPE and LLDPE. Copyright © 2021, Elsevier. Adapted with
modified asphalt pavements depends on the careful selection of the plastics and the
Low melting point plastics such as PE (Tm = 100 – 140 °C) and PP (Tm = 150 – 170 °C)
are commonly used as bitumen modifiers and incorporated via the ‘wet method’ where the
plastics are melted with hot bitumen at 160 - 180 °C before the blend is added to hot aggregates
[14]. It is crucial not to find any residues of high melting point plastics, such as PET and PS
(Tm > 200 °C), or impurities, such as paper or metal, in the recycled plastic sources to ensure
that all the plastics are evenly melted in bitumen. Such residues are commonly found in PC
recycled plastics (Figure 1a); hence, a thorough characterisation of the recycled plastic
material is required beforehand to select the most suitable plastic material for bitumen
modification.
The viscosity of plastics is important to consider since low-viscosity plastics ensure a better
dispersion in bitumen than high-viscosity plastics [14]. MFI values are commonly used to
assess the processability of plastics, where high MFI values refer to low-viscosity plastics and
low MFI values refer to high-viscosity plastics. The MFI of EVA (28% VAc), a polymer
commonly used for bitumen modification [10], is comparable to that of virgin PP at 190 °C,
7.2 and 7.5 g/10 min, respectively, whereas virgin LDPE is more viscous with an MFI at 190
°C of 1.7 g/10 min [23], showing that PP is theoretically more suitable than LDPE for bitumen
modification. However, the original plastic grade, the presence of fillers and multiple plastic
streams in recycled plastics can increase or decrease their viscosity (Figure 1c) and therefore
limit their use as bitumen modifiers if their viscosity is too high. A recent study assessed the
MFI of 31 different sources of recycled plastics and demonstrated that the MFI of PE-based
recycled plastics varied from 0.06 to 10.20 g/10 min at 19 °C, whereas virgin LLDPE, LDPE
and HDPE MFI values ranged between 2.03, 1.69 and 0.05 g/10 min, respectively [23]. The
presence of fillers and/or infrequent inclusion of PP in the PE-based recycled plastics could
explain the variability between the MFI values of the different plastic sources (Figure 1a and
b).
Finally, the compatibility between low melting point recycled plastics and bitumen must
be controlled to avoid phase separation issues during the storage of hot plastic-modified
bitumen, specifically when more than 2 wt% of recycled plastic per mass of bitumen is used
(Figure 2a and b). Semi crystalline plastics, such as PE and PP, can induce phase separation
when mixed in bitumen because the non-polar and crystalline phase of the plastics do not
disperse well in the bitumen matrix [10, 25]. A solution to prevent this phenomenon is to graft
the polymer chains to the polar asphaltene molecules of bitumen, which act as micelles in the
maltenic matrix of bitumen [14, 26] (Figure 2c). Although compatibilizers inducing chemica l
crosslinking between plastic crystals and bitumen asphaltene molecules are commercia lly
available [6, 25, 27, 28], they are not specifically designed for recycled plastics whose
composition, and therefore polarity and crystalline fraction, can vary from batch to batch.
Grafting maleic anhydride (MAH) onto recycled LDPE or PP is one of the most common ways
of reducing phase separation with bitumen [27]; however, the grafting procedure needs to be
optimised depending on the molecular weight, branching degree, polymer composition and
functionality of the plastics [27, 29, 30]. In fact, the structure of the resulting MAH-grafted
polyolefin will vary since PE chains tend to crosslink when grafted via melt free radical
polymerisation whereas PP chains are more prone to chain scission [29, 31-33]. Although
MAH is known to improve the compatibility between plastics and bitumen [27], there is
currently no universal method to graft maleic anhydride onto recycled plastics, which renders
the use of recycled plastics as bitumen modifiers more difficult. Finally, the asphaltene content
of bitumen can impact its compatibility with plastics since a higher content of asphaltenes is
likely to improve the compatibility between plastic and bitumen due to the higher number of
asphaltene molecules likely to interact with the plastics [14]. A thorough understanding of the
the asphaltene content can vary between different bitumen sources [26].
(dark area) at a plastic content of 2 wt% and b) phase separation between LDPE-rich phases
(light area) and bitumen-rich phases (dark area) at a plastic content of 5 wt%. Copyright ©
and hydrogen bonding (blue), metal coordination (red), hydrophobic interactions (orange) and
π-π stacking (green) Copyright © 2011, American Chemical Society. Adapted with permissio n
High melting point and amorphous plastics, such as PET and ABS, respectively, can be
used as asphalt aggregate substitutes and incorporated in asphalt via the ‘dry method’, where
plastics are mixed with hot aggregates at 150 - 160 °C before bitumen is added to the mix [14].
One of the main challenges of incorporating PET and ABS particles in asphalt mixes remains
the compaction of asphalt due to the natural viscoelastic properties of PET and ABS. The
compressive strength and elastic deformation of ABS are typically higher than those of PET
due to the presence of styrene groups in ABS [36], which explains the tendency of ABS to
expand after compaction in ABS-modified asphalt and of PET to reduce the compactability of
PET-modified asphalt when used at high contents (> 4 wt% per mass of the asphalt mix) [18].
The size and shape of these plastics must also be carefully considered because plastic particles
can only replace aggregates of the same size range and shape to ensure that the void content of
the asphalt mix is consistent with the required standards, the mixture is workable and the
durability of the asphalt is maintained [37]. Some plastic materials can come as large as chunks
(i.e. 10-15 mm), elongated particles or powders (Figure 3), which limits the use of these
plastics unless an additional processing step is performed during recycling, such as sieving or
pulverizing, to obtain the desired particle size. The hardness of the plastics used as aggregate
substitutes should also be considered to ensure that the plastic particles do not breakdown into
smaller particles when mixed with aggregates or subjected to traffic. The mechanical properties
of recycled plastics can significantly differ from those of virgin plastics due to the mechanic a l
and thermal history acquired throughout their manufacturing, use, disposal and recycling [38].
Contact with water, UV radiation and oxygen as well as exposure to high/low temperatures can
induce the oxidation, cracking and embrittlement of plastic materials, resulting in a change in
the chemical and mechanical properties of recycled plastics, which may not be suitable for
bitumen/asphalt modification [39]. Overall, incorporating recycled plastics in asphalt via the
‘dry method’ is easier from a processing point of view and up to 10-20 times more plastics can
be added into the asphalt mix compared to the ‘wet method’. However, the dry method may be
significantly affected by the plastic size and shape and obtaining a particle size distribution that
The ‘mixed method’ derives from a combination of both the ‘dry’ and ‘wet’ methods and
involves the addition of low melting point plastics to hot aggregates to form a polyole fin
coating onto the aggregates before neat bitumen is added to the mix, possibly allowing for the
diffusion of part of the plastics into bitumen [13]. The main challenges related to this method
are related to the temperature, speed and duration of the mixing phase that contribute to a
uniform dispersion of the plastic and its incorporation into the bitumen to provide a partial
polymer modification [13]. A few fundamental studies have been published to date on this
A tool supporting the selection of recycled plastic sources for bitumen/asphalt modifica tio n
would be useful for recyclers to develop ‘road-grade’ plastics with dedicated production lines
for the bitumen/asphalt industry. One recent study presented a ranking tool based on eight
criteria applied to 31 different sources of recycled plastics to predict which types of recycled
plastic are more suitable for bitumen/asphalt modification and highlighted that, overall,
LDPE/LLDPE-based plastics were the most suitable, whereas comingled plastics (three or
more plastic streams) were the least appropriate, although still usable [23]. The compositio n,
chemical and physical properties of the recycled plastics were used to rank the recycled plastics
against virgin plastics and EVA, a polymer commonly used for bitumen modification, which
ranked higher than all the other plastic sources [23]. Another scoring system was recently
presented to assess the recycling quality of end-of-life plastics for a specific application based
on the plastic of interest content in the waste, the recovery of the waste management system,
the substitutability of the recycled plastic against its virgin counterpart and the market response
[22]. This scoring system could be useful for life cycle assessment (LCA) and more
fundamental studies rather than being a decision tool for recycling facilities due to the need for
data specific to each plastic assessed, such as the plastic content in the waste, its recovery and
current market response, which may not be readily and easily accessible. However, the
‘substitutability’ factor could be applied to recycled plastics for bitumen/asphalt modifica tio n
following the same principles in the eight-criterion ranking tool specifically developed for the
bitumen/asphalt sector [23]. Such tools could therefore be adopted by plastic recycling facilities
to regularly check the quality of the recycled plastic they produce and the suitability for road
applications.
Building roads from recycled plastic is still a nascent technology worldwide due to
challenges hindering its development; hence, small stretches of plastic roads of less than 1 km
have been built in many countries as prototypes to assess the real-time performance of plastic
roads [42-45]. However, given that the oldest plastic roads built under controlled conditio ns
are less than 8 years old and that asphalt roads are built to last for 20 years, the long- term
performance of plastic roads remains unclear. Many standards are used worldwide to
empirically test bitumen and asphalt materials under laboratory conditions [46]; however, these
conditions are not necessarily representative of the real circumstances in the field. An
alternative would be to conduct accelerated pavement testing using specific facilities, such as
the Heavy Vehicle Simulator [47] or the Pavement Fatigue Carousel [48], to better represent
field scenarios. Although sensors are currently being used to test for surface and structural
changes of asphalt upon accelerated testing [49], some performance indicators cannot be
assessed via accelerated pavement testing, such as gaseous emissions when laying hot asphalt
and the release of microplastics when plastic-modified roads are open to traffic due to abrasion
polyaromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs), when heated and
processed to build roads [50, 51]. Although the replacement of part of bitumen by recycled
between fumes and plastics [52], this strategy could also contribute to further increasing the
generation of fumes since plastics are known to emit fumes when processed above their melting
temperature [53]. Plastic particles are also known to sorb VOCs and PAHs at their surface due
to their low crystallinity and hydrophobicity [54], a trend confirmed by the few studies that
investigated the fuming of plastic-modified asphalt [52, 55]. However, the total amount of
fumes emitted from plastic-modified asphalt would ultimately depend on the selection of the
bitumen working temperature, where lower temperatures would decrease fuming and
emissions from both bitumen and plastics [51, 53]. Although experiments in laboratory-
controlled settings can provide a very accurate estimate of the differences between the
compounds emitted by two or more products, these cannot be utilised for toxicologic a l
assessments, as other external representative factors are not considered (Figure 4a). In fact,
various climatic factors, such as wind, can significantly affect the magnitude of the problem,
and the fumes concentration (expressed in µg/m3 ) measured in enclosed areas can actually be
far from the fumes to which workers are exposed in the field. The workers’ location and tasks
also significantly impact their exposure to fumes, since those who are close to the paver, such
emission compounds than those further away, such as the drivers of the rollers. In the
laboratory, fumes are collected from the top of hot bitumen/asphalt containers where emissio ns
concentrations are the highest, whereas these are of reduced magnitude when measured through
Figure 4. a) Laboratory setup for fuming testing, b) personal fume sampler used in the field,
c) wet track abrasion machine for MP release assessment and d) pavement friction tester.
The environmental impact of plastic roads has recently been investigated via LCA, which
demonstrated that, overall, incorporating recycled plastics in asphalt via wet or dry methods
could be more environmentally beneficial than asphalt modified with virgin polymers (SBS,
EVA) and standard asphalt [57]. However, the release of microplastics (MPs) from plastic
modified roads upon traffic and road wear has not been considered in LCA to date, despite
being one of the main environmental impacts related to the construction of plastic roads.
Although bitumen modifiers such as ethylene-based polymers (EVA) and SBS have been used
since the 1970s-1980s and crumb rubber (polyisoprene and SBR) since 1956 [10, 11],
environmental concerns about microplastics have been raised only very recently. In Norway,
it was estimated that almost 10 tons of rubber MPs were released annually from studded tyres,
while 28 tons of SBS MPs originated from SBS-modified roads and up to 180 tons of MPs
originated from road markings [58]. Estimations were based on the road wear factor caused by
studded tyres but not on field-collected samples of road dust, which therefore limits the
extrapolation of these data to other types of roads. The contribution of plastic roads to MPs
pollution is also unclear because most reports released to date have focused on MPs found in
road dust, whereas differentiating between the MPs released from the road itself and those
originating from nearby construction sites, tyres or road markings remains complex [59-61].
The main challenges in the study of MPs release from the asphalt material itself are the lack of
technology to detect these particles, whose size can vary from 5 mm to a few nanometres [62],
and the need for standard equipment simulating road traffic. Although pavement friction testers
are commonly used in the field to evaluate the degradation of the road (Figure 4d), such
equipment is not designed to generate and collect MPs released upon abrasion. A rotary abrader
equipped with sandpaper has been used previously to assess MPs release from road markings
[59]; however, such an instrument is not suitable for thick and rough asphalt samples and the
use of sandpaper is not representative of road traffic. An alternative was developed recently
with a wet track abrasion machine that is commonly employed to test the abrasion resistance
of slurry seals used as pavement preservation treatment [63] (Figure 4c). An abrasion
procedure was designed based on this instrument to assess the release of MPs from PE-, PP-,
ABS- and PET-modified bitumen/asphalt after modification of the abrasion hose and redesign
of the pan holding the sample [18]. The phenomenon of MPs release from roads is still under
debate, primarily because it depends on the way plastics are incorporated into bitumen/aspha lt.
Plastics incorporated via the ‘wet’ method would be more easily found in the thin bitumen film
on top of the asphalt pavement that is subjected to direct abrasion from vehicles. In contrast,
plastics used as aggregate substitutes may or may not be exposed directly to vehicle abrasion,
as they can be located deeper in the asphalt layer. The type of plastic used in asphalt could also
impact the generation of MPs, since brittle plastics would be prone to breakage, whereas
stronger plastics could resist more abrasion and vehicle loads. UV ageing could also favour the
formation of MPs by weakening the plastics, specifically if recycled plastics were already
weakened due to their thermal and mechanical history [22]. Finally, abrasion of roads mainly
occurs where tyres are in contact with the asphalt, and its effect depends on tangential stresses
exerted by vehicles and the temperature of the pavement; hence, not all of the road surface is
abraded the same way. The long-term abrasion of the road is also likely to vary depending on
the mechanical properties of the road as well as external climatic conditions. Hence, the results
temperature, water pH and duration cannot be directly correlated to real traffic scenarios [63],
which could prove to be extremely challenging to replicate. Such laboratory testing for MPs
release should rather be used as a tool to benchmark new plastic-modified asphalt products
Plastics use in the sublayers of a road pavement would never be worn out by traffic and
therefore are not supposed to contribute to MPs pollution. However, MPs could contribute to
asphalt leaching by acting as vectors of asphalt contaminants, such as heavy metals, VOCs or
PAHs [64], into sublayers and eventually groundwater [65]. This potential environme nta l
economical solution to tackle current plastic waste management issues; however, to date, only
a small volume of plastic-modified asphalt has been laid worldwide, mostly for monitor ing
purposes. The main limitations preventing local authorities from approving the construction of
plastic roads include the variability of the plastic feedstock whose composition varies
seasonally, compatibility issues between plastic and bitumen and the lack of understanding of
the potential environmental impacts associated with plastic roads in terms of fuming,
microplastics release and leaching. The lack of knowledge about the long-term performance of
plastic roads remains an obstacle to their construction since most plastic roads currently being
monitored are less than 8 years old, with the majority of them just being recently built.
recycled plastic stream should be implemented in recycling facilities based on the properties
of the recycled plastics to ensure that such plastics meet the quality criteria of the
bitumen/asphalt industry. New testing procedures are needed to assess the long- term
performance of plastic roads, based on either field or laboratory testing. Standards should also
be developed to assess the contribution of plastic roads to fuming, MPs pollution and
contaminant leaching. Although few procedures have been developed, certified procedures are
required for bitumen/asphalt manufacturers to test and compare their own products against
asphalt products would ultimately help policy makers set MPs and fuming thresholds and
The authors would like to acknowledge Austroads for their contribution in this research through
the funding of the project APT6305 – Use of road-grade recycled plastics for sustainab le
asphalt pavements.
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Graphical abstract text
The main challenges related to the construction of plastic roads include the wide variability in
the plastic composition and properties after recycling, which affect the mechanical and
environmental properties. Standard procedures are required to foster the construction of
plastic roads if proved to be a sustainable practice.
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