Cet Aprs STP CBRN 0403 508

o p y
National Institute for Occupational Safety and Health
C
National Personal Protective Technology Laboratory
d
le
P.O. Box 18070
l
Pittsburgh, PA 15236
r o o p y Revision: 1.1 Date: 21 December 2005
t
Procedure No. CET-APRS-STP-CBRN-0403
o n d C
c e
DETERMINATION OF CBRN ACID GASES (HYDROGEN CYANIDE)
Un ll
SERVICE-LIFE TEST, AIR-PURIFYING ESCAPE RESPIRATORS
o STANDARD TEST PROCEDURE (STP)
n t r p y
o o
1. PURPOSE
c C
Un e d
This test establishes the procedure for ensuring that the level of protection provided by
o l l
the CBRN Acid Gases (Hydrogen cyanide) Service Life Test, Air Purifying Escape
y
Respirators Standard Test Procedure submitted for Approval, Extension of Approval, or
n t r o p
examined during Certified Product Audits, meet the minimum certification standards set
c o C
forth in 42 CFR Part 84, Subpart G, 84.63(a)(c)(d); Volume 60, Number 110, June 8,
d
e
1995 and the Statement of Standard for Chemical, Biological, Radiological, and Nuclear
U n l l
(CBRN) Air Purifying Escape Respirator, Dated September 30, 2003.
o
2.
t
GENERAL
n r p y
c o C o
This STP describes the Determination of CBRN Acid Gases (Hydrogen Cyanide) Service
Un ed
Life Test, Air-Purifying Escape Respirators Standard Test Procedure test in sufficient
l
l
detail that a person knowledgeable in the appropriate technical field can select equipment
o py
with the necessary resolution, conduct the test, and determine whether or not the product
r o
o n t
passes the test.
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3.
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EQUIPMENT/MATERIAL
l e d
Un 3.1.
r o l
The list of necessary test equipment and materials follows:
n t o p y
o
3.1.1. Miller Nelson Research Model 401 Flow-Temperature-Humidity Control
c C
Un
System or equivalent. This system is an automated system to control the
ed
airflow, temperature, and humidity of an air supply for an operating
l
l
system. Laboratory air and distilled water are supplied to the unit. The unit
t r o py
output is air of the variable volume/flow dependant on the size of unit
o
(10% of max flow to max flow in liters per minute (Lpm) ± 2%), and
c o n C
relative humidity (10%–98% ± 3%) and temperature (20ºC–30º 0C ±
d
e
0.3%).
U n o l l
n t r
o
Approvals: 1st Level 2nd Level 3rd Level
c
Un
o
Revision: 1.1
p yDate: 21 December 2005 Page 2 of 10
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le
3.1.2. EdgeTech Dew Prime II Hygrometer, Model 2000 or equivalent. A
r o l p y
micro- processor based programmable dew point instrument. The
hygrometer uses the dew point and ambient temperature to calculate the
n t C o
relative humidity. Dew point and ambient temperature range is: -50 to 130
o d
o
C ± 0.2 o C; relative humidity is 1 to 95 %± 0.5%.
c l e
Un o l
3.1.3. Labview software developed for NIOSH Service Life Testing.
n t r p y
3.1.4. California Analytical Instruments, Model 1314 Photoacoustic Multigas
c o o
Monitor with UA0980 optical filter or equivalent.
C
Un l l e d
3.1.5. Gas Chromatograph, Shimadzu, Model 14A with Flame Ionization
Detectors or equivalent.
t r o o p y
n
3.1.6. Mass Flow Controller, Brooks Instruments, Variable flow rate depending
c o d C
on use.
U n l le
3.1.7. Read out and Control Electronics, Brooks Instruments, Model 0154,
tr o y
Power supply and controller for the Brooks Mass Flow Controller.
o n o p
C
3.1.8. Dry Test Meter, American Meter Company, Model and size depending on
c d
Un
air flow to be measured.
l l e
y
3.1.9. Certified cylinders of 10 ppm, 500 ppm and 1000 ppm hydrogen cyanide,
t r o o p
balance gas Nitrogen.
o n d C
3.1.10. Hydrogen cyanide permeation tube.
c l e
Un o l
3.1.11. Cyanogen permeation tube.
r
n t p y
3.1.12. Hydrogen Cyanide cylinders, 2% hydrogen cyanide, balance gas of
o
c o helium.
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Un
3.1
l ed
Test fixture for mounting canisters.
l
3.3
r o py
The test chamber consisting of a 12" x 11½" x 7" air tight metal box with door
t o
n C
opening lined with gasket material. Two ½" bulkhead Swaglok® fitting located
n c o d
on the backside of the test chamber for the introduction of the test concentration
e
l
and for the exit of the test fixture. This fixture is not commercially available.
U
3.4
r o l
Resistance tester consisting of a vacuum source capable of delivering 85 Lpm, a
n t
6-inch water column slant manometer or electronic manometer and connections
o
appropriate for items being tested. See description in RCT-APR-003 and RCT-
c
Un
APR-007.
o p
Revision: 1.1 y Date: 21 December 2005 Page 3 of 10
d C
4.
l yle
TESTING REQUIREMENTS AND CONDITIONS
o
t r o p
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4.1. This test procedure is only valid if the respirator system has first completed
o d
NIOSH Standard Test Procedure entitled Determination Of Durability Test For
c l e
Un
Environmental And Transportation Conditions And Rough Handling Drop Test
r o l
On Chemical Biological Radiological Nuclear (CBRN) Air-Purifying Escape
Respirators Standard Test Procedure (STP).
n t o p y
c o 4.2. Prior to beginning any testing, all measuring equipment to be used must have
C
Un d
been calibrated in accordance with the manufacturer's calibration procedure and
l e
schedule. At a minimum, all measuring equipment utilized for this testing must
l
have been calibrated within the preceding 12 months using a method traceable to
t r o p y
the National Institute of Standards and Technology (NIST).
o
c o n4.3
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Any laboratory using this procedure to supply certification test data to NIOSH
U n le
will be subject to the provisions of the NIOSH Supplier Qualification Program
l
(SQP). This program is based on the tenets of ISO/IEC 17025, the NIOSH Manual
tr o y
of Analytical Methods and other NIOSH guidelines. An initial complete quality
o n p
system audit and follow on audits are requirements of the program. Additional
o
C
details of the Program and its requirements can be obtained directly from the
c d
Un
institute.
l l e
y
4.4 Precision and accuracy (P&A) must be determined for each instrument in
r o o p
accordance with laboratory procedures and NIOSH/NPPTL guidance. Sound
t
n C
practice requires, under NIOSH Manual of Analytical Methods, demonstrating a
c o l e d
tolerance range of expected data performance of a plus or minus 25% of a 95%
Un
confidence interval of the stated standard requirement. NIOSH/NPPTL P&A
o l
tolerance can be higher but not lower.
r
4.5
n t p y
Compressed gas cylinders must meet all applicable Department of Transportation
o
c o C
requirements for cylinder approval as well as retesting / requalification.
Un
4.6
l ed
Normal laboratory safety practices must be observed. This includes safety
l
o y
precautions described in the current NIOSH Pittsburgh Health and Safety
n t r
Program.
o p
c o
4.6.1
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Safety glasses, lab coats, and hard-toe shoes must be worn at all times.
U n l le
o
4.6.2. Work benches must be maintained free of clutter and non-essential test
n t r
equipment.
o
4.6.3 When handling any broken glass laboratory equipment, lab technicians
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Un
and personnel must wear special gloves, which protect against lacerations
o p
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le
or punctures.
r o
4.7l p y
Please refer to Material Safety Data Sheets and the NIOSH Health and
n t C o
Safety Manual for the proper protection and care in handling, storing, and
o d
disposing of the chemicals and gases used in this procedure.
c l e
Un o l
5. PROCEDURE
n t r p y
Note: Reference Section 3 for equipment, model numbers and manufacturers. For
c o o
calibration purposes use those described in the manufacturer's operation and
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Un d
maintenance manuals.
5.1.
l l e
Follow individual instruction manuals for set up and maintenance of equipment
t r o p y
used in this procedure prior to beginning testing. Malfunctioning equipment must
o
n
be repaired or replaced and properly set up and calibrated before starting all tests.
c o d C
U n
5.2.
le
Calibrate photoacoustic monitor for hydrogen cyanide using a certified hydrogen
l
cyanide gas cylinder. For the general category standard the monitor is calibrated
tr o y
for the challenge concentration of 470 ppm. For the specific category standard the
o n p
monitor is calibrated for the challenge concentration of 940 ppm.
o
c d C
Un
5.3 After the manufacturer's specified warm-up period, calibrate the Gas
l e
Chromatograph using the Kin-Tek gas generator with the hydrogen cyanogen and
l y
cyanogen permeation tube.
t r o o p
n C
5.4 Start automatic sampling mode on the gas chromatograph. Monitor and record the
c o l e d
upstream and downstream concentrations.
Un 5.5
o l
Set up test equipment as shown in Figure 1. The humidity reading controlled by
r
t y
the Miller Nelson system and monitored the Dew Point Hygrometer. The sample
n p
pickup for the hygrometer is place into the air stream via a tee after the Miller
o o
c C
Nelson and before the introduction point of challenge agent. The thermocouple
Un d
for the hygrometer is placed in the challenge gas stream immediately before the
test chamber.
l l e
5.6
r o py
Verify the following equipment is on:
t o
c o n
5.6.1
d C
Miller Nelson Unit.
U n l le
o
5.6.2 Air and water supplies.
5.6.3
n t r
Gas Chromatograph
c o
Un
5.6.4 NIOSH Service Life Apparatus Controller software program.
o p
d C
5.7
o l yle
Establish the correct humidity and temperature using chilled mirror dew point
t r p
hygrometer per the test standard in paragraph 6.3.
o
o n 5.8
d C
Set the airflow to the required airflow for the test. Verify the airflow from the test
c l e
Un
fixture using the appropriate dry test meter.
5.9
r o l
Weigh and record initial weight of the test canister on Test Data Sheet.
n t o p y
c o 5.10 Take initial inhalation and exhalation resistances of the canister mounted on the
C
Un d
facepiece at 85 liters per minute. Record the values on Test Data Sheet.
5.11
l l e
Make sure the diverter valve in the system is diverting the challenge concentration
t r o p y
airflow to the discharge and not into the test chamber Turn on the hydrogen
o
n
cyanide cylinder.
c o d C
U n
5.12
le
Mount canister onto test fixture in testing chamber.
l
5.13
tr o y
Turn on the hydrogen cyanide cylinder.
o n o p
C
5.14 Establish the test concentration of 470 ppm hydrogen cyanide for general
c d
Un
category standard or 940 ppm hydrogen cyanide for specific category standard.
l l e
y
5.15 Once the hydrogen cyanide concentration has been established, testing may begin.
t r o o p
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5.16 Direct challenge concentration airflow into test chamber
c o l e d
Un
5.17 Start timer. Airflow out of the fixture is directed into the breakthrough detector.
o l
Monitor and record the upstream and downstream temperatures of the air stream
r
t y
throughout testing. Record breakthrough values and times.
o n o p
c C
5.18 Run test until breakthrough of 10 ppm hydrogen cyanide and cyanogen is
Un d
observed or minimum service life is surpassed.
l l e
o y
5.19 Direct challenge concentration airflow out of the test chamber.
n t r o p
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5.20 Weigh and record final weight of the test canister on Test Data Sheet.
n c o e d
l
5.21 Allow clean air to purge through the test chamber for 5 minutes.
U
5.22
r o l
Repeat steps 5.7 through 5.22 for each test described in section 6.3.
5.23
o n t
End sampling mode program in the gas chromatograph.
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Un
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5.24 When all tests are complete turn off hydrogen cyanide cylinder, clean regulator by
r o l p y
purging with air, set temperature and humidity to zero and allow air to pass
through the system for 30 minutes.
n t C o
o d
6. PASS OR FAIL CRITERIA
c l e
Un o l
6.1. The criterion for passing this test is set forth in 42 CFR Part 84, Subpart G,
r
Section 84.63(a)(c)(d) and Subpart I, Section 84.110(c); Volume 60, Number 110,
n t June 8, 1995.
o p y
c o C
Un d
6.2. This test establishes the standard procedure for ensuring that:
l l e
84.63 Test requirements; general.
t r o o p y
n
(a) Each respirator and respirator component shall when tested by the applicant
c o d C
and by the Institute, meet the applicable requirements set forth in subparts H
U n le
through L of this part.
l
tr o y
(c) In addition to the minimum requirements set forth in subparts H through L of
o n p
this part, the Institute reserves the right to require, as a further condition of
o
C
approval, any additional requirements deemed necessary to establish the
c d
Un
quality, effectiveness, and safety of any respirator used as protection against
l e
hazardous atmospheres.
l
r o o py
(d) Where it is determined after receipt of an application that additional
o n t C
requirements will be required for approval, the Institute will notify the
d
applicant in writing of these additional requirements, and necessary
c l e
Un
examinations, inspections, or tests, stating generally the reasons for such
o l
requirements, examinations, inspections, or tests.
r
6.3
n t p y
HYDROGEN CYANIDE BENCH TEST FOR CANISTERS.
o
c o C
Un d
6.3.1. General Category Standard.
l l e
o y
6.3.1.1. Resistance to airflow of both canister and system will be taken
n t r o p
before and after each test.
c o d C
6.3.1.2. Three canisters will be tested at 64 Lpm, continuous airflow, 25
U n l le
% ± 5 % relative humidity (RH), 25 oC ±5 oC, containing 470
o
ppm hydrogen cyanide Minimum service life will be 15, 30, 45 or
n t r 60 minutes as per manufacturer request.
c o 6.3.1.3. Three canisters will be tested at 64 Lpm, continuous airflow, 80
Un
% ± 5 % relative humidity (RH), 25 oC ± 5oC, containing 470
o p
d C
le
ppm hydrogen cyanide. Minimum service life will be 15, 30, 45
r o l p y
or 60 minutes as per manufacturer request.
n t C o
o d
% ± 5 % relative humidity (RH), 25 oC ± 5oC, containing 470 ppm
c l e
Un
hydrogen cyanide. Minimum service life for all canisters will be
r o l 5 minutes.
n t p y
6.3.1.5. End of service life concentration is 10 ppm, which is the sum of
o
c o C
the breakthrough products of hydrogen cyanide and cyanogen.
Un l e d
6.3.2. Specific Category Standard.
l
t r o p y
6.3.2.1. Resistance to airflow of both canister and system will be taken
o
n
before and after each test.
c o d C
U n l le
% ± 5 % relative humidity (RH), 25 oC ± 5 oC, containing 940
tr o y
ppm hydrogen cyanide Minimum service life will be 15, 30, 45 or
o n p
60 minutes as per manufacturer request.
o
c d C
Un
l l e % ± 5 % relative humidity (RH), 25 oC ± 5oC, containing 940
y
ppm hydrogen cyanide. Minimum service life will be 15, 30, 45
t r o o p
or 60 minutes as per manufacturre request.
o n d C
c l e
Un
% ± 5 % relative humidity (RH), 25 oC ± 5oC, containing 940 ppm
r o l hydrogen cyanide. Minimum service life for all canisters will be
t y
5 minutes.
o n o p
c C
6.3.2.5. End of service life concentration is 10 ppm, which is the sum of
Un d
the breakthrough products of hydrogen cyanide and cyanogen.
l l e
o y
7. RECORDS AND TEST SHEETS
n t r o p
C
7.1. All test data will be recorded on the CBRN HYDROGEN CYANIDE SERVICE
n c o d
LIFE test data sheet.
e
U
7.2.
o l l
All videotapes and photographs of the actual test being performed, or of the tested
n t r
equipment shall be maintained in the task file as part of the permanent record.
7.3.
o
All equipment failing any portion of this test will be handled as follows:
c
Un
o p
d C
le
7.3.1. If the failure occurs on a new certification application, or extension of
r o l p y
approval application, send a test report to the CET Section Chief and
prepare the hardware for return to the manufacturer.
n t C o
o d
7.3.2. If the failure occurs on hardware examined under an Off-the-Shelf Audit
c l e
Un
the hardware will be examined by a technician and the CET Section Chief
r o l for cause. All equipment failing any portion of this test may be sent to the
manufacturer for examination and then returned to NIOSH. However, the
n t p y
hardware tested shall be held at the testing laboratory until authorized for
o
c o release by the CET Section Chief, or his designee, following the standard
C
Un d
operating procedures outlined in Procedure for Scheduling, and Processing
l l e Post-Certification Product Audits, RB-SOP-0005-00.
t r o o p y
c o n d C
U n l le
tr o y
o n o p
c d C
Un l l e
y
t r o o p
o n d C
c l e
Un r o l
n t o p y
c o C
Un l l ed
t r o o py
c o n d C
U n l le
t r o
c o n
Un
o p
d C
8.
l
ATTACHMENTS
o le
y
t r o p
n C
8.1 Bench Top Set-Up.
c o l e d
Un
8.2 Data Sheet.
r o l
n t o p y
c o C
Un l l e d
t r o o p y
c o n d C
U n l le
tr o y
o n o p
c d C
Un l l e
y
t r o o p
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c l e
Un r o l
n t o p y
c o C
Un l l ed
t r o o py
c o n d C
U n l le
t r o
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Revision History
r o
Revision l Date
p y Reason for Revision
00
n t C o
21 September 2004 Historic document
o d
1.1 21 December 2005 Update header and format
c l e
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No changes to method
r o l
n t o p y
c o C
Un l l e d
t r o o p y
c o n d C
U n l le
tr o y
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Un l l e
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t r o o p
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Un r o l
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o p y

National Institute for Occupational Safety and Health

r o o p y Revision: 1.1 Date: 21 December 2005

o STANDARD TEST PROCEDURE (STP)

n t r 60 minutes as per manufacturer request.

c o 6.3.1.3. Three canisters will be tested at 64 Lpm, continuous airflow, 80

l l e % ± 5 % relative humidity (RH), 25 oC ± 5oC, containing 940

r o l hydrogen cyanide. Minimum service life for all canisters will be

l l e Post-Certification Product Audits, RB-SOP-0005-00.

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