CN109052588A Removal method and device of heavy metal ions in seaweed extracts based on

electrodialysis technology

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Method for removing heavy metal ions in seaweed extract based on electrodialysis technology and device
thereof

Technical field

The invention belongs to the field of membrane separation, in particular to a method and a device for removing
heavy metal ions in an algae extract based on electrodialysis technology, and the removal of heavy metal ions in
the seaweed extract by electrodialysis.

Background technique

Seaweed extract is a pure natural marine biological product containing alginic acid, crude protein,
multivitamins, enzymes and trace elements. After absorption through the skin, this nutrient can reduce surface
blood lipids and enhance surface hematopoiesis. And there are functions of weight loss, heat preservation and
thickening. Seaweed extract has a wide range of uses. In agricultural applications, it can promote plant growth,
improve soil water retention capacity, promote the growth of beneficial microorganisms and strengthen soil
health; in medical applications, it has anti-tumor effect and anti-cancer effect. Seaweed extract is the main
component of brown algae cell wall, while seaweed cell wall is the main accumulation place of heavy metal ions
(mercury, arsenic, lead, chromium, copper, nickel, etc.). When seaweed extract is enriched with a large amount
of heavy metal ions, it will be greatly reduced. The functional action of seaweed extracts may even produce
toxic effects, so the removal of heavy metals from seaweed extracts is the key to their function.

Traditional heavy metal treatment methods have obvious shortcomings: chemical precipitation has a large
dosage of chemicals, high cost of chemicals, and there is a risk of secondary pollution; adsorption of heavy
metals in general is more efficient, but the reaction conditions are more stringent, adsorption Reagent
regeneration is usually difficult, and there are difficulties in solid-liquid separation and disposal of adsorbents,
which is not conducive to the recovery of heavy metal ions. Biological treatment of heavy metal ions has the
disadvantages of slow propagation rate and reaction rate of functional bacteria, and difficulty in recycling the
treatment liquid. Moreover, when the concentration of heavy metal ions is high, the growth of microorganisms
is inhibited; in addition, patent CN107497502 discloses the use of strong acidic ion exchange resins to remove
heavy metal ions in seaweed, but the ion exchange resin requires a large amount of chemicals to be regenerated
and eluted. water. Therefore, how to efficiently remove heavy metal ions in the seaweed extract without
reducing its functional function, without secondary pollution, reducing the cost of heavy metal ion removal, and
making the seaweed extract exert its maximum effect, will become an urgent need for the skilled person in the
art to solve The problem.

Summary of the invention

In view of the technical deficiencies of the existing removal of heavy metal ions in seaweed extracts, the present
invention provides a method and apparatus for removing heavy metal ions in seaweed extracts based on
electrodialysis technology, and the present invention has the present invention compared with the prior art. The
utility model has the advantages of low chemical consumption, low energy consumption, good separation effect,
compact and durable equipment, high ion recovery rate and no secondary pollution.

In order to achieve the above object, the present invention provides a method for removing heavy metal ions in
an algae extract based on electrodialysis technology, which comprises the following steps:

（1）The seaweed extract solution is pretreated to remove the solid particles and then transferred to the raw
material liquid storage tank;
（2）The seaweed extract solution in the raw material liquid storage tank is pumped into the desalination
chamber, and the equal concentration of water is injected into the concentration chamber, and then the
desalination chamber circulation pump, the polar chamber circulation pump and the concentrating chamber
circulation pump are turned on, and electrodialysis is performed. The DC reactor is added to the membrane
stack. Under the action of the DC electric field and the anion and cation exchange membranes, the heavy metal
ions (mercury, arsenic, lead, chromium, copper, nickel, etc.) in the seaweed extract continuously migrate from
the desalination chamber to the concentration chamber. Further, the removal of heavy metal ions in the seaweed
extract is achieved.

（3）According to the value of the conductivity meter of the desalination chamber and the concentrating
chamber, it is judged whether the electrodialysis device reaches the end point of the operation, and after the set
conductivity value is reached, the electrodialysis device stops working, and the desalination chamber discharge
valve and the concentrating chamber discharge valve are opened. The seaweed extract solution and the
concentrate are discharged from the electrodialysis unit.

（4）During the operation of the electrodialysis unit, the membrane stack should be cleaned periodically to
increase the service life of the ion exchange membrane. During the cleaning, the cleaning tank passes through
the raw material liquid storage tank and enters the electrodialysis unit without any DC electric field. Cycling
cleaning, general physical cleaning is washed by distilled water, and chemical cleaning is performed by the
disposed chemical. The chemical agent may be a reagent such as citric acid, hydrochloric acid, sodium
hypochlorite or sodium hydroxide. The cleaning tank includes a physical cleaning tank and a chemical cleaning
tank.

Further, the seaweed extract in the step (1) may be a digestive juice of the seaweed extraction process, and does
not require an acidification or calcification treatment process, specifically: washing the seaweed with water,
removing water-soluble impurities such as inorganic salts, and chopping Thereafter, after adding sodium
carbonate for digestion, filtration or air flotation, a sodium alginate solution is obtained, which is an sodium
alginate extract.

Further, to the effluent of the desalting chamber in the step (3), an appropriate amount of NaOH solution is
added, and then concentrated into an ultrafiltration membrane device for concentration, and then centrifuged and
dried to obtain a sodium alginate product.

A heavy metal ion removal device for seaweed extract based on electrodialysis technology, comprising raw
material liquid feed regulating valve, raw material liquid storage tank, raw material liquid discharge regulating
valve, raw material liquid discharging pump, desalination room water tank, desalination chamber Material
regulating valve, desalination chamber circulating pump, desalination chamber circulating flow meter, polar
chamber circulating flow meter, polar chamber circulating pump, polar chamber water tank, concentrating
chamber circulating flow meter, concentrating chamber circulating pump, concentrating chamber water tank,
concentrating chamber discharging adjustment a valve, a concentrating chamber feed regulating valve and an
electrodialysis membrane stack; a raw material liquid feed regulating valve is installed on the raw material
liquid storage tank feeding line, and a raw material liquid discharging regulating valve and a raw material liquid
discharging pump raw material liquid are sequentially disposed The storage tank discharge line is connected
with the desalination chamber water tank, and the desalination chamber discharge regulating valve is fixedly
arranged on the decontamination chamber water tank discharge line, and the concentration chamber feed
regulating valve and the concentration chamber discharge regulating valve are respectively installed in the
concentration chamber water tank feeding. On the pipeline and the discharge pipeline, the desalination chamber
water tank, the desalination chamber circulation pump, the desalination chamber circulation flowmeter and the
desalination chamber in the electrodialysis membrane reactor constitute a circulation loop, the polar chamber
water tank, the polar chamber circulation pump, the polar chamber circulation Meter with electrode
compartment electrodialysis membrane stack configuration cycle, tank concentrating compartment,
concentrating compartments circulation pump, a flow meter cycle concentrating compartment electrodialysis
membrane stack and the electrode chamber configuration cycle.

Further, the heavy metal ion removal device in the seaweed extract based on electrodialysis technology further
comprises a physical cleaning storage tank, a chemical cleaning storage tank, a physical cleaning infeed valve
and a chemical cleaning infeed valve, and a physical cleaning storage tank discharging device. The pipeline and
the chemical cleaning tank discharge line are connected to the raw material liquid storage tank feed line, and the
physical cleaning feed valve is respectively disposed on the physical cleaning storage tank discharge line and
the chemical cleaning storage tank discharge line. Chemically clean the feed valve to control the flow of water
during physical and chemical cleaning.

Further, the heavy metal ion removal device in the seaweed extract based on electrodialysis technology further
comprises an on-line conductivity monitor, a liquid level on-line detector, a physical cleaning storage tank, a
chemical cleaning storage tank, a raw material liquid storage tank, The liquid level on-line detector is installed
in the water tank of the desalination chamber and the water tank of the concentrating chamber, and the electric
conductivity on-line detector is set in the raw material liquid storage tank, the desalination chamber water tank
and the concentrating chamber water tank, and the PLC device and the electric conductivity online monitor and
the liquid respectively Online detector, feed regulating valve, raw material liquid discharge regulating valve,
raw material liquid discharging pump, desalination chamber discharging regulating valve, desalination chamber
circulating pump, desalination chamber circulating flow meter, polar chamber circulating flow meter, polar
chamber circulation Pump, concentrating chamber circulating flow meter, concentrating chamber circulating
pump, concentrating chamber discharge regulating valve, concentrating chamber feeding regulating valve,
electrodialysis unit DC power controller, physical cleaning feed valve and chemical cleaning feed valve
connection, realize heavy metal The remote control of the ion removal device includes three methods of manual
control/remote automatic control/remote semi-automatic step operation.

The above specific method for removing heavy metal ions in the seaweed extract based on electrodialysis
technology:

1、The pretreated seaweed extract solution is transported to the raw material liquid storage tank through the raw
material liquid feed regulating valve for temporary storage, and the liquid level in the storage tank is monitored
in real time through the liquid level online monitor in the raw material liquid storage tank. When the maximum
liquid level is set, the PLC device controls to close the raw material feed regulating valve, and the feeding is
completed.

2、After the seaweed extract solution enters the raw material liquid storage tank, the PLC device controls to
open the raw material liquid discharge regulating valve and the raw material liquid discharging pump to
transport the seaweed extract solution into the desalination chamber water tank, and the PLC device controls to
open the concentration chamber feeding adjustment. The valve transports the clean water to the concentrating
chamber water tank, and monitors and controls the liquid level in real time through the liquid level on-line
detector in the desalination chamber water tank and the concentrating chamber water tank. When the specified
liquid level setting value is reached, the PLC device automatically discharges the raw material liquid. The
material pump, the raw material liquid discharge regulating valve and the concentrating chamber feed regulating
valve are closed, and the electrodialysis device is finished.

3、When the electrodialysis unit is finished feeding, the PLC device opens the desalination chamber circulation
pump, the polar chamber circulation pump and the concentrating chamber circulation pump through automatic
control, wherein the seaweed extract solution, the polar chamber solution and the clean water are respectively
delivered to the electrodialysis membrane pile. In the desalination chamber, the pole chamber and the
concentrating chamber, when the desalination chamber circulation flow meter, the pole chamber circulation
flow meter and the concentrating chamber circulation flow meter are stable, the PLC device connects the
electrodialysis membrane stack to the DC electric field, and the DC electric field thereof The size is fixed by a
preset value, and under the combined action of the DC electric field and the selective permeability of the anion-
cation exchange membrane in the membrane stack, the heavy metal ions in the algae extract migrate
directionally into the concentration chamber in the fresh water chamber, and the desalination chamber After the
conductivity monitor in the water tank is lowered to the set value, the PLC device first turns off the DC current
of the membrane stack, and then turns off the desalination chamber circulation pump, the polar chamber
circulation pump and the concentrating chamber circulation pump, and the heavy metal ions in the seaweed
extract are off. except.

4、After the electrodialysis device is finished, the PLC device controls to open the desalination chamber
discharge regulating valve and the concentrating chamber discharge regulating valve to discharge the seaweed
extract solution in the desalination chamber water tank and the concentrated liquid in the concentrating chamber
water tank respectively. When the liquid level of the liquid level detector in the concentrating chamber water
tank is 0, the PLC device controls the desalination chamber discharge regulating valve and the concentrating
chamber discharging regulating valve to be closed, and the system control enters the next round of work.
5、When the electrodialysis unit, the membrane stack cycle time exceeds the set value or uses for a period of
time, the cleaning is performed first, then the physical cleaning is performed first, then the chemical cleaning is
repeated twice, and finally the physical cleaning is performed.

Physical cleaning: The PLC device confirms that the distilled water in the physical cleaning storage tank reaches
the set liquid level by the liquid level on-line detector, and then opens the physical cleaning feed valve, the raw
material liquid feed regulating valve, the raw material liquid discharge regulating valve, and the raw material
liquid discharging. The pump and the concentrating chamber feed regulating valve respectively inject a certain
amount of distilled water into the fresh water chamber water tank and the concentrating chamber water tank,
open the desalination chamber circulating pump and the concentrating chamber circulating pump, and the
electrodialysis device is cyclically operated without adding a DC electric field. After the preset cycle time, the
desalination chamber circulation pump and the concentrating chamber circulation pump are turned off, and the
desalination chamber discharge regulating valve and the concentrating chamber discharge regulating valve are
opened to discharge the liquid in the desalination chamber water tank and the concentrating chamber water tank.

Chemical cleaning: After confirming that the chemical agent in the chemical cleaning tank reaches the set liquid
level by the online liquid level detector, the chemical cleaning feed valve, the raw material liquid feed regulating
valve, the raw material liquid discharge regulating valve, and the raw material liquid are opened. The material
pump and the concentrating chamber feed regulating valve respectively inject a certain amount of chemical into
the fresh water chamber water tank and the concentrating chamber water tank, open the desalination chamber
circulating pump and the concentrating chamber circulating pump, and the electrodialysis device is circulated in
the case of no DC electric field. After the preset cycle time is reached, the desalination chamber circulation
pump and the concentrating chamber circulation pump are turned off, and the desalination chamber discharge
regulating valve and the concentrating chamber discharge regulating valve are opened to discharge the liquid in
the desalination chamber water tank and the concentrating chamber water tank.

Compared with the prior art, the invention has the following advantages: 1 Compared with other traditional
methods for treating heavy metal ions in seaweed extracts, electrodialysis has less chemical consumption, low
energy consumption, good separation effect, and compact and durable equipment. The ion recovery rate is high
and does not cause secondary pollution; 2 electrodialysis device has good selectivity, low resistance, thermal
stability and chemical stability; 3 saves time and effort by monitoring and controlling the operation of the PLC
automatic control device The control is more flexible and convenient, and saves operating costs.

Electrodialysis system can directly process the digestive juice in the algae extraction process, omitting the
acidification and calcification treatment process, simplifying the algae extraction process, and simultaneously
constructing the new digestion + The sodium alginate extraction process of filtration/air flotation +
electrodialysis + ultrafiltration is easy to control, and the sodium alginate yield is high and the quality is stable.

DRAWINGS

1 is a schematic view showing the structure of a heavy metal ion removal device in an algae extract based on
electrodialysis technology, wherein: 1 physical cleaning storage tank, 2 chemical cleaning storage tank, 3 raw
material liquid feed regulating valve, 4 raw material liquid storage tank 5 raw material liquid discharge
regulating valve, 6 raw material liquid discharging pump, 7 desalination room water tank, 8 desalination
chamber discharging regulating valve, 9 desalination chamber circulating pump, 10 desalination chamber
circulating flow meter, 11-pole circulating flow meter, 12 Polar chamber circulating pump, 13-pole chamber
water tank, 14 concentrating chamber circulating flow meter, 15 concentrating chamber circulating pump, 16
concentrating chamber water tank, 17 concentrating chamber discharge regulating valve, 18 concentrating
chamber feeding regulating valve, 19 electrodialysis membrane stack, 20 PLC device, 21 physical cleaning feed
valve, chemical cleaning feed valve 22.

Detailed ways

The present invention will be further described below in conjunction with the accompanying drawings and
specific embodiments:
A heavy metal ion removing device for seaweed extract based on electrodialysis technology, comprising raw
material liquid feed regulating valve 3, raw material liquid storage tank 4, raw material liquid discharging
regulating valve 5, raw material liquid discharging pump 6, desalination chamber water tank 7. Desalination
chamber discharge regulating valve 8, desalination chamber circulation pump 9, desalination chamber
circulation flowmeter 10, polar chamber circulation flowmeter 11, pole chamber circulation pump 12, pole
chamber water tank 13, concentration chamber circulation flowmeter 14, concentration chamber a circulation
pump 15, a concentrating chamber water tank 16, a concentrating chamber discharge regulating valve 17, a
concentrating chamber feed regulating valve 18, and an electrodialysis membrane stack 19; and a raw material
liquid feed regulating valve 3 is installed on the feed liquid storage tank 4 feed line The raw material liquid
storage tank 4 and the raw material liquid discharge pump 6 are sequentially provided with the raw material
liquid storage tank 4 discharge line communicating with the desalination chamber water tank 7, and the
desalination chamber discharge is fixedly disposed on the discharge line of the depleting chamber water tank 7
The regulating valve 8, the concentrating chamber feed regulating valve 18 and the concentrating chamber
discharging regulating valve 17 are respectively installed on the feeding line and the discharging line of the
concentrating chamber water tank 16, the desalination chamber water tank 7, the desalination chamber
circulating pump 9, and the desalination chamber circulation The flow meter 10 and the desalination chamber in
the electrodialysis membrane stack 3 constitute a circulation loop. The polar chamber water tank 13, the pole
chamber circulating pump 12, the pole chamber circulating flow meter 11 and the pole chamber in the
electrodialysis membrane stack 3 constitute a circulation loop, the concentrating chamber water tank 16, the
concentrating chamber circulating pump 15, the concentrating chamber circulating flow meter 14 and the
electricity The pole chamber in the dialysis membrane stack 3 constitutes a circulation loop.

Further, the heavy metal ion removal device in the seaweed extract based on electrodialysis technology further
comprises a physical cleaning storage tank 1, a chemical cleaning storage tank 2, a physical cleaning feed valve
21, and a chemical cleaning feed valve 22, physical cleaning The storage tank 1 discharge line and the chemical
cleaning storage tank 2 discharge line are all connected with the raw material liquid storage tank 4 feed line, and
the physical cleaning storage tank 1 discharge line and the chemical cleaning storage tank 2 discharge pipe A
physical cleaning feed valve 21 and a chemical cleaning feed valve 22 are provided on the road to control the
flow of water during physical cleaning and chemical cleaning.

Further, the heavy metal ion removal device in the seaweed extract based on electrodialysis technology further
comprises an on-line conductivity monitor, a liquid level on-line detector, a physical cleaning storage tank, a
chemical cleaning storage tank, and a raw material storage. A conductivity on-line monitor is arranged in the
tank 4, the desalination chamber water tank 7 and the concentrating chamber water tank 16, and a liquid level
on-line detector is arranged in the raw material liquid storage tank 4, the desalination chamber water tank 7 and
the concentrating chamber water tank 16, respectively, and the PLC device respectively On-line monitor with
conductivity, liquid level on-line detector, feed adjustment valve 3, raw material liquid discharge regulating
valve 5, raw material liquid discharge pump 6, desalination chamber discharge regulating valve 8, desalination
chamber circulation pump 9, desalination chamber Circulating flowmeter 10, polar chamber circulation
flowmeter 11, pole chamber circulation pump 12, concentrating compartment circulation flowmeter 14,
concentrating compartment circulation pump 15, concentrating compartment discharge regulating valve 17,
concentrating compartment feed regulating valve 18, electrodialysis device The DC controller, the physical
cleaning feed valve 21 and the chemical cleaning feed valve 22 are connected to realize remote control of the
heavy metal ion removal device, and specifically have three methods of manual control/remote automatic
control/remote semi-automatic step operation. Select.

Further, the physical cleaning storage tank 1 discharge line, the chemical cleaning storage tank 2 discharge line,
the raw material liquid storage tank 4 feed line, the raw material liquid storage tank 4 discharge line, the
desalination chamber water tank discharge line Check valves and flow control valves are provided on the inlet
and outlet lines of the concentrating compartment water tank to prevent backflow and control fluid flow.

Further, the circulating liquid of the polar chamber water tank is a solution of NaCl, Na2SO4, NaNO3, and
MgSO4.

Further, the connection mode of the electrodialysis membrane stack is one-stage, one-stage, multi-stage and
multi-stage.

The above specific method for removing heavy metal ions in the seaweed extract based on electrodialysis
technology:
1、The pretreated seaweed extract solution is sent to the raw material liquid storage tank 4 for temporary
storage through the raw material liquid feed regulating valve 3, and the liquid level in the storage tank is
monitored in real time through the liquid level online monitor in the raw material liquid storage tank 4. When
the set maximum liquid level is reached, the PLC device 20 controls to close the raw material liquid feed
regulating valve 3, and the feeding is completed.

2、After the seaweed extract solution enters the raw material liquid storage tank 4, the PLC device 20 controls
the opening of the raw material liquid discharge regulating valve 5 and the raw material liquid discharging pump
6 to transport the seaweed extract solution into the desalination chamber water tank 7, while the PLC device 20
controls The concentrating compartment feed regulating valve 18 is opened to deliver the clean water to the
concentrating compartment water tank 16, and the liquid level on-line detector in the depleting compartment
water tank 7 and the concentrating compartment water tank 16 is used to monitor and control the liquid level in
real time, when the specified liquid level setting is reached. After the value, the PLC device 20 automatically
closes the raw material liquid discharge pump 6, the raw material liquid discharge regulating valve 5, and the
concentrating chamber feed regulating valve 18, and the electrodialysis device feed ends.

3、After the feeding of the electrodialysis device is completed, the PLC device 20 opens the desalination
chamber circulating pump 9, the polar chamber circulating pump 12, and the concentrating chamber circulating
pump 15 by automatic control, wherein the seaweed extract solution, the polar chamber solution and the clean
water are respectively delivered to The desalination chamber, the pole chamber and the concentrating chamber
in the electrodialysis membrane stack 19, after the desalination chamber circulation flowmeter 10, the pole
chamber circulation flowmeter 11 and the concentrating compartment circulation flowmeter 14 are stably
stabilized, the PLC device 20 will electrodialysis membrane stack 19 is connected to the DC electric field, and
the magnitude of the DC electric field is fixed by a preset value. Under the combined action of the DC electric
field and the selective permeability of the anion-cation exchange membrane in the membrane stack, the heavy
metal ions in the algae extract are in fresh water. The indoor orientation migrates to the concentrating chamber.
When the conductivity online monitor in the desalination chamber water tank 7 is lowered to the set value, the
PLC device 20 first turns off the direct current of the membrane stack, and then turns off the desalination
chamber circulating pump 9 and the polar chamber circulating pump 12 And the concentrating chamber
circulation pump 15, the heavy metal ions in the seaweed extract are removed.

4、After the electrodialysis device is completed, the PLC device 20 controls the open desalination chamber
discharge regulating valve 8 and the concentrating chamber discharge regulating valve 17 to discharge the
seaweed extract solution in the depleting compartment water tank 7 and the concentrated liquid in the
concentrating compartment water tank 16, respectively. When the liquid level of the liquid level on-line detector
in the depleting compartment water tank 7 and the concentrating compartment water tank 16 is 0, the PLC
apparatus 20 controls the desalination chamber discharge regulating valve 8 and the concentrating compartment
discharge regulating valve 17 to be closed, and the system control enters the lower A round of work.

5、When the electrodialysis unit, the membrane stack cycle time exceeds the set value or uses for a period of
time, the cleaning is performed first, then the physical cleaning is performed first, then the chemical cleaning is
repeated twice, and finally the physical cleaning is performed.

Physical cleaning: After the PLC device 20 confirms that the distilled water in the physical cleaning storage tank
1 reaches the set liquid level by the liquid level on-line detector, the physical cleaning feed valve 21, the raw
material liquid feed regulating valve 3, and the raw material liquid discharging regulating valve 5 are opened.
The raw material liquid discharge pump 6 and the concentrating chamber feed regulating valve 18 respectively
inject a certain amount of distilled water into the fresh water chamber water tank 7 and the concentrating
chamber water tank 16, and open the desalination chamber circulation pump 9 and the concentrating chamber
circulation pump 15, without adding direct current In the case of the field, the electrodialysis unit is circulated,
and after reaching a preset cycle time, the desalination chamber circulation pump 9 and the concentrating
chamber circulation pump 15 are turned off, and the desalination chamber discharge regulating valve 8 and the
concentrating chamber discharge regulating valve 17 are opened. The liquid in the desalination chamber water
tank 7 and the concentrating compartment water tank 16 is discharged.

Chemical cleaning: After the PLC device 20 confirms that the chemical agent in the chemical cleaning storage
tank 2 reaches the set liquid level by the online liquid level detector, the chemical cleaning feed valve 22, the
raw material liquid feed regulating valve 3, and the raw material liquid discharging regulating valve are opened.
5. The raw material liquid discharge pump 6, the concentrating chamber feed regulating valve 18, inject a
certain amount of chemical into the fresh water chamber water tank 7 and the concentrating chamber water tank
16, respectively, and open the desalination chamber circulating pump 9 and the concentrating chamber
circulating pump 15, without In the case of a DC electric field, the electrodialysis unit is circulated, and after
reaching a predetermined cycle time, the desalination chamber circulation pump 9 and the concentrating
chamber circulation pump 15 are turned off, and the desalination chamber discharge regulating valve 8 and the
concentrating chamber discharge regulating valve 17 are opened. The liquid in the depleting compartment water
tank 7 and the concentrating compartment water tank 16 is discharged.

Example 1:

The relevant parameters of the electrodialysis membrane reactor are: the assembly mode of the membrane
reactor is vertical assembly, the membrane stack has 15 pairs of membranes, the cation exchange membrane is a
sulfonic acid type homogeneous cation exchange membrane, and the anion exchange membrane is a quaternary
ammonium type homogeneous phase. An anion exchange membrane, the anode electrode material is titanium
coated crucible, the cathode electrode material is stainless steel, and the separator is a polypropylene non-circuit
separator. The seaweed extract solution is a sodium alginate solution in which the heavy metal ion is copper ion
and the copper ion concentration is 4.5 mg/L.

The solution uses the above steps 1-4 to remove heavy metal copper ions, wherein the desalination chamber
water tank 7 and the concentrating chamber water tank 16 feed are 2 L, and the circulation flow rate of the
desalination chamber, the concentrating chamber and the polar chamber is 60.0 L/h. The DC voltage was 7.2 V.
After circulating for 70 min, the copper ion content in the depleting compartment water tank 7 was 1.06 mg/L,
and the removal rate was 76.4%.

Example 2:

The relevant parameters of the electrodialysis membrane reactor are: the assembly mode of the membrane
reactor is vertical assembly, the membrane stack has 20 pairs of membranes, the cation exchange membrane is a
sulfonic acid type homogeneous cation exchange membrane, and the anion exchange membrane is a quaternary
ammonium type homogeneous phase. An anion exchange membrane, the anode electrode material is titanium
coated crucible, the cathode electrode material is stainless steel, and the separator is a polypropylene non-circuit
separator. The seaweed extract solution is a sodium alginate solution in which the heavy metal ion is lead ion
and the lead ion concentration is 4.2 mg/L.

The solution uses the above steps 1-4 to remove heavy metal copper ions, wherein the desalination chamber
water tank 7 and the concentrating chamber water tank 16 feed are 2 L, and the circulation flow rate of the
desalination chamber, the concentrating chamber and the polar chamber is 65.0 L/h. The DC voltage is 10 V.
After circulating for 70 min, the lead ion content in the depleting compartment water tank 7 is 0.60 mg/L, and
the removal rate is 85.7 %.