Chemical kinetics BI For the reaction ar Oc 4a) ——74 NOx, peoacy) of sige QN20s cq) 24 dlisappeanamte Cobeukat (he wate of feotion ip S08 6 "FP oaio2? Of NzO5¢q) Lx 1st Ars aN 225g INGE? aonoed a ato) ofte ion acto 7G we pate of an oes ir e oe A fit order. reaction Lakes 30 minutes for 20%. decomposition. Caltulate t),% Clog ore a bs ominnhs = let a= 10 c3Manks) x2 207-G 10% 22° £ 303 3 2 pena coyt Ie 2 Bo = 2:30? fon [00 ay 302 2.393 (Goglo-2 2092? . oo f ‘ 0.3010) 2 2022.303CI- SRO: Te le = 2.303C0-09F) lo 300 At 6 k= 0.0074 min g 20.693 . 43.65 anim 2 os 2a Hleglo Oy? Ee) San: 63 Th ° Rein ninth 8 pl Kinetics Tf concentration. ofA tnurcased to . : ree times, how will it affect the ate of foumation, 06 2 ons? Am A —8 sicabe Rose =k CAD” =k C24) i 24 kCAl Rate of, formation of ineaecl by mine brmes |im 20 mbnutes % 00k 4 A fastada Reaction %& 50%> bom amin lomenukes o& 3201 Caloubake arkinodion energgCba) 029) $n Be reaction Cp-8.3I4 5 ela!) i Chinen Gog? ~ o.4t#) 3M Ans ky = 0-693 . 0693. grixtormia! T)= 300k Eh, 3 a he 220k kp = 0.693 = 0813 = 6.93x (0 THE ty lo é ei 3-Ea x ae Gog? ayae 160° Eas OFF KVL XqGD20 320-300 >) Zo Ea=4sB4e smh! fog, 693x158" 2 Ea Dane? 2.3) Alo" 2. dK BAN 300x320 = 42.85 k5 me" —. es. | ee weenieBS Fo.aseartion 7 240, —2—_~ (laline wed 2H,0 +0, Me propesede meat tegiver below O 40+ T—74 * qo" Cs 4) © wo4+10°— 9 +Dt 0, Cast? © Waite ate Law br the neation @ Waite the pyenate owe Be seattle © ont of step Toma 2 which one4 . Avs 7 cami NG step a Ars @ Rate =kLHOICE J @ Step! foo step 38% sala dat6s BE Fora fist order reaction derive the aelations kage rtaoy, Ars 447. oe asl we a qior =14 Begg fe = 238? 3 — a Te 4 axl any, > 2203 fag 82 Too-44 £ Fay. = LEE? Logie Eagy, 2242393 -O k hip Qo7. complelia am ee . lor 240 £aot. = 2 1302 be ae; a . boy Fe fost Kaay = Ax £7.B= See at Ot The rate cons ieee aa dd in. the Just order, 2 % N,Os is given by ie pling gente decomp sition lr keasxidts! e259? Cakcukate Ea. 4% this seation amd. rake constant of oz) ‘Us Bal, lhe petod. he 300 monnkes 3M Ars es a.sxidistel (-26000)/T Asn Gorkus enpntion for pstorder aA eet aeaction Tea = ~ 250 » [F428 RT Ti a Ear -ggooox8-3!4 @) Koon? = 207 850 7mt 2.3lxictate lt ois. > Q0F.85 kT wkag The decomposition of NHs, on Platinum gusgace , is a 2ew ade reartion. Y cate constant ck) is 4X10 Ms 4ow fong wilh it take ty reduce the imntia£ aol4 Concentration of NH: m O-[M to 0-064M- of NH ge ere Ars ke yxis?® Ms! CR lM £7 Lay o08t™ Zero coker, seartion b= Cele Ce) z te G1 0-064 _ 9.036 36 _ 4 seconds uxlo~™04 Fm Bereaction = AN,Oceg) ——? NGPA, Be sate of formation of NO Cg) is a. “i oP Ms Cobeutate, te nate sp ctoppearonce ob NPD ACNOvI. 424 oe t be pa enon 809-4 Hi ANNs). L aLNor) er ad -ACN2Os)2 % a@.cNovd e 4 ae < axle” » SF x 4GlO 7h ° | — attend dacta.ts Obtaimecl duntng the fon daa Amal decomposition, of SO, h, at constant $02,123) ——> 0,68) + eee Expt se I S aoe prgsure Cad 1 " poutade the 10le 2 (oo °: + a 6 Ars So, C2, C ae = So 2,2, Ca) —a S0,64) + 2,4) sMooha Ie = 2.30% Bo Po ey PL * 2:303 bog OH > 2:323 fog ou 2 Joo oe OF 2 %303 303 23 Goat = 2.323 gy 2239 7 ues? 9 on 03 x 0.6021 2 La R6x Is? gs!on Avs e : mn He Syotgie ofmmetiyl actate in anpeors 40 lution the he following results are obtamed I Je Als ° lo 2o ols CHsCooCl, j 3 oct o.l0 o.05 0.025 (amoal: Calenkoke He oncrage rate of seartion bebseen the Hime interval lo to 20 second: Rake = [3 Avenage qate bebveen 10 £0.20 8&condds. PACE) = ~(.0.025-0.05) . 0.028 " DE Ro-lo 10 ett gx io? male” §GI2 A fist rder reattion i 40% com dL im 60 minutes Cobeuhote, volue of rate constame CE).In what tame With the reaction. be 4070 dompletedT tons 20-4482.) (202°) i 3 Mankes ns yw ee owe b> 2303(loglo- M90? aot: e2 YoY. Go =4O 8° A 3081-09902) b= 23° % fog A = 2B28 log A =U meee 2,203 n0- 208 be 2.303 top l0e come HeZBOD Mog (Oe (Spm - - joo-"}o. geo 190-40 6.38 XI0 3 at GBEAID u = 2.303 £=QB03 Lyle k a Soa 128 Sexe?” 360.63 winutkyGIS Fe, He reattion A +3B—, 20 the rake of formation of C ts 2.5% 15 mL LS CoLenkae tre O Rak ofseaction 202° © Rake of tésoppearamce of B- amos Ars ace) - 2sxis% moh o's! ak Rake ¢ rearhon > - acay.- 1408) 21 ace) ak Sake 2 At Rake qreavbon > 4 ace) © Rated hanppemae, oe peas Rake gacarhion = “4a Lexie tages - ACB) 2 3x Rake ¢reate dE oy ms —— S3XL2Exlo BEX moG O°!= SSSA oy . Sa GIM The rate of reaction becomes four. times when temperature Bamges fiom anrk to 213k. Cakeubate Lhe enrrgg % acivationCa) of the seaction axsurniing hak ié does rae mot Rammge with £empuatine Cee 8-314 Spe me” fog 201% Ans. le 24k Te 2AB le Besse amanls fog Kx fa (BEM) Tet paospe Te Eo. = 0-6021K2.303% &.3I4 XB 1B AZAD ki. Ew wac2t ) 20 Ey g gosp BBK293 Ea = 52863 Smt’! Logue Ea 2p 52.86 eSmo2"! 3 2303x8314 (i )See 1S: Bn Phe nenttian. A+B— P He cate & given by Rate: KLAICB)™ © How ts the sate of reaction affeced- i, the 201s Concentration of B ts doubled: al O What is the overall order ofreartion % A ds present ww Carge exters?. Ws) poe~ecasceit, 27 a | READC28)" wil beome 24 KCAD cB)* indlep endlent of concentration. of A Rake becomes 4 Hines Rake = kcBJ*916 a fist order reaction has a rate constamt Ix(o"® pes second. How Gong wilh 54 4 thi sectant bake to ceduce #342 log = 0.4 #41, Logs > 0-699") 2022 re amas 23 fon [Ro eRe aescosteaonie k - = 2.303 3 * ke fog ss 2 2.303K o-22laxl? > sil see 2.303 (Lo, S- 209? 1x10"? : 3a eee ee alt A yt neaction & eaction & second order imA amt fost ade iB . Wade the digg erentio£ nate equotion How & the xake apgertedt on imacosing the concentotinn GA freee times” sake o4fpeter fen concontalinn of both A and B axe dowsbed- 2018 @ Hows Ars cm Rael cay’ C8) pMone @ Rake EL3ay C8) 2 a Rcayee) 34 himes @ Rake ~ kK cay ced je L2ay* 028) 8 cea C89 28 fmes—— Ss os The following aesnlt Rove been obtaimeot. duxiny cx Tea’) Trea : (rod £") cone £°9 sarmobion af, we 1 oe ole. rl 2020 By 0.3? 0.30 axle, za o.lo 0.3? 3xiot 2 0.20 o4o @xlor* er petermine rate 2? expreuron i Ans Robe ole CEST? paxide LE oauicon xm co.te 3: ax" =e COI Cosas 4. 3xle : ate? Kod poset 3 wy ail 42° Rake=k cp)"GAA The rate constant mig the the fa a 0h HO, t giver by ec gen decomposition y fog k = 14.2. ~ 11% Colenlote Ea. fy, this xeavtion amd Ze is 2oomunukes CR > nate constant f Ky ole cl a. oe aie TIE Saale 4 %& Roy An Fi =0.| kK > bog A- EX E2068 fog k > A" a a03RT th, Bogle = 4 2~ txts 20.613 “zee ees -Eo ec lxte™ z BMS XI0 mix 2303RT 7 Kio TXB 42.303 Ea Lat ust Te"! Lag eS moe!G20 Exo. xeastion id and, at, N,G)t BGP Rakerk 0 Wide He erder and. mo lecubanity of his i acon’? © Wule Heo unk ofk AS © zew ardu ame Molecubontly> +a © ume ogee makes Qolk aMaxls