Chemistry

KENDRIYA VIDYALAYA SANGATHAN
AHMEDABAD REGION
WORKSHEETS FOR CLASS XII

SUBJECT CHEMISTY (043)
SESSION 2023-24
OUR INSPIRATION
CHIEF PATRON
Mrs. Shruti Bhargava

Deputy Commissioner
Ahmedabad Region
****************
PATRON
Mrs. Vinita Sharma
Assistant Commissioner
Ahmedabad Region
****************
MENTOR
Mr. L. R. THAKAN
Principal,
KV No. 1 BARODA,
Ahmedabad
WORKSHEET DEVELOPMENT
TEAM
Name Designation Name of K.V. Chapter Alloted
Mr. Dinesh Kumar Tank PGT-Chemistry K. V. 1 Baroda Solutions
Mr. Anil Sharma PGT- Chemistry K. V. Rajkot Electrochemistry
Mr. Bharat Pandya PGT- Chemistry K. V. 3 Surat Chemical Kinetics
Mr. Mukesh Solanki PGT- Chemistry K. V. Rajkot d- and f-block Elements
Mrs. Archana Singh PGT-Chemistry K. V. 2 Army Baroda Coordination compounds
Mr. Atul Tiwari PGT-Chemistry K. V. 2 Army Baroda Haloalkane and Haloarene
Mrs. Anju Bala PGT-Chemistry K. V. 1 Ahmedabad Alcohol Phenol and ether
Dr. Sangeeta Lamba PGT-Chemistry K. V. Himmatnagar Aldehyde ketone and

carboxylic acid
MR Lokesh Suredia PGT-Chemistry K. V. ONGC Mehsana Amines
MR S K Soni PGT-Chemistry K. V. Ahmedabad Cantt Biomolecules
EDITED AND COMPILED BY

Name Designation K.V.
Mr. Dinesh Kumar Tank PGT-Chemistry K. V. 1 Baroda
Mr. Anil Sharma PGT- Chemistry K. V. Rajkot

INDEX
Chapter No. Of worksheets
Solutions 2
Electrochemistry 2
Chemical Kinetics 2
d- and f-block Elements 2
Coordination compounds 2
Haloalkane and Haloarene 2
Alcohol Phenol and ether 3
Aldehyde ketone and carboxylic acid 3
Amines 2
Biomolecules 2
KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CLASS: XII WORKSHEET No: 01
CHAPTER: SOLUTION TIME: 35 MINUTES
Q.1 Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality (b) decrease in molarity
(c) decrease in mole fraction (d) decrease in % (w/w)
Q.2 The value of Henry’s constant KH is:
(a) greater for gases with higher solubility (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases
Q.3 Which of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0 (b) ΔVmixing = 0
(c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture
Q.4 If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be_
(a) 0.25 mol L-1 (b) 0.5 mol L-1
(c) 5 mol L-1 (d) 1.0 mol L-1
Q.5 If two liquids A and B form minimum boiling azeotrope at some specific composition then _____.
(a) A–B interactions are stronger than those between A–A or B–B.
(b) vapour pressure of solution increases because a greater number of molecules of liquids A and B can
escape from the solution.
(c) vapour pressure of solution decreases because a smaller number of molecules of only one of the
liquids escape from the solution.
(d) A–B interactions are weaker than those between A–A or B–B
Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points
either greater than both the components or less than both the components.
Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
Q.7 Assertion (A): Soda bottles are sealed under high pressure.
Reason (R): High pressure increases the solubility of carbon dioxide gas
Answer the questions in short
Q.1 (a) Define Mole fraction: (b) Azeotropes
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.2 State the law co-relating the pressure & solubility of a gas in a liquid. State an application of this law.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
Q.3 What type of deviation is shown by mixture of ethanol and acetone? Give reason.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
___________________________________________________________________________________
Q.04 Write two differences between the solutions showing positive & negative deviation from
Raoult’s law.
Ans:
Solutions having Positive deviation Solutions having Negative deviation
Q.05 On mixing liquid X and liquid Y , the volume of the resulting solution increases _
(a) What type of deviation from Raoult’s law is shown by the resulting solution?
(b) What change in temperature would you observe after mixing liquids X and Y?
Ans:
(a) ___________________________________________________
(b) ___________________________________________________
Q.06 A solution of glucose (C6H12O6) in water is labelled as 10% by weight. What would be the molality
of the solution? (Molar mass of glucose = 180 g mol–1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.7 Give reason for followings
(a) Why are aquatic species more comfortable in cold water than in warm water?
(b) Deep sea divers are advised not to come to surface immediately from deep waters. Why?
(c) Cooking is faster in pressure cooker than in cooking pan
(d) Two liquids A and B boil at 120oC and 160oC respectively. Which of them has higher vapour
pressure at 70oC?
(e) Name the substances which are used by deep sea divers to neutralize the toxic effects of nitrogen
dissolved in the blood.
Ans:(a)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(b)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(c)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(d) _________________________________________________
Ans:(e) __________________________________________________
CHAPTER: SOLUTION TIME: 35 MINUTES
Q.1 Colligative properties depend on:
(a) the nature of the solute (b) the number of solute particles in solution
(c) the physical properties of solute (d) the nature of the solvent
Q.2 The most suitable colligative property to determine molecular weight of biomolecules is:
(a) Lowering of vapour pressure (b) Osmotic pressure
(c) Elevation of boiling point (d) Depression of freezing point
Q.3 Which has highest boiling point:
(a) 1 M Glucose (b) 1 M NaCl
(c) 1 M CaCl2 (d) 1 M AlF3
Q.4 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount
of ‘A’ is added to the solution. The solution is _________.
(a) saturated (b) supersaturated
(c) unsaturated (d) concentrated
Q.5 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are_____.
(a) 2, 2 and 2 (b) 2, 2 and 3
(c) 1, 1 and 2 (d) 1, 1 and 1
Q.6 Assertion(A): Boiling point of 0.1 M KCl solution is higher than 0.1 M Glucose solution.
Reason: Glucose is a non-electrolyte while KCl molecule dissociates in aqueous state.
.
Q.07 Assertion (A): Human blood cell swell-up when it is placed in a NaCl solution having concentration more
than 0.9%.
Reason (R): Osmosis involves movement of solvent molecules from its higher concentration to its lower concentration.
Q.1 Define (a) Abnormal molar mass: (b) van’t Hoff factor
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.2 Give reasons:
(a) RBC shrink when placed in saline water but swell in distilled water.
(b) 0.1 M KCl has higher boiling point than 0.1 M Glucose.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
______________________________________________________
Q.3 A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This
solution has a boiling point of 100.420C. What mass of glycerol was dissolved to make this solution?
(Kb for water = 0.512 K Kg mol -1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_______________________________________________________________________________
Q.4 A solution containing 15 g urea (molarmass= 60 g mol–1) per liter solution in water has the Same
osmotic pressure (isotonic) as a solution of glucose (molar mass= 180 g mol –l) in water. Calculate the
mass of glucose present in one liter of its solution.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_______________________________________________________________________________
Q.5 Calculate the freezing point of a solution when 20 g of CaCl2 (M=111 g mol -1) was dissolved in 500
g of water, assuming CaCl2 undergoes complete ionization. (Kf for water = 1.86 K kg mol-1)
OR
Calculate the boiling points of solution when 2 gm of Na2SO4 (molecular mass 142 gm/mol) was
dissolved in 50 gm of water assuming Na2SO4 undergoes complete ionization. (Kb for water = 0.52 K Kg
mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_____________________________________________________________________________
Q.6 A 5% solution (by mass ) of cane sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% solution (by mass ) of glucose in water
(Molecular mass: Glucose C6H12O6 : 180 amu; Cane –sugar C12H22O11: 342 amu)
OR
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62K.
Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated)
(Given molar mass of benzoic acid = 122 g mol -1, Kf for benzene = 4.9 K kg mol -1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________
CHAPTER: ELECTROCHEMISTRY TIME: 35 MINUTES
Q.1 The difference between the electrode potentials of two electrodes when no current is drawn through
the cell is called______
(a) Cell potential (b) Cell emf (c) Potential difference (d) Cell voltage
Q.2 An electrochemical cell can behave like an electrolytic cell when ____
(a) Ecell = 0 (b) Ecell > Eext (c) Eext > Ecell (d) Ecell = Eext
Q.3 The positive value of the standard electrode potential of Cu2+/Cu indicates that ____
(I) This redox couple is a stronger reducing agent than the H+/H2 couple.
(II) this redox couple is a stronger oxidising agent than H+/H2.
(III) Cu can displace H2 from acid.
(IV) Cu cannot displace H2 from acid.
Identify the correct statement/s:
(a) Statement I & III (b) Statement I & IV
(c) Statement II & III (d) Statement II &IV
Q.4 Which of the following statement is wrong about a galvanic cell?
(a) cathode is positive charged (b) anode is negatively charged
(c) reduction takes place at the anode (c) reduction takes place at the cathode
Q.5 For the given cell, Incorrect option is:
Mg|Mg2+|| Cu2+|Cu
(a) Mg is Anode (b) The cell reaction is Mg2+ + Cu → Mg + Cu2+
(c) Cu is cathode (d) Cu is the oxidising agent
Q.6 Assertion : Assertion: Copper sulphate can be stored in zinc vessel.
Reason: Zinc is more reactive than copper.
Q.7 Assertion: ECell should have a positive value for the cell to function.
Reason: for a possible/feasible cell reaction the reduction potential should be in order Ecathode < Eanode.

Q.1 Given that the standard electrode potentials (Eo) of metals are
K+/K=-2.93 V, Ag+/Ag=+0.80 V,Cu2+/Cu=+0.34 V,Mg2+/Mg=2.97 V,Cr3+/Cr=-0.74 V, Fe2+/Fe=-0.44 V.
Arrange these metals in an increasing order of their reducing power.
Ans:____________________________________________________________________________________
Q.2 Fluoride does not exhibit any positive oxidation state. Why?
Ans:____________________________________________________________________________________
Q.3 Depict the galvanic cell in which the following reaction takes place:
Zn (s) + 2Ag+ (aq) → Zn+2 (aq) + 2Ag (s) Also indicate that in this cell:
(i) Which electrode is negatively charged?
(ii) What is the carrier of the current in the cell?
(iii) What is the individual reaction at each electrode?
Ans:(i)________________________________________________________________________________
(ii)__________________________________________________________________________________
(iii) __________________________________________________________________________________
Q.04 Calculate the standard cell potentials of galvanic cell in which the following reaction take place:
2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
Calculate the ΔrG0 value for the reaction. Given E0(Cr3+/Cr) = -0.74 V ; E0 (Cd2+/Cd) = -0.40 V , F= 96500 C mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.05 The cell where the following reaction occurs
2Fe3+ ( aq) + 2 I- (aq)  2 Fe2+ (aq) + I2 (s) has E0(cell) = 0.236 V at 298 K .
Calculate the standard Gibbs energy of the cell reaction. (Given: 1 F = 96500 C mol -1)
Ans:_______________________________________________________________________________________
_____________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
____________________________________________________________________________________
Q.06 A voltaic cell is set up at 250C with the following half cells:
Al| Al3+ (0.0010 M) and Ni | Ni2+ (0.50 M)
(i) Write the equation for the cell reaction that occurs when the cell generates an electric current.
(ii) Determine the cell potential. (Given E0 (Ni2+/Ni) = - 0.25 V , E0 (Al3+/Al) = -1.66 V)
(iii) Write the direction of flow of current when an external opposite potential applied is
(a) less than 1.41 V and (b) greater than 1.41 V
Ans:(i)______________________________________________________
Ans:(ii)_____________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
___________________________________________________________________________
Ans:(iii) (a) ___________________________________________________________
Ans:(iii) (b) ____________________________________________________________
Q.7 Calculate the log Kc for the given reaction at 298K :
Ni (s) + 2 Ag+ (aq) ↔ Ni2+ (aq) + 2 Ag (s)
Given: E Ni2+/Ni = -0.25 V, E0Ag+/Ag = +0.80 V , 1F = 96500 C mol-1
0
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________
CHAPTER: ELECTROCHEMISTRY TIME: 35 MINUTES
Q.1 Which of the statements about solutions of electrolytes is not correct?

(a) Conductivity of solution depends upon size of ions.
(b) Conductivity depends upon viscosiy of solution.
(c) Conductivity does not depend upon solvation of ions present in solution.
(d) Conductivity of solution increases with temperature.
Q.2 The quantity of charge required to obtain one mole of aluminium from Al2O3 is ___________.
(a) 1F (b) 6F (c) 3F (d) 2F
Q.3 The cell constant of a conductivity cell _____________.
(a) changes with change of electrolyte. (b) changes with change of concentration of electrolyte.
(c) changes with temperature of electrolyte. (d) remains constant for a cell.
Q.4 Saturated solution of KNO3 is used to make 'salt bridge' because
(a) velocity of K+ is greater than that of NO3- (b) velocity of NO3- is greater than that of K+
(c) velocity of both K+ and NO3- are nearly the same (d)) KNO3 is highly soluble in water
Q.5 The electrolyte used in Leclanche cell is
(a) paste of KOH and ZnO (b) 38% solution of H2SO4
(c) moist paste of NH4Cl and ZnCl2 (d) moist sodium hydroxide
Q.6 Assertion: For measuring resistance of an ionic solution an AC source is used.

Reason: Concentration of ionic solution will change if DC source is used.
Q.7 Assertion: Conductivity of all electrolytes decreases on dilution.

Reason: On dilution number of ions per unit volume decreases.

Q.1 Name the type of cell which was use in Apollo space programme for providing electrical power
Ans: ____________________________________________________________________________________
Q.2 Write two advantages of fuel cell.

Ans (1) _________________________________
(2) _________________________________
Q.3 (a) What type of cell is a lead storage battery?
(b) Write the anode and cathode reactions and the overall cell reaction occurring in the use of a lead storage
battery?
Ans: (a)_______________________________________
(b)________________________________________________________________________________________
______________________________________________________________________________________
Q.04 Calculate the time to deposit 1.17 g of Ni at cathode when a current of 5 A was passed through the
solution of Ni(NO3)2. (Molar mass of Ni=58.5 g mol-1, 1F = 96500 C mol-1)
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________________
Q.05 (a) What is the role of ZnCl2 in a dry cell?
(b) Account for the following: -
(i) Alkaline medium inhibits the rusting.
(ii) Iron does not rust even if zinc coating is broken down at any point in a galvanized pipe.
Ans:
(a)______________________________________________________________________________________
(b)(i) ___________________________________________________________________________________
(ii) _____________________________________________________________________________________
Q.06 During the construction of some public building, the contractor intends to fix iron frames for windows and
railings to reduce the cost of construction. After due considerations, it is finally recommended to use
aluminium frames for windows and steel railings instead of iron.
Answer the following questions:
(i) As a chemist, do you agree with the new recommendations? (ii) Give reasons for your choice.
Ans:
(i)______________________________________________________________________________________
(ii)______________________________________________________________________________________
________________________________________________________________________________________
Q.7 The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905 × 10-5 S cm-1. Calculate its molar
conductivity and degree of dissociation(α).
Given λ0(H+) = 349.6 S cm2mol-1 and λ0(CH3COO-) = 40.9 S cm2 mol-1.
Ans:_______________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
_________________________________________________________________________
Q.8 Out of the following pairs, predict with reason which pair will allow greater conduction of electricity:
(i) Silver wire at 30oC or silver wire at 60oC.
(ii) 0·1 M CH3COOH solution or 1 M CH3COOH solution.
(iii) KCl solution at 20oC or KCl solution at 50oC.
Ans:(i)_____________________________________________________________________________________
______________________________________________________________________________________
Ans:(ii)_____________________________________________________________________________________
_____________________________________________________________________________________
Ans:(iii)____________________________________________________________________________________
______________________________________________________________________________________
Q.9 Predict the products of electrolysis in each of the following:

(i) Molten NaCl. (ii) An aqueous solution of NaCl.
Ans: (i) _________________________________________________________________________________
(ii)
_______________________________________________________
_____________________
CHEMICAL KINETICS CLASS-XII (CHEMISTRY) WORKSHEET-I
1 The rate constant of a reaction is 2.5x10-2 Lmol-1s-1,.What is the order of reaction is:
(A) Zero (B) one (C) half (D) Two
2 The differential rate law of the above first order reaction is: 2A  B
𝑑𝑥 1 𝑑𝑥 1
(A) 𝑑𝑡
= 2𝑘 ln{[𝐴0] /[𝐴]} (B) 𝑑𝑡
= 𝑘 ln{[𝐴0] /[𝐴]}
𝑑𝑥 1 𝑑𝑥 1
(C) = ln{[𝐴] /[𝐴0]} (D) = log{[𝐴0] /[𝐴]}
𝑑𝑡 2𝑘 𝑑𝑡 2𝑘
3 The rate of reaction, A+B→Products, is given by the equation, r=k[A][B],if B is taken in large excess,
the order of the reaction would be;
(a) 2 (b) 1 (c) 0 (d) Unpredictable
4 The rate law for the reaction, RCl+NaOH(aq.) →ROH+NaCl is given by, Rate=k[RCl], the rate of
reaction will be:
(a) Unaffected by increasing the temperature of the reaction\
(b) Doubling on doubling the concentration of NaOH
(c) Halved on reducing the concentration of NaOH to one half
(d) Halved on reducing the concentration of RCl to one half.
5 The hypothetical reaction, A2+B22AB, follows the following mechanism:

A2↔A+A (fast)
A+B2AB+B (slow)
A+BAB (fast)
The order of the overall reaction is:
(a)zero (b)1 (c) 2 (d)3/2
6- In each of the following questions, an Assertion (A) is followed by a corresponding
7 Reason(R). Use the following keys to choose the appropriate answer:
(A) If both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) If both (A) and (R) are correct and (R) is not correct explanation of (A)
(C) If (A) is correct and (R) is wrong
(D) If (A) is wrong and (R) is correct
6 (A) : The rate constant of a zero order reaction has same unit as that of the rate of the reaction
(B) : The concentration of reactants is taken to be unity while determining rate Constant
7 (A): Increase in temperature increases rate of a chemical reaction.
(B): Increase in temperature decreases activation energy of the reaction
8 P + Q -------- R, the rate of this reaction quadruples when concentration of P
is doubles and remains same when concentration of Q is doubled.
(a) Write differential rate law of the reaction
(b) What is the order of the reaction and unit of rate constant of reaction?
Ans:…………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
9 A first order reaction completes 90% in 50 minutes. How long will it take to complete 20% ?
Ans:…………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
10 It is observed that on increasing temperature of the reaction by 10K, the rate of reaction
doubles. By what factor the rate of a reaction will increase if temperature of a reaction is raised
from 500C to 1000C?
11 For the reaction R(s) --------- P(g) , the potential energy diagram is given below:
(a) What is the activation energy of the reaction?

(b) What is ΔH of the reaction?
(c) Predict the sign of the ΔG of the reaction
(d) Draw PE diagram for the reverse reaction of this.
12 A---------.>B , For the given reaction the plot between concentration of reactant
against time has been shown below:
(a) What is the order of the reaction

(b) What does the slope of the line indicate in this graph?
13 2A + B -------- 4C, In the given reaction the rate law is given by, rate = k [A]2[B]
If value of k is 2.0 x 10-2 l2/mol2/s then:
(i) Find initial rate of reaction when [A]= 0.5 M and [B] = =0.4 M
(ii) Find the rate of reaction when B is reduced to 0.2 M
(iii) Write rate law when B is taken in excess, what will be order of reaction in this
case?
KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD
CHEMICAL KINETICS CLASS-XII (CHEMISTRY) WORKSHEET-II
1 Which of the following is the correct graph for the first order reaction?
(A) (B)
(C) (D)
2 75% of a first order reaction was completed in 32 minutes., when was 50% of the reaction completed?
a)4min (b) 8 min. (c)24 min. (d)16 min.
3 Activation Energy of a chemical reaction can be determined by:
(a) changing concentration of the reactants
(b) evaluating rate constant at standard temperature.
(c) evaluating rate constants at two different temperatures.
(d) evaluating velocities of reaction at two different temperatures.
4 According to the collision theory of reaction rates:
(a) Every collision between reactant molecules leads to a chemical reaction.
(b) Rate of reaction is proportional to the velocity of the molecules.
(c) Rate of reaction is proportional to the average energy of the molecules.
(d) Rate of reaction is proportional to the number of collisions per second.
5 A catalyst
(a) increases the rate of reaction by decreasing ΔG of a reaction.
(b) increases the rate of reaction by increasing ΔG of a reaction.
(c) increases the rate of reaction by decreasing activation energy of the forward reaction.
(d) increases the rate of reaction by providing an alternative pathway via an intermediate with lower
activation energy
6-7 In each of the following questions, an Assertion (A) is followed by a corresponding
Reason(R). Use the following keys to choose the appropriate answer:
(A) If both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) If both (A) and (R) are correct and (R) is not correct explanation of (A)
(C) If (A) is correct and (R) is wrong
(D) If (A) is wrong and (R) is correct
6. (A) : The rate of reaction always depend on concentration of reactant
(R) : For zero order reactions concentration of reactant does not affect rate
7 (A) : The order of a reaction may be fractional but molecularity is never
(B) : The order of reaction is experimental but molecularity depends on stoichiometric co-
efficient of the reactants in the balanced chemical equation.
8 The value of rate constant of reaction is as below given, identify the order of the
reaction: (a) mol/L s-1 (b) L/mol s-1
A)…………………………. B)……………………………
9 The rate constant of a reaction is given by:
log k = 13.25 – (1.28 x103)K/T
Find activation energy and pre-exponential factor
10 Analyse the given graph, drawn between concentration of reactant vs. time
(a) Predict the order of reaction.

(b)Theoretically, can the concentration of the reactant reduce to zero after infinite time?
Explain.
ANS: (A)………..
(B) ……………………………………………………………………………
11 Half life of a reaction at two temperatures 300K and 320K are observed as 69.3 minutes and
17.325 minutes. Find activation energy of the reaction.
12 Suppose 50 bacteria are placed in a flask containing nutrients for the bacteria so that
they can multiply. A study at 35°C gave the following results
Time (minutes) 0 15 30 45 60
Number of bacteria 100 200 400 800 1600 Then
(i) This multiplication of bacteria follows a
(a) zero order reaction (b) 1st order reaction
(c) 2nd order reaction (d) 3rd order reaction
(ii) The rate constant for the reaction is
(a) 0.0462 min–1 (b) 0.462 min–1 (c) 4.62 min–1 (d) 46.2 min–1
(iii) The rate of the reactions initially is
(a) 4.62 bacterias per minute (b) 23.1 bacterias per minute
(c) 23.1 bacterias per sec (d) 0.231 bacterias per sec
(iv) The t1/2 for the reaction is
(a) 1.5 sec (b) 1.5 min (c) 150 min (d) 15 min
(v) The expression used for calculating the rate constant value in this experiment is
Ans: (i) ….. (ii) …… (iii) ….. (iv) ….. (v)……..

CHAPTER: d & f-Block Elements TIME: 35 MINUTES
Q.1 Which pair of compounds is expected to show similar colour in aqueous medium?
(a) FeCl2 and CuCl2 (b) FeCl2 and MnCl2
(c) VOCl2 and CuCl2 (d) VOCl2 and FeCl2
Q.2 Transition elements form alloys easily because they have

(a) Same atomic number (b) Same electronic configuration
(c) Nearly same atomic size (d) None of the above
Q.3 Which of the following does not represent the correct order of the property stated against it?
(a) V2+ < Cr2+ < Mn2+ < Fe2+ : paramagnetic behaviour
(b) Ni2+ < Co2+ < Fe2+ < Mn2+ : ionic size
(c) Co < Fe < Cr < Sc
3+ 3+ 3+ 3+
: stability in aqueous solution
(d) Sc < Ti < Cr < Mn : number of oxidation states
Q.4 Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals.
Which of the following is not the characteristic property of interstitial compounds?
(a) They have high melting points in comparison to pure metals.
(b) They are very hard.
(c) They retain metallic conductivity.
(d) They are chemically very reactive.
Q.5 Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they
show similar physical and chemical properties because.
(a) Both belong to d-block.
(b) Both have same number of electrons.
(c) Both have similar atomic radius.
(d) Both belong to the same group of the periodic table.
Q.6 Assertion: Copper cannot liberate hydrogen from acids.
Reason: Standard electrode potential of Copper is greater then Zero
 2
Q.7 Assertion: Cu is more stable then Cu .
Reason: Cu is having 3d10 4s0 but Cu2 is having 3d 9 4s0

Q.1 Give reason:
Give reason: (a) The elements of 2nd and 3rd transition series have almost similar atomic radii.
(b) Cr 2+-chromium -(II) is strongly reducing while Mn3+ -manganese (III) is strongly oxidizing although both
have d4 electronic configuration.
Ans:(a)
(b)
Q.2 Give reason:
(a) Transition elements exhibit their highest oxidation state in their oxides not in Fluorides.
(b) Vanadium pentoxide act as a catalyst?
Ans:(a)
(b)
Q.3 Give reason:

(a) Transition metals show several/variable oxidation states.
(b) Transition metals have a strong tendency to form complexes
Ans:(a)
(b)
Q.4 The Elements of 3d transition series are given as:

Atomic No 21 22 23 24 25 26 27 28 29 30
Element Sc Ti V Cr Mn Fe Co Ni Cu Zn
Answer the following:
(a) Write the name of element which is not regarded as transition element.
(b) Write the element which can show an oxidation state of +1.
(c) Which element is softest?
(d) Which element shows maximum number of oxidation states.
(e) Which element has the highest melting point?
(f) Which element shows only +3 oxidation state?
Ans: (a) (b) (c)

(d) (e) (f)
Q.5 Give reason:

(a) Give reason: Zn, Cd and Hg are not regarded as transition metal.
(b) Explain why, Zn (II) salts are white while Mn (VII) are deep purple in colour?
(c)The enthalpies of atomization of the transition metals are high.
(d) The E0 (M2+/M) value for copper is positive (+0.34V).
OR
(a) Silver atom has completely filled d orbitals (4d10) in its ground state but it is a transition element.
(b) The transition metals generally form colored compounds.
(c) Zn, Cd and Hg are soft metal.
(d) Explain why Cu+ ion is not stable in aqueous solution?
Ans:(a)
(b)
(c)
(d)
CHAPTER: d & f-Block Elements TIME: 35 MINUTES
Q.1 Gadolinium belongs to 4f series. Its atomic number is 64. Which of the following is the correct electronic
configuration of gadolinium?
(a) [Xe] 4f7 5d1 6s2 (b) [Xe] 4f6 5d2 6s2
8 2
(c) [Xe] 4f 6d (d) [Xe] 4f9 5s1
Q.2 Which of the following oxidation state is common for all lanthanoids?
(a) +2 (b) +3 (c) +4 (d) +5
Q.3 What is the percentage of lanthanoid metal in mischmetal?

(a) 90% (b) 20% (c) 5% (d) 95%
Q.4 KMnO4 acts as an oxidizing agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide ion
is oxidized to.
(a) I2 (b) IO− (c) IO3− (d) IO4−
Q.5 Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3
of lanthanoids?
(a) Ce (b) Eu (c) Yb (d) Ho.
Given below are two statements labelled as Assertion (A) and Reason (R)
Select the most appropriate answer from the options given below:
Q.6 Assertion : Zirconium (Zr) and Hafnium (Hf) have almost same atomic radius
Reason: Zr and Hf are belong to same group of periodic table.
Q.7 Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.
Reason: Actinoids can utilize their 5f orbitals along with 6d orbitals in bonding but
lanthanoids do not use their 4f orbital for bonding.

Q.1 Name an important alloy, which contains some of the lanthanide metals. Mention its uses
Ans:
Q.2 One among the lanthanides, Ce(III) can be easily oxidized to Ce (IV)., why?
Ans:
Q.3 (a) Name the lanthanoid element which forms tetra positive ions in the aqueous solution.
(b) Why the chemistry of actinoids is not as smooth as lanthanoids.
Ans:(a)
Ans:(b)
Q.4 What is lanthanide contraction? What are the consequences of lanthanide contraction?
Ans:
Q.05 Give reason

(a) HCl cannot be used in place of sulphuric acid to acidify KMnO4 solution in volumetric analysis
(b) Which is more basic La(OH)3 or Lu(OH)3 and why?
Ans:(a)
Ans:(b)
Q 06 (a) When a chromite ore ‘A’ is fused with sodium carbonate in free excess of air and the product is
dissolved in water, a yellow solution of compound ‘B’ is obtained. After treatment of this yellow solution with
sulphuric acid compound ‘C’ can be crystallize from the solution. When compound ‘C’ is treated with KClorange
crystals of compound ‘D’ is crystallizes out. Identify ‘A’ to ‘D’ and write the reaction from ‘A’ to ‘B’.
(b) How does the potassium dichromate reacts with following and write the ionic equations with:
(i) iodide (ii) Fe(II) ions (iii) H2S
Write the ionic equations for the reactions
OR
(a) Write the chemical equation involved in the preparation of potassium permanganate.
(b) How does the acidified permanganate solution react with
(i) Fe(II) ions (ii) SO2 and (iii) oxalic acid?
Write the ionic equations for the reactions.
Ans:
CHAPTER: COORDINATION CHEMISTRY TIME: 35 MINUTES
Q.1 Which of the following species is not expected to be a ligand

(a) NO (b) NH4+ (c)NH2CH2CH2NH2 (d) CO
Q.2 The correct IUPAC name of [Pt(NH3)2Cl2] is____
(a) Diamminedichoridoplatinum(II) (b) Diaminedichoridoplatinum(IV)
(c) Diaminedichoridoplatinum(0) (d)dichloridodiammineplatinum(IV)
Q.3 The compounds [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 represent

(a) Linkage isomerism (b) ionization isomerism
(c) coordination isomerism (c) no isomerism
Q.4 Which of the following is expected to be paramagnetic complex?
(a)[Ni(H20)6] 2+ (b) [Ni(CO)4] (c)[Zn(NH3)4]2+ (d) [Co(NH3)6]3+
Q.5 The correct structure of Fe(CO)5 is:
(a) octahedral (b) tetrahedral (c) square pyramidal (d) trigonal pyramidal
Given below are two statements labelled as Assertion (A) and Reason (R) Select the
most appropriate answer from the options given below:
Q.6 Assertion : Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason : Ambidentate ligand has two different donor atoms.
Q.7 Assertion: low spin tetrahedral complexes are rarely observed

Reason: crystal field splitting is less than pairing energy for tetrahedral complexes..

Q. 1 Nickel does not form low spin octahedral complexes. Why?
Ans:
Q.2 Which of the following is a more stable complex and Why? [Co(en)3]3+ and [Co(NH3)6]3+
Ans:
Q.3 Write the structural formulae of the following compoundsl:

(i) Dichloride(ethylenediamine)cobalt(IV)sulphate
(ii) Tetramminechloridonitrocobalt(IV) sulphate
(iii) Tetraaquadichloridochromium (III) nitrate
Ans:(i) (ii)
(iii)
Q.04 Using valence bond theory, explain the following in the relation to the paramagnetic complex [Mn(CN)6]3-
(a) Type of hybridization
(b) Magnetic moment value
(c) Type of complex- inner or outer orbital complex.
Ans: __________________________________________
Q.05 (a)what is the difference between ambidentate ligand ana a() chelating ligand?
(b) Arrange the following complexes in the increasing order of conductivity of their solution
:[Co(NH3)3Cl3],[Co(NH3)4Cl2]Cl, [Co(NH3)6]Cl3,[Co(NH3)5Cl]Cl2
(c) magnetic moment of [MnCl4]2- is 5.92 BM. Explain giving reason
Ans:
Q.06 (a) Draw figure to show the splitting in octahedral crystal field.
(b) Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the
following complexes. (a) K3[Co(C2O4)3] (b) cis-[CrCl2(en)2]Cl (c) [Mn(H2O)6]SO4
Ans:(a)
Q.07 Discuss briefly giving an example in each case the role of coordination compounds in:
(a)biological systems (b)analytical chemistry (c) medicinal chemistry (d)extraction/metallurgy of metals
Ans:
CHAPTER: COORDINATION CHEMISTRY TIME: 35 MINUTES
Q.1 Which of the following complexes are hetroleptic

(a)[Cr(NH3)6]3+ (b) [Ni(CN)4]2- (c)[Mn(CN)6]4- (d) [Ni(NH3)4Cl2]
Q.2 The oxidation number of cobalt in K[Co(CO)4] is
(a) +1
(b) +3
(c) -1
(d) -3
Q.3 Amongst the following ions which one has the highest magnetic moment?
(a) [Cr(H2O)6]3+ (b) [Fe(H2O)6]2+ (c) [Zn(H2O)6]2+ (d) [Cu(NH3)4]2+
Q.4 Wilkinson’s catalyst, [(Ph3P)3RhCl] is used for

(a) hydrogenation of carboxylic acids (b) hydrogenation of alkynes
(c) hydrogenation of alkenes (d) polymerization of alkenes
Q.5 What kind of isomerism exists between [Cr(H2O)6]Cl3(violet) and [Cr(H2O)5Cl]Cl2.H2O(greyish green)?
(a) Linkage isomerism (b) solvate isomerism (c)ionization isomerism (d) coordination isomerism
Q.5 The stabilization of coordination compounds due to chelation is called the chelate effect. Which of the
following is the most stable complex species?
(a) [Fe(CO)5] (b) [Fe(CN)6]3- (c) [Fe(C2O4)3]3- (d) [Fe(H2O)6]3+
Given below are two statements labelled as Assertion (A) and Reason (R) Select the
most appropriate answer from the options given below:
Q.7 Assertion: Toxic metal ions are removed by chelating ligands.
Reason: Chelate complexes tend to be more stable.
Q.8 Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has always two different donor atoms.

Q.1 What is the effect of synergic bonding interactions in a metal carbonyl complex?
Ans:
Q.2 On the basis of crystal field theory, write the electronic configuration of d4 in terms of t2g and eg in an
octahedral complex when.
(a) ∆0 ˃ P (b) ∆0 ˂ P
Ans:
Q.3 (a) Give the electronic configuration of the d- orbitals of Ti in [Ti(H2O)6]3+ion in the octahedral crystal field.
(b) Why is this complex coloured? Explain on the basis of distribution of electrons in d-orbitals.
Ans:
Q.4 (a) Explain why [Fe(H20)6]3+ has magnetic moment value of 5.92 BM whereas [Fe(CN)6]3- has a value of only
1.74 BM.
(b)CuSO4.5H2O is blue in colour while CuSO4 is colourless . why?
(c) A complex of the type[M(AA)2X2]n+ is known to be optically active. What does this about the
structure of the complex? Give one example of such complex.
Ans:_________________________________________________________________________________________
_______________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
______________________________________________________
Q.5 CoSO4.Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 solution to give white
ppt but does not react with BaCl2 solution. Isomer ‘B’ gives white ppt with BaCl2 solution but does not react
with AgNO3 solution. Answer the following questions:
(a) Identify ‘A’ and ‘B’ and write their structural formulas.
(b) Name the type of isomerism involved.
(c) Give the IUPAC name of ‘A’ and ‘B’.
Ans:_________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
________________________________________________________________________
Q.6 Using VBT, explain the following in relation to the complexes given below:
[Mn(CN)6]3-, [Co(NH3)6]3+
(a) Type of hybridization
(b) Inner or outer orbital complex
(c) Magnetic behaviour
(d) Spin only magnetic moment value
Ans:_________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_______________________________________________________________
CLASS: XII-CHEMISTRY WORKSHEET No: 01
CHAPTER: HALOALKANES AND HALOARENES (till SN1 & SN2) TIME: 35 MINUTES
Q.1 Tertiary alkyl halides are practically inert to substitution by SN2 mechanism
because of
(A) steric hindrance (B) inductive effect (C) instability (D) insolubility
Q.2 Which of the following is the correct order of decreasing SN2 reactivity?
(A) RCH2X > R2CHX > R3CX (B) R3CX > R2CHX >RCH2X
(C) R2CHX >R3CX > RCH2X (D) RCH2X >R3CX >R2CHX
Q.3 Which of the following reaction will yield 2,2-Dibromopropane:
(A) CH3-C≡CH +2HBr → (B) CH3-CH=CH-Br +HBr →
(C) CH≡CH +2HBr → (D) CH3-CH=CH2 +HBr →
Q.4 The position of –Br in the compound in CH3CH=CH-C(Br)(CH3)2 can be
classified as:
(A) Allyl (B) Aryl (C) Vinyl (D) Secondary
Q.5 Flurobenzene can be synthesized in laboratory
(A) by heating phenol with HF and KF
(B) by heating the benzene diazonium salt with HBF4
(C) by direct fluorination of benzene with F2 gas
(D) by heating 1-Bromobenzene with NaF solution
Given below question no 6-7 consist of an "Assertion" (A) and "Reason" (R) Type
questions. Use the following Key to choose the appropriate answer.
A.If both (A) and (R) are true, and (R) is the correct explanation of (A).
B.If both (A) and (R) are true but (R) is not the correct explanation of (A).
C.If (A) is true but (R) is false.
D.If (A) is false but (R) is true.
Q.6 Assertion: Nucleophilic substitution is more difficult to carry out on vinyl
chloride than ethyl chloride.
Reason : vinyl group is an electron donating group.
Q.7 Assertion : Haloalkanes are immiscible in water.
Reason : halogen of haloalkane form hydrogen bond with water.
SHORT ANSTER TYPE OF QUESTIONS

Q.8 Write IUPAC names of given compounds:
a. (CH3)3CCH2Br
b.
Q.9 Write given Naming reactions :

a. Finkelstein reaction
b. Sandmeyers reaction
c. Swarts reaction
Q.10 Explain why:

(i) The dipole moment of chlorobenzene is lower than that of cyclohexyl
chloride?
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
(ii) Haloalkanes react with KCN to form alkyl cyanides as main product
while AgCN forms isocyanides as the chief product. Explain.
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
----------------------------------------------------------------------------------
Q.11 a. Which one undergoes substitution reaction faster and why?
b. which one undergoes SN1 reaction faster and why?
1. or
2. or
Q.12 How the following conversions can be carried out?
a. 1-Bromopropane to 2-bromopropane
b. Aniline to chlorobenzene
c. But-1-ene to n-butyliodide
Q. 13 Arrange the compounds of each set in order of reactivity towards SN2 displacement:
(i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
Q.14 Arrange the compounds of each set-in order of reactivity towards SN2 displacement
(i) The four isomeric bromobutanes
(ii) C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5 )Br

CLASS: XII-CHEMISTRY WORKSHEET No: 01
CHAPTER: HALOALKANES AND HALOARENES (stereochemistry to last) TIME: 35 MINUTES
1. In the solvolysis of 3-Methyl-3 chlorohexane, which of the following statement is
not correct?
(A) It involves carbocation intermediate
(B) the intermediate involves sp2hybridised carbon
(C) it involves inversion of configuration
(D) the rate of reaction depends on 3-Methyl-3 chlorohexane concentration
2. Toluene reacts with a halogen in the presence of iron (III) chloride gives X and in
presence of light gives Y then X and Y are
(A) X= m-Chlorotoluene , Y= p-Chlorotoluene
(B) X= o and p-Chlorotoluene , Y= Trichloromethylbengene
(C) X= Benzyl chloride , Y= m-Chlorotoluene
(D) X= Benzyl chloride , Y= o-Chlorotoluene
3. Carbon atoms present in the molecule given below are asymmetric?
(A) a, b, c, d (B) b, c (C) a, d (D) a, b, c

4. Compounds in increasing order of rate of reaction towards nucleophilic
substitution:
(A) (a)<(b)<(c) (B) (c)<(b)< (a) (C) (a)<(c)<(b) (D) (c) < (a) < (b)
5. What is name of following reaction:
(i) Wurtz Reaction (ii) Fitting Reaction

(iii) Wurtz- Fitting Reaction (iv) swartz reaction
Given below question no 6-7 consist of an "Assertion" (A) and "Reason" (R) Type
questions. Use the following Key to choose the appropriate answer.
A.If both (A) and (R) are true, and (R) is the correct explanation of (A).
B.If both (A) and (R) are true but (R) is not the correct explanation of (A).
C.If (A) is true but (R) is false.
D.If (A) is false but (R) is true.
6. Assertion: 2-bromopentane gives pent-2-ene as the major product when
heated with alcoholic KOH.
Reason : In dehydrohalogenation reactions, the preferred product is that
alkene which has the greater number of alkyl groups attached to the doubly bonded
carbon atoms.
7. Assertion : It is difficult to replace chlorine by –OH in chlorobenzene in
comparison to that in chloroethane.
Reason : Chlorine-carbon (C—Cl) bond in chlorobenzene has a partial double
bond character due to resonance
SHORT ANSTER TYPE OF QUESTIONS
8. Write given Naming reactions :
(a) Wurtz-Fittig reaction
(b) Friedel craft alkylation of chlorobenzene with propyl chloride
9. Give Reasons for the following:

(i) C–X bond length in halobenzene is smaller than C–X bond length in CH3–X.
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
(ii) (±) 2–Butanol is optically inactive.
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
------------------------------------------------------------------------------
10. Define the following terms : (a) Enantiomers (b) Racemic mixture
-----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
----------------------------------------------------------------------------------
-----------------------------------------------------------------------------------
11. How will you bring about the following conversions?

(i) Ethanol to ethyl fluoride
(ii) Toluene to benzyl alcohol
Ans. (i) Ethanol to ethyl fluoride
(ii) Toluene to benzyl alcohol

12. Draw the structures of major monohalo products in each of the following reactions:
(a)
(b)
(c)
13. Primary alkyl halide C4H9Br (a) reacted with alcoholic KOH to give compound (b).
Compound (b) is reacted with HBr to give (c) which is an isomer of (a). When (a) is
reacted with sodium metal it gives compound (d), C8H18 which is different from the
compound formed when n-butyl bromide is reacted with sodium. Give the structural
formula of (a) and write the equations for all the reactions.
14. (a) Write equation for preparation of 1-iodobutane from 1-chlorobutane.

(b) Out of 2-bromopentane, 2-bromo-2-methylbutane and 1-bromopentane,
which compound is most reactive towards elimination reaction and why?
(c) Give IUPAC name of
CLASS:XII CHAPTER: ALCHOHOLS, PHENOLS AND ETHERS
TIME: 40 MIN WORK SHEET NO:1(ALCOHOLS)
NAME OF STUDENT:………………………………………………………….. ROLL NO……….
MCQ
1. In the reaction given below, X is:
C-H2SO4/heat
Neopentyl alchohol------------------------ →X
(a) 2 – methylpentane (b) 2 - methylpent-2-ene (c) 2 - methylbut-2-ene (d) neopentane
2. The most suitable reagent for the conversion CH3CH2OH can be converted into CH3CHO by……
(a) catalytic hydrogenation (b) treatment with LiAlH4
(c) treatment with pyridinium chlorochromate (d) treatment with KMnO4
3. Iodoform can be prepared from all except-
(a) Ethyl methyl ketone (b) Isopropyl alcohol (c) 3–Methyl – 2– butanone (d) Isobutyl alcohol
4. Give IUPAC name of the compound given below.
CH3CH(Cl)CH2CH2CH (OH) CH3
(a) 2-Chloro-5-hydroxy hexane (b) 2-Hydroxy-5-chlorohexane
(c) 5-Chlorohexan-2-ol (d) 2-Chlorohexan-5-ol
5. Which of the following alcohols gives 2-butene on dehydration by conc. H2SO4?
(a) 2-methyl propene-2-ol (b)2-methyl 1 -propanol (c) Butane-2-ol (d) Butane 1-ol
Assertion- Reason
Given below are two statements labelled as Assertion (A) and Reason (R) Select the most
appropriate answer from the options given below:
6. Assertion : In Lucas test, 3º alcohols react immediately.
Reason : An equimolar mixture of anhyd. ZnCl2 and conc. HCl is called Lucas reagent.
Ans:……………………………………………………………………………………………………………………………………
7. Assertion : Ethanol is a weaker acid than phenol.
Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueousNaOH.
Ans:………………………………………………………………………………………………………..
2 MARKS QUESTIONS
8. Write the mechanism of acid catalyzed hydration of an alkene to form corresponding alcohol.
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………..
………………………………………………………………………………………………………………………………………………………………….
9. Write the structures of the products when Butan-2-ol reacts with the following:
(a) CrO3 (b) SOCl2
Ans:…………………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………
…………………………………………………………………………………………
3 MARKS QUESTIONS
10. An organic compound ‘ A ‘ having molecular formula C3 H6 on treatment with aq.H2SO4 give ‘B’ which
on treatment with Lucas reagent gives ‘C’. The compound ‘C’ on treatment with ethanolic KOH gives
back ‘ A’ Identify A, B , C .
Ans:…………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………….………………………
…………………………….…………………………………………………………………………………………………………………………………
…………………………………………………….…………………………………………………………………………………………………………
11. How are the following conversions carried out?

(i) Propene to Propan-2-ol
(ii) Ethylmagnesium chloride to propan-1-ol.
(iii) Benzyl chloride → Benzyl alcohol
Ans:………………………………………………………………………………………………………………………………………………………….
………………………………………………………………………………………………………………………………………….…………………
…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………
5 MARKS QUESTIONS
12. (a) What happens when-
(i) propene is treated with B2H6 followed by H2O2/ OH-
Ans:…………………………………………………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………………………………………………..
(ii) Ethanol reacts with CH3COCl/ pyridine?
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………………………………………………....
(b) A compound 'A' is optically active. On mild oxidation, it gives a compound 'B' but on vigorous oxidation
gives another compound 'C'. C along with D is also formed from B by reaction with iodine and alkali. Deduce the
structures of A, B, C, and D.
Ans:………………………………………………………………………………………………………………………………………………………….
………………………………………………………………………………………………………………………………………….…………………
…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………
TIME: 40 MIN WORK SHEET NO:2(PHENOLS)
MCQ
1. Phenol on reduction with H2 in the presence of Ni catalyst gives
(a) benzene (b) toluene (c) cyclohexane (d) cyclohexanol
2. Picric acid is a yellow coloured compound. Its chemical name is
(a) m-nitrobenzoic acid (b) 2, 4, 6-trinitrophenol (c) 2, 4, 6-tribromophenol (d) p-nitrophenol
3. C-O bond length in phenol is less than C-O bond length in methyl alcohol because
(a) partial double bond character in aromatic ring (b) sp2Hybridisation Carbon
3
(c) sp Hybridisation Carbon (d) both (a) and (b)
4. IUPAC name of m-cresol is
(a) 3-methylphenol (b) 3-chlorophenol (c) 3-methoxyphenol (d) benzene-1, 3-diol
5. When Phenol is distilled with zinc dust, it gives
(a) Benzene (b) Toluene (c) Benzaldehyde (d) Benzoic acid
Assertion- Reason
(e) Both A and R are true and R is the correct explanation of A
(f) Both A and R are true but R is not the correct explanation of A
(g) A is true but R is false
(h) A is false but R is true
6. Assertion : Phenols give o-nitrophenol and p-nitrophenol on nitration with cone. HNO3 and
H2SO4 mixture.
Reason : -OH group in phenol is o-,p-directing.
Ans:……………………………………………………………………………………………………………………………………
7. Assertion : Phenols are more acidic than aliphatic alcohols.
Reason: Phenoxides are stabilized by resonance.
Ans:………………………………………………………………………………………………………………..
2 MARKS QUESTIONS
8. Illustrate the following name reactions :
(c) Reimer-Tiemann Reaction (b) Kolbe's reaction
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
9. (i)Ortho nitrophenol has lower boiling point than p-nitrophenol. Why ?

(ii) Ortho-nitrophenol is more acidic than ortho-methoxyphenol. Why?
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
3 MARKS QUESTIONS
10. An aromatic compound 'A' on treatment with CHCl3/KOH gives two compounds 'B' and 'C'. Both B
and C give the same product 'D' when distilled with Zinc dust. Oxidation of D gives E having molecular
formula C7H6O2. The sodium salt of E on heating with soda lime gives F which may be obtained by
distilling A with zinc dust. Identify A to F.
Ans:…………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………….…………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
11. (i) How will you convert Phenol to aspirin?

(ii) distinguish between following pairs of compounds
(a) Phenol and ethyl alcohol (b) phenol and benzoic acid
Ans:………………………………………………………………………………………………………………………………………………………….
………………………………………………………………………………………………………………………………………….…………………
……………………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………..
5 MARKS QUESTIONS
12. (a) Write IUPAC name of the following -
(i) (ii)
Ans:………………………………………………………………………………………………………………………………………………………….
(b) What happens when – (i)Phenol reacts with bromine water
(ii)Phenol treated with concentrated HNO3 (iii)Phenol is treated with zinc dust
Ans:…………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………..
………………………………………………………………………………………………………………………………………….…………………
…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………..
TIME: 40 MIN WORK SHEET NO:3 (ETHERS)
MCQ
1. Which of the following cannot be made by using Williamson Synthesis:
(a) Methoxybenzene (b) Benzyl p-nitrophenyl ether (c) tert. butyl methyl ether (d) Ditert. butyl ether
2. The I.U.P.A.C. name of the ether CH2 = CH-CH2O CH3 is
(a) Alkyl methyl ether (b) 1-Methoxy-2-propene (c) 3-Methoxy-1-propene (d) Vinyl dimethyl ether
3. Dehydration of alcohol to ethers is catalysed by
(a) cone. H2SO4 at 413 K (b) Hot NaOH (c) Hot HBr (d) Hot HNO3
4. What are the products when ethyl isopropyl ether is cleaved with concentrated HI?
a) ethanol and 2-iodo-2-methylpropane b) ethanol and 2-methylpropane
c) iodoethane and isopropyl alcohol d) iodoethane and 2-methylpropane
5. An ether is more volatile than an alcohol having the same molecular formula. What is the reason for
this difference?
a) dipolar character of ethers (b) alcohols having resonance structures
c) inter-molecular hydrogen bonding in ethers (d) inter-molecular hydrogen bonding in alcohols
Assertion- Reason
(i) Both A and R are true and R is the correct explanation of A
(j) Both A and R are true but R is not the correct explanation of A
(k) A is true but R is false
(l) A is false but R is true
6. Assertion : Ethers behave as bases in the presence of mineral acids.

Reason : Due to the presence of lone pairs of electrons on oxygen
Ans:……………………………………………………………………………………………………………………………………
7. Assertion : tert-Butyl methyl ether is not prepared by the reaction of tert-butylbromide with
sodium methoxide
Reason: Sodium methoxide is a strong nucleophile.
Ans:………………………………………………………………………………………………………..
8. Explain the mechanism of following reaction:
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………..……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………...........................................................................................................................................
9. Illustrate the following reactions giving a chemical equation for each :

(i) Williamsons synthesis of an ether (ii) Friedel crafts acylation of Anisole
Ans:…………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………….
10. Write the equation of the reaction of hydrogen iodide with:
(i) 1-propoxypropane (ii) Methoxybenzene and (iii) Benzyl ethyl ether
Ans:…………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………….…………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………………
11. Give reasons:

(i) Diethyl ether does not react with sodium.
(ii) Anisole reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol.
(iii)Boiling point of ether is lower compared to alcohol having same number of carbon atoms.
Ans:…………………………………………………………………………………………………………………………………………………………
………….………………………………………………………………………………………………………………………………………….…………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
Q 12. Ethers can be prepared by Williamson synthesis in which an alkyl halide is reacted with sodium
alkoxide.
Williamson synthesis involves nucleophilic substitution of the halogen atom of an alkoxide group as
shown below: R−O−Na + R′−X ------ → R−O−R′ + NaX
When alkyl halide used in the reaction is primary, Williamson synthesis proceed via SN2 mechanism
leading to the formation of an ether. By this method both symmetrical and unsymmetrical ethers can be
prepared.
1. Why is Williamson synthesis not applicable with tertiary alkyl halides?
2. What happens when benzyl ethyl ether reacts with HI?
3. Name the alkyl halide and sodium alkoxide used to synthesize tert-butyl ethyl ether.
4. What are the products of heating of tert-Butyl Ethyl Ether with HI at 373K
Ans:…………………………………………………………………………………………………………………………………………………………
………….………………………………………………………………………………………………………………………………………………………
…………………….……………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………………………
CLASS:XII CHAPTER: ALDEHYDE, KETONE AND CARBOXYLIC ACIDS
TIME: 40 MIN WORK SHEET NO:1 NAME OF STUDENT:………………………………….. ROLL NO……….
Q1. The oxidation of toluene to benzaldehyde by chromyl chloride is called
(a) Etard reaction (b) Riemer-Tiemann reaction (c) Stephen’s reaction (d) Cannizzaro’s reaction
Q2. Which of the following substances is the least water-soluble?
(a) Methanal (b) Pentanal (c) Propanone (d) Ethanal
Q3. Which of the reactions below can result in ketones?
(a)Oxidation of primary alcohols (b)Oxidation of secondary alcohols
(c) Dehydrogenation of tertiary alcohols (d)Dehydrogenation of primary alcohols
Q4. The IUPAC name of CH3-CH=CH-CHO is:
(a) But-2-enal (b) Ethane (c) But-2-en (d) Buten-2-al
Q5. Which of the following compounds is formed when benzyl alcohol is oxidised with KMnO 4?
(a) CO2 and H2O (b) Benzoic acid (c) Benzaldehyde (d) Benzophenone
Given below are two statements labelled as Assertion (A) and Reason (R). Select the most
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
Q6. A: Strong oxidizing agents oxidises toluene and its derivatives to benzoic acids.
R: It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents.
Ans………………….
Q7. A: The boiling points of aldehydes and ketones are higher than hydrocarbons and ethers of
comparable molecular mass.
R: There is a weak molecular association in aldehydes and ketones arising out of the dipole-
dipole interactions.
Ans…………………….
Q8. Convert the following: (a) Benzene to m-nitrobenzaldehyde (b) Bromobenzene to benzoic acid
Ans………………………………………………………………………………………………………………………………………….
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
Q9. Alkenes (C=C) and carbonyl compounds (C=0) contain a pie bond, but alkenes show
electrophilic addition reactions, whereas carbonyl compounds show nucleophilic addition
reactions. Explain.
Ans. ……………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…................................................................................................................................................
..................................................................................................................................................
Q10. Arrange the following in the increasing order of their property indicated:
(a) Benzoic acid, Phenol, Picric acid, Salicylic acid (pka values).
(b) Acetaldehyde, Acetone, Methyl tert. butyl ketone (reactivity towards NH2OH).
(c) ethanol, ethanoic acid, benzoic acid (boiling point)
Ans. ……………………………………………………………………………………………………………………………………….
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………..
Q11. Write the equations involved in the following reactions:
(i) Rosenmund reduction. (ii) Gatterman – Koch reaction (iii) Stephen
Ans.............................................................................................................................................
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………..
Q12.(a) How will you bring about the following conversions:
(i) Ethanol to 3-hydroxybutanal (ii) Benzaldehyde to Benzophenone
(b) An alkene ‘A’ (Mol. formula C5H10) on ozonolysis gives a mixture of two compounds ‘B’ and
‘C’. Compound ‘B’ gives positive Fehling’s test and also forms iodoform on treatment with I 2 and
NaOH. Compound ‘C’ does not give Fehling’s test but forms iodoform. Identify the compounds
A, B and C. Write the reaction for ozonolysis and formation of iodoform from B and C.
Ans.............................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...............................
Q13. Write the structures of products of the following reactions;
TIME: 40 MIN WORK SHEET NO:2
Q1. A + B dil NaOH C6H5-CH=CH-CO-C6H5 Identify A and B:
(a) A = 1-phenylethanal, B = acetophenone (b) A = Benzophenone B = formaldehyde
(c) A = Benzaldehyde, B = acetophenone (d) A = Benzophenone,B = acetophenone
Q2. What is the IUPAC name of the ketone A, which undergoes iodoform reaction to give
CH3CH=C(CH3)COONa and yellow precipitate of CHI3?
(a) 3-Methylpent-3-en-2-one (b) 3-Methylbur-2-en-one
(c) 2,3-dimethylethanone (d) 3-Methylpent-4-one
Q3. Which of the following tests/ reactions is given by aldehydes as well as ketones?
(a) Fehling’s test (b) Tollen’s test (c) 2,4 DNP test (d) Cannizzaro reaction
Q4. Formic acid and acetic acid are distinguished by
(a) NaHCO3 (b) FeCl3 (c) Victor Mayer test (d) Tollen's reagent
Q5. The product of hydrolysis of ozonide of 1-butene are
(a) ethanol only (b) ethanal and methanal (c) propanal and methanol (d) methanal only
Q6. A: Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction.
R: Aromatic aldehydes are almost as reactive as formaldehyde.
Ans. ……………………..
Q7. A: The α-hydrogen atom in carbonyl compounds is less acidic.
R: The anion formed after the loss of α-hydrogen atom is resonance stabilised.
Ans……………………..
Q8. Give reasons to support the answer:
(a) Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.
(b) Aldehydes are more reactive than Ketones towards nucleophilic additions.
Ans………………………………………………………………………………………………………………………………………..
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
………………………..
Q9. (a) Out of p-tolualdehyde and p-nitrobenzaldehyde ,which one is more reactive towards
nucleophilic addition reactions, why?
(b) Write the structure of the product formed when acetone reacts with 2,4 DNP reagent.
Ans………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
………………..
Q10. Give chemical tests to distinguish between the following pairs of compounds :
(i) Acetophenone and Benzophenone (ii) Pentan-2-one and Pentan-3-one (iii) Benzaldehyde and
Acetophenone
Ans………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………….
Q11. You are given four organic compounds “A”, “B” , “C” and “D”. The compounds “A”, “B” and
“C” form an orange- red precipitate with 2,4 DNP reagent. Compounds “A” and “B” reduce
Tollen’s reagent while compounds “C” and “D” do not. Both “B” and “C” give a yellow
precipitate when heated with iodine in the presence of NaOH. Compound “D” gives brisk
effervescence with sodium bicarbonate solution. Identify “A”, “B”, “C” and “D” given the
number of carbon atoms in three of these carbon compounds is three while one has two carbon
atoms. Give an explanation for y our answer.
Ans……………………………………………………………………………………………………………………………………………..
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………….
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………….
Q12. When liquid ′A′ is treated with a freshly prepared ammonical silver nitrate solution, it gives
a bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium
hydrogen sulphite. Liquid ′B′ also forms a white crystalline solid with sodium hydrogen sulphite,
but it does not give a test with ammoniacal silver nitrate. Which of the two liquids is aldehyde?
Write the chemical equations of these reactions also.
(a) Identify (A) and (B). (b) Write the reaction of (A) and (B) with NaHSO3.
(c) Write the reaction of A with ammoniacal silver nitrate.
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………
TIME: 40 MIN WORK SHEET NO:3 NAME OF STUDENT:…………………………….. ROLL NO……….
Q1. Heating a mixture of sodium benzoate and soda lime gives
(a) calcium benzoate (b) benzene (c) sodium benzoate (d) methane
Q2. Benzoic acid reacts with conc.HNO3 and conc.H2SO4 to give
(a) o-nitrobenzoic acid (b) p-nitrobenzoic acid (c) m-nitrobenzoic acid (d) o,p-dinitrobenzoic acid
Q3. Benzoic acid gives benzene on heating with X and phenol gives benzene on heating with Y. X
and Y are respectively
(a) Sodalime and copper (b) Zn dust and NaOH (c) Cu and sodalime (d) Sodalime and Zn dust
Q4. Which is the most suitable reagent for the following conversion?
(a) Tollen’s reagent (b) Benzoyl peroxide (c) I2 and NaOH solution (d) Sn and NaOH solution
Q5. HCHO and HCOOH are dintingished by treating with:
(a) Tollens reagent (b) NaHCO3 (c) Fehling’s solution (d) Benedict soluton
Q6. A: Compounds containing —CHO group are easily oxidised to corresponding carboxylic acids.
R: Carboxylic acids can be reduced to alcohols by treatment with LiAlH 4.
Ans……………………….
Q7. A: Benzoic acid does not undergo Friedel-craft’s reaction.
R: The carboxylic group is activating and undergo electrophilic substitution reaction.
Ans……………………………
Q8. Give chemical tests to distinguish between the following pairs of compounds :
(i) Phenol and Benzoic acid (ii) Benzoic acid and Ethyl benzoate
Ans……………………………………………………………………………………………………………………………………………..
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
Q9. Arrange the following compounds in increasing order of their acid strength:
(i) F – CH2COOH, O2N – CH2COOH, CH3COOH, HCOOH
(ii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid
Ans……………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………….
Q10. Explain:
(a) Write the equations when Salicylic acid is treated with acetic anhydride in the presence of
conc. H2SO4
(b) what happens when Sodium benzoate is heated with soda lime?
(c) Why carboxylic acid does not give reactions of carbonyl group.
Ans………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………….
Q11. Carry out the following conversions : (i) Benzoic acid to aniline
(ii) Benzoic acid to benzaldehyde (iii) Ethyl benzene to Benzoic acid
Ans....................................................................................................................................................
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………………………………...
Q12. An organic compound (A) with molecular formula C 2Cl3O2H is obtained when (B) reacts
with Red P and Cl2. The organic compound (B) can be obtained on the reaction of methyl
magnesium chloride with dry ice followed by acid hydrolysis. (i) Identify A and B
(ii) Write down the reaction for the formation of A from B. What is this reaction called?
(iii) Give any one method by which organic compound B can be prepared from its corresponding
acid chloride. (iv) Which will be the more acidic compound (A) or (B)? Why?
(v) Write down the reaction to prepare methane from the compound (B).
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
KENDRIYA VIDYALAYA AHEMDABAD REGION
CLASS-XII CHAPTER-AMINE WORKSHEET-01
1 Aniline on treatment with excess of bromine water gives
(A)Aniline bromide (B)o-bromoaniline (C)p-bromoaniline (D)2, 4, 6-tribromoaniline
2 Primary amines can be distinguished from secondary and tertiary amines by reacting with
(A)Chloroform and alcoholic KOH (B)Methyl iodide (C)Chloroform alone (D)Zinc dust
3 KCN reacts readily to give a cyanide with

(A)Ethyl alcohol (B)Ethyl bromide (C)Bromobenzene (D)Chlorobenzene
4 Nitration of aniline also gives m-nitro aniline, in strong acidic medium because
(A)In electrophilic substitution reaction amino group is meta directive
(B)In spite of substituents nitro group always goes to m- position
(C)In strong acidic medium, nitration of aniline is a nucleophic substitution reaction
(D)In strong acidic medium aniline present as anilinium ion
5 Amine are Lewis base due to

(A)Higher electronegativity (B)Unavailability of d subshell
(C)Presence of lone pair (D)Smaller Size
4 The correct order of increasing basicity in aqueous medium is -

NH3 CH3 – CH2 – NH2 (CH3 – CH2)2 – NH ( CH3 –CH2)3-N
I II III IV
(a) II < I < IV < III (b) II < I < III < IV (c) I < II < IV < III (d) I > II > IV >III
Reduction of methyl isocyanide gives

(A)Ethylamine (B)Methylamine (C)Dimethylamine (D)Trimethylamine
(A) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(B) Assertion and Reason both are correct statements but Reason is not correct explanation for Assertion.
(C) Assertion is correct statement but Reason is wrong statement.
(D) Assertion is wrong statement but Reason is correct statement.
6 Assertion: In order to convert R-Cl to pure R-NH2, Gabriel pthalimide synthesis can be used.
Reason: -With proper choice of alkyl halide, pthalimide synthesis can be used to prepare10,20 or 30
amines.
7 Assertion: In Hoffmann bromide reaction, the amine formed has one carbon atom less than the parent 1 0 amide
Reason:-N-methyl acetamide undergoes Hoffmann bromide reaction.
8 Aniline does not undergo Friedel Craft’s reaction. Why?

Answer:-
………………………………………………………………………………………………………………
……………………………………………………………………………………………………………..
9 Complete the reaction
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
10 Explain the following (a)Diazotisation (b)Carbylamine reaction (c)Gabriel Phthalimide synthesis
Answer
11 Assign reason for the following :

(i) Amines are less acidic than alcohols of comparable molecular masses.
(ii) Aliphatic amines are stronger bases than aromatic amines.
(iii) Aliphatic amines are stronger bases than aromatic amines.
Answer
12 How will you bring about the following conversion:

Nitrobenzene to phenol
Aniline to chlorobenzene
Aniline to benzonitrile
Answer:-
13 How will you bring about the following conversion:
(i)Nitrobenzene to phenol (ii)Aniline to chlorobenzene (iii)Aniline to benzonitrile.
14 Write the structures of A, B and C in the following :
Answer
15 An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound’ which
on heating with Brand KOH forms a compound ‘C’ of molecular formula C6H7N.Write the structures
and IUPAC names of compounds A, B and C.
Answer
KENDRIYA VIDYALAYA AHEMDABAD REGION
CLASS-XII CHAPTER-AMINE WORKSHEET-02
1 Which of the following is 1o amine
(A)Ethylene diamine (B)Dimethyl amine (C)Trimethyl amine (D)N-methyl aniline
2 C3H9N represents
(A)Primary amine (B)Secondary amine (C)Tertiary amine (D)All of these
3 Which one of the following is the strongest bae in aqueous solution?

(A)Methyl amine (B)Trimethyl amine (C)Aniline (D)Dimethyl amine
4
Which order of basicity is correct?
(A)Aniline>m-toluidine>o-toluidine (B) Aniline>o-toluidine >m-toluidine
(C) o-toluidine< Aniline>m-toluidine (D) o-toluidine >Aniline>m-toluidine
5 What is the decreasing order of basicity of aqueous primary, secondary and tertiary ethylamine and NH3?
(A)NH3 >C2H5NH2>(C2H5)2NH >(C2H5)3N (B) (C2H5)3N >C2H5NH2>(C2H5)2NH > NH3
(C) (C2H5)2NH >C2H5NH2>(C2H5)3N> NH3 (D) (C2H5)2NH >(C2H5)3N >C2H5NH2 > NH3
(A) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(B) Assertion and Reason both are correct statements but Reason is not correct explanation for Assertion.
(C) Assertion is correct statement but Reason is wrong statement.
(D) Assertion is wrong statement but Reason is correct statement.
6 Assertion: Order of basicity of amines in gaseous phase is NH3> primary amine > secondary amine >
tertiary amine.
Reason: In gaseous phase, the basic nature of aliphatic amine increases with the increase in number of
alkyl groups.
7 Assertion: Aliphatic amines are weaker bases than ammonia and aromatic amines are stronger bases
than ammonia.
Reason: +I- effect of alkyl groups on aliphatic amines increase the electron density on nitrogen atom.
Aromatic amines are weaker due to electron withdrawing nature of the aryl group
8 Illustrate the following reactions giving a chemical equation in each case

(i) Ammonolysis (ii) Hofmann’s bromamide reaction.
9 Give IUPAC names of the following compounds :
10 Account for the following observations(any two)

(i) pKb for aniline is more than that for methylamine.
(ii) Methylamine solution in water reacts with ferric chloride solution to give a precipitate of ferric
hydroxide.
(iii) Aniline does not undergo Friedel-Craft’s reaction.
11 An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound’ which on
heating with Br and KOH forms a compound ‘C’ of molecular formula C6H7N.Write the structures and
IUPAC names of compounds A, B and C.
12 Give one chemical test each to distinguish between the following pairs of compounds :
(i) Ethylamine and aniline
(ii) Aniline and N-methylaniline
(iii)Methyl Amine and Dimethyl amine
13 Complete the reaction

14 Write the structures of main products when benzene diazonium chloride (C6H5N2+Cl-) reacts with the
following reagents: (a) HBF4 (b) Cu/HBr
15 An aromatic compound ‘A’ of molecular formula C7H7ON undergoes a series of reactions as shown
below. Write the structures of A, B, C, D and E in the following reactions :
Answer
15 Illustrate the following reactions giving a chemical equation in each case

(i) Gatterman reaction
(ii) Sandmeyer reaction
(B) Describe a chemical test each to distinguish between the following :
(i) Ethylamine and aniline
(ii) Methylamine and dimethylamine
(iii) Aniline and N-methylaniline
Answer:-
WORK SHEET_01_CHEMISTRY THEORY_ CHAPTER-BIOMOLECULES_(2023 -24)
General Instructions: Read the following instructions carefully.
(a) There are 10 questions in this question paper.
(b) Question 1 to 5 are multiple -choice questions carrying 1 mark each.
(c) Question 6 and 7 are short answer questions carrying 2 marks each.
(d) Question 8 and 9 are short answer questions carrying 3 marks each.
(e) Question10 is a long answer question carrying 5 marks.
(g) All questions are compulsory.
--------------------------------------------------------------------------------------------------------------------------------------
Q.1 In nucleic acids, the sequence is: Fill Correct Option
a) Base - sugar - phosphate b) Base - phosphate - sugar
c) Phosphate - sugar - base d) Sugar - base – phosphate ( )
Q.2 Enzymes are regarded as ______
a) biocatalysts b) messengers c) inhibitors d) antibodies ( )
Q.3 Which of the following amino acids is optically inactive?
a) Glycine b) Alanine c) Lysine d) Valine ( )
Q.4 Proteins are polymers of ______
a) α-amino acids b) β-amino acids c) γ-amino acids d) δ-amino acids ( )
Q.5 The compound is a component of which of the following? ( )
a) RNA b) DNA
c) Adenine
d) Guanine
--------------------------------------------------------------------------------------------------------------------------------------
Q.6 What happens when D-glucose is treated with. the following reagents?
(i)HI (ii) Bromine water
Ans: (i)_____________________________________________________________________________
__________________________________________________________________________________
(ii)_____________________________________________________________________________
__________________________________________________________________________________
Q.7 Differentiate between α- helical and β- pleated sheet structure of secondary protein?
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
____________________________________________________________________________________
Q.8 Differentiate between following
(i) Globular protein and Fibrous protein
(ii) Nucleotide and Nucleoside
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
Q.9 What information do we get when D-glucose reacts with following reagent, write the reaction also
(a)Hydroxylamine (iii)acetic anhydride (iii) nitric acid
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
____________________________________________________________________________________
Q.10 (a)Explain the cyclic structure of Glucose?

(b) Explain and show that how Nucleotides are joined together in DNA molecule?
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
___________________________________________________________________________________
WORK SHEET_02_CHEMISTRY THEORY_ CHAPTER-BIOMOLECULES_(2023 -24)
General Instructions: Read the following instructions carefully.
(a) There are 10 questions in this question paper.
(b) Question 1 to 5 are multiple -choice questions carrying 1 mark each.
(c) Question 6 and 7 are short answer questions carrying 2 marks each.
(d) Question 8 and 9 are short answer questions carrying 3 marks each.
(e) Question10 is a long answer question carrying 5 marks.
(g) All questions are compulsory.
------------------------------------------------------------------------------------------------------------------------------------------
Fill Correct Option
Q.1 Two monosaccharides are joined through a ______ bond to form a disaccharide. ( )
a) ionic b) peptide c) glycosidic d) phosphodiester
Q.2 Which of the following statement is not true for glucose?
a) The pentaacetate of glucose does not react with hydroxylamine to give oxime ( )
b) Glucose gives Schiff's test for aldehyde
c) Glucose exists in two crystalline α and β forms
d) Glucose reacts with hydroxylamine to form oxime
Q.3 Nucleotides are joined together by ( )
a) peptide linkage b) disulphide linkage c) glycosidic linkage d) phosphodiester linkage
Q.4 Sucrose consists of which of the following monosaccharide units? ( )
a) Fructose, galactose b) Fructose, glucose c) Galactose, glucose d) Glucose, glucose
Q.5 Identify the saccharide from the Haworth projection shown below. ( )
a) Lactose
b) Maltose
c) Sucrose
d) Trehalose
------------------------------------------------------------------------------------------------------------------------------------
-----
Q.6 What are the hydrolysis products of (i) Maltose and (ii)lactose
Ans: (i)_______________________________________________________________________________
(ii)_______________________________________________________________________________
Q.7 Write the important two structural differences between DNA and RNA?
Ans:_________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
Q.8 (a)Explain the formation of peptide linkage in protein?
(b)What are the two types of protein on the basis of molecular shape?
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
Q.9 (a)What are reducing and non-reducing sugar? Give one example of each?
(b)What are anomers?
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
Q.10 (a) What is Zwitter ion? How is it formed?

(b) Explain Cyclic structure of Fructose?
Ans:_________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_____________________________________________________________________________________
_

Chemistry

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chemistry

Uploaded by

Copyright:

Available Formats

KENDRIYA VIDYALAYA SANGATHAN

WORKSHEETS FOR CLASS XII

Mrs. Shruti Bhargava

Mr. Anil Sharma PGT- Chemistry K. V. Rajkot Electrochemistry

Mr. Bharat Pandya PGT- Chemistry K. V. 3 Surat Chemical Kinetics

Mr. Mukesh Solanki PGT- Chemistry K. V. Rajkot d- and f-block Elements

Mrs. Archana Singh PGT-Chemistry K. V. 2 Army Baroda Coordination compounds

Mr. Atul Tiwari PGT-Chemistry K. V. 2 Army Baroda Haloalkane and Haloarene

Mrs. Anju Bala PGT-Chemistry K. V. 1 Ahmedabad Alcohol Phenol and ether

Dr. Sangeeta Lamba PGT-Chemistry K. V. Himmatnagar Aldehyde ketone and

MR S K Soni PGT-Chemistry K. V. Ahmedabad Cantt Biomolecules

EDITED AND COMPILED BY

Mr. Anil Sharma PGT- Chemistry K. V. Rajkot

d- and f-block Elements 2

Haloalkane and Haloarene 2

Alcohol Phenol and ether 3

Aldehyde ketone and carboxylic acid 3

Q.1 Increasing the temperature of an aqueous solution will cause:

Answer the questions in short

Answer the questions in short

Q.1 Which of the statements about solutions of electrolytes is not correct?

Q.6 Assertion: For measuring resistance of an ionic solution an AC source is used.

Q.7 Assertion: Conductivity of all electrolytes decreases on dilution.

Answer the questions in short

Q.2 Write two advantages of fuel cell.

Q.9 Predict the products of electrolysis in each of the following:

5 The hypothetical reaction, A2+B22AB, follows the following mechanism:

(a) What is the activation energy of the reaction?

(a) What is the order of the reaction

(a) Predict the order of reaction.

Ans: (i) ….. (ii) …… (iii) ….. (iv) ….. (v)……..

Q.2 Transition elements form alloys easily because they have

Answer the questions in short

Q.3 Give reason:

Q.4 The Elements of 3d transition series are given as:

Ans: (a) (b) (c)

Q.5 Give reason:

Q.3 What is the percentage of lanthanoid metal in mischmetal?

Answer the questions in short

Q.05 Give reason

Q.1 Which of the following species is not expected to be a ligand

Q.3 The compounds [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 represent

Q.7 Assertion: low spin tetrahedral complexes are rarely observed

Answer the questions in short

Q.3 Write the structural formulae of the following compoundsl:

Q.1 Which of the following complexes are hetroleptic

Q.4 Wilkinson’s catalyst, [(Ph3P)3RhCl] is used for

Answer the questions in short

SHORT ANSTER TYPE OF QUESTIONS

Q.9 Write given Naming reactions :

Q.10 Explain why:

while AgCN forms isocyanides as the chief product. Explain.

Q.11 a. Which one undergoes substitution reaction faster and why?

b. which one undergoes SN1 reaction faster and why?

(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane

(ii) C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5 )Br

(A) a, b, c, d (B) b, c (C) a, d (D) a, b, c

(i) Wurtz Reaction (ii) Fitting Reaction

(b) Friedel craft alkylation of chlorobenzene with propyl chloride

9. Give Reasons for the following:

(ii) (±) 2–Butanol is optically inactive.

11. How will you bring about the following conversions?

(ii) Toluene to benzyl alcohol