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B 0 nA fA nA (fA)
C 0 nAo fA nAo (fA)
n A
Total nAo o
A fA n o
(1 + fA)
1.2
Express the mole fraction of each species in terms of fA.
(Moles of A) n oA (1 f A) (1 f A)
XA o (6)
(Total Moles) n A (1 f A ) (1 f A )
fA
XB (7)
1 fA
fA
XC (8)
1 f
A
Substitute equations (6), (7), and (8) into equation (2), above, and solve for fractional
conversion (fA).
f A2
K Ptot (9)
(1 f A )(1 f A )
Exercise 2:
H2 H
C C
H3C CH3 + 1/2 O2 H3C CH2 + H2O
1.3
Exercise 3:
1-butene (A)
H
H2C C
H2C CH 3
k3 k1
k-3 k-1
CH3 k2
H H H
C CH C C
H3C H3C CH 3
Part a)
Express the equilibrium constants for each step in terms of partial pressures.
P
K a1 K P1 B (1)
PA
PC
K a 2 K P2 (2)
PB
PA PA PB
K K (3)
a3 P3
PC PB PC
Therefore, K3 = 0.108.
Part b)
1.4
0 1 1 0 A
0 0 1 1 B And Det(Matrix) (1 1) (11) 0
Therefore, all equations are not independent (i.e. only need 2 equations to solve).
Assuming a basis of 1 mole of 1-butene, write a mole balance for the system.
PC 3
K (7)
1
a3
PB
Solving for ξ1 and ξ3 gives an equilibrium conversion of 1-butene = 0.932.
X1-butene = 0.068
Xcis-2-butene = 0.296
Xtrans-2-butene = 0.636
Exercise 4:
First, find K for each reaction from DGo, using equation (1), assuming ideal behavior.
G 0
ln(K ) (1)
R g T
De Marseille à Ajaccio 5
Lui ! 19
Dimanche corse 32
Les Quais 38
Les Pélerinages 45
Fleurs d’exil 52
Les Voceri 59
Le seize août en Ajaccio 67
Sous les Châtaigniers 81
Le Village 95
Quelques Bandits 107
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