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International Conference on Chemical, Biological and Environment Sciences (ICCEBS'2011) Bangkok Dec.

, 2011

A Preliminary Study on Batik Effluent in


Kelantan State: A Water Quality Perspective
Noor Syuhadah Subki and Rohasliney, H.

Abstract— Batik industries generate a huge contribution to Obviously, textile industries consume large amount of
Malaysia’s economy development. However, batik industries also water and chemicals during their wet processing. The
produce large amounts of effluents with a high concentration of chemicals reagent used in textile sector are diverse in
pollutants which required extensive treatment before discharging into
the environment. The Kelantan Department of Environment (DOE),
chemicals composition ranging from inorganic to organic.
in this study, has found that the batik industry in the state has the Generally, textile effluent is colored with high pH,
lowest level of compliance with the department’s law and temperature, biological oxygen demand (BOD), chemical
regulations. Its director, Khairuddin Mohamad Idris said the study oxygen demand (COD), total dissolve solid (TDS) and total
revealed that between January and September 2010, the batik suspended solid (TSS) [5, 9, 7]. Color is imparted to textile
industry in Kelantan only recorded a five per cent level of effluents because of the various dyes and pigments used to
compliance compares to other manufacturing industries. Therefore a
study was carried out within five batik factories in Kota Bharu,
color the fabric. Wastewaters from the batik building mostly
Kelantan as a preliminary study aiming to describe the batik effluent discharged after minimal or no pretreatment into the adjoining
from factories selected. In this study, the physical parameter such as water channels, streams and estuaries. The presence of dyes in
pH, dissolve oxygen (DO), total dissolve solid (TDS), chemical the wastewaters will cause severe damage to the aquatic
oxygen demand (COD) and salinity were measured. This study biology. This is because dyes have a synthetic origin and a
showed that the value of COD is between 700 to 4900 mg/L which is complex molecular structure which makes them more stable
higher than the acceptable condition for discharge of industrial
and difficult to be biodegraded [6].
effluent containing COD for textile industry. Correlation analysis
showed that COD was positively correlated with temperature and pH,
and was negatively correlated with DO and TDS. With the increase Some parameters of the textile (including batik) must
demand of batik products, the effluent with high COD value will also comply with the Environmental Quality Act (1974)
increase and making it one of the main sources of severe pollution in regulations for Industrial Effluent 2009 (1974) [1]. The
Malaysia. Therefore, awareness education of batik effluent pollution Kelantan Department of Environment (DOE), indicated that
to the batik industry entrepreneurs is very crucial, especially on the
the batik industry in the Kelantan state has the lowest level of
importance of clean practices in the production of batik.
compliance with the department’s law and regulations. Its
Keywords— batik, COD, effluent. director, Khairuddin Mohamad Idris revealed that between
January and September 2010, the batik industry in Kelantan
I. INTRODUCTION only recorded a five per cent level of compliance compares to
other manufacturing industries [8]. Therefore this research
was aim to determine the physical characteristic of the batik
T HE rapidly growing textile industries in Malaysia
especially the batik industries in the East Cost of
Peninsular Malaysia have contributed positively to the
effluents. The chemical oxygen demand (COD) level also will
be disclosed in this study.
Malaysia’s economic growth. In Kelantan, batik is mostly
produced by small medium enterprises (SME) and also by a II. MATERIALS AND METHODS
small scale industry which is known as cottage industry. SME
normally built its industrial units in many places and some of Five of medium to small batik industrial units had been
them were built alongside of the river. However, the cottage selected as sampling stations (Figure 1) for this study. Water
industry manufacturers prefer to build its industrial unit in samples were collected from the last pond of the effluents
their home backyard. (after dyeing and washing process), before it is being
discharged. The physical parameters such as temperature, pH,
dissolve oxygen (DO) and total dissolve solid (TDS) were
Noor Syuhadah Subki analyzed in situ using YSI Model 556 (Yellow Springs, OH,
School oh Health Sciences, Universiti Sains Malaysia, USA) multiprobe meter while the chemical oxygen demand
16150 Kota Bharu, Kelantan, Malaysia (COD) were analyzed in the laboratory using HACH
e-mail: syuhadah_subki@yahoo.com.
fax: 609-7677515 Spectrophotometer (DR 2800).
Rohasliney, H.
School oh Health Sciences, Universiti Sains Malaysia,
16150 Kota Bharu, Kelantan, Malaysia
e-mail: rohasliney_hashim@yahoo.com.

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International Conference on Chemical, Biological and Environment Sciences (ICCEBS'2011) Bangkok Dec., 2011

the chemical and biological system of the water. Meanwhile,


the impact of organic pollutant on the waste water is
expressed in COD which all depends on the DO value [3].

TDS is also used to define the organic content of the water


and the total ions in solution respectively [10]. The value of
TDS and DO are depending on the various chemicals and
reagent that have been used in the batik making process.
Therefore, the value obtained from the both parameters will
affect COD value in the batik wastewater.

TABLE I
DATA OF PHYSICAL PARAMETER
Para Units EQA Factory Factory Factory Factory Factory
meter (1974) A B C D E
Temp °C 40 32.43 30.29 28.15 26.94 29.21
pH - 5.5–9.0 7.92 8.29 8.88 7.65 9.52
TDS mg/L 3000 5.91 4.11 3.16 9.33 3.22
DO mg/L * 1.77 2.23 2.1 2.05 2.01
COD mg/L 250 1473.33 1422.67 772.67 945.00 4944.00
* Not stated in Environmental Quality Act (Industrial Effluent Regulations,
2009)

The discussion above shows that the value of COD is


influenced by the value of temperature, pH, TDS and DO of
the batik effluent. The measurement of oxygen demand is an
= sampling station
easy way to detect the degree of pollution by organic matter.
Fig.1 represents sampling station used in the study The discharge of the effluents with high COD value to the
receiving stream or drainage can lead to the depletion of
dissolve oxygen and thus creates anaerobic condition [4].
III. RESULTS AND DISCUSSION Under anaerobic condition foul smelling compound such as
hydrogen sulfides may be produced. This will consequently
Data obtained was analyzed and compared with the distress the biological activity especially in the receiving
industrial effluents standard in Environmental Quality Act stream.
1974 (Table 1). The effluent showed that temperature average
value for the five batik factories was 29.40°C, average pH was IV. CONCLUSION
8.45, average TDS was 5.15 mg/L, average DO was 2.03
mg/L, average salinity was 4.49 mg/L and average for COD In batik making process, the effluents are often rich in color
was 1911.53 mg/L. From the six parameters that have been and organic pollutants which require a proper treatment before
analyzed, the average value of temperature, pH and TDS were discharging into the environment. It is known that high
within the standard limit while the average value of COD was demand of batik products will contribute in the production of
higher than the standard limit. more effluent with high COD value and creating it as one of
the main sources of severe pollution in Malaysia. This
Correlation analysis was carried out between COD and preliminary finding should be a starting point to find an
other parameter. The correlation analysis showed that COD intriguing application for the treatment of liquid effluents in
was positively correlated with temperature and pH, and was local industries such as batik industry. Therefore, awareness
negatively correlated with DO and TDS. The temperature of education of batik effluent pollution to the batik industry
the batik wastewater is acceptable since it is under the entrepreneurs and manufacturers is essential especially
standard limit. High temperature will reduce the solubility of emphasized on the importance of clean practices in the
gases in water that ultimately express as high COD. While production of batik. We hope someday, Kelantan will produce
extremely low temperature will affects adversely the what we called a ‘green batik’.
efficiency of sedimentation in the effluent [2]. The pH value
of the effluents has a direct affect on organisms and indirect ACKNOWLEDGMENT
effect on the toxicity of certain pollutants in the water. At
either very high or very low pH, the water cannot support Special appreciation to the Environmental And
most of the organisms. Therefore pH is an important factor in Occupational Health Laboratory of School of Health Sciences,
USM Health Campus and Postgraduate Laboratory of Faculty

275
International Conference on Chemical, Biological and Environment Sciences (ICCEBS'2011) Bangkok Dec., 2011

of Agro Industry and Natural Resources, Universiti Malaysia


Kelantan for providing equipment used in this research.
Special gratitude to the five batik entrepreneur for information
and for their co-operation and permission during data
collection. Cordial appreciation also goes to all staff from
research offices of School of Health Sciences.

REFERENCE

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[8] Jabatan Alam Sekitar Negeri Kelantan (2009). Laporan Tahunan Jabatan
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