PINNAACLE CLASSES

46. Ans. 7
Sol. wt. of KOH in mixture = 2.80
wt. of Ca(OH)2 in mixture = 3.33
2. 8 3 . 33×2
+
So 56 74 = V × 10–3 × 20
 0.14 = V × 2 × 10–2
14
V= 2 mL = 7 ml

47. Ans. 6
Sol. Zn2+ + H2O Zn(OH)+ + H+
c (1 – ) c c
cα2
KH = 10–9 = (1−α )
Considering  <<1
 = √ 10 = 10–3
−6

 [H+] = c = 10–6 or pH = 6

48. 6 JEE Main 2020

9.8 −3
MH S O4 ⇒=10
2
98× 100
4 −3
M NaOH ⇒ =10
40 ×100
−3 −3
40 ×10 −10 ×10 ×2 20 −3
¿ = × 10
50 50
¿
2 −3
pOH = ×10
5
pOH =3.397
pH=10.603
49. 141 JEE Main 2021
−9
K SP ( PbI 2) =8 ×10
+2 −¿ ( aq ) ¿
PbI 2 ( s ) ⇌ Pb ( aq )+2 I
S+0.1 2S
K SP =[ Pb+2 ] ¿ ¿
−9 2 −9 2
8 ×10 =( S+ 0.1 )( 2 S ) ⇒ 8 ×10 ≃ 0.1 × 4 S
2 −8
⇒ S =2× 10
S=1.414 ×10 mol/Lit
−4

¿ x × 10 mol/Lit ∴ x=141.4 ≃ 141

−6

50. 7 JEE Main 2021

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 PINNAACLE CLASSES
3 −¿¿
+¿+P O 4 ¿
( N H 4 ) 3 P O4 ⇌ 3 NH 4
¿
1
pH= p k a+
2
{ p k w − p k a −p k b }
1
pH=5.23+ {14−5.23−4.75 }
2
1
pH=5.23+ ( 4.02 )=7.24 (Nearest Integer)
2

Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371