This document discusses civil engineering materials, focusing on metals defects including corrosion, fatigue, and fracture. It provides details on the electrochemical process of corrosion, how it affects different metals like steel and aluminum, and metals that are more corrosion resistant. Fatigue is described as being caused by fluctuating stresses over many cycles, and factors that influence it like stress concentration and temperature. Fracture is the separation of a solid into parts, and can occur through different loading types or environments in either a brittle or ductile manner depending on the material's plasticity.
This document discusses civil engineering materials, focusing on metals defects including corrosion, fatigue, and fracture. It provides details on the electrochemical process of corrosion, how it affects different metals like steel and aluminum, and metals that are more corrosion resistant. Fatigue is described as being caused by fluctuating stresses over many cycles, and factors that influence it like stress concentration and temperature. Fracture is the separation of a solid into parts, and can occur through different loading types or environments in either a brittle or ductile manner depending on the material's plasticity.
This document discusses civil engineering materials, focusing on metals defects including corrosion, fatigue, and fracture. It provides details on the electrochemical process of corrosion, how it affects different metals like steel and aluminum, and metals that are more corrosion resistant. Fatigue is described as being caused by fluctuating stresses over many cycles, and factors that influence it like stress concentration and temperature. Fracture is the separation of a solid into parts, and can occur through different loading types or environments in either a brittle or ductile manner depending on the material's plasticity.
Metals defects- Corrosion ➢Electrochemical process ➢Requires the following four elements ▪ Anode— electrode where corrosion occurs. ▪ Cathode—electrode needed to form a corrosion cell. ▪ Conductor—metallic pathway for electrons to flow. ▪ Electrolyte— liquid that can support flow of electrons.
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Metals defects- Corrosion ➢Changes the appearance of metal ➢Break down; becomes weaker. ➢Damage metallic objects.
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Corrosion- ➢Rusting ▪Corrosion of iron. ▪Chemical reaction between iron, oxygen and water. ▪Chemical name for rust is “hydrated iron oxide”. ▪Salt; the rate of rusting. CE-1005-CIVIL ENGINEERING MATERIALS 7 Metals defects- ➢Do all metals corrode? ▪ Metals behave differently when exposed to environment. ▪Example : Gold
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Corrosion- Steel ➢Transfer is between iron and oxygen; oxidation & reduction. ➢Can cause serious problems. ➢Corrosion of steel structures may result: ▪Lowering weight limits. ▪Costly steel replacement. ▪Collapse of the structure.
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Corrosion- Steel ➢Corrosion of steel structures: ▪ Highway bridges ▪ Gas and liquid transmission pipelines ▪ Waterways and ports ▪ Hazardous materials storage ▪ Airports ▪ Railroads.
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CE-1005-CIVIL ENGINEERING MATERIALS 11 Corrosion - Aluminium ➢Reactive metal; doesn’t corrode ➢Aluminium atoms react with oxygen ▪Thin layer of Aluminium oxide; protects the metal from corrosion.
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Corrosion- Aluminium ➢Oxide film protects from further oxidation. ➢Alloying element alter the corrosion resistance of the Aluminium. ➢Extra protection by painting or “cladding” with a thin coat of a corrosion-resistant alloy.
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Metal That Are Corrosion Resistant or Don’t Rust ➢Not all metals contain iron ➢Corrode or tarnish in other oxidizing reactions. ➢Choose metals;“rust-proof” or “corrosion-proof.” ▪Stainless steel ▪Aluminum metal ▪Copper; bronze or brass ▪Galvanized steel
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Metal That Are Corrosion Resistant or Don’t Rust ➢Stainless steel: ▪Some amount of iron; easily oxidizes to form rust. ▪Contain a high percentage of chromium (18%); even more reactive than iron. ▪The chromium oxidizes quickly to form a protective layer of chromium oxide on the metal surface. CE-1005-CIVIL ENGINEERING MATERIALS 15 Metal That Are Corrosion Resistant or Don’t Rust ➢Copper, Bronze and Brass: ▪ Copper oxidizes to form a green patina; protects the metal from further corrosion. ▪ Bronze: Mixture of copper, tin, and small amounts of other elements; much more resistant to corrosion than copper. ▪ Brass: An alloy of copper, zinc, and other elements; also resists corrosion. CE-1005-CIVIL ENGINEERING MATERIALS 16 Metal That Are Corrosion Resistant or Don’t Rust ➢Aluminium metal: ▪ Oxide layer is quite resistant to further corrosion ➢Galvanized Steel: ▪ Takes a long time to rust ▪ Galvanized; coated, with a thin layer of zinc. ▪ Zinc acts as a barrier preventing oxygen and water from reaching the steel. CE-1005-CIVIL ENGINEERING MATERIALS 17 Metal defects- Fatigue
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Metal defects- Fatigue
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Fatigue - Factors ➢Basic factors: ▪Maximum tensile strength ▪Variation or fluctuation in the applied stress. ▪Large numbers cycles of the applied stress.
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Fatigue - Factors ➢Additional factors: ▪ Stress concentration. ▪ Corrosion ▪ Temperature ▪ Overload ▪ Residual stress ▪ Combined stress ▪ Metallurgical structure CE-1005-CIVIL ENGINEERING MATERIALS 21 Fatigue ➢Fatigue process can be divided into the following process: ▪ Crack initiation: Early development of fatigue development. ▪ Removed by a suitable thermal treatment (Annealing) ▪ Slip band crack growth : Deepening of the initial crack on plane of high shear stress CE-1005-CIVIL ENGINEERING MATERIALS 22 Fatigue – Surface effects ➢Sensitive to surface conditions. ➢Fatigue normally starts at the surface ➢Divided into three categories: ▪Surface roughness ▪Change in surface properties. ▪Surface residual stress.
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Fatigue – Effects of metallurgical variables ➢Fatigue property improved by arranging the designs; reducing stress concentration, introducing compressive stress on the surface. ➢Frequently correlated with tensile properties.
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Fatigue – Effects of corrosion ➢Fatigue corrosion occurs when material is subjected to cyclic stress in a corrosive condition.
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Fatigue – Effects of temperature ➢In high temperature fatigue; transition from fatigue failure to creep failure. ➢Coarse grained metal: higher fatigue strength- at high temperature. ➢Fined grained metal: higher fatigue strength at low temperature.
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Metal defects – Fracture ➢Separation of fragmentation of a solid body into two or more parts, under the action of stresses. ➢Occurs in many ways: ▪ Normal loading ▪ Impact Loading ▪ Fatigue ▪ Creep ▪ Environmental effects (cracking, stress corrosion etc.) CE-1005-CIVIL ENGINEERING MATERIALS 27 Fracture – Process ➢Subdivided into the following categories: ▪Damage accumulation. ▪Nucleation of one or more cracks or voids. ▪Growth of cracks of void. (involves a coalescence of the cracks or void)
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Fracture – Fundamentals ➢“Ductile” or “Brittle” depending upon the plastic deformation of the material. ➢Properties which influence the plastic deformation are: ▪Modulus of elasticity ▪Crystal structure
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Fracture – Fundamentals a) Highly ductile fracture. b) Moderately ductile fracture with necking. ◦ Called a cup and cone fracture c) Brittle fracture ◦ No plastic deformation occurring
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Fracture – Brittle fracture ➢Characterized by the rate of crack propagation with the minimum energy of absorption. ➢Adjacent parts separated by stresses normal to the fracture surface. ➢Fracture occurs along crystallographic planes; cleavage fracture. ➢No plastic deformation. CE-1005-CIVIL ENGINEERING MATERIALS 31 Fracture – Ductile fracture ➢Slow propagation of crack; considerable amount of plastic deformation. ➢Three successive events involved in ductile fracture are: ▪Specimen begins necking and minute cavities; formation of cavities is closely linked to plastic deformation.
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Fracture – Ductile fracture ➢ Small micro cracks are formed at the center of the specimen. ➢ Finally these cracks grow out ward ;direction 45 degree to the tensile axis; resulting in a cup-end-con-type fracture.
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Ductile fracture - Stages a) Initial necking. b) Cavity formation c) Cavities form a crack. d) Crack propagation. e) Final shear
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Brittle vs Ductile Ductile material: the crack Brittle material: cracks grows slowly and the grows to a critical size and fracture takes place rapidly. propagates rapidly through the material
Tool-Steel - A Concise Handbook on Tool-Steel in General - Its Treatment in the Operations of Forging, Annealing, Hardening, Tempering and the Appliances Therefor