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MSDS ZAP Grease CENTRAL EP 0 EN-2020-878 2023-08-30
MSDS ZAP Grease CENTRAL EP 0 EN-2020-878 2023-08-30
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PBT, vPvB, SVHC or ED criteria Based on the manufacturer's data, the mixture does not contain any ingredients:
- which meet the PBT or vPvB criteria as laid down in Annex XIII to Regulation (EC) No 1907/2006,
- or which were included in the list established in accordance with Article 59(1) for having endocrine disrupting
..properties,
- or which were identified as having endocrine disrupting properties in accordance with the criteria set out in Commission
..Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605,
at a concentration equal to or greater than 0.1 % by weight.
NOTES:
All mineral oils are considered to be severely refined and not considered to be carcinogenic under IARC. All the oils in this product
contain < 3% DMSO extract (IP 346).
For a full text of H-statements: See SECTION 16.
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Ingestion DO NOT INDUCE VOMITING. Get medical attention. Never give anything by mouth
to an unconscious or convulsing person. If nausea or irritations do not appear after
ingestion, give medical carbon in water slurry (3 tablespoons in one litre water).
4.2. Most important symptoms and effects, both acute and delayed
Prolonged inhalation of unusually high concentrations of product mist or vapours
may cause nose and lung irritation, headache, nausea and drowsiness.
Prolonged or repeated skin contact may produce allergic reactions such as
redness, rash and dermatitis. Prolonged eye contact may cause irritation, redness
and discomfort. If more than several mouthfuls are swallowed, abdominal
discomfort, nausea, and diarrhoea may occur.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Use water fog, dry powder, foam or carbon dioxide. Use water to cool fire-
exposed containers. If the leak or spill has not ignited, use water fog to disperse
the vapours and to provide protection for personnel attempting to stop the leak.
Unsuitable extinguishing media Water jet.
5.2. Special hazards arising from the substance or mixture
Smoke, carbon monoxide, carbon dioxide and other products of incomplete
combustion.
5.3. Advice for firefighters
Special protective equipment The nature of special protective equipment required will depend upon the size of
for firefighters the fire, the degree of confinement of the fire and the natural ventilation
available. Fire-resistant clothing and self-contained breathing apparatus is
recommended for fires in confined spaces and poorly ventilated areas. Full
fireproof clothing is recommended for any large fires involving this product.
Extinguishing procedures In case of fire - Always call the fire brigade. Small fires, such as those capable of
being fought with a hand-held extinguisher, can normally be fought by a person
who has received instruction on the hazards of flammable liquid fires. Fires that
are beyond that stage should only be tackled by people who have received hands-
on training. Ensure escape path’s available.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapour or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation
is inadequate. Put on appropriate personal protective equipment.
For emergency responders If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in “For non-emergency personnel”.
6.2. Environmental precautions Prevent entry into sewers and waterways. Pick up free liquid for recycle and/or
disposal. Residual liquid can be absorbed on inert material.
6.3. Methods and material for containment and cleaning up
Clean-up spill as soon as possible while following the requirements for exposure
control/personal protection. Use sand and sawdust to clean. Use appropriate
cleaning techniques such absorption by fire resistant material or pumping.
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6.4. Reference to other sections See Section 8 for more information on personal protective equipment.
See Section 13 for waste disposal practices.
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Thermal hazards Not applicable.
Hygiene measures When using, do not eat, drink or smoke. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking,
and/or smoking. Routinely wash work clothing to remove contaminants. Discard
contaminated footwear that cannot be cleaned.
Environmental exposure May form an oil film leading to de-oxygenation of water and possible harmful
control effect on aquatic life. Product can penetrate soil until reaching the surface of
ground water (in the presence of ground water).
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Acute toxicity Based on data available for base oils: the classification criteria are not met.
LD50 oral (rats) > 5000 mg/kg (OECD 401)
LD50 dermal (rabbits) > 5000 mg/kg (OECD 402)
LC50 inhalation (rats) > 5 mg/l/4h (OECD 403)
Skin corrosion/irritation Not expected to cause skin corrosion or irritation. Repeated or prolonged contact
with skin may defat or dry the skin resulting in discomfort and dermatitis.
Serious eye damage/irritation Not expected to cause serious eye damage or irritation. May cause eyes irritation.
May cause minimal irritation or redness if accidental eye contact occurs.
Respiratory or skin sensitisation Not expected to be respiratory or skin sensitizer. Prolonged or repeated skin
contact as from clothes wetted with material may cause dermatitis.
Germ cell mutagenicity No data available to indicate product or any components present at levels greater
than 0.1% are mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogenic by IARC, ACGIH, NTP or OSHA.
Nota L – meets EU requirement of less than 3% (w/w) DMSO extract for total
polycyclic aromatic compound using IP 346.
Reproductive toxicity Not expected to damage specific target organs. Based on date for similar
substances.
STOT-single exposure Not expected to damage specific target organs. Based on date for similar
substances.
STOT-repeated exposure Not expected to damage specific target organs. Based on date for similar
substances.
Aspiration hazard The mixture does not meet the criteria for classification.
Other information If material is misted or if vapours are generated from heating, exposure may cause
irritation of mucous membranes and the upper respiratory tract.
11.2 Information on other hazards
Endocrine disrupting properties Based on the manufacturer's data, the mixture does not contain any ingredients:
- which were included in the list established in accordance with Article 59(1) for having endocrine disrupting
..properties,
- or which were identified as having endocrine disrupting properties in accordance with the criteria set out in
..Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605,
at a concentration equal to or greater than 0.1 % by weight.
Other information No data available.
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12.4 Mobility in soil Low, due to low water solubility. Spillage may penetrate the soil causing ground
water contamination.
12.5 Results of PBT and vPvB assessment
This product is not and does not contain any substance that is potential PBT or
vPvB.
12.6 Endocrine disrupting properties
Based on the manufacturer's data, the mixture does not contain any ingredients:
- which were included in the list established in accordance with Article 59(1) for having endocrine disrupting
..properties,
- or which were identified as having endocrine disrupting properties in accordance with the criteria set out in
..Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605,
at a concentration equal to or greater than 0.1 % by weight.
12.7 Other adverse effects May form an oil film leading to deoxygenation of water and possible harmful
effect on aquatic life.
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Regulation (EC) No 1907/2006 of The European Parliament And Of The Council of
18 December 2006 concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH), establishing a European Chemicals Agency,
amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93
and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC
Commission Regulation (EU) 2020/878 of 18 June 2020 amending Annex II to
Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals
(REACH)
Regulation (EC) No 1272/2008 of The European Parliament And Of The Council of
16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
15.2 Chemical safety assessment Not available.
Other information
REACH annexes
Annex XIV Not applicable.
Annex XVII Not applicable.
Regulation 649/2015/EU Not applicable.
Regulation 1005/2009/EC Not applicable.
Regulation 850/2004/EC Not applicable.
Seveso III, Directive 2012/18/EU Not applicable.
Staff working with this product should be trained about the possible risks of
personal protective equipment and first aid. All first aid instructions must be in
accordance with safety, health and environmental regulations. Observe all safety
and hygiene requirements for handling chemicals.
Written first aid instructions must be freely available at the workplace.
Indication of which of the methods of evaluating information referred to in Article 9 of Regulation (EC) No
1272/2008 was used for the purpose of classification.
Classification in accordance Evaluation method used:
with regulation (EC) No
1272/2008:
None. Classification according to calculation procedure.
Revision Information
Version 2.0
Revision date 30.08.2023
Revision No. 1
Revised sections 1 - 16 (full SDS update)
Replaces version 1.0 of 09.08.2021
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List of abbreviations
PBT Persistent, Bioaccumulative, and Toxic
vPvB very Persistent and very Bioaccumulative
ED endocrine disrupting
SVHC Substances of Very High Concern
DMSO Dimethyl sulphoxide
IP 346 London Petroleum Institute standard “Determination of polycyclic aromatics in
unused lubricating base oils and asphaltene free petroleum fractions – Dimethyl
sulphoxide extraction refractive index method.”
LD50 Lethal Dose 50 (median concentration of a toxicant that will kill 50% of the test
animals within a designated period)
LC50 Lethal Concentration 50 (concentration in water having 50% chance of causing
death to aquatic life)
EC50 Half maximal effective concentration
NOEL No-Observed-Effect Level
OECD Organisation for Economic Cooperation and Development
IARC International Agency for Research on Cancer
ACCGIH American Conference of Governmental Industrial Hygienists
NTP National Toxicology Program (USA)
OSHA Occupational Safety and Health Administration (USA)
Log Kow Logarithm (base 10) of the octanol-water partition coefficient
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
RID Regulation concerning the International Carriage of Dangerous Goods by Rail
ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
IMDG International Maritime Dangerous Goods (code)
IATA International Air Transport Association
IMO International Maritime Organization
A list of relevant hazard statements and hazard classes
H315 Causes skin irritation
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Eye Irrit. 2 Eye irritation - Hazard Category 2
Skin Irrit. 2 Skin irritation - Hazard Category 2
Aquatic Chronic 2 Aquatic hazard (long-term) - Hazard Category 2
This information is the best of our current knowledge, and is believed to be correct as of the date hereof, and is intended to describe the
product only in terms of health and safety and environmental requirements. Since the conditions of use are outside our control, any
recommendations and suggestions are made without guarantee.
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