Documento de Maia Tosti

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

R14642A
Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1 Product identifier
Trade name : R14642A

Other means of Identification : 80557
Unique Formula Identifier (UFI) : S536-574S-D008-KDGJ
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Component of lubricant additives
Recommended restrictions on use : This material should not be used for any other
purpose than that recommended without
expert advice.
1.3 Details of the supplier of the safety data sheet
Company : INFINEUM UK LIMITED

P. O. Box 1
Milton Hill
Abingdon
Oxfordshire OX13 6BB United Kingdom
Tel: +44 1235 54 9501
E-mail address for further information SDS@infineum.com
Website for further information http://www.infineum.com
1.4 Emergency telephone number
04-4274.4690 (France) (+33-4.4274.4690)

0221-7499 3355 (Germany) (+49-221-7499 3355)
019-2150 221 (Italy) (+39 019-2150 221)
01235 549777 (UK) (+44 1235 549777)
SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GHS-Classification (REGULATION (EC) No 1272/2008)

Skin irritation: Category 2 H315: Causes skin irritation.
Serious eye damage: Category 1 H318: Causes serious eye damage.
Chronic aquatic toxicity: Category 2 H411: Toxic to aquatic life with long lasting effects.
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2.2 Label elements
GHS-Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :
Signal word : Danger
Hazard statements : H315 Causes skin irritation.

H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : Prevention:

P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/ doctor.
P391 Collect spillage.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Hazardous components which must be listed on the label:

 zinc bis(O,O-diisooctyl) bis(dithiophosphate)
2.3 Other Hazards
Contact with hot material may cause thermal burns
The substance/mixture does not contain components considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
This mixture contains no substance considered to be persistent, bioaccumulating and toxic (PBT)
at >0.1%.
This mixture contains no substance considered to be very persistent and very bioaccumulating (vPvB)
at > 0.1%.
Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may be
released; this can cause rapid respiratory collapse, coma and death without necessarily any warning
odour being sensed.
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SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixtures
Hazardous components
Component EC-No. Concentration Classification

Registration number [%] (REGULATION (EC) No
1272/2008)
zinc bis(O,O-diisooctyl) 249-109-7 >=90 - <=100 Skin Irrit. 2; H315

bis(dithiophosphate) 01-2119953278-28 Eye Dam. 1; H318
Aquatic Chronic 2; H411
Eye Irrit. 2 H319 >= 15 %
Eye Dam. 1 H318 >= 15 %
ATE
Oral LD50 3.760 mg/kg
Dermal LD50 > 5.000 mg/kg
Distillates (petroleum), 265-159-2 >=1 - <10 Asp. Tox. 1; H304

solvent-dewaxed light 01-2119480132-48
paraffinic
For the full text of the H-Statements mentioned in this Section, see Section 16.
All concentrations are weight percent units for liquids or volume percent units for gaseous products.
Other ingredients are either not hazardous or are below the regulatory disclosure limit..
SECTION 4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.
If inhaled : Consult a physician after significant exposure.

If unconscious, place in recovery position and seek medical
advice.
If breathing has stopped, assist ventilation with a mechanical

device. Do not use mouth-to-mouth resuscitation if exposure
to hydrogen sulphide is suspected.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of burns apply cold water until pain subsides then
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seek medical advice.
In case of eye contact : Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists: Get medical advice/ attention.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : corrosive effects

irritant effects
Dermatitis
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Show this safety data sheet to the doctor in attendance.

The first aid procedure should be established in consultation
with the doctor responsible for industrial medicine.
If a person vomits when lying on his back, place him in the
recovery position.
Keep patient warm and at rest.
SECTION 5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing : Use water fog, foam, dry chemical or carbon dioxide (CO2) to
media extinguish flames
Unsuitable extinguishing : High volume water jet

media
5.2 Special hazards arising from the substance or mixture
Combustibility : Not classified as flammable or combustible, but will combust if

ignited.
Hazardous combustion : Hydrogen sulphide, Sulphur oxides and Phosphorus oxides
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products
Zinc oxides
Carbon monoxide, carbon dioxide and unburned

hydrocarbons (smoke).
Flammable properties : See Section 9 for information on flammability.
5.3 Advice for firefighters
Protective equipment and : In the event of fire, wear self-contained breathing apparatus.
precautions for firefighters Exposure to decomposition products may be a hazard to
health.
Fire Fighting Instructions : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
In the event of fire and/or explosion do not breathe fumes.
Fire-fighters should exercise extreme caution in enclosed

spaces due to the possible presence of toxic decomposition
and combustion products. Self-contained full-face
overpressure breathing apparatus should be used in enclosed
spaces. Use standard body protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Advice for emergency responders

Ensure adequate ventilation.
Use personal protective equipment.
Material can create slippery conditions.
For personal protection see section 8.
Advice for non-emergency personnel

Avoid contact with spilled material. Do not touch or walk
through spilled material.
6.2 Environmental precautions
Environmental precautions : Prevent entry into waterways, sewers, basements or

confined areas.
Local authorities should be advised if significant spillages

cannot be contained.
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
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Try to prevent the material from entering drains or water

courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.
See attached ES
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Prevent further leakage or spillage if safe to do so.

Large Spills: Dyke far ahead of liquid spill for later recovery
and disposal.
Recover by pumping or with suitable absorbent
Report spills as required to appropriate authorities.

Seek the advice of a specialist before using dispersants.
Dispose of according to local regulations.
In the event of a spill or accidental release, notify relevant
authorities in accordance with all applicable regulations.
Material will sink to the sediment layer
Remove debris in path of spill prior to oiling and remove
contaminated debris from shoreline and water surface.
Soak up with inert absorbent material (e.g. sand, silica gel,

acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Clean contaminated floors and objects thoroughly while
observing environmental regulations.
6.4 Reference to other sections
Other information : For personal protection see section 8.

See section 13
SECTION 7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes.

For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application area.
Dispose of rinse water in accordance with local and national regulations.
Handle and open container with care.
This product contains a thermally sensitive substance. Do not heat above the maximum
loading/unloading temperature to minimise possible release of toxic hydrogen sulfide.
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This product contains Zinc Dialkyl DithioPhosphate (ZDDP), a thermally sensitive substance.
Do not heat this product except as described below. Do not reheat above the maximum loading
temperature. Higher temperatures can result in exothermic decomposition leading to the release of
highly toxic hydrogen sulphide and extremely odorous alkyl mercaptans. Alkyl mercaptans can be
smelled at extremely low concentrations, and vapours may travel for many miles at detectable
concentrations. These decomposition vapours are also flammable and may suddenly ignite when
mixed with air in the presence of ignition sources such as sparks or flames. With proper facilities, no
heating is required for pumping at ambient temperatures. Lower temperatures may result in some
crystallisation of the product. If extreme cold weather conditions necessitate heating, then tempered
water or oil, not exceeding the maximum loading temperature are recommended. Product
temperature must never exceed the maximum loading temperature. If heated, product temperature
should be constantly monitored, and product should be agitated to avoid localised temperatures in
the container above the maximum loading temperature. Higher temperatures will lead to degradation
of product quality and eventually to decomposition. Product should be stored at the recommended
storage temperature. Extreme caution must be used in tank gauging or similar operations as lethal
concentrations of hydrogen sulphide could accumulate in the head-space of containers.
Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may
be released; this can cause rapid respiratory collapse, coma and death without necessarily any
warning odour being sensed.
If decomposition is suspected, or if the product has been overheated, do not open the container,
discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary
precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as
evacuation of contaminated areas, and use of suitable respiratory protection.
Normal measures for preventive fire protection.
Products may load from Infineum manufacturing site above the standard loading/unloading range.
Loading/unloading : 10 °C (50 ° F) - 60 °C (140 ° F)

temperature
Viscosity @ : 50 cSt - 1.047 cSt

Loading/unloading
temperature
Static accumulator : This material is not a static accumulator.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
No decomposition if stored and applied as directed.
Do not reheat above: 60 °C (140 ° F)
Storage temperature : 10 °C (50 ° F) - 40 °C (104 ° F)
Incompatible materials and : Polyethylene, butyl-rubber, Butadiene Rubber, Styrene
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coatings Rubber
7.3 Specific end use(s)
Specific use(s) : : See attached ES for uses
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Exposure limits for materials that can be formed when handling this product: When mists/aerosols can
occur, the following are recommended: 5mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL
Limits/standards shown for guidance only. Follow applicable regulations.
Recommended monitoring : This product contains ingredients with exposure limits,

procedures personal, workplace atmosphere or biological monitoring may
be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use
respiratory protective equipment.
Reference should be made to European Standard EN 689 for

methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for
methods for the determination of hazardous substances.
DNEL
zinc bis(O,O-diisooctyl) : End Use: Workers
bis(dithiophosphate) Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 6,55 mg/m3
End Use: Workers

Exposure routes: Skin contact
Value: 9,29 mg/kg bw/day
End Use: Consumers

Exposure routes: Inhalation
Value: 1,61 mg/m3
End Use: Consumers

Exposure routes: Skin contact
End Use: Consumers

Exposure routes: Ingestion
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PNEC
zinc bis(O,O-diisooctyl) : Fresh water
bis(dithiophosphate) Value: 0,004 mg/l
Marine water
Value: 0,0046 mg/l
Intermittent use/release
Value: 0,038 mg/l
Sewage treatment plant

Value: 3 mg/l
Fresh water sediment

Value: 0,144 mg/kg dry weight (d.w.)
Marine sediment
Soil
Secondary Poisoning
Value: 8,33 mg/kg food
8.2 Exposure controls
Appropriate engineering : No special requirements under ordinary conditions of use and

controls with adequate ventilation.
If decomposition is suspected, or if the product has been
overheated, do not open the container, discontinue heating
and secure the unit. Initiate emergency procedures, taking all
necessary precautions to avoid exposure to noxious or
flammable gases (e.g. hydrogen sulphide), such as
evacuation of contaminated areas, and use of suitable
respiratory protection.
See attached ES
Personal protective equipment
Respiratory protection : In the case of vapour formation use a respirator with an

approved filter.
The applicable European standard can be found in EN 140,

EN 137, EN 143, EN 14387.
Hand protection
Remarks : Polyvinyl alcohol or nitrile- butyl-rubber gloves Before
removing gloves clean them with soap and water. Please
observe the instructions regarding permeability and
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breakthrough time which are provided by the supplier of the

gloves. Also take into consideration the specific local
conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time. When handling
hot material, use heat resistant gloves.
The selected protective gloves have to satisfy the

specifications of Regulation (EU) 2016/425 and the standard
EN 374 derived from it.
Eye/face protection : Eye wash bottle with pure water

Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Ensure that eyewash stations and safety showers are close to
the workstation location.
The applicable European standard can be found in EN 166.
Skin and body protection : Impervious clothing

Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Long sleeved clothing
The applicable European standard can be found in EN 14605.
Advice on general occupational hygiene
Hygiene measures : When using do not eat or drink.

When using do not smoke.
Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Environmental exposure controls

General advice : Prevent entry into waterways, sewers, basements or confined
areas.
Local authorities should be advised if significant spillages

cannot be contained.
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Try to prevent the material from entering drains or water
courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.
See attached ES
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
Physical state : liquid
Form : viscous
Colour : tan
Odour : hydrocarbon-like
Odour Threshold : not determined
Relative density : not determined
Bulk density : Not applicable
Density : 1,078 g/cm3 at 15 °C (59 ° F)

Method: ASTM D 1298
Flash point : 95 °C (203 ° F)

Method: Pensky-Martens Closed Cup (ASTM D93)
Flammability (solid, gas) : not determined
Flammability (liquids) : not determined
Lower flammability limit : 1,00 %(V)
Upper flammability limit : 5 %(V)
Auto-ignition temperature : 345,1 °C (653,2 ° F)
Initial boiling point and boiling : not determined

range
Vapour density (Air = 1.0) : not determined
Vapour pressure : 0,12 hPa (0,09 mmHg) at 20 °C (68 ° F)
Evaporation rate (N-butyl : negligible

acetate=1)
pH : Not applicable
Partition coefficient: n- : not determined

octanol/water
Water solubility : < 0,0001 g/l
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estimated
Viscosity, kinematic : 13,4 mm2/s at 100 °C (212 ° F)

Method: ASTM D 445
132 mm2/s at 40 °C (104 ° F)
Method: ASTM D 445
Explosive properties : not determined
Oxidizing properties : See Section 2
Decomposition temperature : not determined
Melting point/freezing point : not determined
Pour point : not determined
9.2 Other information
DMSO extract by IP346 : Less than 3.0 wt% (mineral oil component only)
Volatile organic compounds : no VOC duties

(VOC) content
Coefficient of thermal : 0,00076 1/°C AM-S 020-20

expansion
SECTION 10. STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No hazards to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid : Excessive heat.
10.5 Incompatible materials
Incompatible materials : Strong oxidizing agents, water
10.6 Hazardous decomposition products
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Hazardous decomposition : Hydrogen Sulfide

products
If decomposition is suspected, or if the product has been overheated, do not open the container,
discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions
to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of
contaminated areas, and use of suitable respiratory protection.
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects

Product
Acute oral toxicity : No data is available on the product itself.
Acute inhalation toxicity : No data is available on the product itself.
Acute dermal toxicity : No data is available on the product itself.
Skin corrosion/irritation : No data is available on the product itself.
Serious eye damage/eye : No data is available on the product itself.

irritation
Respiratory or skin : No data is available on the product itself.
sensitisation
Germ cell mutagenicity
Genotoxicity in vitro : No data is available on the product itself.
Genotoxicity in vivo : No data is available on the product itself.
Carcinogenicity : No data is available on the product itself.
Reproductive toxicity : No data is available on the product itself.
STOT - single exposure : Assessment: No data is available on the product itself.
STOT - repeated exposure : Assessment: No data is available on the product itself.
Aspiration hazard : No data is available on the product itself.
Components:
zinc bis(O,O-diisooctyl) bis(dithiophosphate):

Acute oral toxicity : LD50 Rat: 3.760 mg/kg
Method: OECD Test Guideline 401
Test substance: yes
Remarks: May be harmful if swallowed.
Acute inhalation toxicity : study scientifically unjustified
Acute dermal toxicity : LD50 Rabbit: > 5.000 mg/kg

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Test substance: Read-across (Analogy)

Remarks: Based on available data, the classification criteria
are not met.
Skin corrosion/irritation : Species: Rabbit

Exposure time: 48 h
Result: Skin irritation
Test substance:yes
Causes skin irritation.
Serious eye damage/eye : Species: Rabbit

irritation Exposure time: 72 h
Result: Causes serious eye damage.
Method: 16 CFR 1500.42
Test substance: yes
Specific concentration limits : Eye Irrit. 2 H319 >= 15%; Eye
Dam. 1 H318 >= 15%.
Respiratory or skin : Test Method: Maximisation Test

sensitisation Species: Guinea pig
Result: Does not cause skin sensitisation.
Test substance: yes
Based on available data, the classification criteria are not met.
Test Method: Buehler Test

Species: Guinea pig
Result: Does not cause skin sensitisation.
Test substance: yes
Germ cell mutagenicity

Genotoxicity in vitro : Type: Ames test
Test species: Salmonella typhimurium
with and without metabolic activation
Result: negative
GLP: yes
Type: In vitro gene mutation study in mammalian cells
Test species: mouse lymphoma cells
with and without metabolic activation
Result: negative
Genotoxicity in vivo : Type: Chromosome aberration test in vitro
Test species: MouseApplication Route: Intraperitoneal
injection
GLP: yes
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Result: negativeBased on available data, the classification
criteria are not met.
Carcinogenicity : No data available
Reproductive toxicity : Screening for reproductive/developmental toxicitySpecies: Rat

Application Route: Oral
NOAEL: 160 mg/kg,
F1: 160 mg/kg, Method: OECD Test Guideline 422
GLP: yes
Screening for reproductive/developmental toxicitySpecies: Rat

Application Route: Oral
NOAEL: 30 mg/kg,
F1: 30 mg/kg, Method: OECD Test Guideline 421
GLP: yes
STOT - single exposure : Assessment: Based on available data, the classification

STOT - repeated exposure : Assessment: Based on available data, the classification

Aspiration hazard : Based on available data, the classification criteria are not met.
Distillates (petroleum), solvent-dewaxed light paraffinic:

Carcinogenicity : No data available
Aspiration hazard : May be fatal if swallowed and enters airways.
11.2 Information on other hazards
11.2.1 Endocrine Disrupting Properties
Product
Assessment : No data is available on the product itself.
11.2.2 Other information
Product
None
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SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity
Product:
Toxicity to fish : No data is available on the product itself.
Toxicity to daphnia and other : No data is available on the product itself.

aquatic invertebrates
Toxicity to algae : No data is available on the product itself.
Components:
zinc bis(O,O-diisooctyl) bis(dithiophosphate) :

Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 3,8 mg/l
Exposure time: 96 h
Test Method: static test
Test substance: yes
GLP: yes
Toxic to aquatic life.
Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 510 mg/l
aquatic invertebrates Exposure time: 48 h
Test substance: yes
GLP: yes
Toxicity to algae : EL50 (Desmodesmus subspicatus (green algae)): 240 mg/l

Exposure time: 72 h
Analytical monitoring: no
GLP: yes
12.2 Persistence and degradability

Product:
Biodegradability : No data is available on the product itself.
Components:

Biodegradability : aerobic
activated sludge
Result: Not readily biodegradable.
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Biodegradation: < 5 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
According to the results of tests of biodegradability this
product is not readily biodegradable.
12.3 Bioaccumulative potential

Product:
Bioaccumulation : No data is available on the product itself.
Partition coefficient: n- : not determined

octanol/water
Components:

Bioaccumulation : Due to the distribution coefficient n-octanol/water,
accumulation in organisms is not expected.
Partition coefficient: n- : log Pow: 2,87 at 20 °C

octanol/water
12.4 Mobility in soil

Product:
Mobility : No data is available on the product itself.
Components:

Mobility : immobile
Distillates (petroleum), solvent-dewaxed light paraffinic :

Mobility : After release, adsorbs onto soil.
12.5 Results of PBT and vPvB assessment

Product:
This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
Components:

Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).
Distillates (petroleum), solvent-dewaxed light paraffinic :

Assessment : This substance is not considered to be persistent,
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bioaccumulating and toxic (PBT)., This substance is not

considered to be very persistent and very bioaccumulating
(vPvB).
12.6 Endocrine Disrupting Properties

Product:
12.7 Other adverse effects

Product:
Additional ecological : None known.
information
SECTION 13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product : The product should not be allowed to enter drains, water

courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of contents/ container to an approved waste disposal
plant.
Disposal recommendations based on material as supplied, Disposal must be in accordance with

applicable laws and regulations, and material characteristics at time of disposal
For the safety of persons conducting disposal, recycling or reclamation activities, refer to the information
in Section 8, Exposure control and personal protection.
Empty containers.
Empty Container Warning (where applicable): Empty containers may contain residue and can be
dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers
should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and
in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY
OR DEATH.
Regulatory disposal information
European Waste Code : 13 02 XX

waste engine, gear and lubricating oils
SECTION 14. TRANSPORT INFORMATION
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ADR / RID / ADN
14.1 UN number
UN number UN3082
14.2 UN proper shipping name
Proper shipping name ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S.(Zinc alkyl
dithiophosphate)
14.3 Transport hazard class(es)
Transport hazard class 9
14.4 Packing group
Packing group III
Labels 9
Hazard Identification 90
Number
Hazchem Code .3Z
14.5 Environmental hazards
Environmentally yes
hazardous
14.6 Special precautions for user
Footnote No special precautions required.
14.7 Maritime transport in bulk according to IMO instruments
Remarks Not applicable
IMDG
14.1 UN number
UN number UN3082

SUBSTANCE, LIQUID, N.O.S. (Zinc alkyl
dithiophosphate)
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14.4 Packing group
Packing group III
Labels 9
EmS Number 1 F-A
EmS Number 2 S-F
Marine pollutant yes
IATA
14.1 UN number
UN number UN3082

SUBSTANCE, LIQUID, N.O.S.(Zinc alkyl
dithiophosphate)
14.4 Packing group
Packing group III
Labels 9
Hazard Identification 90
Number
Hazchem Code .3Z
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Environmentally yes
hazardous
SECTION 15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National chemical inventory status:
List Status
TSCA : Listed
DSL : Listed
AICS : Listed
NZIoC : Listed
ENCS : Listed
KECI : Listed
PICCS : Listed
IECSC : Listed
TCSI : Listed
To import this product into the EU your company requires registrations for all constituent substances that
are subject to REACH registration. To discuss the possibility of setting up an Only Representative
agreement with Infineum, please e-mail Only.Representatives@Infineum.com
REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, mixtures and articles (Annex XVII)
Status : Not applicable
REACH - List of substances subject to authorisation (Annex XIV)
Regulation (EC) No 1005/2009 on substances that deplete the ozone layer
Regulation (EC) No 850/2004 on persistent organic pollutants
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REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
15.2 Chemical safety assessment
A Chemical Safety Assessment has been carried out for one or more of substances within this mixture.
SECTION 16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
Revision changes since the previous version are marked in the margins throughout this document
Sources of key data used to compile the Safety Data Sheet:
Austria: Regulation on Combustible Liquids VbF AT V1.2

EU Registration, Evaluation and Restriction of Chemicals regulation (REACH): Classification and
Labelling Inventory
Denmark: Executive Order No. 301 Bekendtgørelse om fastsættelse af kodenumre Arbejdstilsynets
bekendtgørelse nr. 301 af 1. maj 1993 (MAL Code)
France: Installations Classées pour la Protection de l'Environnement. (Loi 76/663 (modifiée) relative
aux installations classées).
France: le code de la sécurité sociale (titre VI du livre IV). (maladies professionnelles)
Germany: Administrative regulation for water hazardous substances # VwVwS of 17 May1999 (WGK).
Germany: LGK. Combined storage of chemicals # Federation of Chemical Industries dated July 1998.
Germany: TA Luft
UN Economic Commission for Europe: European Agreement Concerning the International Carriage
of Dangerous Goods by Road (ADR)
Austria: Regulation on Combustible Liquids VbF AT V1.2
EU Registration, Evaluation and Restriction of Chemicals regulation (REACH): Classification and
Labelling Inventory
Denmark: Executive Order No. 301 Bekendtgørelse om fastsættelse af kodenumre Arbejdstilsynets
bekendtgørelse nr. 301 af 1. maj 1993 (MAL Code)
France: Installations Classées pour la Protection de l'Environnement. (Loi 76/663 (modifiée) relative
aux installations classées).
France: le code de la sécurité sociale (titre VI du livre IV). (maladies professionnelles)
Germany: Administrative regulation for water hazardous substances # VwVwS of 17 May1999 (WGK).
Germany: LGK. Combined storage of chemicals # Federation of Chemical Industries dated July 1998.
Germany: TA Luft
UN Economic Commission for Europe: European Agreement Concerning the International Carriage
of Dangerous Goods by Road (ADR)
Infineum studies
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International Agency for Research on Cancer

International Air Transport Association: Dangerous Goods Regulations.
International Maritime Organization: International Maritime Dangerous Goods Code
Component supplier data
Key or legend to abbreviations and acronyms used in the safety data sheet
DSL : Domestic Substances List (DSL)

NDSL : Non-Domestic Substances List (NDSL)
PICCS : Inventory of Chemicals and Chemical Substances (PICCS)
TSCA : TSCA Inventory
AICS : Australia Inventory of Chemical Substances (AICS)
IECSC : China. Inventory of Existing Chemical Substances in China
(IECSC)
ENCS : Japan. ENCS - Existing and New Chemical Substances
Inventory
KECI : Korea. Korean Existing Chemicals Inventory (KECI)
NZIoC : New Zealand. Inventory of Chemical Substances
EINECS : European Inventory of Existing Commercial Chemical
Substances (EINECS)
ELINCS : European List of Notified Commercial Substances (ELINCS)
ATE : Acute toxicity estimate
STEL : Short term exposure limit
TWA : Time weighted average
LC50 : Lethal Concentration to 50 % of a test population
LD50 : Lethal Dose to 50% of a test population (Median Lethal Dose)
PPE : Personal Protection Equipment
TCSI : Taiwan Chemical Substance Inventory
Procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]
Classification Classification procedure:

Skin irritation, Category 2, H315 Calculation method
Serious eye damage, Category 1, H318 Calculation method
Chronic aquatic toxicity, Category 2, Calculation method
H411
The information contained in this document is based upon data believed to be reliable at the time of
going to press and relates only to the matters specifically mentioned in this document. Although
Infineum has used reasonable skill and care in the preparation of this information, in the absence of
any overriding obligations arising under a specific contract, no representation, warranty (express or
implied), or guarantee is made as to the suitability, accuracy, reliability or completeness of the
information; nothing in this document shall reduce the user's responsibility to satisfy itself as to the
suitability, accuracy, reliability, and completeness of such information for its particular use; there is no
warranty against intellectual property infringement; and Infineum shall not be liable for any loss,
damage or injury that may occur from the use of this information other than death or personal injury
caused by its negligence. No statement shall be construed as an endorsement of any product or
process. For greater certainty, before use of information contained in this document, particularly if the
product is used for a purpose or under conditions which are abnormal or not reasonably foreseeable,
this information must be reviewed with the supplier of such information.
Revision Date : 18.10.2021
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Prepared by : Infineum Product Stewardship and Regulatory Compliance
Issuing date : 08.04.2024
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Annex
Exposure Scenario
Number Title
ES1 Formulation or re-packing; Hydraulic fluids (PC17).; Lubricants, greases, release products
(PC24).; Metal working fluids (PC25).
ES2 Use at industrial sites; Hydraulic fluids (PC17).; Lubricants, greases, release products
(PC24).
ES3 Use at industrial sites; Lubricants, greases, release products (PC24).
ES4 Widespread use by professional workers; Hydraulic fluids (PC17).; Lubricants, greases,
release products (PC24).
ES5 Widespread use by professional workers; Lubricants, greases, release products (PC24).
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ES1: Industrial formulation of lubricant additives, lubricants and greases
1.1. Title section
Structured Short Title : Formulation or re-packing; Hydraulic fluids (PC17).; Lubricants,

greases, release products (PC24).; Metal working fluids
(PC25).
Environment
CS1 Formulation into mixture, ESVOC SPERC 2.2.v1 ERC2
Worker
CS2 General risk management measures applicable to all activities CS135

CS3 General exposures PROC2
CS4 Mixing operations, Dedicated facility, Batch processes at elevated PROC3
temperatures
CS5 Mixing operations (open systems), Non-dedicated facility, Batch PROC4,
processes at elevated temperatures PROC5
CS6 Process sampling PROC4,
PROC5,
PROC8b
CS7 Bulk transfers PROC8b
CS8 Drum/batch transfers, Dedicated facility PROC8b
CS9 Drum/batch transfers, Non-dedicated facility PROC8a
CS10 Equipment cleaning and maintenance PROC8a,
PROC8b
CS11 Drum and small package filling PROC9
CS12 Laboratory activities PROC15
CS13 Disposal of wastes PROC8b
CS14 Storage PROC1,
PROC2
1.2. Conditions of use affecting exposure
1.2.1. Control of environmental exposure: Formulation into mixture (ERC2)
Amount used, frequency and duration of use (or from service life)
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Maximum daily site tonnage - MES : 1667 kg/day

Annual amount per site : 500 tonnes/year
Fraction of EU tonnage used in region : 0,1
Fraction of Regional tonnage used : 1
locally
Maximum allowable site tonnage : 19.406 kg
(MSafe)
Emission days : 300
Technical and organisational conditions and measures
Prevent discharge of undissolved substance to or recover from onsite wastewater.

Do not apply industrial sludge to natural soils.
Common practices vary across sites thus conservative process release estimates used.
Conditions and measures related to sewage treatment plant
STP type : Municipal Sewage Treatment Plant

STP sludge treatment : Sewage sludge should be incinerated, contained or reclaimed.
STP effluent : 2.000 m3/d
Conditions and measures related to treatment of waste (including article waste)
Waste treatment : External treatment and disposal of waste should comply with
applicable local and/or national regulations.
External recovery and recycling of waste should comply with
Other conditions affecting environmental exposure
Local freshwater dilution factor : 10

Local marine water dilution factor : 100
1.2.2. Control of worker exposure: General measures applicable to all activities (CS135)
Product (article) characteristics
Covers concentrations up to 100 %

Physical form of product : Liquid
Vapour pressure : < 0,5 Pa
Duration : Covers daily exposures up to 8 hours
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Assumes a good basic standard of occupational hygiene is implemented

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
Conditions and measures related to personal protection, hygiene and health evaluation
Use suitable eye protection and gloves.

Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training.
Other conditions affecting workers exposure
Temperature : Assumes use at not more than 20°C above ambient

temperature.
1.2.3. Control of worker exposure: Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment conditions (PROC2)
Handle substance within a closed system.
1.2.4. Control of worker exposure: Manufacture or formulation in the chemical industry in closed batch
processes with occasional controlled exposure or processes with equivalent containment condition
(PROC3)
1.2.5. Control of worker exposure: Chemical production where opportunity for exposure arises
(PROC4) / Mixing or blending in batch processes (PROC5)
No other specific measures identified.
1.2.6. Control of worker exposure: Chemical production where opportunity for exposure arises
(PROC4) / Mixing or blending in batch processes (PROC5) / Transfer of substance or mixture
(charging/discharging) at dedicated facilities (PROC8b)
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1.2.7. Control of worker exposure: Transfer of substance or mixture (charging/discharging) at

dedicated facilities (PROC8b)

1.2.9. Control of worker exposure: Transfer of substance or mixture (charging/discharging) at non

dedicated-facilities (PROC8a)

dedicated-facilities (PROC8a) / Transfer of substance or mixture (charging/discharging) at dedicated
facilities (PROC8b)
Drain down and flush system prior to equipment break-in or maintenance.
1.2.11. Control of worker exposure: Transfer of substance or mixture into small containers (dedicated
filling line, including weighing) (PROC9)
1.2.12. Control of worker exposure: Use as laboratory reagent (PROC15)
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Clear up spills immediately and dispose of waste safely.
1.2.14. Control of worker exposure: Chemical production or refinery in closed process without
likelihood of exposure or processes with equivalent containment conditions (PROC1) / Chemical
production or refinery in closed continuous process with occasional controlled exposure or
processes with equivalent containment conditions (PROC2)
Store substance within a closed system.
1.3. Exposure estimation and reference to its source
1.3.1. Environmental release and exposure: Formulation into mixture (ERC2)
Compartment Exposure level RCR

Freshwater 0,086
Freshwater sediment 0,086
Marine water 0,084
Marine sediment 0,084
Agricultural soil 0,058
Additional information on exposure estimation

EUSES 2.1.1 in combination with solvent industry (ESVOC) Specific Environmental Release Class
(spERC) estimates (www.cefic.org).
1.3.2. Worker exposure: General measures applicable to all activities (CS135)

CEFIC Chemical Safety Assessment Template tool (www.cefic.org) modified using ECETOC Targetted
Risk Assessment model exposure estimates (www.ecetoc.org) in combination with ATIEL-ATC use
group descriptors (www.atiel.org).
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1.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling
may be necessary to define appropriate site-specific risk management measures.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
If scaling reveals a condition of unsafe use (i.e., RCRs > 1), additional RMMs or a site-specific chemical safety
assessment is required.
For further information see http://atiel.org/reach/introduction.
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ES2: General industrial use of lubricants and greases in vehicles or machine
2.1. Title section
Structured Short Title : Use at industrial sites; Hydraulic fluids (PC17).; Lubricants,
greases, release products (PC24).
Environment
CS1 ESVOC SPERC 4.6a.v1 ERC4, ERC7
Worker

CS3 Initial factory fill of equipment PROC9
CS4 Initial factory fill of equipment, Manual PROC8b
CS5 Initial factory fill of equipment, Closed systems PROC2,
PROC9
CS6 Initial factory fill of equipment, Open systems PROC8b
CS7 Use in contained systems PROC1
CS8 Equipment cleaning and maintenance PROC8b
CS10 Storage PROC1,
PROC2
2.2.1. Control of environmental exposure: Use of non-reactive processing aid at industrial site (no
inclusion into or onto article) (ERC4) / Use of functional fluid at industrial site (ERC7)

locally
(MSafe)
Emission days : 300
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Exhaust ventilation equipped with scrubbers.

Negligible wastewater emissions as process operates without
water contact.



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temperature.
2.2.3. Control of worker exposure: Transfer of substance or mixture into small containers (dedicated

2.2.5. Control of worker exposure: Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment conditions (PROC2) /
Transfer of substance or mixture into small containers (dedicated filling line, including weighing)
(PROC9)

likelihood of exposure or processes with equivalent containment conditions (PROC1)
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Drain down system prior to equipment break-in or maintenance.

2.3.1. Environmental release and exposure: Use of non-reactive processing aid at industrial site (no
inclusion into or onto article) (ERC4) / Use of functional fluid at industrial site (ERC7)

Freshwater 0,686
Marine water 0,709
Sewage treatment plant 0,008

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ES3: Industrial application of lubricant to work pieces or equipment by dipping, brushing or

spraying (without exposure to heat)
3.1. Title section
Structured Short Title : Use at industrial sites; Lubricants, greases, release products
(PC24).
Environment
CS1 ESVOC SPERC 4.6a.v1 ERC4
Worker

CS3 Material transfers, Manual PROC8b
CS4 Material transfers, Use in contained systems PROC8b,
PROC9
CS5 Roller, spreader, flow application PROC10
CS6 Spraying PROC7
CS7 Treatment by dipping and pouring PROC13
CS10 Storage PROC1,
PROC2
3.2.1. Control of environmental exposure: Use of non-reactive processing aid at industrial site (no
inclusion into or onto article) (ERC4)

locally
(MSafe)
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Emission days : 300

water contact.


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temperature.


dedicated facilities (PROC8b) / Transfer of substance or mixture into small containers (dedicated
3.2.5. Control of worker exposure: Roller application or brushing (PROC10)
3.2.6. Control of worker exposure: Industrial spraying (PROC7)
Ensure material transfers are under containment or extract ventilation.
Wear a respirator conforming to EN140 with Type A filter or better.
3.2.7. Control of worker exposure: Treatment of articles by dipping and pouring (PROC13)
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3.3.1. Environmental release and exposure: Use of non-reactive processing aid at industrial site (no
inclusion into or onto article) (ERC4)

Freshwater 0,686
Marine water 0,709
Sewage treatment plant < 0,01

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ES4: Professional use of lubricants and greases in vehicles or machinery
4.1. Title section
Structured Short Title : Widespread use by professional workers; Hydraulic fluids

(PC17).; Lubricants, greases, release products (PC24).
Environment
CS1 ESVOC SPERC 9.6b.v1 ERC9a,

ERC9b
Worker

CS3 Use in contained systems PROC1
CS4 Equipment cleaning and maintenance, Non-dedicated facility PROC8a
CS5 Equipment cleaning and maintenance, Dedicated facility PROC8b
CS6 Equipment cleaning and maintenance PROC20
CS8 Storage PROC1,
PROC2
4.2.1. Control of environmental exposure: Widespread use of functional fluid (indoor) (ERC9a) /
Widespread use of functional fluid (outdoor) (ERC9b)

locally
(MSafe)
Emission days : 365
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water contact.



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temperature.
likelihood of exposure or processes with equivalent containment conditions (PROC1)


4.2.6. Control of worker exposure: Use of functional fluids in small devices (PROC20)

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4.3.1. Environmental release and exposure: Widespread use of functional fluid (indoor) (ERC9a) /
Widespread use of functional fluid (outdoor) (ERC9b)

Freshwater 0,086
Marine water 0,084


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ES5: Professional application of lubricant to work pieces or equipment by dipping, brushing

or spraying (without exposure to heat)
5.1. Title section
Structured Short Title : Widespread use by professional workers; Lubricants, greases,

release products (PC24).
Environment
CS1 ESVOC SPERC 8.6c.v1 ERC8a,

ERC8d
Worker

CS3 Material transfers, Manual PROC8a
CS4 Roller, spreader, flow application PROC10
CS5 Spraying PROC11
CS6 Treatment by dipping and pouring PROC13
CS9 Storage PROC1,
PROC2
5.2.1. Control of environmental exposure: Widespread use of non-reactive processing aid (no
inclusion into or onto article, indoor) (ERC8a) / Widespread use of non-reactive processing aid (no
inclusion into or onto article, outdoor) (ERC8d)

locally
(MSafe)
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Emission days : 365

water contact.


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temperature.

5.2.4. Control of worker exposure: Roller application or brushing (PROC10)
5.2.5. Control of worker exposure: Non-industrial spraying (PROC11)
Ensure material transfers are under containment or extract ventilation.

Avoid carrying out activities involving exposure for more than 1 hour per day.
Wear a respirator conforming to EN140 with Type A filter or better.
5.2.6. Control of worker exposure: Treatment of articles by dipping and pouring (PROC13)

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5.3.1. Environmental release and exposure: Widespread use of non-reactive processing aid (no
inclusion into or onto article, indoor) (ERC8a) / Widespread use of non-reactive processing aid (no
inclusion into or onto article, outdoor) (ERC8d)

Freshwater 0,086
Marine water 0,084


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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

1.1 Product identifier

Trade name : R14642A

Use of the Substance/Mixture : Component of lubricant additives

1.3 Details of the supplier of the safety data sheet

Company : INFINEUM UK LIMITED

E-mail address for further information SDS@infineum.com

Website for further information http://www.infineum.com

1.4 Emergency telephone number

04-4274.4690 (France) (+33-4.4274.4690)

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS-Classification (REGULATION (EC) No 1272/2008)

Serious eye damage: Category 1 H318: Causes serious eye damage.

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

2.2 Label elements

GHS-Labelling (REGULATION (EC) No 1272/2008)

Signal word : Danger

Hazard statements : H315 Causes skin irritation.

Precautionary statements : Prevention:

Hazardous components which must be listed on the label:

2.3 Other Hazards

Contact with hot material may cause thermal burns

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component EC-No. Concentration Classification

zinc bis(O,O-diisooctyl) 249-109-7 >=90 - <=100 Skin Irrit. 2; H315

Distillates (petroleum), 265-159-2 >=1 - <10 Asp. Tox. 1; H304

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice : Move out of dangerous area.

If inhaled : Consult a physician after significant exposure.

If breathing has stopped, assist ventilation with a mechanical

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

seek medical advice.

Symptoms : corrosive effects

Treatment : Show this safety data sheet to the doctor in attendance.

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

5.2 Special hazards arising from the substance or mixture

Combustibility : Not classified as flammable or combustible, but will combust if

Hazardous combustion : Hydrogen sulphide, Sulphur oxides and Phosphorus oxides

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

Carbon monoxide, carbon dioxide and unburned

Flammable properties : See Section 9 for information on flammability.

5.3 Advice for firefighters

Fire-fighters should exercise extreme caution in enclosed

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Advice for emergency responders

Advice for non-emergency personnel

6.2 Environmental precautions

Environmental precautions : Prevent entry into waterways, sewers, basements or

Local authorities should be advised if significant spillages

Version 1.0 Revision Date 18.10.2021 Print Date 08.04.2024

Try to prevent the material from entering drains or water

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Prevent further leakage or spillage if safe to do so.

Report spills as required to appropriate authorities.

Soak up with inert absorbent material (e.g. sand, silica gel,