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SAFETY DATA SHEET

CEBEX 200

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CEBEX 200

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Free expansion grout admixture

1.3. Details of the supplier of the safety data sheet

Manufacturer Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Carc. 1B -
H350

Environmental hazards Aquatic Chronic 2 - H411

Human health Dust may irritate the eyes and the respiratory system. May cause skin disorders if contact is
repeated or prolonged. May cause skin sensitisation or allergic reactions in sensitive
individuals.

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H302 Harmful if swallowed.

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H350 May cause cancer.
H411 Toxic to aquatic life with long lasting effects.

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Precautionary statements P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Contains BASIC COPPER CARBONATE, HYDRAZINIUM SULPHATE

Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P321 Specific treatment (see medical advice on this label).
P330 Rinse mouth.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

CALCIUM LIGNOSULPHONATE 10-30%

CAS number: 8061-52-7 EC number: 232-506-4

Classification
Not Classified

BASIC COPPER CARBONATE 10-30%

CAS number: 12069-69-1 EC number: 235-113-6

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 -
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
STOT SE 3 - H335

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HYDRAZINIUM SULPHATE 5-10%

CAS number: 10034-93-2 EC number: 233-110-4
M factor (Acute) = 1 M factor (Chronic) = 1

Classification
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
Skin Sens. 1 - H317
Carc. 1B - H350
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Remove affected person from source of contamination.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing.

Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to
an unconscious person. Get medical attention if any discomfort continues.

Skin contact Wash skin thoroughly with soap and water. Remove contaminated clothing. Wash
contaminated clothing before reuse. Get medical attention if irritation persists after washing.

Eye contact Do not rub eye. Remove any contact lenses and open eyelids wide apart. Rinse immediately
with plenty of water. Continue to rinse for at least 15 minutes. Get medical attention if irritation
persists after washing.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases.

Ingestion Ingestion of large doses may result in irritation to the gastrointestinal tract.

Skin contact May have an irritating effect on moist skin after prolonged contact, or may cause dermatitis
after repeated contact.Prolonged skin contact with wet preparation may cause serious burns
without pain being felt, including through clothing.

Eye contact Prolonged or repeated exposure may cause severe irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

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Specific hazards Water used for fire extinguishing, which has been in contact with the product, may be
corrosive.

Hazardous combustion No known hazardous decomposition products.

products

5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known.
firefighting

Special protective equipment Use protective equipment appropriate for surrounding materials.
for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin and eyes. Wear protective clothing and gloves. Avoid inhalation of
dust.

6.2. Environmental precautions

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into
suitable waste disposal containers and seal securely. Waste, residues, empty containers,
discarded work clothes and contaminated cleaning materials should be collected in
designated containers, labelled with their contents.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Wear protective clothing, gloves, eye and face protection. Wash skin thoroughly after
handling.

Advice on general Do not eat, drink or smoke when using this product. Wash at the end of each work shift and
occupational hygiene before eating, smoking and using the toilet. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
CALCIUM LIGNOSULPHONATE
Long-term exposure limit (8-hour TWA): ACGIH/TLV:0.1 mg/m3 res
TLV - Threshold Limit Value ppm 5 mg/m³

BASIC COPPER CARBONATE (CAS: 12069-69-1)

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PNEC - Fresh water; 7.8 µg/l

- marine water; 5.2 µg/l
- STP; 230 µg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation.

controls

Personal protection Personal protection equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.

Eye/face protection Wear tight-fitting, dust-resistant, chemical splash goggles if airborne dust is generated.

Hand protection Use impervious, abrasion and alkali resistant gloves. Butyl rubber. Polyvinyl alcohol (PVA).
Nitrile rubber. Neoprene. Barrier cream applied before work may make it easier to clean the
skin after exposure, but does not prevent absorption through the skin.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Exercise good industrial hygiene practice. Wash after handling, especially before eating,
drinking or smoking. Remove contaminated clothing immediately.

Respiratory protection Wear a suitable dust mask. Wear a respirator fitted with the following cartridge: Particulate
filter, type P2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Solid.

Colour Grey.

Odour No characteristic odour.

pH <6

Melting point Not applicable.

Initial boiling point and range > 1000 ℃

Flash point Not applicable.

Upper/lower flammability or The product is not flammable.

explosive limits

Bulk density 1 g/cm3

Solubility(ies) Slightly soluble in water.

Partition coefficient Not determined.

Viscosity Not applicable.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

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Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Stable when kept dry until usage.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Water, moisture.

10.5. Incompatible materials

Materials to avoid Reducing agents.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 1,245.67

Acute toxicity - dermal

ATE dermal (mg/kg) 4,267.43

Acute toxicity - inhalation

ATE inhalation (dusts/mists 7.11
mg/l)

Inhalation Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases.

Ingestion May be harmful if swallowed.

Skin contact Prolonged skin contact may cause temporary irritation.

Eye contact Prolonged or repeated exposure may cause severe irritation.

Route of exposure Skin and/or eye contact

Toxicological information on ingredients.

BASIC COPPER CARBONATE

Acute toxicity - oral

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Acute toxicity oral (LD₅₀ 1,350.0

mg/kg)

Species Rat

ATE oral (mg/kg) 1,350.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,000.0

mg/kg)

Species Rat

HYDRAZINIUM SULPHATE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 601.0

mg/kg)

Species Rat

Acute toxicity - inhalation

ATE inhalation 0.5

(dusts/mists mg/l)

SECTION 12: Ecological information

Ecotoxicity Harmful to aquatic organisms, may cause long term adverse effects in the aquatic
environment

12.1. Toxicity
Toxicity May cause long-term adverse effects in the aquatic environment.

12.2. Persistence and degradability

Persistence and degradability The product is not biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient Not determined.

12.4. Mobility in soil

Mobility The product is water-soluble and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Do not empty into drains, sewers or water courses. The generation of waste should be
minimised or avoided wherever possible.

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Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3077

UN No. (IMDG) 3077

UN No. (ICAO) 3077

UN No. (ADN) 3077

14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS
(ADR/RID) HYDRAZINIUM SULPHATE)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS
HYDRAZINIUM SULPHATE)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS
HYDRAZINIUM SULPHATE)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS
HYDRAZINIUM SULPHATE)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M7

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

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EmS F-A, S-F

ADR transport category 3

Emergency Action Code 2Z

Hazard Identification Number 90

(ADR/RID)

Tunnel restriction code (-)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

Guidance Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms ATE: Acute Toxicity Estimate.

used in the safety data sheet
vPvB: Very Persistent and Very Bioaccumulative.
CAS: Chemical Abstracts Service.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
PBT: Persistent, Bioaccumulative and Toxic substance.
PNEC: Predicted No Effect Concentration.
LC₅₀: Lethal Concentration to 50 % of a test population.

General information For professional use only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 27/07/2018

Revision 00

SDS number 26588

Hazard statements in full H301 Toxic if swallowed.

H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

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The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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