onintroducing KOH solution volo, used: ; 22 FO, left unused is ound by wrijol and noting the decrease in ja of gaseous hydrocarbon is jar formu a , ne volume ofit forms °x’volumes ‘umes of water vapour. o used= (= 2) vol sium of O2 ume of CO produced =x vol. : i J, i 214% traction OO explosion and cooling x ume of liquid water is neglected) {f Molecular Mass by ination 01 germinal ctor Meyer’s Method : veown mass of the volatile substance is Me ictor meyer’s method. ured in Vis /apours obtained displaces an equal volume into graduated tube. ‘volume of air displaced is calculated at STP _ Ah Ae ition byusing “~~ 7, _mass of volatile substance = Massof substance taken _Massof substance taken 2400 ime of air displaced in mal at STP 9. 10. Tetravalence of Introduction , Carbon, Strcutural Representation of Organic Compounds Organic compounds can be formed by 1) Plants only 2) Animals only 3) Plants and Animals 4) Plants, animals and can be synthesized in laboratory ‘The first carbon compound prepared from its elements is 1) Urea 2) Acetic acid 3) Methane 4) Benzene Generally organic compounds are 1) Amorphous 2) Complexes 3) Covalent 4) Electrovalent Marsh gas mainly contains NOGH, 26H, 3)CH, 4) CHe Energy required for the excitation of carbon atom is 1) 501. 6 KJ/ mol 2) 827.0 KJ/ mol 3) 341.0 KJ/mol 4) 610.0 KJ/ mol Hybridisation at 2nd carbon in CH, = CH - CH; is 1) sp 2) sp? 3) sp? 4) sp3d Which of the following has maximum C — H bond length DCH, 2)GH, 3)C,H, 4)C Hg The cylindrical shape of alkynes is due to 1)ThreegC —C bonds 2) Three C—Cbonds 3) Two oC—C andtwo #C-C bonds 4) One oC-C and two 7 C—C bonds Which of the following statement is not correct? 1) Double bond is shorter than a single bond 2) Sigma bond is weaker than x (Pi) bond 3) Double bond is stronger than hydrogen bond 4) Covalent bond is stronger than hydrogen bond Toluene has 1) 6c- and 37-- bonds 2) 9¢- and 37 - bonds 3) Qg- and 67r- bonds 4) 15c- and 37 - bonds a511. Ta which of the compound given below contains morethan onekind of hybridization (97°) for carbon 1) CH,cH,cH,cH, 2) CH, -CH =CH-CH, 3) CH, =CH-CH=CH, 4) H-C=C-H 12. The carbon atomsin the compound (CN),C, are 1) spand sp hybridised 2).sp” hybridised 3) sp hybridised 4) sp, sp? and sp’ hybridised 13. The ratio of the number of sp, sp”, and sp" orbitals in the compound is CH, ~CH =C =CH-C=C-CH, DUET 22:21 3)3:2:1 Classification of Organic Compounds, TUPAC Nomenclature 14, Which isan alicyclic compound 4334 1) Benzene 2) cyclohexane 3) pyridine 4) pyrrole 15. The TUPAC name of the compound cH, CH,;—CH,—CH—CO0C,H, is 1)2- Ethyl-ethylacetate 2) Ethyl - 3 - methyl butanoate 3) Ethyl-2- methyl butanoate 4) 2- methyl butanoic acid 16. Functional group present in amides is 1)- COOH 2) -NH, 3) -CONH, 4)- COO - 17. The correct decreasing order of priority for the functional groups of organic compounds in the TUPAC system of nomenclature is (AIEEE-2008) 1) -COOH,-SO,H,-CONH, -CHO 2) -SO,H,-COOH,-CONH, -CHO 3) -CHO,-COOH,-SO,H,-CONH, 4) -CONH, -CHO,-SO,H,-COOH 18 The functional group presnt in anisole is I)ketone 2)aldehyde 3)amine 4) ether 19, I.U.P.A.C name of ester is 1) Alkoxy alkane 2) Alkylalkanoate 3) Alkanoy! balide 4) Alkanoic anhydride 20, 3-methyl penta-1,3, ICH, = CH (CH, 2) CH, = CHCH (CHyd,, - 3) CHSCH = C(C14 OCH 4) CH, = C= Car (oy! * Cp 21. The TUPAC name op 2 1) 4-hydroxy-2- me 2) Dhyoxy meth et 4 3) 4tyroxy-2-methyi pee 4) 2hydrony-f- methine The correct IUPAC name gf” CH—C=C—cH, CH, GH, 1) 1,2-diethyl butene 2)2-ethyl -3- methy! 3)3,4- dimethyl exe 4)2,3- dimethyl pent -2- ene The structure of isoprene jg 1) CH,-CH =C=cH, cH, 2) CH, =¢-cH=cn, cH, 22. 23. I 3) HC =C-C=CH, fs 4) CH, =C-CH, -CH =CH, |. The IUPAC name of the compoun CHy- ECHO CH, 1)2- Ethyl prop-2-ene-1-ol 2)2-Hydroxymethyl butan-1-ol 3)2-Methylene butan-1-o1 4) 2-Ethyl - 3hydroxyprop-I-ene TUPAC name of HOOC-CH, - 1) Formylethanoic acid 2) 2-Car 3) Prop-3-al-I-oic acid 4) Prop-1 y = 25,ie ‘The IUPAC name of the yi-1-hydroxpeyetohexane -3-cyclohexanol fnybI- cyclohexanol “3- hydroxycyclohexane erism™ # s nd epurane jsobutane are a pair of 2) position isomers ens 4) functional isomers yet rand Alkoxyalkanes are arkamn0ls Mi isomers 2) Keto-enol tautomers 1) Funct tical jsomers4) Not isomers at all jsomers 360" pound which is not isomeric with compoun 1 eer et opylmethyl ether Dati-ol 3) 2+ Methylpropan-2-of Buta 4yButanone ible position isomers for ber of possible pi Nom pichlorobenzene is 2 23 3)4 4)5 02 9 ¢ I rhe molecules CH;—C—CH;~ C—O—CH OH and CH_-C—CH—C— O—G)H, are })Geometricalisomers 2) Tautomers 3)Diastereomers 4) Metamers The isomerism exhibited due to the difference in the size of the alkyl groups attached to the same functional group is ate 1) Tautomerism 2) Stereo isomerism 3) Metamerism 4) Optical isomerism Fundamental Concepts in Organic Reaction Mechanism (Reaction Intermediates and Electronic Effects): Heterolysis of propane gives 1) Methyl and ethyl free radicals 2)Methyl carbocation and ethyl free radicals 3) Methyl anion and ethyl carbocation 4)Methyl free radical and ethylcarbocation ORGANIC CHEMISTRY «5 34 35 36 37. 38 39, 40 41 42 SS err: Removal of hydride ton from a methane molecule will give a 1) Methyl radical 2) Carbonium ion 3) Carbanion 4) Methyl group The shape of carbonium ion is 1) Planar 2) Linear 3) Pyramidal 4) Tetrahedral Which of the following contains only three Pairs of electrons 1) Carbocation 2)Carbanion 3) Free radical 4) Allofthese Which of the following species is paramagnetic 1)Acarboniumion —_2) A free radical 3) Acarbanion 4) Allofthese The reaction intermediate produced by homolytic cleavage of bond is called 1) carbocations 2) carbanion 3) free radical 4) carbenes Which one of the following statement is not correct for electrophile 1) Electron deficient species are electrophiles 2) Electrophiles are Lewis acids 3)Alll positively charged species are electrophiles 4) AICI, and SO, are electrophiles Which of the following statements are correct for nucleophile 1) All negatively charged species are nucleophiles 2) Nucleophiles are Lewis bases 3) Alkenes, alkynes, benzene and pyrrole are nucleophiles 4) Allare correct ‘Which statement is correct for inductive effect: 1) It isa permanent effect 2) Itis the property of single bond 3) Itcauses permanent polarisation in the molecule 4) Allare correct The displacement of electrons in a multiple bond in the presence of attacking reagent is called 1) inductive effect 2) electromeric effect 3) resonance 4) Hyper-conjugation aexercise . Tetravalence of Carbon, Representation of Organic Mormost ofthe organic compounds 2) Petroleum 4) Ammonia £7 nic compound was synthesized 2) Kolbe 4) Neil Barthlot sys unds are numerous since oa as high catenation ability bomencyofcarbon smoforemi compounds palo ae * sollowing contains acetic acid? wien oft y Molasses 3)Coal tar 4) Butter nee \d angle in benzene is about cece bom 1) 10928" 2180 3120". 4) 100° cH, CH,. Hybridisation of central —— 3)sp)__ 4) sp*d 2) 2 ofthe folowing has minimum C-H bond rength Nel, DEH, ICH, ACH Which of the following is not a cyclic ‘compound? 1) Anthracene 2) Pyrrole 3) Phenol 4) Isobutylene Which of the following bonds is strongest? 1) 2e-c% 2) >C=C< 3)-C-C= 4) -C=C- The no. of o & x bonds present in C,H, respectively are W12-2)21 —-3)5,2— 4)3,2 Which hybrid orbitals are involved in the CH,-CH=CH— CH, compound !)spand sp3 2) sp? and sp? 3)spand sp? 4) only sp? GE 12. 13. 14, 15 16. 17. 19. SEE SIT In which of the following compounds, carbon uses SP? hybrid orbitals only for bonding? 1) HCOOH 2) cH,cHO 3)(CH,), COH 4) (NH), CO Which compound given below has sp’, sp? and sp orbitals in the ratio of 6:3:2? 1) CH, - CH =CH -~CH, -C=C-CH, 2) CH,-CH =CH -CH,-C=CH 3) CH,~CH,-C=C-CH =CH, 4) CH,-CH =CH-C=CH Classification of Organic Compounds, TUPAC Nomenclature : Which of the following is hetero cyclic compound? 1) Anthracene 3) Phenol 2) Pyrrole 4) Isobutylene ||__ group is present in —1__eroupis pi 1) ketones only 2) aldehydes only 3) Carboxylic acid only 4) Allthe above In IUPAC system of naming of organic compounds. Which of the following functional group has more preference than others (in a poly functional compound) 1)-OH — 2)-CHO 3)-CO-4)-CONH, ‘The functional group present in acylchlorides is ° i 1) -cr 2) -C-cl ° 3) -C-ocl 4) -CH, - IUPAC name of ethers is 1) alkoxy alkane 2) alkanol 3) alkanal 4) alkylalkanoate The correct IUPAC name of CH;—C = CH CH, C,H, 1) 1,2-diethyl butene 2)2- ethyl -3- methyl pentene 3)3 , 4- dimethyl hex -3- ene 4)2 - methyl pent -2- ene oc 91Se et eee 20. The TUPAC name of the compound CH,-CH(OH)-COOH is 1) Lactic acid 2)2-Hydroxy propanoic acid 3)3 - Hydroxy propanoic acid 4) Carboxy propanol 21 The IUPAC name of the following. CH, -C(CH,), ~CH, — CH = CH, 1s 1)2,2- Dimethyl-4-pentene 2)4,4-Dimethyl-1-pentene 3) 1, 1, I-trimethyl-3-butene 4) 4,4, 4-trimethyl-I-butene 22, The structure of allylehlorideis 1) City =CH-CH,CI 2) CH = C(Cl)-CH3 3) CH(Cl) =CH-CHy 4) CH(CI) = C(CI)-CH3 compound 23 The IUPAC name of OH (CH;—C—CH,—CH—CH, is CH, CH, 1)2, 4-Dimethyl pentanol -2 2)2, 4- Dimethyl pentanol-4 3)2, 2 - Dimethy! butanol - 2 4) Butanol -2 24, IUPAC name of CH, - CHCI- CH, -CHO is 1, 2-chloro-4-butanol 2, 3-chlorobutanol 3. 2-chloro-4-butanal 4, 3-chlorobutanal 25. The correct IUPAC name of CH = CHOH is 1) ethenol 2)ethanol 3)ethenal 4) ethanal 26. 4—methyl penta-1, 2- diene is 1) CH, =CH(CH,), CH, 2) CH, = CHCH (CH,)CH,CH, 3) CH,CH = C(CH,)CH =CH, 4) Cll, =C=CH~CH(CH,), 27. The IUPAC name of NH, cH, CH;-CH—CH;—CH—cyy, 1) 4-amino -2- methyl pentanay 2) 2-bydroxy -4- methyl pentanay 3) 4-hydroxy-2-methyl pentano] 4) 2-bydroxy-4- methyl pentang) Isomerism: 28, n-Butanol and 2-methylpropang of which isomers ? »PANO| ap 1) Position DR 3) Metamers 4) Chai 29 neo Pentane and iso pentane ar, 1) Functionalisomers 2) Chain 3)Geometrical isomers 4) Positi, 30. Carboxylic acids and esters are 1) Functional isomers 2) Keto-eno] tay 3) Geometrical isomers4) Not isomers 31. Number of possible monochtoro beast pi 2)3 25 pee 32. Which of the following pairs of compo tautomers? 1) Propanol & propanone 2) Ethanol & vinyl alcohol 3) Ethanol & allyl alcohol 4) Vinylalcohol & ethanal 33. CH,CH,CH, OH is a functional isomer of 1) C,H,OCH, 2) CH,OC,H, 3) CH,CH,CH,OCH,CH, 4) CH,CHOHCH, Fundamental Concepts. in. Organic Reaction Mechanism (Reaction Inter- mediates and Electronic effects); 34, Heterolysis of C-Clbond produces 1) Two free radicals 2) Two carboniumions: 3) Two carbanions 4) One cation and oneanion 35 Cleavage of Grignard reagent results in the 8 ban, formation of 1) carbonium ion 2)carbanion. 3) free radical 4) carbene 36. The geometry of a methyl carbanion Islikely tobe ri 1) Pyramidal 3) Planarits is oi jons 2) very stable p" te Fi 4) all of these tal chat npaired electron ite Presence of an UMP! 3) ahe : it {0 ical are 2) Anions | net five 4) Chemically reactive ortcall ang free radicals is ceape of 2) Pyramidal hes oe 4) Linear Pan eda 1 rarabeag are 3) soph ng speci eet ering species ; Me oni greagents4) Lewis base 2K cleus OVINE ign is 3) xr carbonium on™ wis base Nueteorile 4) Both ‘a’ and ‘b’ yeast ihe following is an electrophilic niet of oe 2) OH” na 4) allof these 3) NO2 jc effect in organic compounds ‘rheelectromerie © isa fect 2) Permanent effect ‘Temporary ¢ yemporay ‘or permanent effect ithe above ‘ oaaance is due to +p aelocalsation of sigma electrons > ymigration of H atoms 3)migration of proton =} debocalisation of pielectrons +, Hyperconjugation involves overlap of the fallowing orbitals No-o 2o-p ae 4) a- ‘6, Hyperconjugation phenomenon is possible in I) H,C=CH, 2) CH,CH, CH=CH, 3) C,H,CH =CH, 4) (CH,), C—CH =CH, 41. The most stable carbonium ion is 1) Methyl carbonium ion 2) Primary carbonium ion 3) Secondary carbonium ion 4)Tertiary carbonium ion 49, 50. 51. 52. 53. 54. @ )) CHs~CH,~CH, ® 2.) CHy ~CHy ~CHy -C Hy B e ) CH3-CH-~CH, 4) 2 CH ~CHy~CH-CH, Methods of Purification of Organic Compounds: A mixture contains four solid organic compounds A,B,C and D. On heating only C changes from solid state to vapour state directly. C can be separated from the rest in the mixture by 1) Distillation 2) Sublimation 3) Fractional distillation 4) Crystallisation Anthracene is purified by 1) Filtration 2) Crystallisation 3) Distillation 4) Sublimation Separation of two substances by fractional crystallisation depends upon their difference in 1) Densities 3) melting point 4) Boiling points Simple distillation can be used to separate 1) Amixture of benzene (b.p. 80°C) and thiophene (bp. 84°C) 2) Amixture of ethanol (b.p. 78.16C) and water (bp. 100°C) 3) Amixture of ether (b.p. 35°C) and toluene (b.p. 110°C) 4) None of the above Ortho and para nitrophenols can be separated by 1) crystallization 2) Steam distillation 3) sublimation 4) solvent extraction ‘Two volatile liquids A and B differ in their boiling points by 15°C. The process which can be used to separate them is 1) Fractional distillation 2) Steam distillation 3) Distillation under reduced pressure 4) Simple distillation 93RCISE-I1(C.W). Introduction, Tetravalence of Carbon, Structural representation of Organic DRCH CHE OH oy OH OH I 4) HC-CHE CH = CR, Ch, Compounds : Neo-heptyl alcohol is correety 1. The first organic compound synthesised in the i "h laboratory from an inorganic compound is ad DNH.NCO 2) NH, -CO-. ) CHy~P—FH—CHy~ CH, 3) CH,COOH 4)CH, CH,OH 2. Bond length orderis CH, 1 2) CHP CH CHs~ CH CH, D-¢-c-> >C=C< >—Cec— OH iat CH, 2) Ce Guee oe t 3) CHy—C—CHs- CH CH= oy hee) i D-E- =>C=C<=-Cac— CH, ria GH; 9 E-C > acacc = Ce 4) CHe-C—on 2 The ratio of pure and hybrid orbitals ee eae ae i Staats . ch isan alicyclic compoun ec H,C = CH ~CH =CH, benzene 2) cyclo pentene 7:12 2)14:13 3) pyridine ‘pymole 3) 12:10 45:6 Classification of Organic Compounds, IUPAC Nomenclature: “ 7. According to Huckel’s rule a compound is sald structure is to bearomaticifit contains HO: 1) 4n bonds 2) 4n atoms 3) 4n+2}atoms 4)(4n+2) x electrons cH, & The number of x electrons Present in Phenanthrecene 0) H;C—CH,—CH—CH,—cH— CH, 1) 10 214 416 a 9. Which of the following is an aromatic Non Phot 2) Naphthal on CH, 3)Pyridine ANC see 2H,C—cH—caz cr,—dn-cr rH, 10. The TUPAC name of the given compound f i hb du ae “-E CH, 1) 2-methyl butane 2) 3-methyl butane 3) Pentane 4) Isopentane —més of Eth : “) Methyl-n-butyl amine ts ofthe compound js (ATEEE-2004) fohexane carbaldehyde xy eyclohexane nt iydrony eyelohexane panel 3 -cyetohexanol a name the compound “uPs! yy propane ~1.s 2g aricyano Propane hie 2,3 - tricarbonitri le Pate TUPAC name of the following CHO yéroxy cyclohex - 2-ene- 1 -al wydroxy cyclohex - 1 - ene-3-al + hydroxy cyclohex - 5- ene carbaldehyde |) formyl eyelohex - 5 - enal ‘The IUPAC name of 1)3-Cyclopropyl-3-cthyl -2- propene 2)l-Cyclopropyl-1-etyhl propene 3)3-Cyclopropyl-2-pentene 4\{-ethyl-1-propenyl)cyclopropane i. 18. 19. 20. 21. 22 23. 24, 25. TUPAC name of CH,CH,CH,COCH, is 1) 2-pentanone 2) Pemtan-2-onie 3) pentanone-2 4) all the above The systematic name of (CH,),CH ~COOH 1) 2-Propanoie acid 2) Isobutanoic acid 3)2-Methylpropanoic acid 4)2-Methylbutanoic acid isomerism : Which isomer of C,H,, has two isopropyl groups 1)2-Methylpentane 2) 3-Methylpentane 3)2,3-Dimethylbutane 4) 2,2-Dimethyfbutane The number of structural alcoholic isomers for C,H,90 is 12 2)3 3)4 4)5 The number of aromatic isomers possible for GH,O is 12 2)3 3)4 4)s ‘The number of isomeric amines possible for the formula C,H, 4 2)3 3)5 4)6 Identify the compound that exhibits tautom- erism 1) 2-Pentanol 3)2-Butanone 2)Phenol 4) Lactic acid Fundamental Concepts in Organic Reaction Mechanism (Reaction Inter- mediates and Electronic effects): ‘Which of the following pairs is/ are correctly matched? I. Carbocation : electrophile IL. Free radical : paramagnetic IIL. Carbene: Incomplete octet IV. Carbanion: Incomplete octet Select the correct answer using the codes given below: 1) Only 2)Tand II 3) 1, 1, Mand IV 4)1, Wand IIL Jn carbonium ion the carbon bearing the positive charge is 1) sp hybridized 3) sp? hybridized 2) sp? hybridized 4)un hybridized 97, coo Methods of Purification of cele : "4 " Jectrophile 26. InaFriedel- Craft's reaction, the electro compounds : is . liquid vapours , . Organic liquid vapourises at a ¢9 1) cr or X" 2)CH,* or CH,CO below its boiling point in steam coc! because y 3) CH,Cl 4) CHy Z < 27. The reaction of HBr with ethene is an eX 1) Mixture boils when sum of vapour, 5 a Feaetisa water and organic liquid become, ample of react atmospheric pressure. 3 nats a Connon 2) Steam distillation is actualy distlaign addition ; : eased pressure. lr 28. Which amon; the following compounds behave inet both asan slectrophile aswellasanucleophile| 3) ae vapour does not contribute to itg lag point. Sate: a) CH, =CH, 4) Atmospheric pressure is reduced . |. A liquid which decomposes a oF bel; ° ° boiling point can be purified by “ 1 I 1)steam distillation 2) simple distillation 9.CH,-C-CH, CH, -C-Cl 3) factional distillation a 4) distillation under reduced pressure 1) Onlya 2)aandb |. Which of the following statement is incorrect? Bycanda 4) be and d 1) Fixed melting point can be used to test the purty 29, Among the following carbocations which is ofthe solid organiccompound score stabi 2) Hydrogen peroxide is purified by steam distillation 3) Impurities cause a decrease in the melting point D(GoHs), O° x») ‘i ofthe compound 4) crystallisation is based on sparingly solubility o compound at low temperature 3 9 Meee Qualitative Analysis of Organic Or Compounds 30. Which free radical is the most stable 35. The covalent compound which does not give positive test in Lassaigne’s test is Nome en 1)1,3-Dinitrobenzene 2) Glycine CH, -CH; ») CH, =CH-CH, 3) Urea ome : fi 36. Nitrie acid is added to sodium extract and 3)CH,-CH-CH, a) CH, CO CH boiled before adding silver nitrate to test le halogens because 3 1)To neutralise alkaline solutic i fc 31. Arrange the following groups in order of extract, SE es decreasing R(or-M) He 2) To convert sodiam cyanide and sodium sulphide 2Ne, pes ae HCN and HS which are volatile. 3 dium cyan : Da>c>b>d 2)a>b>o>d into sodium nen nie snd sodium sulphide 3)a>d>c>b 4)d>c>b>a on aceecoa 'o get white precipitate of 4gCN and black ooart) = S. The compound which ja, at 20. Be tea orcas group Is on c 1)2.2.3.3-tetramethyl pentane § 2)2,2-dimethyl pentane & C-C-OH 3)2,2,3-trimethyl pentane 4) 2-methyl pentane : 6. The structural formuta of methane is methyl ay 1) (CH,), CH NH, 2) (CH), 22. 79-7) SYantines srs fonctions isomers EXERCISE-II(H.W) Introduction , Tetravalence of carbon, Streutural Representation of Organic 3) (CH,), NH 4) CH Hy The number & type of carbon ‘ator, | Compounds 2 ag 1. When a mixture of potassium cyanate and in neopentane are esa, ammonium chloride is heated, it gives 1) four 1° carbons , one 4° carbon 1) Urea 2) Methanmide 2) two I°carbons , two 2° carbons 3) Ethanamide 4) Ethanamine 3) one 1° carbon, one 4° carbon 2. C—C bond length in benzene is 4) one 1° carbon, one 4° carbon DLS44° 2)1.34.4° 3)1.39.4° 4)1.204° Classification of Organic Compra, 3. Ratio of pure and hybrid orbitals in TUPAC Nomenclature benzene 8. Which of the following sets conta; N32 2)2:3 3:2 42:1 carbocyclic compounds? 1) Thiophene, Oxirane, Pyrrolidine 4. + ‘NH, i 2) Piperidine, Cyclohexane, Benzene "2 which of the following explains 2) Naphtatene, Cielopropane Brent 4) Pyridine, Thiophene, Oxetane The number of = electrons in anthracene is 16 210 3)12 414 Which of the following is non aromatic CH, 10. 1) CH; CNH, compound 1)Phenol 2) Naphthalene ‘CH, fon 3) Pyridine 4) Cyclo octatetraene 5 i. The IUPAC name of the given structure 2) CH;~ CH;— CH—NH, $i (or) Hie 3) NH;~ C—CH— CH, I 1)2,2- Dimethyl butane 2) Isohexane CH, 3)2,3- Dimethyl butane 4) Diisohexane 12, The TUPAC name of the compound this structure cH, vali CH ~ CH(NH)CHCOOCH, is 4) NH; ie NE: 1) Methyl-2- amino butanoate cH, 2) Methyl3- amino butanoate 3) Methyl-4 - amino butanoate 4) 2-amino pentanoate3 opel anne 2 are eof the following compound . cna ew’ cl is ‘NO2 4-dinitro benzene ~*y a-dinitro benzene -2- chloro benzene Mt jedinitro benzene CH ~CH,-COOH * cooH sie pentane - 1, 5~ dioic acid 3- Cat 1,2,3- trioie acid 2) ProPaM carboxylic propane (19,3 - tricarboxylic acid of CH,OH — CH,OH is ~ gdroxy ethane 2) Ethylene glycol 1.2-dhyroMgiol 4) Ethane - 1, 2- dial : : eth TUPAC name of the follo cd 1)3- chloro eyelo hexa - 1, $ - diene 2)$- chloro cyclo hexa - 1, 3 - diene 3)1-chloro cyclo hexa - 2, 5 - diene 4)2- chloro cyclo hexa - 1, 4 - diene the IUPAC name of the following Zn ERIC 1) Ethenylcyclo pentane Bm 2)eyclopentyl ethene» 3) eyelopentylethylene 4) vinyleyclopentane \ 19. ‘The structureot bromoyere te 3 Br 1) CH,-C=cH, 2) CH,-CH =CH-Br 3) CH\-C=CH~Br br 4) Br-CH, -CH =CH, 20. The TUPAC name of the compound shown Cc ‘Br -chlorocyclohex-1-ene 2) 6-bromo-2-chlorocyclohexene 3) 3-bromo-1-chlorocyclohexene 4) 1-bromo-3-chlorocyclohexene 21. The systematic name of (CH,),CH - COOH 1)2-Propanoicacid _2) Isobutanoic acid 3) 2-Methylpropanoic acid 4) 2-Methylbutanoic acid Isomerism : 22. The number of primary alcoholic isomers for C,H, ,0 is 12 2)3 3)4 23. Primary, secondary and tertiary a 1) Chain isomers 2) Position isomers 3) Functional isomers 4) Tautomers 24. Which of the following compounds is isomeric with trimethyl amine? 1) 1-Propanamine 2)2-Propanamine 3) Both 1 and 2 4)2-Butanamine 25. Which ofthe following classes of organic ‘compounds show metamerism? 1)ethers 2) Secondary amines 3) ketones 4) Allthe three 26. The type of isomerism found in urea molecule is 1) Chain 2)Position 3)Tautomerism 4) Geometricalirthat isnot? fhe following the P™ 27. Amongt pair of metamers 1) CH,OCH,CH,CHs 2) CH,OCH,CH:CHs & CH &cHy cH,oCHs» & CH; ocH(CHs): 4) CH,COCH,CH:CHy 28 The reaction, (CH), example of 1) Homolytic fission 3) Cracking Fundamental C cor a(hs 2) Heterolstc fission 4) Allthe above ‘oncepts in Organ Mechanism pencties es and Electronic Effects): in from a ketone Reaction Intermediat ‘The formation of cyanohydri is an example of 1) Nuclephilic addition 2) Electrophilic Substitution 3) Nucleophilic Substitution 4) Electrophilic addition ‘Among the following the true property H,C~_e about oe HC 1)non- planar 2) C*is sp? - hybridised 3) Electrophile can attack on C* 4) Does not undergo hydrolysis Methyl carbanion is 1) Electrophile 2) Lewis acid 3) Both (1) and (2) 4) Nucleophile Which one of the compound behaves as an electrophile as well as nucleophile. 1) Acetone 2) Cyanide ion 3)nitrte ion 4) Sulphite ion Which of the following statements is correct about, inductiveeffect ° 1) Implies the transfer of lone pair of electrons from more electronegative atomto lesser electronegative atom ina molecule 2) Implies the transfer of lone pair of electrons from lesser electronegative atom to the mor electronegative atomina molecule i 3) inerases with increase in distance in iF 9 lines the atoms ability to cause bond 29. 30. 32. 33. 37 36. 38. 39, hich is least stable ? 1)eCH; 3) CH3 -CH- CH groups is 1) -o 3)- OH 4) -NHCE Methods of Purification of 6 Compounds : 2 Which of the following statem regarding purification of liq distillation? 1) Impurities must be non-volatile” 2) The liquid must be completely. water 3) The liquid must possess high boil 4) The liquid must be miscible in wa Distillation under reduced pressure used to purity the liquids in wi 1) have high boiling points 2) have low boiling points 3) do not decompose at their boi 4)highly volatile B Components of rectified spi separated by distillation becaus 1) it forms an Azeotropic mixture = 2) ithas components with same 3) it contains immiscible liquids 4) it has high vapour pressure1. The hybridisation of carbon atoms in C-C single bond is HC = C—CH =CH, Is 1) Sp>—Sp? 2) Sp?-Sp* 3) Sp-Sp* 4) Sp’ -Sp 2. Which ofthe following order regarding the size of hybrid orbital of carbon is correct? 1) Sp > Sp? > Sp* 2) Sp< Sp? < SP 3) Sp > Sp? Sp” 3. Which of the following orders regarding the electronegativity of hybrid orbital of carbon is correct? 1) Sp > Sp? > Sp’ 2) Sp< Sp? < Sp 3) Sp> Sp? Sp* 4. Theleast priority functional group among the following is: 1) -O# 2) -C=C- 3) c= ce 4) -NH, 5. 18 C-Hand 7 C-C sigma bonds are in 1) cyclohexane 2)3,3-dimethylpentane 3)2,2,3-trimethylpentane 4)n-heptane 6. The IUPAC name of vinyl acetylene is : 1) Pent-I-en-4-yne 2) Pent-4-yne-I-ene 3) But-I-en-3-yne 4) But-I-yn-3-ene 7. The IUPAC name of acrolein is: 1) But-2-enal 2) Prop-2-enal 3)But-3-enal 4) 2-Methyl prop-2-enal OH 8. mmeturacaameet I is ‘OH 1) but - 2- ene - 2, 3- diol 2) pent- 2 -ene -2, 3- diol 3) 2- methyl but- 2 - ene- 2,3-diol 4) hex -2 - ene -2, 3 -diol 9, The IUPAC name of the following COOH OH CN 1)3 cyano -2 - carboxy benzalgayes 2)2-cyano - 6 - formyl benzoic aig 3) 6 - cyano - 2 - formyl benzoic a 4)2- formyl - 6 - cyano benzoic agi 10, The TUPAC name of the given strug, a 1) 6-Bromo-5-chlorocyelohexen-3.ymq" 2) 5-Bromo-6-chloro: 3) 6-Bromo-5-chloro. 4) 4-Bromo-3-chloro-1-cyclohexen§ 11, TheIUPAC names of the following ‘compounds 1) Cis-1,2 dimethyl cyclobutane and dimethyl cyclo butane ¥ 2) 2-Butene and methylpropene 3) Trans-2-butene and cis-2-butene 4) Methylpropene and methylpropene _ 12, The correct IUPAC name of HCH, CH,CH;-C—CH—CH, CHCI, 1)1-Chloro-2-butylcyclopropane 2) 1-Chloro-2-cyclopropylbutane 3)1-Chloro-methyl-1-ethyl cyclo propane » 4)3-Chloro metyl-1,2-methylenepentane 13, TUPAC name of the compound CH, CH;—CH;—N(CH,)—CH fh CH, 1) N-ethyl-N-methyl isopropane 2) N-ethyl-N-methyl amino propane 3) N-ethyl-N-methyl-1-amino propane 4) N-ethyl-N-methyl-2-propanamine| _gunv-dimettyl4-hexanamine yatta Oh Nedimethyl 4-butanamine shyt-Ne methyl 3-methyl- 3~ peo ethylamino) _-5-methylhexane 2 TUPAC name of the com- Br und is tyi-bromo-3- cyano phenol como-S-hydroxybenzonitrile no-4-hydroxy bromobenzene 4) @-bromo-3-hydroxy benzo nitrile The structure of N-Ethyl-N-phenyl- butanamide is ds IL 1) HYC“CH-C— CHT NC CoHs Zs ‘CoHs 2) CHy—CH,—CH-C—N. 20. 21. 22. 23. is 4) HC—CH-C—CH AN. Scu,ch, .. The structure of 2-(chloromethoxy) ethanol 1) CICH,OCH,CH,OH 2) H,CO—CH—CH,OH cr oR 3) H,CO—CH—CH, 1 OH | 4) CI-H,CO—CH—CH, CHs-COOH ‘The TUPAC name of § [eo CH; COOH 1) 2-hydroxy-1,2.3-propanetricarboxylic acid 2) 3-hydroxy-1,2,3-pentane trioie acid 3) 3-carboxy-3-hydroxy-1,5-pentandioie acid 4) 1,2,3+tri carboxy-2-propanol C,H,N cannot present 1) 1° Amines 3). 3° Amines 2) 2° Amines 4) Quaternary salt Identify the compound that exhibits tautom- erism: (2011) 1)2-Butene 2) Lacticacid 3) 2-Pentanone 4) Phenol ‘The order of stability of the following cabocations CH, = CH -CH?; CH,CH,CH? CHACH: is {2013} Dileuet 2) H>U>l 3) IPI 4) UDP I 105= s are of an organic compound in Kjeldahrs vatnod neutralized 30 ml of 0.25 yy 77, SO,, - ercentage of nitrogen in the compound is 28 2)50 3) 80 4) 14 928 g of an organic compound in Dumas " method liberated 24 ml of nitrogen at STP. The percentage of nitrogen in the compound is 1)20 2)10.71 3)80 4) 50 The IUPAC name of [2007] !) 3-ethyl-4-4-dimethylheptane 2)1, |-diethyl-2,2-dimethylpentane 3)4, 4-dimethyl-5,5-diethylpentane 4)5, 5-diethy] -4,4-dimethylpentane. Presence ofa nitro group in a benzene ring deactivates the ring towards electrophilic titution 2) acti “lvates the ring t titution .