iGnited Chemistr ractice Material for XI Annual Exam a SECTION A the following questions are multiple-choice questions with one correct answer. Each question carries 1 mark, Phere is no internal choice in this section. Sample-L 1, Which of the following is the lightest? Xa 0.2 mole of hydrogen gas (b) 6.023% 10% (c) 0.1 mole of oxygen gas (c) Ig af wate molecules of nitrogen. 2. Asub-shell with n= 4.,1= 3 can accommodate a maximum of {aY 14 electrons (b) 36 electrons (c) Welectrons (a) 6 electrons 3. Which of the follow ng electronic configuration of an atom has the highest.) F electronegativity? {a) Is? 2s' 4. Which of the followi pe3s! — (c) Ls? 2s? 2p {ay Ts? 2s? 2p 2 substances has a dipole moment is greater than zero? aps (b) Is? a7 Water —(b) Methane (c) Carbon dioxide (d) Nitrogen 5, The element with atomic number 53 belongs to (a) d= Block (b) f- Block Xp - Block Ws 6. In which ofthe following, functional group isomerism is not possible? {a} Alcohols (b) Aldehydes (@}Aikyl halides (a) Cyanides 7. Which of the following is not correct? (a) AGis zero fora reversible reaction. (b) AG is positive fora spontaneous reaction Vv {6P"AG is negative for a spontaneous reaction (a) AGis positive for a non-spontaneous reaction. 8, Pure methane can be prepared by Block {27Soda lime decarboxylation (b) Kolbes electrolytic method (c) Wurtz reaction (a) Reduction with He o-The increasing order of reduction of gly halides with zinc and dilute HCL (a) R-Cl< R-l< R-Br WAR-Cl< R-Br< RT (co) Rc R-Br< R-Cl (d) R-Br< R-I (a)-6 er (#2 (a2 bond is favoured by (b) Large cation and large anion (a) Small cation and small anion 11. According to Fajan’s rule, covalent (a) Large cation and small anion {c¥Small cation and large anion 12. The position of double bond in alkenes can be tocated by : {a) Hydrogenation of oil {oyOzonolysis (C) Photolysis (a) Hydration 13. Consider the following reaction: dn + Cue Zn + Co With reference to the above, which one of the following is the corr sta 1 Prepared by. Dusmant PageiGnited Chemistry Practice Material for XI Annual Exam (a) Zn is reduced to Zn“ ions. Wx7Zn is oxidised to Zn2* ions. = (c) Zn2* ions are oxidised to Zn, (d) Cu?" ions are oxidized to Cu, 14, Arrange the following carbanions in order of their decreasing stability. (a) HC-C aC BH iG; (©) H,C—cH, (a)A>B>C {OB>A>C (\C>B>A (dC>A>B 15, Assertion : In a triad, the three elements present have same gaps of atomic masses, Reason : Elements ina triad have similar properties (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and R are true but Ris not the correct explanation of A. (c) Ais true but R is false. Wayhis false but R is true. 16. Assertion: The entropy of ice is less than that of water: Reason: Ice has a cage like structure. (a) Both A and R are true and R is the correct explanation of A. Both A and Rare true but R is not the correct explanation of A. (0) Ais true but Ris false. (4) Ais false but Ris true. 17. Assertion (A) : Toluene on Friedel Crafts methylation gives o- and p-xylene. Reason (R) : CHs-group bonded to benzene ring increases electron density at o-and p- position, weyBoth Aand R are correct and R is the correct explanation of A. (b) Both A and R are correct but R is not the correct explanation of A. (c) Ais true but Ris false. (4) Ais false but Ris true. 18, Assertion (A) : All the carbon atoms in H2C = C = CH2 are sp? hybridised Reason (R): In this molecule all the carbon atoms are attached to each other by double bonds. (a) Both A and Rare correct and Ris the correct explanation of A. (b) Both A and Rare correct but R is not the rire explanation of A. (c) Ais true but Ris false. ‘Ais false but Ris true. Sample-2 1. Which of the following pair of compounds obey law of multiple proportion? a.Sodium chloride and sodium bromide b.Water and heavy water ~cAulphur dioxide and sulphur trioxide d. Magnesium hydroxide and magnesium oxide 2. Iftravelling at the same speeds, which of the following matter waves have the shortest wavelength? a. Electron {ufalpha particle (He?) (c) Neutron (d) Proton 3. The statement that is not correct for periodic classification of elements is (a) They «lic function oftheir atomic numbers. eee aeiGnited Chemistry Practice Material for XI Annual Exam _ (b)_ Non-metallic elements arelessinnumber than metallic elements. (©) Fortransition clements,the3d-orbitals are illed with electrons after 3p-orbitals and before 4s orbitals. (4) Thefirstionizationenthalpies ofelements generally increase withinereaseinatomicnumber as wego along aperiod. 4. Anything that influences the valence electrons will affect the chemistry of the element Which one of the following factors does not affect the valence shell? (a) Valence principal quantum number (n) (b) Nuetear charge (2) luclear mass {d) Number of core el Which of the followin central atom? (a) NHs oft. {c) PCls (a) Bs 6, ‘The outer orbitals of Cin ethene molecu cctrons, nolecule has two bond pair and two lone pair of electrons on the e can he considered to be hybridized to give three ‘equivalent sp* orbitals. The total number of sigma (s) and pi (p) bonds in ethene molecule is (a) L sigma (s) and 2 pi (p) bonds ) ia (s) and 2 pi (p) bonds (c) 4 sigma (s) and 1 pi (p) bonds § sigma (s) and 1 pi (p) bonds 393.5 and -283.0 k] mol The enthalpies of combustion of carbon and carbon monoxide ar ‘ respectively. The enthalpy of formation of carbon monoxide is: (a) -676k] (b) 110.5 Kt 4G -110.5 by (a) 6765 kh 8. Theoxidation of sulphur in the anions $,0,°", S07 and $,0,°" follow the order Gs 0?” < $03 < 8:06°° < SO (d) $,0,°° < S,0,°> < SO} ©, The displacement of electrons in a multiple bond in the presence of attacking reagent is called a. Inductive effect Ysffilectromeric effect (cResonance (d) Hyper conjugation. 10. The structure of 4-Methylpent-2-en-L-ol is: (a) CHACH2CH=CHCHLOH (b) (CH)2C=CHCHCHLOH ef (Cy) ,CHCH=CHCHLOH (d) CHaCH(OHJCH-CH=C(CHa)e 1. Blectroph addition reactions proceed in two steps. The first step involves the addition ofan electrophile, Name the type of intermediate formed in the first step of the following addition reaction. HaC—HC +H 3? 3°Carbanion (b) 1° Carbocation fe{2" Carbocation (a) 1° Carbanion Butene-1 may be converted to butane by reaction with ES PAsHe (b) Zn- HCl (co) Sn- HCl (d) 2n- Hg 13, When propyne is treatd with HgSOs/H2S0s the product is, (a) Propanol (b) Propanal Propanone (d) Propanoic acid 14. Which alkene on ozonolysis gives CHsCH2CHO and CHsCOCH:? 4) CH ~ CHa - CH = C (CHs}e (b) CHa CHoCH = CH CHoCHy ‘repared by-- Dusmant Kumar Sahu, Lect.-in-Chemistry mob-637 1637836 Page 3ited Chemistry Practice Material for X1 Annual Exam —S———— (e) CHACHE CH= CH CH (a) (CHa C= cHeH 18, Given below Assertion (A): Reason (R): atom. e hwo statements labelled as Assertion (A) and Re: Smaller the son (R) ize ol an atom greater is the electronepativity lectronegativity relers to the tendency af atom so share electrons with other (a) Both A and Rare true and R is the correct explanation of A. (b) Both Aand Rare true but Ris not the correct ef Ais true but Ris false. (d) Ais false but R is true. planation of A. 16. Given below a Asset {wo statements labelled as Assertion (A) and Reason (R) ion (A): Heat of neutralization for hoth 1,80, and HCL with NaOH is 53. 7lehmol Reason (R): Both HCland 10) are strong acids, <4 Both A and Rare true and Ris the correct explanation of A. (b) Both Aand Rare true but R is not the correct explanation of A. (c) Ais true but Ris false, (d) Ais false but Ris true. 7 7. Given below are two sta tements labelled as Assertion (A) and Reason (R). Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of a disproportiona jon reaction, Reason (R): The oxygen of peroxide is in -1 oxidation state and it is converted to 7 oxidation state in Oz and ~2 oxidation state in H.0. (2S Both A and Rare true and Ris the correct explanation of A (b) Both A and Rare true but Ris not the correct explanation of A. (c) Ais true but Ris false, (d) Ais false but Ris true, 18, Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A): Boiling point of alkanes increa with increase in molecular weight. Reason (R): van cler Waal’s forces increase with increase in molecul: ar weight. GefBoth A and R are true and Ris the correct explanation of A, (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false. (d) Ais false but Ris true. Sample=3 1. An organic compound on analysis was found to contain 10.06% carbon, 0.84% hydrogen and 89.10% chlorine, What will be the empirical formula of the substance? : (@) CHaCk @Y CHC (©) CCl. (a) CHCl 2._The period number in the long form of the periodic table is equal to Prepared by- Dusmant Kumar Sahu, mob-6371637836 PageiGnited Chemistry Practice Material for XI Annual Ex (a) magnetic quantum number of any element of the period (b) atomic number of any element of the period \(¢}maximum principal quantum number of any element of the period (a) maximum azimuthal quantum number of any element of the period 3. Which of the following molecule does not show hydrogen bonding? (a) HE (b) #20 (c) NH3s_ (HS 4, What is the mass per cent of carbon in carbon dioxide? (a) 0.034% —(b}27.27% = (c)_ 3.4% — (A) 28.7% Hyperconjugation involves overlapping of which of the follo (aa-o byo-p (Opp (da-w 6. Warming ammonium chloride with sodium hydroxide in a test tube is an example of (a) closed system (b) isolated s \(eYopen system (d) none of these Relation between wavelength (@) and momentum (P) of a material particle is _. (a) P (b) A=h+P — (c) A=h-P Ash/P. 8. When an inert gas, such as helium, is added to a system at equilibrium (a) No effect on the equilibrium would occu (b) The product would be favoured. (¢}4€ would affect equilibrium only if it produces changes in concentral partial pressures) of the reactants or products. (a) It would affect equilibrium only if it reacts with one of the substances involved in. the equilibrium. 9, Oxidation number of carbon in CH2Ch is. @-+ +4 ©3 WO 10. Which of the following is not true for a chemical equilibrium? (a) When the experimental conditions are not changed, no change in the concentration of any of the substance occurs. wrno reaction, neither forward nor reverse occurs at equilibrium. (c) The ratio of the rate constants of forward and reverse reactions is constant. (d) The relative amounts of reactants and products at equilibrium vary greatly for different chemical reactions. LL, Which of the compounds with molecular formula CsH0 yields acetone on ozonolysis? ~{a) 2-methylbut-1-ene (c) 3-methylbut-1-ene (b) 2-methylbut-2-ene (d)_cyclopentane 12. Nitrobenzene can be prepared from benzene by using mixture of conc. HNOs and conc. HeSOs. In the nitrating mixture, nitric acid acts as “(aT base (b) acid (c)catalyst —(d) reducing agent 13, Reductants are substances which (a) Show increase in their oxidation number during a change. (b) Lose electrons during a change. (0) Reduce other and oxidise themselves. May AN 14. When no heat energy is allowed to enter or leave a system, then itis called (a) isothermal process (b) reversible p <(eFadiabatic process («) irreversible proce: Given below are two statements labelled a g orbitals, n (or Assertion (A) and Reason (R) mob-6371637836 Page 5aRrVeraTIOR | RE iGnited Chemistry Practice Material for XI Annual Exam — Assertion: Octet theory cannot account for the shape of the molecule. Reason: Octet theory can predict relative stability and energy of a molecule. Select the most appropriate answer from the options given below: a. Hoth A and fare true and Ris the correct explanation of A b, Hoth A and Rare true but R is not the correct explanation of A. Ris true ut iis fa d. Ais false but Ris true. 16, Given below are two statements labelled as Assertion (A) and Reason (R) Assertion Acyclic compounds consist of straight or branched chain compounds. Reason Alicyclic compounds contain carbon atoms joined in the form ofa ring. Select the most appropriate answer from the options given belov a, Both A and Rare true and Ris the correct explanation of A Jicfioth A and R are true but R is not the correct explanation of A. © Ais true but Ris false. 4. Ais false but Ris true, 17. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion: Isoelectronic species have same radi Reason: They contain same number of electrons. Select the most appropriate answer from the options given below a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of c. Ais true but R is false. \d-fis false but Ris true. 18. en bel low are two statements labelled as Assertion (A) and Reason (R) Assertion It is impossible to determine the exact position and exact momentum of an electron simultaneously. Reason The path of an electron in an atom is clearly defined. Select the most appropriate answer from the options given belo a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. AR is true but R is false. d. Ais false but R is true. Sample-4 The percentage of an element b mass is about: (a) 45 (b) 18 (o) 36 27 is 53 in its oxide of molecular formula M203. Its atomic 1¢ angular momentum of an electron is zero. In which orbital may it be present? (b) 2p {c) 3d (d) 4f According to (n+) rule, after np level is filled with electrons, the next electron will enter into: (a) (n+1) p h(n) (2 (1d (d) nd 4. Which of the following process involves absorption of energy? (a) Clte + (b) O46 OQ) St 9S LD O +e 30° Prep: ¥y- Dusmant Kumar Sahu, Lect.-in-Chemistry ‘mob-637 1637836 PageéiGnited Chemistry Practice Material for XI Annual Exam For one of the element various successive ionization enthalpies (in k] mol) are given below: ist___ | 2nd 3rd artigos lee stiri | |s775 [1180 2750 [11,580 | 14,280 ‘The element is: son f@P (b) Mg (0 Si fa] Al 6. Which of the following are not state functions? qtw (i) q, ay ow, (lv) H-TS (a) (Nand (IV) (b) (1, (1D and (IV) (ce) (1), (11) and (11) fe) (i) and (11) 7. Atequilibrium of the reaction, 2X (g)+ Y(g) > X2¥ (g), the number of moles of X2¥ at equilibrium is affected by: \(aJ temperature and pressure _(b) temperature only (c) pressure only (d) temperature, pressure and catalyst used 8, Which of the following will occur if a 0.1M solution ofa weak acid is diluted to 0,01 M at constant temperature? (a) [H*] will decrease to 0.01 M (b) pH will decrease «(oypercentage ionization will increase (c) Ka will increase eR ca Bhat 9. HNO» acts as an oxidant with which one of the following reagent: (a)KMn0, Go] HS (6) KaCra (a) Bre 10. The oxidation state of Cr in Crs is: (a) +10 (b) +5 AKT +6 (d) +3 11. Electrophiles are electron seeking species. Which of the following group contains only electrophiles? \Waf AICIs, S03, NO2” (a) BF, NHs, HO (©) NOz*, CHs", CHs C* 0 (d) Colts", CoHs,CoHs* 12. The increasing order of stability of the following free radicals. (a) (Cotts)3€ < (CoHls)2CH < (CHs)3€ < (CHa)2CH (b) (Gatts)oCH < (Catls)sC< (CHs}s€ < (CHs)2CH (c) (CHa)oCH < (CHs)s€ < (ColHs)3€ < (CoHs)2CH SAF (CHs)aCH < (CHs)s6 < (Cobls}2CH « (Cols)3C 13. Arrange the following compounds in decreasing order of their boiling point. {i)n- butane (ii) 2-methylbutane (ii) n-pentane iv) 2,2-dimethylpropane i : tah tists V(b) tie iis vei (0 iviit> ii>i UG) ili> ii>iv>i .ct IUPAC name for diethylbromomethane? }) 3- Bromopentane (d) 1- Bromopentane mob-6371637836 Page 7 14. What should be the corre (a) 1-Bromo-1, 1- diethylmethane thylpropane () 1- Bromo:iGnited Chemistry Practice Material for Xt Annual Exam tn ortion (A) andl Heanor (1) Pe abotled as A tical compentned where ay enntie a te with widely dilferent tat tatlay ye | 1S, Given below are wo statements Assertion (A): Clinabar bs ache Reason (1): Cinnabar ahvays contains 0.2% Une sulphur by welt, Brass can be made capper anid ing ia) Hoth Aand Bare trie and Bobs the correct’ (b) Both and Rare tine but Bis nat he caret Ww Ais trie but Ris Lalse, (a) Ais talso but Ris tue, xphmation of A xphanation of A ( wn (I) yi where ements Labelled as Assertion (A) ann Re ofa prorbital have posite ve sgt te charge whereas Jo. Given below are two state Assertion (A): The opposite lobes + lobes of d-orbital have the Reason (RJ: The opposite lobes of a prorbital have opHe the apposite lobes af orbital have (he sane chine { il Ris the correct explanation oF A the oppe (a) Both Aand Rare tu {hh} Both Aand Rare true but B és not the correct exphination oF 4 ste} Ais tre but is false ( () Ais tase but Bis true, 4 17, Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A); Sixth period is the longest period in the periodic table Reason (R):_ Sixth period involves the filling ofall orbitals of the sixth “a energy lev « (a) Both Aand Rare true and R is the correet explanation of A, (b) Both A and Rare trac but R is not the correet explanation of uM ce} Nis true but Ris false (a (@) Ais false but B is true. i 18, Given below are two statements labelled as Assertion (A) and Reason (R) le Assertion (A): For the reaction 2NMy(g) + No(g) + 3H2(3), AH > al o Reason (R):. Enthalpy change is always greater than internal energy change. ; (a) Both Aand Rare trueand Ris the correct explanation of A. 12 (b) Both Aand Rare true but Ris not the correct expl tion of A, . “OAs true but Ris false. a (d) Ais false but Ris true, (c) Sample-5, 4 \ 1. The maximum number of molecules is present in @ [a) 35 gofO2 gas AYES gofHe gas (C)S Leg of Ne gas.at STP (A)1.5 1 of CO, atsTP yey 2, A gaseous mixture contains oxygen and nitrogen in the ratio of L=4 by weight. Therefore, 14 0 of their no af molecules is, @ (a) (b) 18 ey 7:82 (3:16 15. 3, ‘The total number ofatomic orbitals in third energy level of an atom is f@ 3 () 6 oe ome Prepared by- Du Tob 647 16N706 Pare Plee ————————————— iGnited Chemistry Practice Material 4, Orbitals having 3 angular nodes and 3 total nodes is (a) 3d ey at o 5p (a) 6d 5, Which ofthe oxides is most basic in nature? (a) Bed (b) MgO (c) ALO; ety Nad 6. Noand Oe are converted to monocations Nf and Of respectively. Which of the following, statement is wrong? sa NE becomes diamagnetic (b) In Of, paramagnetism decreases (o)_ NJ, N-N bond weakens, (d) In Of, the 0-0 bond order increases 7. Which of the following is a polar molecule? (a) SiFa (b) BC iq} CHC (@) CC 8. The oxide, which cannot act as a reducing agent is, (a) SQ2 (b) Cloz ( NOz Nay COz 9, Under which of the following condition is the relation AH = AU + PAV valid for a closed system? ey constant pressure (b) constant temperature (c) constant temperature and pressure (d) constant temperature, pressure and composition. 10. Molar heat ony of water in equilibrium with ice at constant pressure 6) infinity (Q 4050K)K* (@) 75.48 )KAmolt 11. Enthalpy of sublimation of a substance is equal to (a) zero sfaf enthalpy of fusion + enthalpy of vapourisation (b) enthalpy of fusion © (4) twice enthalpy of vapourisation 12. Which of the following has the highest boiling point? fn pentane (b)2-methylbutane (3) 2,2-dimethylpropane (a) n-butane 13. Which of the following can be used as the halide component for Friedel-Crafts reaction? (8) Cholorobenzene (b) Bromobenzene ‘ef Ethyl chloride {d) Choloroethene 14. Which of the following contain acidic hydrogen? (a) n-butane © q-butyne — (c)_-2-butyne (d) 2-butene 15. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A): Sixth period is the longest period in the periodic table.: Select the most appropriate answer from the options given below: (2) Both Aand Rare true and Ris the correct explanation of A () Both Aand Rare true but Ris not the correct explanation of A ey Ais true but Ris false. (a) Ais false but Ris true, 16. Given below are two statements labelled as Assertion (A) and Reason (R), Assertion (A): Decrease in Gibbs energy causes spontaneous reaction. Reason (R): spontaneous reactions are invariably exothermic reactions, Select the most appropriate answer from the options given below: (a) Both Aand Rare true and Ris the correct explanation of A (b) Both Aand Rare true but R is not the correct explanation of A {2 AistruebutRisfalse. — (d)__Ais false but Ris true. 17, Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A): Benzene does not decolourize bromine water: Reason (R): Benzene is stabilized by resonance due to delocalization. Select the most appropriate answer from the options given below: Mf Both Aand Rare true and Ris the correct explanation of A. (b) Both Aand Rare true but Ris not the correct explanation of A ()_ Aistrue but Ris false. (a) Ais false but Ris true. 18. Given below are two statements labelled as Assertion (A) and Reason (R), Assertion (A): Toluene on sulphonation gives m-toluene sulphonic acid. Reason (R): Sulphonation is a reversible reaction, Select the most appropriate answer from the options given below: (@) Both Aand Rare true and Ris the correct explanation of A. (b) Both Aand Rare true but R is not the correct explanation of A. (Ais true but R is false. AU Ais false but Ris true, Sample-6 Vhich of the following contains same number of carbon atoms as are in 6.0 g of carbon (¢ a? 4) 6.0 g Ethane ¥F8.0 g Methane ¢) 21.0 g Propane d) 28.0,CO > Which one of the following sets of ions represents a collection of isoelectronic specle* MET K", Caés, Se, Ch (b) Na*, Ca®*, Se, F Prepared by- Dusmant Kumar Sahu, Lect.-in-Chen mob-637163783610 re iGnited Chemistry Practice Material for XI Annual Exam (c) K+, Ch, Mges, Set (d) Nat, Mg2s, Als, Cl ‘The correct order of first ionization enthalpy among following elements, Be, B, C, N and 0 is {a{BB>C (b) A>C>B (J C>B>A AQJB>C>A The oxidation state of | in H,!O¢ is eit7 (b) +5 ()-1 (d) +1 Which one is strongest acid among following options? (a) CHeECOOH (b) CH2C! (c) CHIC (SCHF.COOH———. terial f XI Annual Exam 7 compoun What is the correct IUPAC name of the following pi Gulls 12 (a) 2-Ethyl-S-methylhex-2-ene (b) 2-Methyl-5-ethylhex s{e}2,5-Dimethylhept-2-ene (d) 3,6-Dimethylhept-S-ene - ‘The most stable carbanion among the following is @) CCH, (b)_HyCO- 2 J : © ei, uh on CH Pure methane can be prepared by {a}Soda lime decarboxylation 14 — (b) Kolbes electrolytic method (c) Wurtz reaction (d) Reduction of alkene with Pd Given below are two statements labelled as assertion (A) and reason (R). Assertion(A): One atomic mass unit is defined as one-twelfth of the mass of one carbon 12 atom. Reason(R): Carbon-12 isotope is the most abundant isotope of carbon and has been chosen as standard Select the most appropriate answer from the options given below. sa-Both A and R are true and Ris the correct explanation of A. b. Both Aand R are true but R is not the correct explanation of A. c. Ais true but Ris false. d. Ais false but R is true. Given below are two statements labelled as assertion (A) and reason (R). Assertion(A): The heat absorbed during the isothermal expansion of an ideal gas agaitst vaccum is zero. Reason(R): The volume occupied by the molecules of an ideal gas is negli 16 Select the most appropriate answer from the options given below. a. Both Aand Rare true and Ris the correct explanation of A. Ne Both Aand Rare true but Ris not the correct explanation of A. GQ true but R is false, d. Ais false but Ris true, Given below are two statements labelled as assertion (A) and reason (R)- 17 Assertion(A): Black body is an ideal body th, frequencies 15 ible. !at emits and absorbs radiations of all Prepared by- Du mob-637 1637836iGnited Chemistry Practice Material for XI Annual Exam LS Reason(R): The frequeney of radiation emitted by a body goes from a lower frequency to higher frequency with an increase in temperature Select the most appropriate answer from the options given below. a. Both A and R are true and R is the correct explanation of A abo Both Aand R are true but R is not the correct explanation of A. © Ais true but Ris false a. Ais false but Ris true. Given below are two statements labelled as assertion (A) and Assertion(A): Energy of resonance hybrid is equal to the avers anonical forms. ason (R). w of energies of all Reason(R): Resonance hybrid cannot be presented by a single structure. Select the most appropriate answer from the options given below. 18 a. Both Aand Rare true and Ris the b. rect explanation of A. Both A and R are true but Ris not the correct explanation of A. c. Ais true but Ris false. Aa Ais false but R is true. Qt The density ofa solution prepared by dissolving 129g of urea in 100g of water is L.15g/ml. The molarity of this solution is, (a)L78M = (b) 102M {e¥2.05M (d) 0.50M Q2 For the reaction Ho(g) + la(g) =2HI(g), the standard tree energy is AG >0 The equilibrium constant (K) would be (ak=0 (W)K>t (KL Ve K A Q3 44g of a colourless oxide of nitrogen occupies 224 ml at STP. The compound N20 (b) NO (N24 (€)NO2 Qt The no. of structural isomers for CoH1a is @3 b)4 WS (ao QS —_ Inwhich pair of species, both species have simitar geometry? (a) COz, Oz (b) NHs, BHs (c) COs*, SOs? UAT SO;?,C1Os Q6 — Theenergies E1 and Ez of two radiations 25 eV and 50 eV respectively.The relation between their wavelength 2 and 42 will be (a)a=% do (D)AL=A2 eFAn=2ke (A) An = Ado 0.7 The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are - 890.3 KJ mol", - 393.5 KJ mol" and ~ 285.8 K] mot" respectively. Enthalpy of formation of CH, will be 45- 74.8 KJ mol (o> 52.27 KJ mol! (c)+74.8K] molt @8f%52.26 KJ molt 08 Ifthe radius of the first Bohr orbit is x,then de-Broglie wavelength of electron in 3" orbit is nearly (a) 3x (b) 9x (0) 2nx Lay Ginx rong the halogens, the correct order of Electron gain enthalpy is Q9 Prepared by. Dusmant Kumar Sahu, Lect-in-Chemistry — mob-6371637836 Page 13,. ee iGnited Chemi: (a)F>Cl>Bro1 (b) F>Cl
t e ()F Brot (d)F iii (b) iP ii> iti>iv (0) iii> iv iv>i> +14 Which of the following arrangements represent increasing oxidation number of if the central atom? UG CrOz" , C1Or,Cr0,2, MnO, (b) ClOx , CrO4, MnO, Cro» (6) CrO>, ClOx, MnOy-, CrO4* (d) CrO?-, MnO, CrOy, ClOy Q45 Assertion: Chemical reactions are generally carried out at constant pressure, (\))__ Reason: We define another state function Gibbs energy, G, which is related to ~ entropy and enthalpy. B Q16 —Assertion(A); A mixture of sodium acetate and sodium propionate forms a buffer solution. (C) Reason (): A buffer solution reacts with small quantities of hydrogen or hydroxyl ions and keeps the pt almost same Q.17, Assertion: The first ionisation enthalpy of Be is greater than that of B, oO Reason: 2p o} lower in energy than 2s i Q.18 Assertion: pi bonds are weaker than sigma bonds, © Reason: pi bonds are formed by the overlapping of pep orbitals along their axes 1 Sample-8 1. “The number of moles of BaCOs which contains 1.5 moles of ox en atoms is [1] i Prepared ‘mob-637 1637836 Page| for XI Annual Exam d iGnited Chemistry Practice Materi ay 05 1 3 (a) 6.02 «1024 2. The electrons of the same orbitals can be distinguished by (a) Principal quantum number A (b) Azimuthal quantum number (¢ySpin quantum number (d) Magnetic quantum number 3. Why the size of an anion is larger than the parent atom? (a) Due to increased repulsion among the electrons. (bp) Due to decrease in effective nuclear charge. (c) Due to increase in effective nuclear charge. (WBoth (a) and (b) 4. Inwhich of the following molecule octet rule is not follow red? (a) NH3 (b) CHs (CO, ayia 5. One mole of which of the following has the highest entropy? (a) Liquid Nitrogen (o)fiydrogen Gas () Mercury (d) Diamond 6. For the chemical reaction 3X (2g) + ¥ (g) = XsY (9) the amount of XsY at equilibrium is affected by (ayTemperature and pressure (b) Pressure only (c) Temperature only (a) Temperature, pressure and catalyst. ‘The oxidation number of Mn is maximum in (a) MnO {b) KeMn0s (J) Mn.0: ayknino, 8. inductive effect involves {oY displacement of ¢ electrons (©) delocalization of o-electrons (a) displacement of r-electrons 49. Which of the following reaction is used to increase the length of the carbon (b) delocalization of r electrons chain? (a) Wolff Kishner reaction (b) Clemmensen reduction (c) Kolhe’s electrolysis (dy Wurtz reaction 10. A sub-shell having n= 6,1 = 2.can accommodate a maximum of (a) 12 electrons (b) 36 electrons, (10 electrons (d) 72 electrons 11. Asystem absorbs 10 kj of heat at constant volume and its temperature rises from, to 37°C. The valueof A U is: (a) 10045 \(bsf 10K (ok (ik Prepared by- 1637836 Page 15 Dusmant Kumar Sahu, Lect.-in-ChemistryiGnited Chemistry Practice Material for XI Annual Exam 12,‘The incorrect statement among the following for a nucleophile is (a Nucleophile is (b) Ammonia is a nucleophile (c) Nucleophiles attack low electrons density sites (a) Nucleophiles are not electron seeking 13. Which of the following compound will exhibit cis-trans isomerism? (a) Butanol (b) But-2-yne (c) 2-Butenol Yah But-2-ene 14, The correct decreasing order of priority for the functional groups of organic compound in the IUPAC system of nomenclature is: (a) -CONHe,-CHO, -SO3H, ‘bY -COOH,-SO3H, (6) -CONH, -SOsH,-COOH, CHO (d) -CONHa, -SO3H,-COOH, -C 15, Given below two statements labelled as Assertion and Reason Assertion: 1.231 has three significant figures. Reason: All numbers right to the decimal point are significant. Select the correct answer from the option given below. Lewis acid (a) Both Assertion and Reason are correct and Reason is the correct explanation for Assertion. (b) Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion (c) Assertion is correct but Reason is incorrect (dyAssertion is incorrect but Reason is correct 16. Given below two statements labelled as Assertion and Reason. Assertion: BF; molecule has zero dipole moment. Reason: F is more electronegative and B-F bonds are polar in nature. Select the correct answer from the option given below. (2) Both Assertion and Reason are correct and Reason is the correct explanation for Assertion. ‘Cof Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion (c) Assertion is correct but Reason is incorrect (d) Assertion is incorrect but Reasoi correct 17. Given below two statements labelled as Assertion and Reason. Assertion: AgcHgeCr (2)20%carbanion (byL%carbocation (eF2"carbocation (d)1°carbanion 11. Arrange the following halogens Fz,Cle Bra,t2 in order of their increasing reactivity with alkanes. GofebeetheeFs (b)Brapedet (os CaCe(s) + CO (2) Given that Ay H® (CaCz) = -14.2 kcal, Ay H? (CO) = -264 keal and Ay H(Ca) = -151.8 kcal (a) $624 kea AtbY LAL x 108 keal (0) 86.24 « 10° (a) 1100 keal 11. An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to: ca | (a) 12PW (b) 6PiV1 Lc¥5PM: @Prv | | 12. A weak acid HX has the dissociation constant 1 * 10°5 M. It forms a salt NaX on reaction With alkali, The degree of hydrolysis of 0.1 M solution of NaX is 0.01% (6) 0.1% (a) 0.15% (a) 0.0001% Prepared by- Dusmant Kumar Sahu, ‘ChemistryiGnited Chemistry Practice Material for XI Annual Exam _ 13, IF equal volumes of 1M KMnO, and 1M K2Cr207 solutions are allowed to oxidize Fe2* in acidic medium. The amount of iron oxidized will be: (a) More with KMnO, 165) More with KoCra0> cao (c) Equal with both oxidising agents (d) Cannot be determined 30, 14. What is the correct IUPAC name of \a¥4-methoxy-2-nitrobenzaldehyde (b) 4-formyl-3-nitro anisole oon (c) 4-methoxy-6-nitrobenzaldehyde (d) 2-formyl-S-methoxy nitrobenzene 15. Assertion (A) : Though the central atom of both NH; and H20 molecules are sp* hybridised, yet H-N-H bond angle is greater than that of H-O-H. Reason (R) : This is because nitrogen atom has one lone pair and oxygen atom has two lonp-airs. wd) Both Aand Rare true and Ris the correct explanation of A (b) Both A and Rare true but R is not the correct explanation of A. (c) Ais true but Ris false. (d) Ais false but R is true. 16. Assertion (A): An aqueous solution of ammonium acetate can act as a buffer. Reason (R) : Acetic acid is a weak acid and NHsOH is a weak base. (a) Both A and R are true and R is the correct explanation of A. ) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false. (4) Ais false but Ris true. 17. Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as oxidising agent. Reason (R) : Oxidation state of manganese changes from +7 to +2 during the reaction Sa Aand Rare true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false. (d) Ais false but R is true. 18. Assertion (A) : Pent- 1- ene and pent- 2- ene are position isomers. Reason (R) : Position isomers differ in the position of functional group or a substituent. 4 Both A and R are true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but R is false (d) Ais false but Ris true. Prepared by- Dusmant Kumar Sahu, Lect.-in-Chemistry mob-6371637836 Page 20 paced ae me” |