FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

(Held On Wednesday 25th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

PHYSICS TEST PAPER WITH SOLUTION

SECTION-A Sol.
1. Electron beam used in an electron microscope, Tsin30
when accelerated by a voltage of 20 kV. has a 60cm
de-Broglie wavelength of o. If the voltage is C
increased to 40 kV. then the de-Broglie 50cm
wavelength associated with the electron beam
would be: mg=20 8×g=80
(1) 30 (2) 90 Taking torque about point C
  T
(3) 0 (4) 0  60 = 20 × 50 + 80 × 100
2 2 2

®
Official Ans. by NTA (4)  3T = 100 + 800
Allen Ans. (4)  = 300 N
Sol. When electron is accelerated through potential 3. A Carnot engine with efficiency 50% takes
difference V, then heat from a source at 600 K. In order to
K.E. = eV increase the efficiency to 70%, keeping the
h h temperature of sink same, the new temperature
  
2m  KE  2meV of the source will be :
(1) 360 K (2) 1000 K
1
   (3) 900 K (4) 300 K
V Official Ans. by NTA (2)
 20 Allen Ans. (2)
  Sol.
0 40
Source

  0 T1 = 600 K
2
2. An object of mass 8 kg is hanging from one
end of a uniform rod CD of mass 2 kg and W
length 1 m pivoted at its end C on a vertical
wall as shown in figure. It is supported by a
cable AB such that the system is in sink
T2
equilibrium. The tension in the cable is : 1
(Take g = 10 m/s2) Initially  
2
A
T2
/ / // / / // / / / // / / // / / / // / / // / / / // / / // / / / // / / // / / / // / /

But  1
T1
30° B 1 T
 1 2
C D 2 600
90° T2 1
   T2 = 300 K
600 2
60 cm 40 cm Now efficiency is increased to 70% and T2 = 300
K, Let temp of source T1 = T
Wall
7 300
8 kg  1
10 T
(1) 240 N (2) 90 N 300 7
(3) 300 N (4) 30 N  1
T 10
Official Ans. by NTA (3) 300 3
Allen Ans. (3)    T = 1000 K
T 10

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4. T is the time period of simple pendulum on the GM g
  
earth's surface. Its time period becomes x T R 3 R
when taken to a height R (equal to earth's
2 R
radius) above the earth's surface. Then, the Now T   2
value of x will be:  g
(1) 4 (2) 2
6400  103
1 1  T  2  3.14 
(3) (4) 10
2 4
Official Ans. by NTA (2)  2  3.14  800sec  1 hour 24 minutes
Allen Ans. (2) 6. A car travels a distance of 'x' with speed V1 and
Sol. At surface of earth time period then same distance 'x' with speed V2 in the
same direction. The average speed of the car is:
T  2 v1v 2 v1  v2
g (1) (2)
2  v1  v 2  2
At height h = R
g g 2x 2v1v2
g'   (3) (4)
v1  v2 v1  v2

®
2 4
 h
1  R  Official Ans. by NTA (4)
  Allen Ans. (4)
x x
 xT  2 A C
g / 4 Sol. v1 B v2
Total displacement
Average velocity 
 xT  2  2 Total time
g
xx 2v1v2
 xT = 2T  x = 2  
x x v1  v2
5. Assume that the earth is a solid sphere of 
uniform density and a tunnel is dug along its v1 v2
diameter throughout the earth. It is found that 7. A parallel plate capacitor has plate area 40cm2
when a particle is released in this tunnel, it and plates separation 2 mm. The space
executes a simple harmonic motion. The mass between the plates is filled with a dielectric
of the particle is 100 g. The time period of the medium of a thickness 1 mm and dielectric
motion of the particle will be (approximately) constant 5. The capacitance of the system is :
(take g = 10 ms-2,radius of earth = 6400 km ) 3
(1) 24 0 F (2) 0 F
(1) 24 hours 10
(2) 1 hour 24 minutes 10
(3) 1 hour 40 minutes (3) 0 F (4) 10 0 F
3
(4) 12 hours Official Ans. by NTA (3)
Official Ans. by NTA (2) Allen Ans. (3)
Allen Ans. (2) Sol.
Sol.

air
x

A
t
d
This can be seen as two capacitors in series
Let at some time particle is at a distance x from combination so
centre of Earth, then at that position field
GM 1 1 1
E x  
R3 Ceq C1 C2
 Acceleration of particle
1 1
GM  
a x K 0 A 0 A
R3 t dt

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 t dt So A-(IV), B-(III), C-(I), D- (II)
 
K 0 A 0 A 10. In an LC oscillator, if values of inductance and
capacitance become twice and eight times,
1 103 1 103 respectively, then the resonant frequency of
 
50 40  104 0 40  104 oscillator becomes x times its initial resonant
1 1 1 frequency 0. The value of x is:
  (1) 1/4 (2) 16
Ceq 20 0 4 0
(3) 1/16 (4) 4
20  4 0 10 0 Official Ans. by NTA (1)
Ceq   F
24 3 Allen Ans. (1)
8. The root mean square velocity of molecules of Sol. The resonance frequency of LC oscillations circuit
gas is is
(1) Proportional to square of temperature (T2). 1
0 
(2) Inversely proportional to square root of LC
1 L  2L
temperature .
T C  8C

®
(3) Proportional to square root of temperature T . 1 1
 
(4) Proportional to temperature (T). 2L  8C 4 LC
Official Ans. by NTA (3) 
Allen Ans. (3)  0
4
Sol. The rms speed of a gas molecule is 1
3RT So x 
VRMS  4

VRMS  T
M
11. The ratio of the density of oxygen nucleus  O
16
8

9. Match List I with List II and helium nucleus  He  is

4
2
List – I List - II (1) 4:1 (2) 8:1
A Surface tension I. Kg m-1 s-1 (3) 1:1 (4) 2:1
B Pressure II. Kg ms-1 Official Ans. by NTA (3)
C Viscosity III. Kg m-1 s-2 Allen Ans. (3)
D Impulse IV. Kg s-2 Sol. Nuclear density is independent of mass number
Choose the correct answer from the options given Au
below : As nuclear density 
4
(1) A-IV, B-III, C- II, D- I  R3
3
(2) A-IV, B-III, C-I, D-II 1
(3) A-III, B-IV, C-I, D-II
Also , R  R 0 A3
(4) A-II, B-I, C-III, D-IV
3 3
Official Ans. by NTA (2) And R  R 0 A
Allen Ans. (2)
Au
F MLT 2  Nuclear density 
Sol. (A) Surface Tension    ML1 T 2 4 3
R A
L 3 0
 Kgs2 (IV) 3u
Nuclear density 
2
F MLT 4 R 30
(B) Pressure = 
A L  Nuclear density is independent of A
 kg m 1s2 (III) 12. A message signal of frequency 5 kHz is used
to modulate a carrier signal of frequency 2
F MLT 2 MHz. The bandwidth for amplitude
(C) Viscosity =  
 dV   1 
2 LT modulation is:
A  L  
 dz   L  (1) 5 kHz (2) 20 kHz
  (3) 10 kHz (4) 2.5 kHz
 ML1T 1  kg m 1 s1 (I) Official Ans. by NTA (3)
Allen Ans. (3)
(D) Impulse   Fdt  MLT 2  T Sol. Given
 MLT 1  Kg ms1 (II) Signal frequency fm  5kHz

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 Carrier wave frequency fc  2MHz 15. Math List I with List II
fc  2000KHz List – I List – II
(Current configuration) (Magnetic field at
The resultant signal will have band width of point O)
frequency given by A I.  I
 fc  fm    fc  fm   B0  0   2 
r
O
4 r
I I
  2000  5    2000  5  kHz
B I II. 0 I
 10 kHz B0 
O 4 r
13. All electromagnetic wave is transporting I
r
energy in the negative z direction. At a certain
C III 0 I
point and certain time the direction of electric
. B0 
2 r
  1
field of the wave is along positive y direction.
What will be the direction of the magnetic
field of the wave at that point and instant? D O
IV 0 I
(1) Positive direction of x
I
r
I B0 
4 r
  1
(2) Positive direction of z

®
(3) Negative direction of x Choose the correct answer from the option given
(4) Negative direction of y below:
Official Ans. by NTA (1) (1) A-III, B-IV, C-I, D-II
Allen Ans. (1) (2) A-I, B-III, C-IV, D-II
Sol. As , poynting vector (3) A-III, B-I, C-IV, D-II
S  E H (4) A-II, B-I, C-IV, D-III
Official Ans. by NTA (3)
Given energy transport = negative z direction Allen Ans. (3)
Electric field = positive y direction Sol.
   
 kˆ   ˆj   ˆi 
  (A)
c
Hence according to vector cross product magnetic
field should be positive x direction. r
O
a e
14. In Young's double slits experiment, the I b d I
position of 5th bright fringe from the central 0 I
Bab  (out of the plane)
maximum is 5 cm. The distance between slits 4 r
and screen is 1 m and wavelength of used  I
Bbcd  0  2  (in the plane)
monochromatic light is 600 nm. The 4 r
separation between the slits is: 0 I
Bde  (out of the plane)
(1) 60 m (2) 48 m 4 r
(3) 12 m (4) 36 m Hence magnetic field at O is
 I  I  I
Official Ans. by NTA (1) B0   0  0  2   0
Allen Ans. (1) 4 r 4 r 4 r
Sol. Given 0 I
B0    1 ………. (III)
D = 1m 2 r
  600  109 m (B)
b I a
n=5
n D O
As y nth  c
r
d
d e
5  600  10 9  1
I
  5  10 2 0 I
d Bab  (out of the plane)
4 r
5  600  10 9  1  I
 d  60  10 6 m Bbcd  0   (out of the plane)
2
5  10 4 r
 d = 60 m 0 I
Bde  (out of the plane)
4 r
Hence magnetic field at O is
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 0 I 0 I  I Sol. Theory based
B0      0 Photodiodes are operated in reverse bias condition.
4 r 4 r 4 r
 I For P-N junction current in forward bias
B0  0   2  …. (I)  for V  V0  is always greater than current in
4 r
(C) reverse bias  for V  Vz  .
e
I Hence Assertion if false but Reason is true
d 17. A solenoid of 1200 turns is wound uniformly
O
c in a single layer on a glass tube 2 m long and
r
a 0.2 m in diameter. The magnetic intensity at
b I the center of the solenoid when a current of 2
0 I
Bab  (in the plane) A flows through it is:
4 r
(1) 2.4 × 103 A m-1
 I
Bbcd  0   (in the plane) (2) 1.2 × 103 A m-1
4 r
(3) 1 A m-1
Bde  0 (at the axis)

®
(4) 2.4 × 10-3 A m-1
Hence magnetic field at O is Official Ans. by NTA (2)
 I
B0  0 1    …. (IV) Allen Ans. (2)
4 r Sol. Magnetic field at centre inside the solenoid is
(D) given by
b O d e
a r B = 0nI
I I So magnetic intensity at centre
c B  1200 
Bab  0 (at the axis) H
0
 nI   2
 2 
0 I
Bbcd    (out of the plane) H = 1.2 ×103 Am–1
4 r 18. A uniform metallic wire carries a current 2 A.
Bde  0 (at the axis)
when 3.4 V battery is connected across it. The
Hence magnetic field at O is mass of uniform metallic wire is 8.92×10–3 kg.
 I
B0  0 …. (II) density is 8.92 ×103 kg/m3 and resistivity is
4r
1.7 × 10–8  –m. The length of wire is :
16. Given below are two statements : one is (1) l =6.8 m (2) l = 10 m
labeled as Assertion A and the other is labeled (3) l = 5 m (4) l = 100 m
as Reason R Official Ans. by NTA (2)
Assertion A: Photodiodes are used in forward Allen Ans. (2)
bias usually for measuring the light intensity. Sol. I = 2A
Reason R: For a p-n junction diode, at applied V = 3.4 V
voltage V the current in the forward bias is Using Ohm’s Law
more than the current in the reverse bias for 3.4
R  1.7 
Vz   V  V0 where Vo is the threshold 2
voltage and Vz is the breakdown voltage. L
1.7 
In the light of the above statements, choose the A
correct answer from the options given below 1.7  A 
L
(1) Both A and R are true and R is correct 
explanation A
M = (density volume)
(2) Both A and R are true but R is NOT the correct
8.92  10 3
explanation A Volume   10 6
3
(3) A is false but R is true 8.92  10

 
(4) A is true but R is false 1.7 1.7
Official Ans. by NTA (3) L2  10 6   10 2
 1.7
Allen Ans. (3)
L=10m

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19. A bowl filled with very hot soup cools from 20 2
98°C to 86°C in 2 minutes when the room tan  
40  10
temperature is 22°C. How long it will take to tan = 1
cool from 75°C to 69°C ? 
 
(1) 2 minutes (2) 1.4 minutes 4
(3) 0.5 minute (4) 1 minute SECTION-B
Official Ans. by NTA (2) 21. A ray of light is incident from air on a glass
Allen Ans. (2)
Q plate having thickness 3 cm and refractive
Sol.  K  T  T0 
t
index 2 . The angle of incidence of a ray is
Q
t

 K Tavg  T0  equal to the critical angle for glass-air
ms  12  98  86  interface . The lateral displacement of the ray
(i)  K   22 
2  2  when it passes through the plate is___×10–
K  98  86 
6   22  2
cm. (given sin 15° = 0.26)

®
ms  2 
K Official Ans. by NTA (52)
6
ms
70  …………(i) Allen Ans. (52)
ms  6  75  69  Sol.
(ii)  K   22 
t  2 
c
6 K
  50  …………(ii)
t ms
(ii)  (i) 
6 50
 = 2
t  6  70 t= 3

7 
t   1.4 min
5
20. A car is moving with a constant speed of 20
m/s in a circular horizontal track of radius 40 c
m. A bob is suspended from the roof of the car
by a massless string. The angle made by the
1
string with the vertical will be : (Take g = 10 sin c 
m/s2) 2
  c = 45°
(1) (2)
6 2 sin c   sin 
 
(3) (4) 1
4 3  2sin
Official Ans. by NTA (3) 2
Allen Ans. (3)
 = 30°
Sol.
Lateral displacement:
T

x  t sin  i  r  sec r
2
mv
R
x  3 sin  45  30  sec30
mg
T cos  mg  2 
x  3  0.26   
 3
mv 2
T sin  
R X = 0.52 cm
v2 x  52  10 2 cm
tan  
Rg

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22. In the given circuit, the equivalent resistance L
Y
between the terminal A and B is_____. A
62.8  102
Y
 
2
 2  103

Y  5  10 4 N / m 2
Official Ans. by NTA (10.00 )
Allen Ans. (10) 24. An object of mass 'm' initially at rest on a
Sol.
smooth horizontal plane starts moving under
the action of force F = 2N. In the process of its
linear motion, the angle  (as shown in figure)
between the direction of force and horizontal
Both 4 resistance gets short. varies as  = kx, where k is a constant and x is

®
Remove the resistors that have no current.
3 2 the distance covered by the object from its
A
initial position. The expression of kinetic
n
2 energy of the object will be E  sin  . The
k

B
value of n is___.
6
R eq  3   2 || 2   6
R eq  3  1  6
R eq  10 
23. As shown in the figure, in an experiment to Official Ans. by NTA (2)
determine Young's modulus of a wire, the
Allen Ans. (2)
extension-load curve is plotted. The curve is a
straight line passing through the origin and Sol.
makes an angle of 45° with the load axis. The
length of wire is 62.8 cm and its diameter is 4
mm. The Young's modulus is found to be x ×
104 Nm-2.
The value of x is _____.

F cos  ma
mvdv
2 cos  kx  
dx
Official Ans. by NTA (5 ) v x
Allen Ans. (5)  vdv  2 cos  kx  dx
Sol. 0 0
L
mv 2 2
 sin kx
2 k
45° 2
F K.E.  sin 
From graph : k
F = L n=2
FL
Y
AL

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25. The wavelength of the radiation emitted is 0 mR 2
when an electron jumps from the second Sol. I cm 
2
excited state to the first excited state of 2
hydrogen atom. If the electron jumps from the mR2  2R  17
IAB   m   mR 2
third excited state to the second orbit of the 2  3  18
hydrogen atom, the wavelength of the I AB 17
20   x  17
radiation emitted will be 0 . The value of x I cm 9
x
is_____. 27. The distance between two consecutive points
Official Ans. by NTA (27) with phase difference of 60° in a wave of
Allen Ans. (27) frequency 500 Hz is 6.0 m. The velocity with
Sol. _____________ n = 4 which wave is traveling is______ km/s
_____________ n = 3
Official Ans. by NTA (18 )
_____________ n = 2
_____________ n = 1 Allen Ans. (18)
2
Sol.   x

®
Second excited state  first excited state 
n = 3 n =2  2
hc  1 1 
  6m 
 13.6   3 
 .......(i)
0 2 2
32     36m
Third excited state second orbit V  f   500Hz  36m 
n=4n=2
= 18000 m/s = 18 km/s
hc  1 1 
 13.6    .......(ii) 28. A uniform electric field of 10 N/C is created
 200 / x  2 2
42 
between two parallel charged plates (as shown
(ii)  (i)
in figure). An electron enters the field
1 1
 symmetrically between the plates with a
x 22 42
 kinetic energy 0.5 eV. The length of each plate
20 1 1
 2
2 2
3 is 10 cm. The angle () of deviation of the path
x = 27 of electron as it comes out of the field is ___
26. ICM is moment of inertia of a circular disc (in degree).
about an axis (CM) passing through its center
and perpendicular to the plane of disc. IAB is
it's moment of inertia about an axis AB
perpendicular to plane and parallel to axis CM
2
at a distance R from center. Where R is the
3
radius of the disc. The ratio of IAB and ICM is Official Ans. by NTA (45)
x: 9. The value of x is___. Allen Ans. (45 )
C A
1 e
Sol. 0.5e  mv2x  v x 
2 m
e
R Along x L  v x t  t
m
eE
Along y v y  t
m
2R
3 vy e
dividing E  Ev x
M B
L m
vy
Official Ans. by NTA (17)  Tan   E  L  10  0.1  1
vx
Allen Ans. (17)
  45
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29. An LCR series circuit of capacitance 62.5 nF
and resistance of 50 . is connected to an A.C.
source of frequency 2.0 kHz. For maximum
value of amplitude of current in circuit, the
value of inductance is ______mH.
(take 2 = 10)
Official Ans. by NTA (100)
Allen Ans. (100)
1
Sol. f 
2 LC
1
2000 Hz 
2 L  62.5  10 9
1
L  0.1H 100mH
4  2000  62.5  10 9
2 2

30. If P  3iˆ  3ˆj  2kˆ and Q  4iˆ  3ˆj  2.5kˆ then,

®
The unit vector in the direction of P  Q is
1
x
 
3iˆ  ˆj  2 3kˆ . The value of x is
Official Ans. by NTA (4)
Allen Ans. (4)
ˆi ˆj kˆ
ˆi ˆj
Sol. P  Q  3 3 2  3   3kˆ
2 2
4 3 2.5

PQ 1 ˆi ˆj 
   3   3kˆ 
P  Q 2  2 2 



1
4
 3 ˆi  ˆj  2 3kˆ  x=4

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 FINAL JEE–MAIN EXAMINATION – JANUARY, 2023
(Held On Wednesday 25th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A

Rate of reaction
31. The compound which will have the lowest rate
towards nucleophilic aromatic substitution on (d)
treatment with OH– is
Cl Cl O Substrate concentration
NO2
(1) (2)
(1) b (2) c (3) d (4) a
NO2 NO2 Official Ans. by NTA (2)
Cl Allen Ans. (2)

®
Cl
(3) NO2 (4) Sol. Fact base.
NO2 33. Identify the product formed (A and E)
Me
Official Ans. by NTA (4)
Br2
Allen Ans. (4) A Sn/HCl B NaNO /HCl
273-278K
C H PO /H O D (i) KMnO /KOH E
2 3 2 2
+
4

(ii) H O 3

Sol. Electron withdrawing groups are highly ineffective NO 2

at meta position in nucleophilic aromatic Me COOH
Br Br
substitution reactions.
(1) A = ,E =
Br Br
NO 2
Hence compound Cl will have lowest
Me COOH
Br Br
NO2
(2) A = ,E =
rate in nucleophilic aromatic substitution.
NO 2
32. The variation of the rate of an enzyme catalyzed
Me Me
reaction with substrate concentration is correctly Br Br
represented by graph (3) A = ,E =
Rate of reaction

NO 2
Me COOH
(a) Br Br
(4) A = ,E =
O Substrate concentration
NO 2 OH
Rate of reaction

Official Ans. by NTA (2)

Allen Ans. (2)
(b)
Sol.
Me Me Me Me
O Substrate concentration Br2
Br
Sn/HCl
Br
NaNO2/HCl
Br
Rate of reaction

273-278K

NO 2 NO 2 NH 2 N2 +Cl–
(A) (B) (C)

H3PO2/H2 O

(c) COOH Me
Br Br
(i) KMnO4/KOH
(ii) H3 O+

O Substrate concentration (E) (D)

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34. Match List I with List II Allen Ans. (Bonus)
List I List II Sol. X 1 Y 1 1
4  11 6 
8 3 2
Colour imparted to
Elements
the flame
 X1 Y1
A K I Brick Red 1
2
B Ca II Violet
C Sr III Apple Green  X2 Y1
D Ba IV Crimson Red 3

Choose the correct answer from the options given

 X1.5 Y1
below:
(1) A-II, B-I, C-III. D-IV  X3 Y2
(2) A-II, B-IV, C-I. D-III 37. The radius of the 2nd orbit of Li2+ is x. The
(3) A-II, B-I, C-IV. D-III expected radius of the 3rd orbit of Be3+ is
(4) A-IV, B-III, C-II. D-I

®
9 4
Official Ans. by NTA (3) (1) x (2) x
4 9
Allen Ans. (3)
27 16
Sol. (3) x (4) x
16 27
Element Colour in flame test Official Ans. by NTA (3)
K Violet
Ca Brick red Allen Ans. (3)
Sr Crimson red Sol. Li2+ Be3+
Ba Apple green
2 2 4k 32
35. Reaction of thionyl chloride with white phosphorus r2 = x = k   r3 = y = k 
3 2 4
forms a compound [A], which on hydrolysis gives
[B], a dibasic acid. [A] and [B] are respectively y 9 3 27
  
(1) P4O6 and H3PO3 x 4 4 16
(2) PCl3 and H3PO3
(3) PCl5 and H3PO4 27
y x
(4) POCl3 and H3PO4 16
Official Ans. by NTA (2)
38. Which of the following conformations will be the
Allen Ans. (2)
most stable ?
Sol. P4  8SOCl2  4PCl3  4SO2  2S2Cl2
[A] Me

H H Me
PCl3  3H2O  H3PO3  3HCl Me
[B]
(1) (2)
H H
36. A cubic solid is made up of two elements X and Y. H H
Atoms of X are present on every alternate corner Me H H
rd
Me
1
and one at the center of cube. Y is at of the H Me Me
3
H
total faces. The empirical formula of the compound (3) (4)
is H H
H Me
(1) X2Y1.5 (2) X2.5Y H H H
(3) XY2.5 (4) X1.5Y2 Official Ans. by NTA (1)
Official Ans. by NTA (2) Allen Ans. (1)
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 Me CH2 OH

H H O
H H
H
Sol. Conformation has lowest OH H
H H Sol. Structure
OH OH

Me H OH
vanderwaal and torsional strain. Hence it must be [A]
most stable.
Represents -D-(+) Glucopyranose
39. Match items of Row I with those of Row II.
CH2OH
Row I :
CH2OH O
H OH
O H
H H
(P) H
Structure OH H
OH H OH H
OH

®
OH
H OH H OH
CH2OH [B]
O
H OH
(Q) H Represents -D-(+) Glucopyranose
OH H
H
OH HOCH2 O
OH CH2OH
H
HOCH2 O CH2OH
(R) Structure H H OH H
H H OH OH

OH H OH H
[C]
HOCH2 O OH
(S)
H H HO CH2OH Represents -D-(–) Fructofuranose

OH H HOCH2 O
OH
Row II :
(i) -D-(–) Fructofuranose. Structure H H HO CH2OH

(ii) -D-(–) Fructofuranose

(iii) -D-(-) Glucopyranose. OH
[D]
H

(iv) -D-(-) Glucopyranose

Correct match is Represents -D-(–) Fructofuranose
(1) Piv, Qiii, Ri, Sii (from the given options best answer is D)
(2) Pi, Qii, Riii, Siv
(3) Piii, Qiv, Rii, Si
(4) Piii, Qiv, Ri, Sii
Official Ans. by NTA (4)
Allen Ans. (4)

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40. Given below are two statements : one is labelled as (2) 2FeS + 3O2  2FeO + 2SO2
Assertion A and the other is labelled as Reason (3) CaO + SiO2  CaSiO3
R: (4) FeO + SiO2  FeSiO3
Assertion A : Acetal/Ketal is stable in basic Official Ans. by NTA (3)
medium. Allen Ans. (3)
Reason R : The high leaving tendency of alkoxide
Sol. CuFeS2  O 2 
Partial roasting

ion gives the stability to acetal/ketal in basic
medium. Cu2S +FeO + SO2 + FeS  Cu 2O
very small
In the light of the above statements, choose the very small

correct answer from the options given below:

Cu 2S  O2  Cu 2O  SO2
(1) A is true but R is false
(2) A is false but R is true FeS  O2  FeO  SO2
(3) Both A and R are true and R is the correct

®
explanation of A FeO  SiO2  FeSiO3
(4) Both A and R are true but R is NOT the correct
explanation of A No formation of calcium silicate (CaSiO3) in
Official Ans. by NTA (1) extraction of Cu.
Allen Ans. (1) ?
PhCOOH + PhCH 2OH
Sol. For Assertion :Acetal and ketals are basically 43. P Q R
ethers hence they must be stable in basic medium
The correct sequence of reagents for the
but should break down in acidic medium.
preparation of Q and R is :
Hence assertion is correct. (1) (i) Cr2O3, 770 K, 20 atm ;
(ii) CrO2Cl2, H3O+ ;
For reason: Alkoxide ion (RO–) is not considered a
good leaving group hence reason must be false. (iii) NaOH ;
(iv) H3O+
41. Inert gases have positive electron gain enthalpy. Its (2) (i) CrO2Cl2, H3O+ ; (ii) Cr2O3, 770 K, 20 atm;
correct order is (iii) NaOH ; (iv) H3O+
(1) Xe < Kr < Ne < He (3) (i) KMnO4, OH– ; (ii) Mo2O3, A; (iii) NaOH ;
(2) He < Ne < Kr < Xe (iv) H3O+
(3) He < Xe < Kr < Ne (4) (i) Mo2O3,  ; (ii) CrO2Cl2, H3O+ ; (iii) NaOH ;
(4) He < Kr < Xe < Ne (iv) H3O+
Official Ans. by NTA (3) Official Ans. by NTA (1)
Allen Ans. (3) Allen Ans. (1)
Sol. Sol. CH3 CHO

Element egH[KJ/mol] (i) Cr2 O3 , 770K, 20 atm (ii) CrO2Cl2

He +48 (P) H3O+
(iii) NaOH Cannizaro
Ne +116 Reaction
Kr +96 COONa CH2OH
Xe +77 +
From NCERT
(iv) H3O+
So, order is Ne > Kr >Xe> He
COOH CH2OH
42. Which one of the following reactions does not
occur during extraction of copper ? +
(Q) (R)
(1) 2Cu2S + 3O2  2Cu2O + 2SO2

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44. The correct order in aqueous medium of basic Sol. An antibiotic should not promote growth or
strength in case of methyl substituted amines is : survival of microorganisms. Antibiotics should
(1) Me2NH > MeNH2 > Me3N > NH3 inhibit growth of microbes.
(2) Me2NH > Me3N > MeNH2 > NH3 47. Compound A reacts with NH4Cl and forms a
(3) NH3 > Me3N > MeNH2 > Me2NH compound B. Compound B reacts with H2O and
(4) Me3N > Me2NH > MeNH2 > NH3 excess of CO2 to form compound C which on
Official Ans. by NTA (1)
passing through or reaction with saturated NaCl
Allen Ans. (1)
solution forms sodium hydrogen carbonate.
Sol. In aqueous medium basic strength is dependent on
electron density on nitrogen as well as solvation of Compound A. B and C, are respectively.
cation formed after accepting H+. After considering (1) CaCl2, NH3, NH4HCO3
all these factors overall basic strength order is (2) CaCl2, NH4+, (NH4)2CO3
Me2NH > MeNH2 > Me3N > NH3 (3) Ca(OH)2, NH3, NH4HCO3

®
45. '25 volume' hydrogen peroxide means
(4) Ca(OH)2, NH4+, (NH4)2CO3
(1) 1 L marketed solution contains 250 g of H2O2.
Official Ans. by NTA (3)
(2) 1 L marketed solution contains 75 g of H2O2.
(3) 100 mL marketed solution contains 25 g of Allen Ans. (3)
H2O2. Sol. Ca  OH 2  2NH 4Cl 

 2NH3  CaCl2  2H 2O
(A) (B)
(4) 1 L marketed solution contains 25 g of H2O2.
Official Ans. by NTA (2)
Allen Ans. (2)
NH3  H2O  CO2 
 NH4 HCO3
(B) (exc) (C)
Sol.
Volume = 11.35 × M
NH4 HCO3  NaCl 
 NaHCO3   NH4Cl
(C)
Strength
48. Some reactions of NO2 relevant to photochemical
25
M M smog formation are
11.35
Sunlight
NO 2 X +Y
g/L = 25 × 34/11.35 A
B
= 74.889
Identify A, B, X and Y
46. Which of the following statements is incorrect for (1) X = [O], Y = NO, A = O2, B = O3
antibiotics?
(2) X = N2O, Y = [O], A = O3, B = NO
(1) An antibiotic must be a product of metabolism.
1
(2) An antibiotic is a synthetic substance produced (3) X = O2, Y = NO2, A = O3, B = O2
2
as a structural analogue of naturally occurring
(4) X = NO, Y = [O], A = O2, B = N2O3
antibiotic.
(3) An antibiotic should promote the growth or Official Ans. by NTA (1)
survival of microorganisms. Allen Ans. (1)
(4) An antibiotic should be effective in low Sol.
concentrations. X Y
Sun light
Official Ans. by NTA (3) NO 2 [O] + NO
Allen Ans. (3) O2 A
O3
B

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49. Match the List-I with List-II : SECTION-B

Cations Group reaction 51. An athlete is given 100 g of glucose (C6H12O6) for
P  Pb2+, Cu2+ (i) H2S gas in presence of dilute HCl energy. This is equivalent to 1800 kJ of energy.
Q  Al , Fe
3+ 3+ (ii) (NH4)2CO3 in presence of NH4OH The 50% of this energy gained is utilized by the
R  Co , Ni
2+ 2+ (iii) NH4OH in presence of NH4CI
athlete for sports activities at the event. In order to
S  Ba , Ca
2+ 2+ (iv) H2S in presence of NH4OH
avoid storage of energy, the weight of extra water
(1) Pi, Qiii, Rii, Siv he would need to perspire is_______g (Nearest
(2) Piv, Qii, Riii, Si integer)
(3) Piii, Qi, Riv, Sii
Assume that there is no other way of consuming
(4) Pi, Qiii, Riv, Sii
stored energy.
Official Ans. by NTA (4)
Given : The enthalpy of evaporation of water is 45

®
Allen Ans. (4)
Sol. kJ mol–1
Cations Group No. Group reagent
Molar mass of C, H & O are 12. 1 and 16 g mol–1.
Pb+2 ,Cu+2 II H2S(g) in presence of
dilHCl Official Ans. by NTA (360)
Al+3, Fe+3 III NH4OH in presence of
NH4Cl Allen Ans. (360)
CO+2, Ni+2 IV H2S in presence of
NH4OH Sol. C6H12O6(s) + 6O2→ 6CO2(g) + 6H2O(l)
+2 +2
Ba , Ca V (NH4)2CO3 in presence Extra energy used to convert H2O(l) into H2O(l)
of NH4OH into H2O(g)
1800
50. In the cumene to phenol preparation in presence of =  900kJ
2
air, the intermediate is
O
 900  n H2 O  45
O CH3
900
n H2 O   20 mole
(1) 45
WH2O  20  18  360 g
O
52. A litre of buffer solution contains 0.1 mole of each
(2) of NH3 and NH4Cl. On the addition of 0.02 mole
of HCl by dissolving gaseous HCl, the pH of the
solution is found to be _________× 10–3 (Nearest
(3)
integer)
O–O–H
[Given : pKb(NH3) = 4.745
(4)
log 2 = 0.301
Official Ans. by NTA (4)
log 3 = 0.477
Allen Ans. (4)
H3 C CH3 H3 C CH3 T = 298 K]
C–H C–O–O–H
Official Ans. by NTA (9079)
Sol. O2/Air

Cumene
hv Allen Ans. (9079)
Cumene hydroperoxide
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Sol. In resultant solution 
If we assume graph between and C
C
n NH3  0.1  0.02  0.08

nNH4Cl  nNH  0.1  0.02  0.12 C

Slope = 0
4

[NH 4 ]
pOH = pKb + log
[NH 3 ]
C
0.12
= 4.745  log
0.08 Assuming  vs C graph

3 RT 0.083  300
= 4.745  log Slope =   6  10 4
2 M M

®
= 4.745 + 0.477 – 0.301
0.083  300 830  300
 M 
pOH = 4.921 6  10 4 6

pH = 14 – pH = 41,500 gm/mole
= 9.079
54. How many of the following metal ions have
53. The osmotic pressure of solutions of PVC in
similar value of spin only magnetic moment in
cyclohexanone at 300 K are plotted on the graph.
gaseous state ?___________
The molar mass of PVC is___________g mol–1
(Nearest integer) (Given: Atomic number : V, 23 ; Cr, 24 ; Fe, 26 ;
Ni, 28)


C V3+. Cr3+, Fe2+, Ni3+
(Atm/g L–1 )

Official Ans. by NTA (2)

C(g L– 1)
Allen Ans. (2)
(Given : R = 0.083 L atm K–1 mol–1)

Official Ans. by NTA (41500) Sol.  s  n(n  2)BM (n=no. of unpaired electrons)

Allen Ans. (Bonus/41500)

n
 W / M
Sol.   M'RT   RT V3+ : [Ar] 3d24s0 2
 V 

Cr3+ : [Ar] 3d34s0 3

 W  1   RT 
       RT  C 
 V   M  M 
Fe2+ : [Ar] 3d64s0 4
 RT
   f(c) Ni3+ : [Ar] 3d74s0 3
C M

Cr3+& Ni3+ have same value of s

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55. The density of a monobasic strong acid (Molar Sol. t1/2 = T50 = 30 min

mass 24.2 g mol) is 1.21 kg L. The volume of its

T75 = 2t1/2 = 30 × 2 = 60 min
solution required for the complete neutralization
57. The total number of lone pairs of electrons on
of 25 mL of 0.24 M NaOH is_____________×
oxygen atoms of ozone is_____
–2
10 mL (Nearest integer)

Official Ans. by NTA (6)

Official Ans. by NTA (12)
Allen Ans. (6)
Allen Ans. (12)

Sol. (Total no, of lone pairs on oxygen atoms = 6

®
Sol. millimole of NaOH = 0.24 × 25

 millimole of acid = 0.24 × 25

 mass of acid = 0.24 × 25 × 24.2 mg

58. In sulphur estimation. 0.471 g of an organic
for pure acid, compound gave 1.4439 g of barium sulphate.

w
V ; (d  1.21 kg / L  1.21 g / ml) The percentage of sulphur in the compound
d
is_____________(Nearest Integer)
0.24  25  24.2
V   10 3
1.12
(Given: Atomic mass Ba: 137 u: S: 32 u, O: 16 u )
= 120 × 10-3 ml
Official Ans. by NTA (42)
= 12 × 10-2 ml

56. For the first order reaction A  B Br the half life Allen Ans. (42)

is 30 mm. The time taken for 75% completion of

the reaction is_____mm. (Nearest mteger) Sol

32 weight of BaSO4formed
Given : log 2 = 0.3010 %sulphur   100
233 weight of organic compound

log 3 = 0.4771
32 1.4439
  100
233 0.471
log 5 = 0.6989
= 42.10
Official Ans. by NTA (60)
Nearest integer 42
Allen Ans. (60)

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59. The number of paramagnetic species from the 60. Consider the cell
following is_____.
Pt(s) H2 (s)(1atm) H (aq,[H ]  1) Fe3 (aq),Fe2 (aq) Pt(s)
[Ni(CN)4]2–, [Ni(CO)4], [NiCl4]2–

[Fe(CN)6]4–, [Cu(NH3)4]2+ Given : EFe3 /Fe2  0.771V and E   0V,T  298K

1
H / H2
2
[Fe(CN)6]3– and [Fe(H2O)6]2+
If the potential of the cell is 0.712 V the ratio of
Official Ans. by NTA (4)
concentration of Fe2+ to Fe2+ is________(Nearest
Allen Ans. (4)
integer)
3d8
2
Sol.  Ni  CN 4  : Ni 2  : Official Ans. by NTA (10)

Allen Ans. (10)

diamagnetic

®
1
–
Sol. H 2 (g)  Fe3 (aq.) 
 H  (aq)  Fe 2  (aq.)
CN : strong field ligand 2

3d10 0.059 [Fe 2  ]

: E  Eo  log
 Ni  CO 4  : Ni  diamagnetic 1 [Fe3 ]

3d8 0.059 [Fe2  ]

 0.712  (0.771  0)  log
 NiCl4  :
2 2
: Ni  paramagnetic 1 [Fe3 ]

Cl– : weak field ligand [Fe2  ] (0.771  0712)

 log  1
[Fe3 ] 0.059
3d6
4
 Fe  CN 6  : Fe 2 :
diamagnetic [Fe2  ]
  10
[Fe3 ]
–
CN : strong field ligand

[Cu(NH3)4]+2 : Cu+2  one unpaired electron :

paramagnetic
3d5
[Fe(CN)6]3– : Fe+3 : :
paramagnetic, –CN : strong field ligand

3d6
2+ 2+ :
[Fe(H2O)6] : Fe :
paramagnetic H2O : Weak field ligand

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 Final JEE-Main Exam January, 2023/25-01-2023/Morning Session

FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

(Held On Wednesday 25th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

r r r r r r r r
SECTION-A (a ´ b)·(c ´ d) = a·(b ´ (c ´ d))
61. Let M be the maximum value of the product of two r rr r rr r
= a·((b·d)c - (b·c)d)
positive integers when their sum is 66. Let the
ì 5 ü rr rr 1
sample space S = íx Î Z : x(66 - x) ³ Mý and = (a·c)(b·d)=
î 9 þ 4
63. Let y = y(x) be the solution curve of the
the event A= { x ÎS : x is a multiple of 3} .
dy y
Then P(A) is equal to differential equation = (1 + xy 2 (1 + log e x)) ,
dx x
15 1
(1) (2) y 2 (x)

®
44 3 x > 0, y(1) = 3. Then is equal to :
9
1 7
(3) (4) x2
5 22 (1)
Official Ans. by NTA (2)
5 - 2x 3 (2 + log e x 3 )
Allen Ans. (2) x2
(2)
Sol. M = 33 × 33 2x 3 (2 + loge x 3 ) - 3
5 x2
x(66 - x) ³ ´ 33 ´ 33 (3)
9 3x 3 (1 + log e x 2 ) - 2
11 £ x £ 55
A : {12, 15, 18, .... 54}
x2
(4)
7 - 3x 3 (2 + log e x 2 )
15 1
P(A) = = Official Ans. by NTA (1)
45 3
r r r Allen Ans. (1)
62. Let a, b and c be three non zero vectors such that
r r dy y
- = y 3 (1 + log e x)
rr r r r b-c r Sol.
dx x
b·c = 0 and a ´ (b ´ c) = . If d be a vector
2
rr rr r r r r
1 dy 1
- 2 = 1 + log e x
such that b·d = a·b , then (a ´ b)·(c ´ d) is equal 3
y dx xy
to 1 2 dy dt
Let - =t Þ 3 =
3 1 y 2
y dx dx
(1) (2)
4 2 dt 2t
1 1 \ + = 2(1 + log e x)
(3) - (4) dx x
4 4
ò dx
2

Official Ans. by NTA (4) I.F. = e x = x 2

Allen Ans. (4) -x2 2 æ x3 ö
r r = ç (1 + log e x ) x - ÷ + C
3

r r r r r r b-c y2 3è 3ø
Sol. (a·c)b - (a·b)c =
2 y(1) = 3
rr 1 rr 1 y2 x2
a·c = , a·b = =
2 2 9 5 - 2x 3 (2 + loge x 3 )
rr 1
\ b·d = OR
2 3
xdy = ydx + xy (1+ logex)dx
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xdy - ydx Sol. Only possibility a = 0, b = 1
= x(1 + log e x)dx
y3 \ equation of circle x 2 + y 2 - x - y = 0
x æ xö Image of circle in x + y + 2 = 0 is
- d ç ÷ = x 2 (1 + log e x)dx
y è yø x 2 + y 2 + 5x + 5y + 12 = 0
æ xö
2
66. The mean and variance of the marks obtained
- ç ÷ = 2 ò x 2 (1 + log e x)dx
è yø by the students in a test are 10 and 4
64. The value of respectively. Later, the marks of one of the
students is increased from 8 to 12. If the new
1 + 2 - 3 + 4 + 5 - 6 + ... + (3n - 2) + (3n - 1) - 3n mean of the marks is 10.2. then their new
Lim variance is equal to :
n®¥
2n 4 + 4n + 3 - n 4 + 5n + 4
(1) 4.04
is :
(2) 4.08
2 +1

®
(1) (3) 3.96
2 (4) 3.92
(2) 3( 2 + 1) Official Ans. by NTA (3)
3 Allen Ans. (3)
(3) ( 2 + 1) n
2 Sol. åx
i =1
i = 10n
3
(4) n

åx
2 2
i - 8 + 12 = (10.2)n \ n = 20
Official Ans. by NTA (3) i =1

Allen Ans. (3) 20

0 + 3 + 6 + 9 + .....n terms åx i
2
20
Sol. Lim Now i =1
- (10) 2 = 4 Þ å x i 2 = 2080
n®¥
2n 4 + 4n + 3 - n 4 + 5n + 4 20 i =1

3n(n - 1) 20

åx
( )
Lim
n®¥
2
- 82 + 122
2n + 4n + 3 - n + 5n + 4
4 4 i
2 i =1
- (10.2)2
20

) ( )
3 3 = 108 – 104.04 = 3.96
= = 2 +1
2 ( 2 -1 2 67. Let
65. The points of intersection of the line ax + by = 0, y(x) = (1 + x)(1 + x 2 )(1 + x 4 )(1 + x 8 )(1 + x16 ) .
(a ¹ b) and the circle x 2 + y 2 - 2x = 0 are Then y '- y" at x = -1 is equal to
A( a ,0) and B(1, b) . The image of the circle with (1) 976 (2) 464
AB as a diameter in the line x + y + 2 = 0 is : (3) 496 (4) 944

(1) x 2 + y 2 + 5x + 5y + 12= 0
Official Ans. by NTA (3)
(2) x 2 + y 2 + 3x + 5y + 8= 0 Allen Ans. (3)
(3) x 2 + y 2 + 3x + 3y + 4= 0 1 - x 32
Sol. y= Þ y - xy = 1 - x 32
(4) x 2 + y 2 - 5x - 5y + 12= 0 1- x
Official Ans. by NTA (1) y '- xy'- y = -32x 31
Allen Ans. (1) y"- xy"- y' - y' = -(32)(31)x 30
at x = – 1 Þ y '- y" = 496

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 Final JEE-Main Exam January, 2023/25-01-2023/Morning Session
r
68. The vector a = - ˆi + 2ˆj + kˆ is rotated through a 70. Consider the lines L1 and L2 given by
right angle, passing through the y-axis in its way x -1 y - 3 z - 2
r L1 : = =
2 1 2
and the resulting vector is b . Then the projection
r r r x-2 y-2 z-3
of 3a + 2b on c = 5iˆ + 4ˆj + 3kˆ is L2 : = =
1 2 3
(1) 3 2 (2) 1 A line L3 having direction ratios 1, –1, –2,
(3) 6 (4) 2 3 intersects L1 and L2 at the points P and Q
respectively. Then the length of line segment PQ is
Official Ans. by NTA (1)
Allen Ans. (1) (1) 2 6
r r r
Sol. b = la ´ (a ´ ˆj) (2) 3 2
r
Þ b = l ( -2iˆ - 2ˆj + 2k)
ˆ (3) 4 3
r r 1 (4) 4
b=a \ 6 = 12 l Þ l = ±

®
2 Official Ans. by NTA (1)
r Allen Ans. (1)
æ 1 ö
çè l = rejected Q b makes acute angle with y axis ÷ Sol. Let P = (2l + 1, l + 3,2l + 2)
2 ø
r Let Q = (m + 2,2m + 2,3m + 3)
b = - 2( - ˆi - ˆj + k)
ˆ
r r r 2l - m - 1 l - 2m + 1 2l - 3m - 1
(3a + 2b)·c Þ = =
r =3 2 1 -1 -2
c
Þ l = m = 3 Þ P(7,6,8) and Q(5,8,12)
69. The minimum value of the function
2
PQ = 2 6
òe
x-t
f (x)= dt is 71. Let x = 2 be a local minima of the function
f (x) = 2x 4 - 18x 2 + 8x + 12 , x Î ( -4,4) . If M is
0

(1) 2(e - 1) (2) 2e - 1

local maximum value of the function f in (–4, 4),
(3) 2 (4) e(e - 1) then M =
Official Ans. by NTA (1) 33 31
(1) 12 6 - (2) 12 6 -
Allen Ans. (1) 2 2
Sol. For x £ 0 33 31
2
(3) 18 6 - (4) 18 6 -
( )
2 2
f (x) = ò e t - x dt = e - x e 2 - 1
0
Official Ans. by NTA (1)
For 0 < x < 2 Allen Ans. (1)
x 2 Sol. f '(x) = 8x 3 - 36x + 8 = 4(2x 3 - 9x + 2)
f (x) = ò e x - t dt + ò e t - xdt = e x + e 2 - x - 2 f '(x) = 0
0 x

For x ³ 2 6-2
\x =
2 2
f (x) = ò e x - t dt = e x - 2 (e 2 - 1) Now
0
æ 9ö
For x £ 0 , f(x) is ¯ and x ³ 2 , f(x) is ­
è 2ø
( )
f (x) = ç x 2 - 2x - ÷ 2x 2 + 4x - 1 + 24x + 7.5
\ Minimum value of f(x) lies in x Î (0,2)
æ 6 - 2ö 33
Applying A.M ³ G.M , \f ç = M = 12 6 -
÷
minimum value of f(x) is 2(e – 1) è 2 ø 2

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72. Let z1 = 2 + 3i and z 2 = 3 + 4i . The set 74. Let S1 and S2 be respectively the sets of all

{ 2 2
S = z Î C : z - z1 - z - z 2 = z1 - z 2
2
} a Î R - {0} for which the system of linear
equations
represents a
ax + 2ay - 3az = 1
(1) straight line with sum of its intercepts on the
coordinate axes equals 14 (2a + 1)x + (2a + 3)y + (a + 1)z = 2
(2) hyperbola with the length of the transverse axis (3a + 5)x + (a + 5)y + (a + 2)z = 3
7
has unique solution and infinitely many solutions.
(3) straight line with the sum of its intercepts on Then
the coordinate axes equals –18 (1) n(S1) = 2 and S2 is an infinite set
(4) hyperbola with eccentricity 2 (2) S1 is an infinite set an n(S2) = 2
Official Ans. by NTA (1) (3) S1= F and S2 = ¡ - {0}
Allen Ans. (1) (4) S1= ¡ - {0} and S2 = F

( (x - 2) ) ( )

®
Official Ans. by NTA (4)
Sol. 2
+ (y - 3) 2 - (x - 3) 2 - (y - 4)2 = 1 + 1
Allen Ans. (4)
Þx+y=7 a 2a -3a
73. The distance of the point (6, -2 2 ) from the Sol. D = 2a + 1 2a + 3 a + 1
common tangent y = mx + c, m > 0, of the curves 3a + 5 a + 5 a+2
x = 2y 2 and x = 1 + y 2 is = a(15a 2 + 31a + 36) = 0 Þ a = 0

(1)
1 D ¹ 0 for all a Î R - {0}
3
Hence S1= R - {0} S2 = F
(2) 5
2x
(3)
14 75. Let f (x) = ò (x 2
+ 1)(x 2 + 3)
dx .
3
1
(4) 5 3 If f (3) = (loge 5 - log e 6) , then f(4) is equal to
2
Official Ans. by NTA (2) 1
Allen Ans. (2) (1) (loge 17 - log e 19)
2
Sol. For (2) loge 17 - loge 18
x 1 1
y2 = , T : y = mx + (3) (log e 19 - log e 17)
2 8m 2
For tangent to y 2 + 1 = x (4) loge 19 - loge 20
2 Official Ans. by NTA (1)
æ 1 ö
Þ ç mx + ÷ +1 = x Allen Ans. (1)
è 8m ø
Sol. Put x2 = t
1 1 æ 1 1 ö
D=0 Þm= dt
2 2 ò (t + 1)(t + 3) = 2 ò çè t + 1 - t + 3÷ø dt
\ T : x - 2 2y + 1 = 0 1 æ x2 + 1ö
f (x) = ln ç 2 +C
6 + 8 +1 2 è x + 3 ÷ø
d= =5
1
9 f (3) = ( ln10 - ln12 ) + C
2
ÞC=0
1 æ 17 ö
f (4) = ln ç ÷
2 è 19 ø

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 Final JEE-Main Exam January, 2023/25-01-2023/Morning Session
76. The statement (p Ù ( : q)) Þ (p Þ ( : q)) is
Sol.
(1) equivalent to ( : p) Ú ( : q)
(2) a tautology
(3) equivalent to p Ú q
(4) a contradiction x+3 y-2 z -3
Equation of line is = = = l
Official Ans. by NTA (2) 3 3 -1
Allen Ans. (2) M(3l - 3,3l + 2,3 - l )
Sol. (p Ù : q) ® (p ® : q) D.R of PM(3l - 7,3l - 4,5 - l )
Since PM is perpendicular to line
º ( : (p Ù : q)) Ú ( : pÚ : q)
Þ 3(3l - 7) + 3(3l - 4) - 1(5 - l ) = 0
º ( : p Ú q) Ú ( : p Ú : q) Þl=2
º: p Ú t º t Þ M(3,8,1) Þ PM = 14
77. Let f : (0,1) ® ¡ be a function defined by 79. Let x, y,z > 1 and

®
1 é1 log x y log x z ù
f (x) = , and
1 - e- x A = êê log y x 2 log y z úú .
g(x) = (f ( - x) - f (x)) . Consider two statements êë log z x log z y 3 úû
(I) g is an increasing function in (0, 1)
(II) g is one-one in (0, 1) Then adj(adj A 2 ) is equal to
Then, (1) 64
(1) Only (I) is true (2) 28
(2) Only (II) is true (3) 48
(3) Neither (I) nor (II) is true (4) 24
(4) Both (I) and (II) are true Official Ans. by NTA (2)
Official Ans. by NTA (4) Allen Ans. (2)
Allen Ans. (4) log x log y logz
1
1+ e x
Sol. A= log x 2 log y logz = 2
Sol. g(x) = f ( - x) - f (x) = log x.log y.log z
1 - ex log x log y 3log z
2e x 4
Þ g '(x) = >0 Þ adj(adjA 2 ) = A 2 = 2 8
(1 - e x ) 2
80. If ar is the coefficient of x10–r in the Binomial
Þ g is increasing in (0, 1)
2
Þ g is one-one in (0, 1) æ a ö
10
expansion of (1 + x) , then å r ç r ÷ is equal
10 3

78. The distance of the point P(4, 6, –2) from the line r =1 è a r -1 ø
passing through the point (–3, 2, 3) and parallel to to
a line with direction ratios 3, 3, –1 is equal to : (1) 4895 (2) 1210
(1) 3 (3) 5445 (4) 3025
(2) 6 Official Ans. by NTA (2)
Allen Ans. (2)
(3) 2 3
Sol. a r = 10C10- r = 10Cr
(4) 14 2
æ 10 C ö æ 11 - r ö
10 10 102
Official Ans. by NTA (4) Þ å r ç 10 r ÷ = å r 3 ç
3
÷ø = å r(11 - r)2
Allen Ans. (4) r =1 è C r -1 ø r =1 è r r =1

10
= å (121r + r
r =1
3
- 22r 2 ) = 1210

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 Final JEE-Main Exam January, 2023/25-01-2023/Morning Session
SECTION-B fog(x) = a(xb + c) – 3

81. Let S = {1, 2, 3, 5, 7, 10, 11}. The number of non- Þ a = 2, b = 3, c = 5

empty subsets of S that have the sum of all
Þ fog(ac) = fog(10) = 2007
elements a multiple of 3, is ____ .
g(f(x) = (2x – 3)3 + 5
Official Ans. by NTA (43)
Þ gof(b) = gof(3) = 32
Allen Ans. (43)
Sol. Elements of the type 3k = 3 Þ sum = 2039

Elements of the type 3k + 1 = 1, 7, 9 83. The vertices of a hyperbola H are ( ±6,0) and its

Elements of the type 3k + 2 = 2, 5, 11 5

eccentricity is . Let N be the normal to H at a
2
Subsets containing one element S1 = 1

®
point in the first quadrant and parallel to the line
Subsets containing two elements
2x + y = 2 2 . If d is the length of the line
S2 = 3C1 × 3C1 = 9
segment of N between H and the y-axis then d2 is
Subsets containing three elements
equal to _____ .
3 3
S3 = C1 × C1 + 1 + 1 = 11 Official Ans. by NTA (216)
Subsets containing four elements Allen Ans. (216)
S4 = 3C3 + 3C3 + 3C2 × 3C2 = 11 Sol.

Subsets containing five elements

K
3 3
d
S5 = C2 × C2 × 1 = 9
P
Subsets containing six elements S6 = 1
(6, 0)
Subsets containing seven elements S7 = 1

Þ sum = 43
x2 y2
82. For some a, b,c Î¥ , let f(x) = ax – 3 and H: - =1
36 9
æ x - 7ö
1/3

g(x) = x b + c, x Ρ . If (fog)-1 (x) = ç , equation of normal is 6x cosq + 3y cotq = 45

è 2 ÷ø
then (fog) (ac) + (gof) (b) is equal to ____ . slope = – 2 sin q = - 2

Official Ans. by NTA (2039) p

Þq =
4
Allen Ans. (2039)
Sol. Let fog(x) = h(x) Equation of normal is 2x + y = 15

1
P : (a secq, b tanq)
-1 æ x - 7ö 3
Þ h (x) = ç
è 2 ÷ø
Þ P(6 2,3) and K(0,15)
Þ h(x) = fog(x) = 2x + 7 3

d2 = 216

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 Final JEE-Main Exam January, 2023/25-01-2023/Morning Session
84. Let 86. Let A1, A2, A3 be the three A.P. with the same

ì æ5 ö ü common difference d and having their first terms

S= ía : log2 (92a-4 + 13) - log2 ç .32a-4 + 1÷= 2ý .
î è 2 ø þ as A, A + 1, A + 2, respectively. Let a, b, c be the

Then the maximum value of b for which the 7th, 9th, 17th terms of A1, A2, A3, respectively such

2 a 7 1
æ ö
equation x - 2 ç å a ÷ x + å (a + 1) b = 0 has that 2b 17 1 + 70 = 0
2 2

è aÎs ø aÎs
c 17 1
real roots, is ____ .
If a = 29, then the sum of first 20 terms of an AP
Official Ans. by NTA (25) whose first term is c – a – b and common
Allen Ans. (25) d
difference is , is equal to ______ .
12
æ5 ö
Sol. log2 (9 2 a- 4 + 13) - log2 ç .32 a- 4 + 1÷ = 2

®
è2 ø Official Ans. by NTA (495)

Allen Ans. (495)

92 a-4 + 13
Þ =4 A + 6d 7 1
5 2 a- 4
3 +1
2 Sol. 2(A + 1 + 8d) 17 1 + 70 = 0
A + 2 + 16d 17 1
Þ a=2 or 3
Þ A = –7 and d = 6
åa =
aÎS
5 and å (a + 1)
aÎS
2
= 25 \ c – a – b = 20
S20 = 495
Þ x – 50x + 25b = 0 has real roots
2
87. If the sum of all the solutions of

Þ b £ 25 æ 2x ö -1 æ 1 - x ö p
2
tan -1 ç 2÷
+ cot ç ÷ = ,
Þ bmax = 25 è1- x ø è 2x ø 3

85. The constant term in the expansion of 4

-1 < x < 1, x ¹ 0, is a - , then a is equal to
5
3
æ 1 2ö
çè 2x + 7 + 3x ÷ø is ____ . ____ .
x
Official Ans. by NTA (2)
Official Ans. by NTA (1080)
Allen Ans. (2)
Allen Ans. (1080)
Sol. Case I : x > 0
n1 -7 n 2 2 n3
5!(2x) (x ) (3x ) p
Sol. General term is å n1 ! n 2 ! n 3 ! tan -1
2x
+ tan -1
2x
=
1- x 2
1- x 2
3
For constant term, x =2- 3
Case II : x < 0
n1 + 2n3 = 7n2
2x 2x p
& n1 + n2 + n3 = 5 tan -1 + tan -1 +p =
1- x 2
1- x 2
3
Only possibility n1 = 1, n2 = 1, n3 = 3 -1
x= Þa=2
3
Þ constant term = 1080

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88. Let the equation of the plane passing through the Official Ans. by NTA (600)
line Allen Ans. (600)
x - 2y - z - 5 = 0 = x + y + 3z - 5 and parallel to Sol.
the line x + y + 2z – 7 = 0 = 2x + 3y + z – 2 be
ax + by + cz = 65. Then the distance of the point
Abscissa of point of intersection of 2y = 5x
2
(a, b, c) from the plane 2x + 2y – z + 16 = 0 is
____ . and y = x 2 + 6 is ± 2
Official Ans. by NTA (9)

Allen Ans. (9)

Sol. Equation of plane is
(x - 2y - z - 5) + b(x + y + 3z - 5) = 0 2a

®
æ 5x 2 ö æ 5x 2 ö
2 5
1 + b -2 + b -1 + 3b Area = 2 ò ç x 2 + 6 - dx = ò ax - dx
è 2 ÷ø çè 2 ÷ø
1 1 2 =0 0 0

2a
2 3 1 5
æ 5x 2 ö
Þ b = 12 Þ ò çè a x -
2 ÷ø
dx = 16
0
\ plane is 13x + 10y + 35z = 65
Þ a 3 = 600
Distance from given point to plane = 9

89. Let x and y be distinct integers where 1 £ x £ 25

and 1 £ y £ 25 . Then, the number of ways of

choosing x and y, such that x + y is divisible by 5,

is _____ .

Official Ans. by NTA (120)

Allen Ans. (120)

Sol. x + y = 5l
Cases :
x y Number of ways
5l 5l 20
5l + 1 5l + 4 25
5l + 2 5l + 3 25
5l + 3 5l + 2 25
5l + 4 5l + 1 25
Total = 120
90. It the area enclosed by the parabolas P1 : 2y = 5x2
and P2 : x2 – y + 6 = 0 is equal to the area enclosed

by P1 and y = ax, a > 0 , then a 3 is equal to

_____ .

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