Suponiendo que la ley de Raoult es válida prepare un diagrama Txy para una presion de 50 kpa para el sistema n-pentano(1) y

i Componente A B C x1 x2
1 n-pentano 13.7965 2723.73 218.267 0 1
2 n-heptano 13.8635 3174.78 211.7 0.1 0.9
0.2 0.8
0.3 0.7
0.4 0.6
0.5 0.5
0.6 0.4
0.7 0.3
0.8 0.2
0.9 0.1
1 0

Diagrama Txy
120

107.326010002709

100 Punto de rocio

97.241777688818 97.241777688818
Vapor
89.2893279363002 89.2893279363002
82.8366694454237 Liqui 82.8366694454237
80 do-V
P.burbuja 77.4708773363005 apor 77.4708773363005
72.9164410177535 72.9164410177535
68.9842552343824 68.9842552343824
65.5407233347767 65.54072333477
62.488899119691862.48889911
T( °C)

60 59.7566821776094
59.756682
57.2893
Liquido

40

20

0
0 0.2 0.4 0.6 0.8 1

x1, y1
0
0 0.2 0.4 0.6 0.8 1

x1, y1
a para el sistema n-pentano(1) y n-heptano(2).

T°C P1sat P2sat P (kPa) y1 y2

107.32601 228.390363 49.9999999 49.9999999 0 1
97.2417777 174.806831 36.1325741 49.9999998 0.34961366 0.65038634
89.2893279 139.835078 27.5412302 49.9999998 0.55934031 0.44065969
82.8366694 115.662753 21.8588185 49.9999989 0.69397653 0.30602347
77.4708773 98.1555628 17.8962928 50.0000008 0.78524449 0.21475551
72.916441 84.9871171 15.0128871 50.0000021 0.84987114 0.15012886
68.9842552 74.7726863 12.8409736 50.0000012 0.89727221 0.10272779
65.5407233 66.6465899 11.1579473 49.9999972 0.93305231 0.06694769
62.4888991 60.0443339 9.82268254 50.0000036 0.96070927 0.03929073
59.7566822 54.5842094 8.74212543 50.000001 0.98251575 0.01748425
57.2893091 49.9999996 7.85283641 49.9999996 1 0

Vapor

366694454237
77.4708773363005
72.9164410177535
824 68.9842552343824
407233347767 65.5407233347767
62.488899119691862.4888991196918
59.7566821776094
59.7566821776094
57.2893090819171

Tx1
Ty1

0.8 1 1.2
0.8 1 1.2
2) Suponiendo que la ley de Raoult es válida prepare un diagrama Pxy para una temperatura de 90 °C para el sistema benceno

i Componente A B C T P1 sat
1 clorobutano 13.7965 2723.73 218.267 90 P2 sat
2 clorobenceno 13.8635 3174.78 211.7

X1 X2 Pburbuja Y1 Y2
0 1 28.2340914 0 1
0.1 0.9 39.6826189 0.35965209 0.64034791
0.2 0.8 51.1311464 0.55824826 0.44175174
0.3 0.7 62.5796739 0.68418078 0.31581922
0.4 0.6 74.0282014 0.77116214 0.22883786
0.5 0.5 85.4767289 0.8348434 0.1651566
0.6 0.4 96.9252564 0.88348097 0.11651903
0.7 0.3 108.373784 0.92184247 0.07815753
0.8 0.2 119.822311 0.9528734 0.0471266
0.9 0.1 131.270839 0.97849173 0.02150827
1 0 142.719366 1 0

160 Diagrama Pxy

142.719366324023
140
131.270838830843
131.270838830843

120 Liquido 119.822311337663119.822311337663

a
buj
e bur 108.373783844483 108.373783844483
nt os d
100
o =pu 96.9252563513025 96.9252563513025
tu rad
o sa
Presion (Kpa)

id 85.4767288581224 r 85.4767288581224
80 Liqu - v apo
o
74.0282013649423 uid 74.0282013649423
Liq
i o Px
60
62.5796738717622 roc
62.5796738717622
e
o sd Py
51.1311463785822 51.1311463785822 unt
o =p
rad Vapor
atu
40 39.6826188854021 39.6826188854021
r s
28.234091392222 V apo
20

0
0 0.2 0.4 0.6 0.8 1
X1, Y1
e 90 °C para el sistema benceno(1) y etilbenceno(2).

142.719366
28.2340914

142.719366324023

131.270838830843
131.270838830843

311337663119.822311337663

108.373783844483

96.9252563513025

4767288581224

3649423
Px1
Py1

Vapor

1 1.2
 P1 sat 1.24
P2 sat 0.89

x1 x2 ϒ1 ϒ2 Pburbuja (kPa) Y1 Y2
0 1 1.8 0 0.89 0 1
0.1 0.9 1.458 0.018 1.34842071 0.39518243 0.60481757
0.2 0.8 1.152 0.072 1.54995448 0.50633737 0.49366263
0.3 0.7 0.882 0.162 1.63121113 0.5509098 0.4490902
0.4 0.6 0.648 0.288 1.66043633 0.5710607 0.4289393
0.5 0.5 0.45 0.45 1.67025248 0.58215962 0.41784038
0.6 0.4 0.288 0.648 1.67288547 0.59317595 0.40682405
0.7 0.3 0.162 0.882 1.66564562 0.61276341 0.38723659
0.8 0.2 0.072 1.152 1.62934188 0.65428755 0.34571245
0.9 0.1 0.018 1.458 1.51873458 0.74816883 0.25183117
1 0 0 1.8 1.24 1 0

b)
0.59212473 0.40787527 1.67291057 solver 5.93E-12
x1 az y1az 1.67291057

Dia
1.8
Líquido
1.6

1.4 V.sat
1.2
Presion (Kpa)

0.8

0.6

0.4

0.2

0
0 0.2 0.4
0.6

0.4

0.2

0
0 0.2 0.4
 Diagrama Pxy

uido L.saturado (P. Burbuja)

V.saturado (P. ro-

cío)

Px1
Py1

Vapor
0.2 0.4 0.6 0.8 1 1.2

X1, Y1
 Vapor
0.2 0.4 0.6 0.8 1 1.2

X1, Y1
Pburbuja T°C 60
Presion=1100Kpa
1°iteracion Xi Ki KiXi
etano 0.1 4.6 0.46
propano 0.2 1.7 0.34
isobutano 0.3 0.9 0.27
isopentano 0.4 0.3 0.12
1.19
presion=1300Kpa
2°iteracion Xi Ki KiXi
etano 0.1 4 0.4
propano 0.2 1.55 0.31
isobutano 0.3 0.75 0.225
isopentano 0.4 0.25 0.1
1.035
presion=1400 Kpa
3°iteracion Xi Ki KiXi
etano 0.1 3.8 0.38
propano 0.2 1.49 0.298
isobutano 0.3 0.7 0.21
isopentano 0.4 0.28 0.112
1
Presion 15 Pa psia 217.557
t=120°F
1°iteracion Yi Ki Yi/Ki
etano 0.42 3.1 0.13548387
propano 0.3 1.15 0.26086957
isobutano 0.15 0.52 0.28846154
isopentano 0.13 0.18 0.72222222
1.4070372

t=140 °F
2°iteracion Yi Ki Yi/Ki
etano 0.42 3.6 0.11666667
propano 0.3 1.4 0.21428571
isobutano 0.15 0.675 0.22222222
isopentano 0.13 0.24 0.54166667
1.09484127

t=145 °F
3°iteracion Yi Ki Yi/Ki
etano 0.42 3.9 0.10769231
propano 0.3 1.5 0.2
isobutano 0.15 0.75 0.2
isopentano 0.13 0.24 0.54166667
1.04935897