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Bramante in Milan Studies in Conservation
Bramante in Milan Studies in Conservation
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Studies in Conservation
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BRAMANTE IN MILAN: THE CASCINA POZZOBONELLI.
TECHNICAL EXAMINATION AND RESTORATION
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G. Alessandrini et al.
In 1986, the Soprintendenza decided to restore sites from which the samples were taken are
the building because of the beauty of the graffito shown in Figure 1. The samples taken are
work, the importance of the artist in question described in Table 1.
and the very poor state of conservation. The
restoration was preceded by extensive labora- Table 1 Sampling
tory investigations into the characteristics of the
materials used for the plain and decorated plas- Sample no. Height from the floor in
ter and graffito work, the techniques employed metres
Graffito
- 4 1 4 9 1-20
.'
10 1.00
11 1-30
12 1-20
13 1-50
14 2-00
-4916-17 16 2-00
. :
...-' 17 1-30
18 1-30 Restoration
19 1.50
... A
.12 12
. 4 ..
20
21 2-30
1.50
1o '-.* .. .. - ? 22 2-00 Restoration
10
23 2-00 Restoration
11 Graffito - Church of S. M
24, 25 apse
26, 27 dome
*15
010 oo:. .
3 State of conservation
14 13
Raccomandazione NORMAL 1/80 [15] was fol-
lowed in evaluating the state of conservation of
the work. The plaster in both the Chapel and the
Figure 1 Cascina Pozzobonelli: planbecause
portico was in very poor condition of the the
and the portico; the walls
pointsand vaults
ofhad been subject to the long-
sampling are sh
term continuous infiltration of rainwater due to
the poor repair of the roof, gutters and down-
2 Sampling pipes, in addition to the lack of suitable drain-
age. Many gaps existed in the plaster, as well as
The samples areas that had become
required for detached
the from the brick-
labora
investigations were work. Superficial
taken erosionin
was noted along with
accordan
Raccomandazione NORMAL 3/80 [14]. The moulds and microorganisms in the space
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Bramante in Milan: the Cascina Pozzobonelli
Figure 2a Graffito in the Chapel (central apse). Figure 2b Graffito in the Chapel (right apse).
between the detached plaster and the brickwork, diameter using a mercury porosimeter, fol-
and damp marks on the surface (Figures 2a, b, lowing Raccomandazione NORMAL 4/80
c; 3a, b; 4a, b). Beltrami had repaired the plaster [17].
(6) Measurement of the quantity of water-
during the restoration undertaken in the early
1900s and it was later patched up again with soluble salts, according to Rac-
coarse mortar. comandazione NORMAL 13/83 [18].
(7) Scanning electron microscope examination
4 Experimental investigation of surfaces and cross-sections, as well as
micro-analyses using an energy dispersive
4.1 Analysis X-ray spectrometer, according to Rac-
The following methods were used: comandazione NORMAL 8/81 [19].
(1) Observation of polished cross-sections (8) Infrared spectrophotometric analysis. The
using a stereoscopic microscope. ground-up samples were extracted in chlo-
roform:
(2) Mineralogical-petrographic analyses of methanol 2:1. In order to eliminate
thin sections, using a polarizing micro-
the hydrolyzed compounds the extract was
scope, following Raccomandazione NOR-
then further extracted in chloroform only.
MAL 12/83 [16].
(3) Evaluation of the binder-filler ratio by
modal analysis*.
*Modal analysis is a method used by petrographers to
(4) Mineralogical analyses using X-ray measure the relative amounts of various mineral com-
diffractometry (Tables 2, 3). ponents in rock (or in this case, plaster). It was done
(5) Measurement of the total porosity and its
by point counting on thin-sections observed with
distribution as a function of the pore polarizing microscope.
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G. Alessandrini et al.
5.1 Graffito
The plaster consists of two layers with a total
thickness of not more than 10mm (Figure 5).
The adhesion to the brickwork is very poor. The
first layer (in contact with the brickwork) is for
A? I
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Bramante in Milan: the Cascina Pozzobonelli
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G. Alessandrini et al.
l(I) +++ + + ++ + - ++
1 (II) + - +++ + - - -
2 (I) +++ + - ++ + - +
3 (I) +++ + - ++ - - ++
4 (I) +++ + + ++ + - ++
4 (II) + - +++ + - - -
5 (I) +++ + + +++ - - ++
5 (II) + - + 4-+ +- -
6 (I) +++ + + ++ - + ++
6 (II) + - +++ + - - -
15 (I) +++ + - +++ + - ++
15 (II) + - + + + + - - -
9 (I) + + - +++ - -
9 (II) + - +++ + - - -
10 (II) + - + + + - - -
11 (I) +++ + - +++ + - +
12 (II) + - + + - -
13 (II) + - + + + - - -
14 (I) +++ + + +++ + -
16 (II) + - + + - - + -
17 (I1) - - +++ + - -
18 ++ - + +++ + +
19 (II) + + +++ + - - -
20 (II) + - + + - - -
21 (I) +++ + - +++ + + ++
21 (11) - - +++ - - -
22 (I) ++ - - +++ + - -
22 (II) + + + - +
23 (I) ++ - - +++ - -
23 (II) + + + -
24 (II) + + + - + - - -
25 (II) + + + - + + - - -
26 (II) + + - + ++ - - -
27(II) + + - + + -
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Bramante in Milan: the Cascina Pozzobonelli
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G. Alessandrini et al.
Figure 9a Finishing plaster (polished cross-section, Figure 9b Finishing plaster (as in Figure 9a): the
SEM x 100): the outer layer is marked by an arrow. distribution of sulphur in the same area as Figure 9a.
shown by technical data, petrographic charac- insoluble anhydrite (anhydrite II, CaSO4),
teristics and historical data). The presence of obtained by heating the material at over 3000C,
magnesite in the lime allows the site of origin of or of mineral anhydrite. Such products require
its raw materials to be identified as the Prealpi of the addition of accelerators for the binding reac-
Varese (some 40km north of Milan). This area tion (potassium sulphate, alum, etc.) [20-22] that
has large outcrops of dolomite and limestone were not found in this case. The suggestion that
that have been used for centuries for the prepa- mineral anhydrite might have been used was
ration of lime for building in Lombardy [23-26]. based on the presence of a large deposit of this
Judging by its petrographic composition (the material, quarried for some time, near Bergamo,
presence of micaschists, the lack of calcareous some 50km north-east of Milan. In the case
rocks, etc.), the sand came from the River Ticino
under investigation, the raw material probably
which has a basin composed of this type of rock came from the northern Appennines, where
(the river is a few km west of Milan and has been there is a Gessoso-solfifera outcrop of the Mio-
linked to the city by a navigable canal since the cene period. In particular, literature records the
fifteenth century). fine quality of gypsum quarried near Bologna
'Plaster of Paris' was used for the second layer. and Rimini [28, 29].
This material is hemihydrated calcium sulphate
(2CaSO4-H20), the product of heating mineral 7 Manufacturing techniques
gypsum (CaSO4 2H20) at temperatures of not
more than 1600C. This material has been in use 7.1 Graffito - general discussion
for centuries (pre-dynastic Egypt) [20, 21, 27]*. No particular comment is required on the first
Laboratory tests disproved the use of layer, which reflects the methods reported by
both the classical authors [30] and the more
recent literature [21, 31]. The material is lime and
sand mortar with added charcoal giving the dark
colour that can be seen through the engraving of
*The presence of soluble anhydrite (anhydrite III,
CaSO4) cannot be excluded, given that the ovensthe
usedtop layer. The same cannot be said of the
composition of the second white layer that is cut
in the fifteenth century could not guarantee either
to create the graffito. Normally this is calcium
uniformity of temperature or exact humidity control
carbonate or, as Vasari [30] calls it: 'bianco della
and were fed with minerals of mixed size [20, 27].
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Bramante in Milan: the Cascina Pozzobonelli
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G. Alessandrini et al.
(b) Bramante used a different plaster technique two-layered plaster was prepared using, for the
for the Cascina Pozzobonelli graffiti from first layer, a mixture of lime, sand and charcoal
that which he adopted for the dome and with the same characteristics and in the same
apse of Santa Maria delle Grazie for aes- proportions as those found in the Cascina Pozzo-
thetic reasons, for example to achieve a bonelli and, for the second layer, a mixture of
greater smoothness or particular surface plaster of Paris and water (1:1) that was easy to
luminosity. spread with a brush.
(c) Bramante chose to use gypsum in order to The following methods of application were
finish the work more quickly. used:
There is another possibility which is that the (a) The spreading and smoothing of the first
use of gypsum as an alternative to lime was wide- layer, the immediate spreading of the plas-
spread in the production of graffiti, in con- ter of Paris and the scribing of the wet plas-
tradiction to Vasari. Whatever the answer to ter with a metal stylus.
these questions, the work was done by someone (b) The spreading and smoothing of the first
with sufficient expertise to be able to judge the layer which was then left to dry, followed by
right ratio of water to gypsum powder, to obtain the spreading of the plaster of Paris and the
a mixture that could be spread by brush (as can scribing of the latter while still wet.
be seen from the many fine brush marks on(c) theThe spreading and smoothing of the first
surface, especially when viewed in raking light), layer, the immediate spreading of the
in a very thin layer and with the required settingplaster of Paris and the scribing of the dry
time. There remains a final question: what tech- plaster.
nique was used to create the graffiti in the Cas-(d) The spreading and smoothing of the first
cina Pozzobonelli? Given that there are different layer which was left to dry, followed by the
compositions, it is reasonable to think that tech- spreading of the plaster of Paris which, in
niques were used that differ from those described turn, was left to dry and scribed.
by Vasari. In the case of (a), the external layer, worked
when wet, became grayish-white (Munsell
7.2 Finishing plaster notation N/8-25), very different to the clear
No special comment has to be made on the first white that is characteristic of the graffiti in the
layer. The crushed brick was added to give the Cascina Pozzobonelli (Munsell notation N/9
plaster hydraulicity,* given the exposed position after cleaning). The plaster was very easy to cut
of the work in question. This technique was in and the edges were clean. The lower layer was
use in Lombardy in the fifteenth century, as is also penetrated in the cutting. Scanning electron
seen in the Church of Santa Maria presso San microscope observations showed diffusion of the
Satiro, which also has some plasterwork by plaster of Paris into the lower layer, and there
was not therefore the clear demarcation line that
Bramante [24].
The second layer, with characteristics similar is typical of the Bramante graffiti.
to those of the graffiti, was applied in the same In the second case (b), the external layer had
the same luminous white colour as the Bramante
way. This confirms that the finishing plas-
terwork and the graffiti were done at the same graffiti (Munsell notation N/9). Scribing was
time and by the same hand. again easy and the edges were clean. Only the
white layer was cut. There was a clear
8 Experimental work on the technique of the demarcation line between the two layers.
graffito plaster In cases (c) and (d), the same external layer
characteristics as for (a) and (b) were obtained.
A series of laboratory tests was carried out in an Scribing, however, was very difficult in order to
obtain the fine decoration which was character-
attempt to reproduce the original technique. A
istic of the Bramante graffiti in the Cascina
*Hydraulic lime (from siliceous or argillaceous lime- Pozzobonelli, and it was impossible to obtain the
stones) sets under water. The addition of crushed different groove sizes. It is therefore held that the
brick to a plaster made from non-hydraulic lime gives Cascina Pozzobonelli graffiti were made using
the plaster better durability in damp conditions. method (b).
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Bramante in Milan: the Cascina Pozzobonelli
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Bramante in Milan: the Cascina Pozzobonelli
17 'Distribuzione del volume dei pori in funzione del in the Conservation of Stone and Wall Paint-
loro diametro', Raccomandazione NORMAL ings, IIC, London (1986) 27-33.
4/80, C.N.R. - I.C.R., Rome (1980). 32 CENNINI, C., II libro dell'arte o Trattato della Pit-
18 'Dosaggio dei sali solubili', Raccomandazione tura, chap. 115, 116, Longanesi, Milan (1975).
NORMAL 13/83, C.N.R. - I.C.R., Rome 33 MILIZIA, F., Principi di architettura civile, part 3,
(1983). book 1, chap. 6, Milan (1853).
19 'Esame delle caratteristiche morfologiche al 34 FERRAGNI, D., FORTI, M., MALLIET, J., MORA, L.,
microscopio elettronico a scansione (SEM)', MORA P., and TORRACA, G., 'La conservazione
Raccomandazione NORMAL 8/81, C.N.R.- degli intonaci sgraffiti - Un esempio: la fac-
I.C.R., Rome (1981). ciata cinquecentesca in via della Fossa a
20 MORA, P., MORA, L., and PHILIPPOT, P., La con- Roma', Ricerche di Storia dell'Arte 24 (1984)
servation des peintures murales, Compositori, 33-43.
Bologna (1977). 35 CAVALLARO, A., GUALDI, R., and TEBALDI, G.,
21 DAVEY, N., A History of Building Materials, Lon- Studi per la valutazione della qualita dell'aria,
don (1965). Provincia di Milano, Milan (1985).
22 DIMos, Tecniche di esecuzione e materiali cos-
titutivi, parte I, modulo 1, Rome (1978). GIOVANNA ALESSANDRINI, graduated in chemistry.
23 ALESSANDRINI, G., BONECCHI, R., BUGINI, R., Since 1960 researcher of the National Research Coun-
FERRARI DA PASSANO, C., GALLETTI, G., and cil at Centro 'Gino Bozza' per lo studio delle cause di
PERUZZI, R., 'Basilica di S. Ambrogio in Mil- deperimento e dei metodi di conservazione delle opere
ano: tecniche costruttive della cupola del sac- d'arte, Milan. Since 1987 director of the same.
ello di S. Vittore in Ciel d'Oro' in Atti del Author's address: Centro CNR 'Gino Bozza',
Convegno Scienza e Beni Culturali, p. Leonardo da Vinci 32, 20133 Milan, Italy.
Bressanone-Padua (1985) 291-310.
24 ALESSANDRINI, G., AULETTA, R., BROGLIA, E., ROBERTO BONECCHI, since 1964 operator of the
National Research Council at Centro 'Gino Bozza'.
BUGINI, R., and PERUZZI, R., 'Basilica di S.
Author's address: as for Alessandrini.
Satiro in Milano: analisi e studi preliminari su
malte e intonaci antichi' in Atti del Convegno
Scienza e Beni Culturali, Bressanone-Padua ROBERTO BUGINI, graduated in geology. Since 1982
researcher of the National Research Council at Cen-
(1985) 275-290.
25 ALESSANDRINI, G., AULETTA, R., BUGINI, R., tro 'Gino Bozza'. Author's address: as for
NEGROTTI, R., PERUZZI, R., and SIMONI, M., Alessandrini.
'Chiesa di S. Maria presso S. Satiro in Milano
- La prospettiva bramantesca - Indagini sui ENzo FEDELI, graduated in chemistry. Since 1960
materiali e sulle tecniche usate nei restauri' in researcher and since 1977 director of the Stazione
Atti del Convegno Scienza e Beni Culturali, Sperimentale Olii e Grassi, Milan. Author's address:
Bressanone-Padua (1986) 149-160. Stazione Sperimentale Olii e Grassi, via Colombo 79,
26 ALESSANDRINI, G., BONECCHI, R., and BUGINI, 20133 Milan, Italy.
R., 'Basilica di S. Paolo Converso (Milano):
analisi di malte e intonaci della fiancata set- SYLVIA PONTICELLI, graduated in architecture. Since
tentrionale', Centro Gino Bozza, R.P.87/07/ 1970 at Soprintendenza BB. AA. AA., Milan. Since
126 (1987). 1977 Soprintendente Aggiunto. Author's address:
27 FRATINI, N., 'Lo stato attuale delle ricerche sulle Soprintendenza ai Beni Ambientali e Architettonici,
fasi del sistema CaSO4 2H20-CaSO4 e sulla p. Duomo 14, 20121 Milan, Italy.
disidratazione del gesso', C.N.R., Rome
(1972). GIOVANNI RossI, restorer. Working since 1972 for the
28 ALBERTI, L.B., De re aedificatoria, book 2, chap. Museums and Soprintendenze of Milan and Lom-
11, Polifilo, Milan (1966). bardy. Author's address: via Cornaggia 5, 20123
29 SCAMOZZI, V., Dell'idea dell'architettura univer- Milan, Italy.
sale, part 2, book 7, chap. 17, Venice (1615).
30 VASARI, G., Le vite de' piti eccellenti architetti, LUCIA TONIOLO, graduated in chemistry. Since 1986
pittori, et scultori italiani da Cimabue insino a' researcher at Centro 'Gino Bozza'. Author's address:
tempi nostri, Introduction, chap. 26, Florence as for Alessandrini.
(1550).
31 KOLLER, M., PASCHINGER, H., and RICHARD, H.,
'Work in Austria on historic stucco - tech- Resum&---Le platre provenant de la 'Cascina
Pozzobonelli' (Milan), probablement construit par
nique, colouring, preservation' in Case Studies
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G. Alessandrini et al.
Bramante au XVe siecle, a 6t6 analyse pour mettre en Bramante (15.Jh.) erbauten 'Cascina Pozzobonelli' in
evidence la composition du produit de base, les tech- Mailand wurden im Hinblick auf ihre Rohstoffe, ihre
niques d'utilisation et les raisons de son d61abrement,Verarbeitung und ihre Verfallsursachen analysiert.
afin d'aider le travail de restauration. Les platres sontDies geschah vor dem Hintergrund geplanter
de deux sortes: un graffito d6cor6 et un platre de Konservierungsmal3nahmen. Die Putze erwiesen sich
finition simple. Le graffito comporte deux couches: laentweder als dekorierter graffito oder als einfacher
premiere faite de calcaire, sable et charbon, et la sec-Feinputz. Der graffito ist in zwei Schichten aufgebaut:
onde de gypse. La seconde couche 6tait appliqube auf einer Schicht aus Kalk, Sand und Holzkohle liegt
apr6s le s6chage de la premiere et ensuite grav~e eine zweite aus Gips. Die obere Schicht wurde dabei
encore humide pour obtenir le graffito. Le plitre sim-nach Abtrocknen der ersten aufgetrageri. Das graffito
ple est 6galement constitu6 de deux couches: la pre-wurde dann in die noch feuchte Schicht eingeritzt. Der
miere faite de calcaire, sable et brique pilee, la secondeeinfache Putz besteht wiederum aus zwei Schichten:
faite de gypse. L'alteration a 6t6 caus6e par I'humiditeeiner Schicht aus Kalk, Sand und zerstol3enen Ziegeln
61ev6e de I'atmosph6re. La restauration a 6te effectube folgt eine, die wieder aus Gips ist. Der Zerfall der
en scellant les parties d6tach6es et en consolidant les Putze wurde durch eine zu hohe Umgebungsfeuchte
r6gions fragiles avec une r6sine acrylique. verursacht. Die Restaurierung wurde unter Sicherung
abgel6ster Partien und Festigung auseinander-
Zusammenfassung-Putze aus der m6glichenfalls vonbr6ckelnder Bereiche mit Acrylharzen vorgenommen.
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