AUXILIAR: EDWIN LIQUE HUMEREZ

𝐾𝑚
= 𝐵 → 𝐾𝑚 = 𝐵 ∗ 𝑉𝑚𝑎𝑥
𝑉𝑚𝑎𝑥

𝐾𝑚 = 5,99𝑥10−6 ∗ 840,33

𝑋 𝑌 1 𝐾𝑚 1 1 𝐾𝑚 = 5,03𝑥10−3
= ∗ +
𝑺 𝒎𝒍 𝟏 𝟏 𝑉 𝑉𝑚𝑎𝑥 𝑆 𝑉𝑚𝑎𝑥
𝑽
𝒔𝒆𝒈 𝑺 𝑽
1𝑥10−3 140 1000 7,14𝑥10−3 𝑌= 𝐵∗𝑋 + 𝐴

2,5𝑥10−3 255 400 3,92𝑥10−3 1

=A 1
𝑉𝑚𝑎𝑥 𝑉𝑚𝑎𝑥 =
4𝑥10−3 428 250 2,34𝑥10−3 1,19𝑥10−3
1
5,5𝑥10−3 449 181,81 2,23𝑥10−3 = 𝑉𝑚𝑎𝑥 𝑉𝑚𝑎𝑥 = 840,33 𝑚𝑙 Τ𝑠𝑒𝑔
𝐴
7𝑥10−3 457 142,85 2,19𝑥10−3

𝐴 = 1,19𝑥10−3 100 % → 1
𝐵 = 5,99𝑥10−6 1% → 𝑥
𝑥 = 0,01
 𝑥2
𝐾𝐶 ^ =
(6 − 2𝑥)2

𝑥2
𝑁2 + 𝑂2 → 2 𝑁𝑂 2𝑥 = 0,55 𝑚𝑜𝑙 1,13 =
𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑜 (6 − 2𝑥)2
1 0,75 − 𝐾𝑐 = 0,55 𝑚𝑜𝑙
𝑟𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠 𝑥=
𝑥 𝑥 2𝑥 2
1−𝑥 0,75 − 𝑥 2𝑥 𝑥2
𝑥 = 0,275 𝑚𝑜𝑙 1,13 =
(6 − 2𝑥)2
2𝑥 2
𝐾𝑐 = 2 𝑁𝑂 → 𝑁2 + 𝑂2 𝑥
1 − 𝑥 0,75 − 𝑥 2 3−𝑥 𝑥 𝑥 1,06 =
6 − 2𝑥
2 ∗ 0,275 𝑚𝑜𝑙 2 6 − 2𝑥
𝐾𝑐 = 6,36 − 2,12𝑥 = 𝑥
1 − 0,275 𝑚𝑜𝑙 0,75 − 0,275 𝑚𝑜𝑙
6,36 = 2,12𝑥 + 𝑥
𝐾𝑐 = 0,878 6,36 = 3,12𝑥
𝑁𝑂 = 6 − 2𝑥 = 6 − 2 2,04 𝑚𝑜𝑙 = 1,92 𝑚𝑜𝑙 6,36 𝑥 = 2,04 𝑚𝑜𝑙
𝑥=
𝐾𝐶 ^ = 1,13 𝑁2 = 𝑥 = 2,04 mol 3,12
𝑂2 = 𝑥 = 2,04 𝑚𝑜𝑙
^ 1 1
𝐾𝐶 = =
𝐾𝐶 0,878
𝑁2 + 𝑂2 → 2 𝑁𝑂
1 1 −
𝑥 𝑥 2𝑥
1−𝑥 0,75 − 𝑥 2𝑥
 𝑡𝑖𝑒𝑚𝑝𝑜 𝑑𝑒 𝑣𝑖𝑑𝑎 𝑚𝑒𝑑𝑖𝑎

𝐴1
𝑡=
2𝐾0
tiempo conc In C 𝟏 𝐴2 = −𝐾0 𝑡 + 𝐴1
222,35
𝑪 𝑡=
𝑌= 𝐵𝑋 + 𝐴 2 ∗ 4,08
0 220 5,39 4,55𝑥10−3
7 195,3 5,27 5.12𝑥10−3 −𝐾0 = 𝐵 𝑡 = 27,248 𝑑𝑖𝑎𝑠
−𝐾0 = −4,08 −1
14 159 5,07 6,29𝑥10−3
21 145,5 4,98 6,87𝑥10−3 𝐾0 = 4,08 𝑡𝑖𝑒𝑚𝑝𝑜 𝑑𝑒 𝑣𝑖𝑑𝑎 𝑢𝑡𝑖𝑙 90 %

28 115 4,74 8,70𝑥10−3

220 → 100 % 𝑡 = 5,96 𝑑𝑖𝑎𝑠
35 71 4,26 0,014
𝑥 → 90 %
𝑜𝑟𝑑𝑒𝑛 𝑐𝑒𝑟𝑜 1𝑒𝑟 𝑜𝑟𝑑𝑒𝑛 2𝑑𝑜 𝑜𝑟𝑑𝑒𝑛 𝑥 = 198 𝑢𝑔Τ𝑚𝑙
𝐴 = 3,39𝑥10−3
𝐴 = 222,35 𝐴 = 5,48 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛 𝑑𝑒 1𝑒𝑟 𝑜𝑟𝑑𝑒𝑛
𝐵 = 2,39𝑥10−4
𝐵 = −4,08 𝐵 = −0,03 𝑖𝑛 𝐴2 = −𝐾1 𝑡 + ln 𝐴1
𝑟 = 0,905
𝑟 = −0,991 𝑟 = −0,961