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successions that consist mainly of interbedded lime- three deeply buried data sets as they may have been
stones and dolostones (Figure 1). Three of these cases at an earlier stage before burial diagenesis.
have been deeply buried, whereas two have never Reservoir quality is examined here using three
been deeper than their present range of 0 –700 m types of data display: (1) histograms of porosity fre-
(0– 2296 ft). Comparisons in each data set allow the quency distribution (Figures 2 – 7), (2) porosity-depth
evaluation of the effects of dolomitization, whereas profiles showing the vertical stratigraphic organization
comparisons between the deeper and shallower data of porosity with respect to lithology and depositional
sets may be relevant to understanding the effects of cyclicity (Figures 8 – 12), and (3) permeability-porosity
burial diagenesis. Details of stratigraphy and geologic crossplots (Figures 13 – 16). These simple visual repre-
setting for each example have been described in pre- sentations facilitate a rapid comprehension of overall
vious publications. The purpose of this article is to similarities and differences between complex data sets.
compare these data sets and point out overall similari-
ties and differences of possible general significance.
Our five data sets represent very diverse and dis- METHODS
similar assemblages of depositional facies and strati-
graphic patterns, so it is relevant to question whether The porosity, permeability, and grain-density data pre-
comparison is meaningful. It is also uncertain to what sented here are from 1-in. (2.5-cm) plugs that were
degree the dolostones of each data set represent the drilled from cores and outcrops. The measurements
same precursor lithofacies as the associated limestones. were made by various laboratories but used similar
These are valid concerns for which we have no clear techniques that are more or less industry standard. Data
answers. However, we suggest that these five data sets and analytical techniques are available for the shal-
are each so unique and complexly heterogeneous that low data sets in Anselmetti and Eberli (2001), Melim
the commonalities observed potentially carry broad et al. (2001a), and Ehrenberg et al. (2004a). Analytical
significance for carbonate reservoirs worldwide. Nev- techniques for the deeply buried data sets are similar:
ertheless, a key issue that we discuss further in this ar- porosity by helium injection and weight-volume rela-
ticle is the degree to which the two shallowly buried tionships and permeability by pressure differential dur-
data sets represent valid analogs for interpreting the ing nitrogen flow.
Ehrenberg et al. 93
Figure 2. Frequency distribution of DI values estimated from mineralogic analyses for each data set examined. Bar fill indicates
limestone (open), intermediate (gray), and dolostone (black) for each data set examined.
Proportions of calcite, dolomite, and noncarbonate gible contents of noncarbonate minerals. X-ray dif-
minerals have been estimated in each plug sample by fraction analyses were also available for many plugs,
various methods using whatever information is avail- but in all other cases, plug mineralogy was confirmed
able for each sample group. For the Finnmark samples, by either testing for reaction with HCl or from thin-
bulk rock x-ray diffraction analyses, bulk chemical anal- section petrography. For Asmari plugs, calcite, dolo-
yses, and thin sections were made for approximately mite, quartz, clay, and anhydrite contents were esti-
every third plug over most cored intervals, and the mated first from qualitative thin-section examination
results were then interpolated to intervening plug sam- (roughly one per meter, approximately equivalent to
ples using information from grain density, core descrip- every third plug), with reference to grain-density values
tions, and, in cases of particular uncertainty, exami- (available for most cores). These estimates were then
nation of the actual plug samples. For the Madison checked against a set of bulk chemical analyses for 478
samples, relative dominance of calcite and dolomite was of the samples. Finally, these results were then inter-
estimated from grain-density values, assuming negli- polated to intervening plug samples using information
from grain density and core descriptions. For the Baha- GEOLOGICAL SETTING
mas plugs, the mineralogic data reported in Anselmetti
and Eberli (2001) and Melim et al. (2001a) were used. The locations of the five data sets studied are shown in
For the Marion Plateau plugs, mineral abundances were Figure 1. Miocene–Pleistocene platform-to-slope strata
estimated from a combination of petrographic obser- of the Great Bahama Bank were sampled in boreholes
vations and bulk chemical analyses of selected plugs Unda and Clino at depths of 33–670 m (108–2198 ft)
(Ehrenberg et al., 2004a) and interpolation using grain- below the mud pit in 7 m (23 ft) of water depth (Eberli
density values, shipboard core descriptions, and x-ray et al., 2001; Melim et al., 2001a). Parts of the cores from
diffraction data (Isern et al., 2002). these locations that consist of fine-grained slope facies
Ehrenberg et al. 95
Figure 6. Frequency distribution of plug
porosity measurements in outcrops and
cores of the Madison Formation (Missis-
sippian, Wyoming and Montana), maxi-
mum burial depth 3300–7500 m (10,826–
24,606 ft).
are excluded from the present comparison involv- United States (Smith et al., 2004; Westphal et al., 2004).
ing platform carbonate facies. Dolomitized platform The maximum burial depth is believed to have been
(reefal) facies occur only in the Unda core at 293 – 3300 – 7500 m (10,827 –24,606 ft). Early dolomitiza-
360-m (961 – 1181-ft) depth, where fabric-preserving tion is interpreted to have occurred by both reflux of
to microsucrosic dolomite is interpreted to have hypersaline brine and circulation of normal-marine sea-
formed shortly after deposition from slightly altered water (Moore, 2001; D. Katz, 2005, personal commu-
seawater (Swart and Melim, 2000; Melim et al., nication), but stable isotope data have been viewed as
2001b). indicating subsequent recrystallization of most Madi-
Miocene platform strata from two carbonate plat- son dolomite in mixed meteoric-marine waters (Budai
forms on the Marion Plateau, offshore northeast Aus- et al., 1987). Later hydrothermal dolomitization oc-
tralia, were sampled at depths of 0 – 650 m (0 – 2133 ft) curred during Laramide thrusting (Katz et al., in press).
in three boreholes drilled by Ocean Drilling Program Data compiled in this study include outcrop samples
(ODP) Leg 194 (Isern et al., 2002; Ehrenberg, 2004a; from the Benbow Mine Road, Shoshone Canyon,
Ehrenberg et al., 2004b). As in the Bahamas cores, do- Sheep Mountain, Wind River Canyon, Casper Moun-
lomitization of the Marion Plateau strata is interpreted tain, Freemont Canyon, Hartville Canyon sections, and
to have occurred by circulation of normal to slightly subsurface samples from the Lysite, Madden Deep, and
altered seawater at low temperature with essentially Beaver Creek cores (Smith et al., 2004; Westphal et al.,
no influence of evaporative concentration (Ehrenberg, 2004).
2004a; Ehrenberg et al., in press). The Oligocene – lower Miocene Asmari Forma-
The Pennsylvanian –Lower Permian Finnmark car- tion is represented by cores from five wells in two
bonate platform was cored in two exploration wells, giant oil fields of southwest Iran (Aqrawi et al., 2004;
offshore north Norway (Ehrenberg et al., 1998a, b, Ehrenberg et al., 2004a). Published information on
2002; Ehrenberg, 2004b). The present burial depth is the Asmari Formation is sparse, but general reviews
1410 –1750 m (4626– 5741 ft), but maximum burial in are given in Hull and Warman (1970) and McQuillan
the early Tertiary was probably 2400 –3300 m (7874 – (1985). The present burial depth in the studied oil
10,827 ft). fields ranges from 1660 to 3700 m (5446 to 12,139 ft),
The Mississippian Madison Formation was sam- but the maximum burial was probably 500 –1500 m
pled in outcrop sections and cores from the Big Horn (1640–4921 ft) deeper. Variable dolomitization of both
and Wind River basins of Wyoming and Montana, the Asmari and Finnmark strata is suggested to have
Ehrenberg et al. 97
Figure 8. Depth-porosity
profiles in two bore-
holes of the Bahamas
Drilling Project. Distance
between locations is
8.5 km (5.2 mi). Hori-
zontal lines indicate bases
of seismic sequences a
to h (Eberli et al., 2001).
Plotting symbols indicate
the dominant mineralo-
gy and depositional set-
ting (large symbols =
platform; small symbols =
slope). The bar to the
right of the porosity data
shows the division of
each sequence into low-
stand + transgression
(black) and highstand
(white).
anhydrite is another key parameter related to lomitization. Samples with DI greater than 0 but less
porosity in the Finnmark and Asmari data sets. Cal- than 25 are commonly wackestones and packstones,
cium sulfate minerals are not present in the Bahamas in which the mud matrix is partly replaced by dolo-
and Marion Plateau sections because of nonarid depo- mite. The relative paucity of intermediately dolomi-
sitional conditions and are absent from the Madison tized rock has been reported previously (Steidtmann,
outcrop samples because of surficial leaching. Both the 1917; Chave, 1954; Institut Français du Pétrole, 1959;
Finnmark and Asmari cores contain subordinate beds of Schmidt, 1965) and may be a general characteristic
dominantly siliciclastic composition, but samples from of carbonate strata, reflecting some intrinsic aspect of
these beds have been excluded from Figures 2 – 7 and the dolomitization process (Blatt et al., 1980, p. 517).
13–16 because this study concerns only carbonate rocks. This characteristic may largely reflect the process of
Figure 2 shows histograms of DI values from sam- dissolution of the remaining calcium carbonate during
ples for which mineral abundances have been estimated or after partial dolomitization, as discussed below.
from direct analytical control (based on petrography, Only for the Finnmark, Bahamas, and Marion Pla-
x-ray diffraction, bulk chemistry, or some combination teau data sets are the constraints of analytical control
of these, as opposed to mineralogic estimation by inter- tight enough to define an intermediately dolomitized
polation between analyzed samples or from grain den- grouping of plugs throughout each data set (for ex-
sity alone). Most samples in each data set are com- ample, Ehrenberg, 2004b). For the Asmari and Madison
posed mainly of either calcite or dolomite, with partly data, it has proved impractical to consistently distin-
dolomitized samples of intermediate composition (DI = guish intermediately dolomitized samples from either
25–75) being subordinate in all cases. In each data set, more pure limestones or more pure dolostones for the
a large proportion of the samples with DI less than majority of plugs where either a thin section or a bulk-
100 but greater than 75 are dolostones in which the chemical analysis is not available. Throughout the re-
calcite occurs only as late cement, postdating do- mainder of this article, therefore, ‘‘limestone’’ and
‘‘dolostone’’ are defined as referring to carbonate- stones and dolostones have similar average porosity,
dominated rocks with DI < 50 and DI > 50, respectively. although the Marion Plateau dolostones are distinctly
This convention lumps relatively pure limestones to- skewed toward higher frequency at lower porosities.
gether with subordinate numbers of partly dolomitized Porosity histograms comparing limestones and do-
limestones and lumps relatively pure dolostones with lostones of the three deeply buried data sets show
subordinate numbers of dolomite-dominated carbonates important features in common (Figures 5–7), which
of intermediate composition. We feel that such simpli- contrast sharply with the histograms of the shallowly
fication is nevertheless preferable to working with an in- buried strata (Figures 3, 4). In each case, the deeply
termediately dolomitized grouping that would likely in- buried limestones have strongly positively skewed po-
clude significant proportions of both pure limestones and rosity distributions with the highest frequency of val-
pure dolostones. In any case, the uncertainties involved ues, or mode, in the range 0–5%, whereas deeply
in the classification of intermediately dolomitized sam- buried dolostones have more symmetrical distributions
ples are believed to be relatively insignificant with regard with the mode about 8–15% and relatively few values
to the overall differences observed in comparing the lime- less than 5%. For Asmari reservoirs in other oil fields,
stones and dolostones defined by the simple 50% rule. Lees (1933) found no relationship between dolomi-
tization and porosity, whereas Chilingar and Terry
(1954) reported a strong relationship.
POROSITY A degree of uncertainty exists for the samples from
the Madison Formation because surficial weathering
Limestone versus Dolostone appears to have leached anhydrite from the outcrop
samples, which make up the major part of this data
Porosity histograms for the two shallowly buried data set, and deep penetration of meteoric water is reported
sets show only modest differences between limestones to have leached anhydrite throughout the subsurface
and dolostones (Figures 3, 4). In each case, the lime- of the Wind River basin (Moore, 2001). Anhydrite is,
Ehrenberg et al. 99
Figure 10. Depth-
porosity profiles in cores
from two exploration
wells on the Finnmark
platform, penetrating
the Gipsdalen Group
(shallow-water carbonate-
dominated section of se-
quences 1 to 4). Hori-
zontal lines indicate the
bases of sequences 1 to 5.
Plotting symbols indicate
the dominant mineralo-
gy. The bar to the right
of the porosity data
shows the division of
each sequence into
transgression (black)
and highstand (white).
however, commonly present in subsurface Madison petrographic categories: (1) grainstones and mud-poor
samples from the Big Horn basin (Sonnenfeld, 1996). packstones in which formerly abundant intergranular,
Insofar as anhydrite may be more abundant in dolo- intrafossil, and moldic macropores have been mostly
stones than limestones, the leaching could have the filled by coarse calcite cement; and (2) mud-supported
effect of enhancing the porosity contrast between Ma- facies that have lost porosity by tight cementation of
dison limestones and dolostones. the mud matrix (dominant process) by filling of intra-
fossil spaces with coarse calcite spar and by mechanical
compaction.
Pore Types and Mechanisms of Porosity Loss Limestones with porosity greater than 10% com-
prise 21% of this data set. Of these 268 plugs, 57 samples
To better understand the comparisons in Figures 3 – 7, represented by thin sections reveal that most macro-
it is necessary to examine the range of lithofacies and porosity consists of primary intergranular and intra-
diagenetic fabrics characterizing the following key groups fossil pores that have been partly but not completely
from each of the three deeply buried platforms: (1) tight filled by calcite cement.
limestones, (2) porous limestones, and (3) porous do- Dolostones with porosity greater than 10% com-
lostones. It is especially pertinent to enquire why the prise 17% of the Finnmark data set. Of these 215
tight limestones of each data set have low porosity. plugs, 59 samples represented by thin sections con-
tain two dominant pore types: intercrystalline pores
Finnmark Platform between dolomite crystals (replacing matrix and bio-
Limestones with porosity less than 5% comprise 24% of clasts and, to some degree, also infilling relict inter-
this data set. Of these 311 plugs, most of the 87 samples granular pore spaces) and moldic pores representing
represented by thin sections can be grouped into two former bioclasts.
serve to initiate stylolitic dissolution. However, bar- and wackestones of a proximal inner-platform setting,
riers are formed by thinner intervals of argillaceous where high porosity reflects preservation of intercrys-
limestones that formed during transgressions marking talline and moldic pores.
the bases of the high-frequency sequences comprising Sequence 4 consists mainly of limestones, which
sequence 3. The late-highstand phase of sequence 3 cor- preserve high porosity in the lower, transgressive part
responds with the deposition of dolomitic mudstones of the sequence, but become tightly calcite-cemented
upward because of increasing frequency of stylolite- bution of both dolomitization and porosity are related
prone clay laminations. Sequence 5 consists of bryozoan- to platform paleogeography in the lower composite
echinoderm grainstone and packstone and is not in- sequence. In the most downdip (seaward) part of the
cluded in the photozoan carbonate strata that are the ramp (Benbow Mine Road and Shoshone Canyon sec-
subject of this article. Uniformly low porosity in tions), dolomitization affected mainly mud-dominated
sequence 5 reflects the combination of frequent stylo- strata, whereas less than 5% of grain-dominated strata
lites and abundant echinoderm sites for syntaxial cal- are dolomitized. Further updip, in the midramp part of
cite cement growth. the platform (Wind River Canyon and Lysite core sec-
tions), there is pervasive dolomitization of all rock types,
Madison Formation whereas the most landward locations (Casper Mountain,
The Madison platform evolved from a ramp profile in Freemont Canyon, Hartville Canyon) have a patchy do-
its lower composite sequence (including sequences I, lomite distribution with both muddy and grainy litholo-
IIa, and IIb of Figure 11) to a flat-topped shelf during gies preserved as limestone in parts of the succession.
the deposition of its upper composite sequence (se- Figure 11 compares porosity and dolomitization
quences III to VI) (Sonnenfeld, 1996). Smith et al. (2004) profiles through three sections from the relatively down-
and Westphal et al. (2004) recognized how the distri- dip (seaward) part of the ramp. Benbow Mine Road and
Shoshone Canyon are located in the most downdip the Madison data set are not shown in Figure 11 but
position, where sequence I shows strong differentiation are located farther updip ( landward), where se-
into an entirely dolomitized and porous transgressive quences I, IIa, IIb, and lower III are pervasively dolo-
tract and a variably dolomitized highstand tract with mitized. In all localities, sequences IV and V consist
generally low porosity. Sequences IIa and IIb (as defined mostly of tight limestone, where porosity loss has oc-
by D. Katz, 2005, personal communication) have low curred mainly by chemical compaction during burial
dolostone porosity, whereas sequence III has a high do- (Crockett, 1994).
lostone porosity throughout. Sheep Mountain is located
farther updip, in a position transitional to the pervasively
dolomitized midramp setting. Higher proportions of Asmari Formation
grain-dominated strata were dolomitized in this loca- The principal barriers to matrix flow in the Asmari
tion, and there are higher proportions of porous dolo- Formation consist of tight limestones (Figure 12), al-
stone in both the highstand tract of sequence I and though the extent to which these are fractured and,
throughout sequences IIa and IIb. In all three locations thus, open to flow between adjacent porous layers is
in Figure 11, porous dolostone occurs mainly in the largely unknown. Fractures are important for Asmari
muddy, transgressive parts of sequences and cycles oil production (Hull and Warman, 1970; McQuillan,
(Smith et al., 2004). The other localities included in 1985). A striking feature is the development of tight
Figure 17. Hypothetical model for the effect of burial diagenesis on permeability-porosity relationships in interlayered limestones
(circles) and early-formed dolostones (diamonds). At shallow burial depth (A), the limestones and dolostones do not have notably
different porosity distribution, but all dolostones have high permeability (black diamonds), whereas the limestones are divisible
into strata with high permeability (black circles) and low permeability (green circles). After deep burial (B), the limestones initially
having low permeabilities have been most strongly affected by burial diagenesis, resulting in postburial permeabilities of 0.01 md
or less. Limestones initially having high permeabilities have been less severely affected because of more grain-supported textures
relatively resistant to permeability loss. As a result, those limestones and dolostones having greater than 0.01 md permeability in
the deeper subsurface do not have notably different overall porosity-permeability relationships.