Elfante, Erika Naelle L.

2ABC
E3D 5 (a) Calculate the standard
.
Gibbs energy of reaction for 4H1(g) + 02 19) ->
212 (5) +

2H20(1) at 398K using the

values of standard entropies and enthalpies of formation given in the resource section .

4 H1 (g) + 02 (g) -> 212(s) +

2H20(1)
0SrxnJ/molK :
206 59205 138 .
.
110 13. 69 9 .

0Hrxn 1/mol =

20 48 .
8 0 -

285 83
.

85 =

E products -

[ reactants

=((2) (116 -
13) +

(2)(69 .
9)) -((4)(206 . 59) + (205 138)] .

=-659 438 .
1kmol

8H =

E products -

Ereactants
=((2)) -

285 .
83) +
(0)] -

((4)(26 48) .
+ (01]
=
474 58K)/mol .

06 =

CH -
TOS

=
-

644 58k/mol -(290k)(

. -0 . 659438k1K moll
06 = 481 07 Kl mol .

ESE 1 (a) The

.

change in the molar volume accompanying fusion of solid CO2 is -1 .

Gem/mol .
Determine the change in the molar Gibbs

energy of fusion when the pressure is increased from /bar to 1000 bar

P, =

1 bar

Pr 1000 bar
=

<
p, =

1 bar 10 Pa =105 Pa
x

I bar

P2 =

1000 bar x
10 Pa =1000 x 104 Pa
I bar

08 =
Um OP

=) 6cm/mol(1004m)")
-

1 .
(1000 x 105 pa -10
=
pa)

16 =

-159 .
84 J1mol
EBE (b) Calculate the the molar Gibbs energy of when its pressure is increased 50 0 kPA
.

change in a perfect gas is othermally from .

to 100 0 kPG at 500K

.
.

86=-RTIn/)
thermal
:

is

18 314kmol) (50K) In
bool
-- .

28816/mol

EBE 4 (b) The change in the Gibbs energy of a certain constant is found fit the expression
pressure process to
-
.

8611 =-73 . 1 +

42 8 .
(T1K) . Calculate the value of ↓S for the process .

06
=

WH-TWS

8616 = -

43 16 .
+

42 . 81K

1/p:
-

&S = -

42 8 (1K .

E3E 5 (b) the Gibbs energy found

change in the of a certain constant-pressure process is fit the expression
.

to

0011 =-43 1 42 8 (T1K) Use the Gibbs Helmholtz equation to calculate the value of OH for the process
+
-
.
.
.
.

(888 q
= -

80(p
8H +
/
= -

T2(8)) 15) 13/p

=
-

45 .
+
142 8 /
.

43 11
=
.

Cp=vTa/ls
1 .

Show that

Its 10
I S (T P(

/
=

ids
T() 9P+
( )p &T
=

0 (((I)
T(q)pdT T()
=

(
*) +
dP = -

/)pdT
Is :
It)s=p 1s :
18/
Cp() via (p
vix//s
+
= =

s
2 .
Show that

18 !!!! J :
V

Write an expression that would allow you to relate WA at two temperatures .

A :

U-TS

FA =

GU-TdS
-

S65

SA =

20-dq-S6T
2A = =

PdU-SdT

1) =

P)r-r
1)
-

s
=

(14) =

() +
*
181)r
(f)( x
( ) Fz(ST A)
-

+
+ -

=
-
=
2

181)) =

161! (r
-
-
(0 !! (v -

Fe

1 ?! ] = - .

I ! ! , Jr =
v

6 =

H -

TS

26 =

GH -

TdS -

565

26 =

56S + VGP-56S-S65
26 =

VGP-S65

to p
1e

p
-
S
=

(ii ! ] =
(2)p+ 6(0)! (o
(8 ! (p
 5)
I( ( )
-
-

Fa
-

-I -
In
6)
I(55
+
-

H
=

-Is

SY 6101)
(I H 8111)
=

3 .
Assume the internal energy of an elastic fiber under tension is
given by ar=TdS
-

Par-Fdl .
Obtain an expression

for
184) p, I

6 =
H -

TS

26 =

GH- TdS -

SAT

66 =

2 (U + PV) -

TdS -

SAT

26 =
20 + PdV +VdP-idS -SAT

26 =

TdS -

Par .

Fre +

Par+vaP-IdS -SdT
66 = -

FGl+ VAP-SOT

lo +"*) , +"ot-slat
.

(2(p
=
-

F
+

0 +

0
+

F
↳(p
-

, +