particular

dependent
dependency)
temperatures, expression
various Where empirical
equation THEORY: CHEMICALS: APPARATUS;
saponification AIM:
ExptNo: 3
Ko /E
(K), In Kz K batchAs
in stand k, The
Phenolphthalein Acetic
acid acetate
hydroxide
Sodium Ethyl Burette
Pipette
Watch
Stop Conical
is To
temperature
term fitscalled establish
influence TEMPERATURE
lexp(-E/RT|)-K, follows:
= we points
=Ky experiment flask reaction
f>
RT,T,/ KÍ can known
exp exp(composition) reactor frequency
as the
=ER{1/T,- 1/T] determine being of one (
(-E/RT)
(T|(-E/RT2) assuming indicator of
nature
well temperature
as 1000 ethyl
-T;) experiment,
afactor K=k,Arrhenius
exp
very over (-E/RT) acetate of
at at the , ml temperature
DEPENDENCY
(K/kz) temp temp requency CAa good wide and size
second with
CB we E equation: on and
T; TË approximation
temperature is
determine
. the Na
From
called 12
factor order of
dependency
rate OH
the 250
the constant solution.
and reaction the activation ranges ml OF
values to
activation value the ) of REACTION
is the
of true and
kinetics of energy expressed reaction
rate temperature is
energy the strongly
constants
rate of rate RATE
(i.e. Date:
the in
(i.e. constant suggested constant
concentration dependency. reaction. terms
temperature at
a
various K for
of
at from This
an the 14
a
 can
HCL
ko [(M-X)/M(I
of factor
corresponding
OH/Normality
10 X)I
HCL)* calculated frequency T;
(-E/R),
of
In
mols/litre Na
V*(Normality linebe the to the [(M-XA)M(1-XA
can and
straight equal
of and
titration)*(Normality k
constant
also slopE 330 O320D5
G9 5
reactor, 10* abe energy
temperatures. 88
temperatures
a T2 XA 3u
mols/itre (20 (20* to with
rate
2mins observed activation o-
the / line
in = mixture
titration the In
T) taken mixture 2,..1 straight
acctatc, which
is twocorresponding XA
temp back ml the
back reaction tvs
OH =20
from other
(For cthyl
Na in in reaction
sample
=
t
)]
M(1-XA the
a
be
which ((M-XAIM(1
In
used
used for (M-1) to
at the observed
of of
CALCULATIONS: excess the from O-3)5
calculations procedure TË XA)]
OH thethe in
concentration OH
concentration
Na Na to in left )/ CAo against kÍ
HCL
minute
left [(M-XA
K In
of of added OHCA to T to
of =(Volume
Volume
OH Na / above equal
noted
above vs equalTABULATION 6-51 0-53
CAO 1 ml
InitialM=Cg
Initial Na -CA) k XA
0-425
=
t (V)=
HCL of In In calculated
be
time, of moles
=(C O the of slope arethe of y-intercept
MODEL
= = = of moles plot valuesplot (mins)
t
CAOCRO the vol. Repeat
With
Repeat
= X The The 2 3 4 5 6
At Ca k
2

ENpevient

23cyoohb
Dhenvshs
 RESULT: from GRAPH:
10 8
slope
2. 1. Plot
Activation
Temperature and a
graph
y-intercept
of
energy In S.No
effect 3 2 1
respectively vsk
on is
determined 1/T,
Rate T; T2 T T
rate
constant constant
and
r0032 1/T
found k
and
to frequency
be K3 K2 KI K

factor -2-3 -29h InK

ko
can
be
calculated

17