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EXERCISE-1
ATOMIC STRUCTURE
JEE MAIN 2020
1
1. n  5, m s   How many orbitals are possible (7JAN_S1)
2
a) 25 b) 30 c) 50 d) 35
2. Amongst the following which is not a postulate of Dalton’s atomic theory (7JAN_S1)
a) Matter is formed of indivisible atoms
b) Under identical conditions of pressure and temperature gases combines and give gaseous products in simple
volume ration
c) During chemical reactions atoms remains conserved and only pass through rearrangement
d) Some atoms have same properties including atomic mass
3. Given, for H–atom (8JAN_S1)
 1 1 
v  RH  2  2 
 n1 n2 
Select the correct options regarding this formula for Balmer series.
a) n 1 = 2
b) Ionization energy of H atom can be calculated from above formula
c)  m a x im u m is for n 2  3
d) If  decreases then spectrum lines will converse
4. Determine Bohr’s radius of L i 2 + ion for n = 2 . Given (Bohr’s radius of H–atom = a 0 ) (8JAN_S2)
3a0 4a0 a0 16a0
a) b) c) d)
4 3 3 9
5. Determine wavelength of electron in 4th bohr’s orbit? (9JAN_S1)
a) 4  a 0 b) 2  a 0 c) 8  a 0 d) 6  a 0
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 1 
6. For emission line of atomic hydrogen from n i = 8 to n f = n , the plot of wave number  v  against  2 
will be
 n 
(The Rydberg constant, R H is in wave number unit) (9JAN_S1)
a) Linear with intercept – R H b) Non linear
c) Linear with slop R H d) Linear with slope – R H
7. Which of the following combination of statements is true regarding the interpretation of the atomic orbitals?
(9JAN_S2)
A) An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital
of lower angular momentum
B) For a given value of the principal quantum number, the size of the orbit is inversely proportional to the
azimuthal quantum number.
h
C) According the wave mechanics, the ground state angular momentum is equal to
2
D) The plot of  v s r for various azimuthal quantum numbers, shows peak shifting towards higher r value
a) A, D b) A, B c) A, C d) B, C
8. Which of the graphs shown below does not represent the relationship between incident light and the electron
ejected from metal surface? (10JAN_S1)

a) b) c) d)
9. The ground state energy of hydrogen atom is –13.6 eV. The energy of second excited sate of H e + ion in eV is
(10JAN_S2)
a) –54.4 b) –3.4 c) –6.04 d) –27.2
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10. Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H–atom
is suitable for this purpose?  R H  1  1 0 5 c m  1 . h  6 .6  1 0  3 4 J s , c  3  1 0 8 m s  1  (11JAN_S1)
a) Paschen,  
 3 b) Paschen, 5 
 3 c) Balmer,  
 2 d) Lyman  
1

11. The de Broglie wavelength    associated with a photo–electron varies with the frequency  v  of the incident
radiation as, [ v 0 is threshold frequency]: (11JAN_S2)
1 1 1 1
a)   b)   c)   d)  
v  v0 
1 3 1

 v  v0  4  v  v0  2  v  v0  2
12. What is the work function of the metal if the light of wavelength 4 0 0 0 A 0 generates photoelectrons of velocity
1
6  1 0 m s from it?
5

31
(Mass of electron = 9  1 0 k g , Velocity of light = 3  1 0 8 m s  1 , Planck’s constant = 6 .6 2 6  1 0  3 4 J s , Charge of
electron = 1 .6  1 0  1 9 J e V 1
) (12JAN_S1)

a) 0.9 eV b) 3.1 eV c) 2.1 eV d) 4.0 eV

13. If the de Broglie wavelength of the electron in n th Bohr orbit in a hydrogenic atom is equal to 1 .5  a 0 ( a 0 is Bohr
radius), then the value of n / z is: (12JAN_S2)
a) 0.40 b) 1.50 c) 1.0 d) 0.75

14. The quantum number of four electrons are given below : (8APR_S1)
I) n  4 , l  2 , m l   2 , m s   1 / 2 II) n  4 , l  2 , m l   2 , m s   1 / 2
III) n  4 , l  1, m l  0 , m s   1 / 2 IV) n  3, l  1, m l  1, m s   1 / 2
The correct order of their increasing energies will be
a) IV < III < II < I b) I < II < III < IV c) IV < II < III < I d) I < III < II < IV
15. If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of light having
wavelength  , then for 1 .5 p momentum of the photoelectron, the wavelength of the light should be
(Assume kinetic energy of ejected photoelectron to be very high in comparison to work function)
(8APR_S2)
3 1 2 4
a)  b)  c)  d) 
4 2 3 9
16. For any given series of spectral lines of atomic hydrogen, let  v  v m a x v m in be the difference in maximum and
minimum frequencies in c m  1 . The ratio  v L y m a n /  v B a lm e r is: (9APR_S1)
a) 4: 1 b) 9: 4 c) 5: 4 d) 27: 5
17. Which one of the following about an electron occupying the 1 s orbital in a hydrogen atom is incorrect? (The Bohr
radius is represented by a 0 ) (9APR_S2)
a) The probability density of finding the electron is maximum at the nucleus
b) The electron can be found at a distance 2 a 0 from the nucleus
c) The magnitude of the potential energy is double that of its kinetic energy on an average
d) The total energy of the electron is maximum when it is at a distance a 0 from the nucleus
2
18. The graph between  and r (radial distance)is shown below. This represents (10APR_S1)

a) 3 s orbital b) 2 s orbital c) 1 s orbital d) 2 p orbital

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19. The isoelectronic set of ions is (10APR_S1)
3 2 2  3  2 2
a) N , O , F a n d N a b) N , Li , M g and O
   2   2 
c) F , L i , N a a n d M g d) L i , N a , O a n d F
20. The ratio of the shortest wavelength of two spectral series of hydrogen spectrum is found to be about 9. The
spectral series are: (10APR_S2)
a) Lyman and Paschen b) Balmer and Brackett c) Brackett and Pfud d) Paschen and Pfund
21. The group number, number of valance electrons, and valancy of an element with atomic number 15, respectively,
are (12APR_S1)
a) 16, 5 and 12 b) 15, 5 and 3 c) 16, 6 and 3 d) 15, 6 and 2
22. The electrons are more likely to be found (12APR_S2)

a) in the region a and c b) in the region

and b c) only in the region a d) only in the region c
a
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23. The radius of the second Bohr orbit for hydrogen atom is
34 31
(Planck’s Const : h  6 .6 2 6 2  1 0 J s ; mass of electron = 9 .1 0 9 1  1 0 k g ; charge of electron
19
e  1 .6 0 2 1 0  1 0 C ; permittivity of vacuume
12 1 3
 o  8 .8 5 4 1 8 5  1 0
2
kg m A )
0 0 0
a) 1 .6 5 A 0 b) 4 .7 6 A c) 0 .5 2 9 A d) 2 .1 2 A
STIOCHIOMETRY
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24.
0.6g of urea on strong heating with NaOH evolves NH3. Liberated NH3 will combine completely with which of the
following HCl solution? (7JAN_S1)
a) 1 0 0 m L o f 0 .2 N H C l b) 4 0 0 m L o f 0 .2 N H C l
c) 1 0 0 m L o f 0 .1 N H C l d) 2 0 0 m L o f 0 .2 N H C l
25. Calculate the mass of F e S O 4 .7 H 2 O , which must be added in 100kg of wheat to get 10 PPM of Fe (8JAN_S1)
26. Given a solution of HNO3 of density 1 .4 g / m L and 63% w/w. Determine molarity of HNO3 solution. (9JAN_S1)
27. One litre sea water  d = 1 .0 3 g / c m 3  contains 1 0 .3 m g O2 gas. Determine concentration of O 2
in ppm. 9JAN_S2)
JEE MAINS 2019-
28. A solution of sodium sulfate contains 92 g of N a + ions per kilogram of water. The molality of N a + ions in that
solution in mol k g  1 is (9JAN_S1)
a) 12 b) 4 c)8 d) 16
29. For the following reaction the mass of water produced from 445 g of C 5 7 H 1 1 0 O 6 is (9JAN_S2)
2 C 57 H 110 O 6  s  + 1 6 3 O 2  g   
 114 C O 2 g  + 110 H 2 ) l 
a) 490 g b) 445 g c) 495 g d) 890g
30. A mixture of 100 m mol of C a  O H  2 and 2 g of sodium sulphate was dissolved in water and the volume was

made upto 100 mL. The mass of calcium sulphate formed and the concentration of O H in resulting solution,
respectively, are : (Molar mass of C a  O H  2 , N a 2 S O 4 and C a S O 4 are 74, 143 and 1 3 6 g m o l  1 , respectively;
of C a  O H  2 is 5 .5  1 0 )
6
K sp
(10JAN_S1)
1 1 1 1
a) 1 .9 g , 0 .2 8 m o l L b) 1 3 .6 g , 0 .2 8 m o l L c) 1 .9 g , 0 .1 4 m o l L d) 1 3 .6 g , 0 .1 4 m o l L

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31. A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 mL of CO2 at T = 298.15
K and P = 1 bar. If molar volume of CO2 is 25.0 L under such condition, what is the percentage of sodium
bicarbonate in each tablet? [Molar mass of N a H C O 3 = 8 4 g m o l  1 ] (11JAN_S1)
a) 0.84 b) 33.6 c) 16.8 d) 8.4
32. 25 mL of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of this
HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solution? (11JAN_S2)
a) 25 mL b) 75 mL c) 50 mL d) 12.5 mL
33. 50 mL of 0.5 M oxalic acid is needed to neutralize 25 mL of sodium hydroxide solution. The amount of NaOH in
50 mL of the given sodium hydroxide solution is (12JAN_S1)
a) 40g b) 10 g c) 20g d) 80 g
34. An organic compound neither reacts with neutral ferric chloride solution nor with Fehling solution. It however,
reacts with Grignard reagent and gives positive iodoform test. The compound is (8APR_S2)

a) b) c) d)
35. For a reaction, N 2  g  + 3 H 2  g   
 2 N H 3  g  ; identify dihydrogen  H 2  as a limiting reagent in the
following reaction mixtures (9APR_S1)
a) 5 6 g o f N 2 + 1 0 g o f H 2 b) 3 5 g o f N 2 + 8 g o f H 2
c) 28 g of N 2 + 6 g of H 2
d) 1 4 g of N 2 + 4 g of H 2

36. At 300K and 1 atmospheric pressure, 10 mL of a hydrocarbon required 55 mL of O 2

for complete combustion, and
40 mL of CO2 is formed. The formula of the hydrocarbon is (10APR_S1)
a) C 4 H 10 b) C 4H 6
c) C 4H 7C l d) C 4H 8

37. The minimum amount of O 2  g  consumed per gram of reactant is for the reaction: (Given atomic mass : Fe = 56,
O =16, Mg = 24, P= 31, C = 12, H =1) (10APR_S2)
a) 4 F e  s  + 3 O 2  g   
 2 Fe 2O 3  s  b) P4  s  + 5 O 2  g   
 P4 O 1 0  s 

c) C 3 H 8  g  + 5 O 2  g   
 3 C O 2  g  + 4 H 2O  I 

d) 2 M g  s  + O 2  g   
 2 M gO s 

38. 5 moles of AB2 weigh 1 2 5  1 0  3 k g and 10 moles of A 2B 2 weigh 300  10

3
kg . The molar mass of A  M A  and
molar mass of B  M B  in kg m ol
1
are (12APR_S1)
3 3 3 3
a) M A
 10  10 and M B
 5  10 b) M A
 50  10 and M B
 25  10
3 3 3 3
c) M A
 25  10 and M B
 50  10 d) M A
 25  10 and M B
 50  10

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39. The ratio of mass percent of C and H of an organic compound  C X H Y O Z  is 6:1. If one molecule of the above
compound  C X H Y O Z  contains half as much oxygen as required to burn one molecule of compound C X H Y
completely to C O 2 and H 2 O . The empirical formula of compound C X H Y O Z is
a) C 2 H 4 O b) C 3 H 4 O 2 c) C 2 H 4 O 3 d) C 3 H 6 O 3

JEE MAINS 2017

40. The most abundant elements by mass in the body of a healthy human adult are: Oxygen  6 1 .4 %  ; Carbon
 2 2 .9 %  , Hydrogen  1 0 .0 %  ; and Nitrogen  2 .6 %  . The weight which a 75 kg person would gain if all
1
H

atoms are replaced by 2 H atoms is

a) 15 k g b) 37.5 k g c) 7.5 k g d) 10 k g

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41. . 1 gram of a carbonate  M 2 C O 3  on treatment with excess HCl produces 0.01186 mole of C O 2 . The molar
mass of M 2 C O 3 in g m o l  1 is
a) 1186 b) 84.3 c) 118.6 d) 11.86
GASEOUS STATE
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42. (7JAN_S2)

Select the correct options

a) A = C M P S , B = C a v e r a g e , C = C RM S b) A = C a v e ra g e , B = C M P S , C = C R M S

c) A = C R M S , B = C a v e ra g e , C = C M P S d) A = C M P S , B = C R M S , C = C a v e ra g e
43. (8JAN_S1)

A) Intermolecular force of attraction of X > Y B) Intermolecular force of attraction of X <Y

C) Intermolecular force of attraction of Z < X
Select the correct option(s)
a) A and C b) A and B c) B only d) B and C
44. Given following reaction, N a C lO 3 + F e  
 O 2 + FeO + N aC l

In the above reaction 492L of O 2

is obtained at 1 atm & 300K temperature. Determine mass of NaClO3 required
(in kg).  R  0 .0 8 2 L a tm m o l  1 k  1  (8JAN_S2)
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45. 0.5 moles of gas A and x moles of gas B exert a pressure of 200 Pa in a container of volume 1 0 m 3 at 1000K.
1 1
Given R is the gas constant in J K m o l , x is (9JAN_S1)
2R 2R 4 R 4 R
a) b) c) d)
4 R 4 R 2R 2R
46. The volume of gas A is twice than that of gas B. The compressibility factor of gas A thrice than that of gas B at
same temperature. The pressures of the gases for equal number of moles are: (12JAN_S1)
a) 3 P A = 2 P B b) 2 P A = 3 P B c) P A = 3 P B d) P A = 2 P B
47. The combination of plots which does not represent isothermal expansion of an ideal gas is (12JAN_S2)

a) B and D b) A and C c) B and C d) A and D

0
48. An open vessel at 2 7 C is heated until two fifth of the air (assumed as an ideal gas) in it has escaped from the
vessel. Assuming that the volume of the vessel remains constant, the temperature at which the vessel has been
heated is (12JAN_S2)
0 0
a) 5 0 0 C b) 5 0 0 K c) 7 5 0 C d) 7 5 0 K
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49. Consider the van der Waals constants, a and b, for the following gases, (9APR_S1)
Gas Ar Ne Kr Xe
 6
a / a tm d m m o l
2 1.3 0.2
 5.1 4.1

b / 1 0  3.2 1.7 1.0 5.0

2 3 1
dm m ol

Which gas is expected to have the highest critical temperature?

a) Kr b) Ne c) Xe d) Ar
50. At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behaviour. Their equation of
RT
state is given as P  at T Here, b is the van der Waals constant. Which gas will exhibit steepest increase in
V b
the plot of Z (compression factor) vs P? (9APR_S2)
a) Xe b) Kr c) Ne d) Ar
51. Consider the following table: (10APR_S1)

Gas a /  k Pa dm m ol  b /  dm m ol 
6 1 3 1

A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are van der Waals constants. The correct statement about the gases is
a) Gas C will occupy more volume than gas A; gas B will be more compressible than gas D
b) Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D
c) Gas C will occupy more volume than gas A; gas B will be lesser compressible than gas D
d) Gas C will occupy lesser volume than gas A; gas B will be more compressible than gas D
52. Points I, II and III in the following plot respectively correspond to ( V m p : most probable velocity) (10APR_S2)

a) V m p o f N 2  3 0 0 K  ; V m p o f O 2  4 0 0 K  ; V m p o f H 2  3 0 0 K 
b) V m p o f O 2  4 0 0 K  ; V m p o f N 2  3 0 0 K  ; V m p o f H 2  3 0 0 K 
c) V m p o f N 2  3 0 0 K  ; V m p o f H 2  3 0 0 K  ; V m p o f O 2  4 0 0 K 
d) V m p o f H 2  3 0 0 K  ; V m p o f N 2  3 0 0 K  ; V m p o f O 2  4 0 0 K 
CHEMICAL EQUILIBRIUM
JEE MAINS 2020
Calculate  f H 0  in k J / m o l  for C 2 H 6  g  , if  c H  C  g r a p h ite     3 9 3 .5 k J / m o l ,
0
53.
 
CH  H  g     286 kJ / m ol and  C H 0  C 2 H 6  g     1 5 6 0 k J / m o l
0
2
(7JAN_S2)

54. Assertion: pH of water increases on increasing temperature (8JAN_S2)


Reason: H 2 O    H + O H is an exothermic process
+

a) Both assertion and reason are correct and reason is correct explanation of assertion
b) Both assertion and reason are correct and reason is not correct explanation of assertion
c) Assertion is true & reason is false
d) Both assertion and reason are incorrect
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55. For B r2  l  (9JAN_S1)

Enthalpy of atomization = x k J / m o l
Bond dissociation enthalpy of bromine = y k J / m o l then
a) x  y b) x  y c) x  y d) Relation does not exist
56. Reactant A represented by square is in equilibrium with product B represented by circles. Then value of
equilibrium constant is (9JAN_S2)

a) 1 b) 2 c) 3 d) 4

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57. Consider the following reversible chemical reactions: (9JAN_S2)
A2  g   B 2  g    2 A B  g  ..................  1  6 AB  g    3 A 2  g   3 B 2  g  ...............  2 
K1 K2


 



The relation between K 1 and3 K 2

is
3 3
a) K 1 K 2 = 1 / 3 b) K 2
= K1 c) K 2
= K1 d) K 1 K 2 = 3
58. The values of Kp/K c
for the following reactions at 300 K are, respectively: (At 300K, RT = 24.62 dm3 atm mol–1)
3 1 6 2 2
a) 1 , 2 4 .6 2 d m a tm m o l , 6 0 6 .0 d m a tm m o l (10JAN_S1)
1 3 6 2
b) 1 , 2 4 .6 2 d m a tm m o l ,1 .6 5  1 0
3 2
dm a tm m ol
2 3 1 2
c) 1 , 4 .1  1 0
6 2
dm a tm m o l, 6 0 6 d m a tm m ol
1 2 3 6 2
d) 2 4 .6 2 d m a tm m o l , 6 0 6 .0 d m a tm m o l , 1 .6 5  1 0 d m a tm m o l
3 6 2 2

0
59. 5.1 g N H 4 S H is introduced in 3.0 L evacuated flask at 3 2 7 C , 30% of the solid N H 4 S H decomposed to N H 3
0
and H 2 S as gases. The K p
of the reaction at 3 2 7 C is (10JAN-S2)

R = 0 .0 8 2 L a tm m o l K
1 1
, m o la r m a s s o f S = 3 2 g m o l , m o la r m a s s o f N = 1 4 g m o l
1 1

4 4 3
a) 0 .2 4 2  1 0 a tm b) 1  1 0 a tm c) 4 .9  1 0 a tm
2 2 2 2
d) 0 .2 4 2 a tm
60. Consider the reaction N 2  g  + 3 H 2  g  2 N H 3  g 
(11JAN_S1)
The equilibrium constant of the above reaction is K P . If pure ammonia is left to dissociate, the partial pressure of
ammonia at equilibrium is given by (Assume that P N H < < P T o ta l
3
at equilibrium)
3/2 1/ 2 2 1/ 2 2 1/ 2 2 3/2 1/ 2 2
3 K P
P K P
P K P
P 3 K P
P
a) b) c) d)
16 16 4 4
K
61. 
In a chemical reaction, A  2 B  

 2 C  D , the initial concentration of B was 1.5 times of the concentration of

A, but the equilibrium concentration of A and B were found to be equal. The equilibrium constant (K) for the
aforesaid chemical reaction is: (12JAN_S1)
a) 4 b) 16 c)1/4 d) 1
62. Two solids dissociate as follows (12JAN_S1)
As 
 B  g   C  g  ; K P  x a tm ; D  s   
 C  g   E  g  ; K P  y a tm
2 2
1 2

The total pressure when both the solids dissociate simultaneously is

b) 2  x + y  a tm c)  x  y  a tm d) x  y a tm
2 2
a) x + y a tm

63. For the following reactions, equilibrium constants are given: (8APR_S2)
S  s   O 2  g   S O 2  g  ; K 1  1 0 ; 2 S  s   3O 2  g  2 SO3  g  ; K 2  10
52 129

The equilibrium constant for the reaction, 2 S O 2  g   O 2  g   2 S O 3  g  is:

154 181 25 77
a) 1 0 b) 1 0 c) 1 0 d) 1 0

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64. For the reaction, 2 S O 2  g   O 2  g   2 S O 3  g  ,  H   5 7 .2 k J m o l  1 and K c  1 .7  1 0

16
. Which of the
following statement is INCORRECT? (10APR_S2)
a) The equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required
b) The equilibrium will shift in forward direction as the pressure increases
c) The equilibrium constant decreases as the temperature increases
d) The addition of inert gas at constant volume will not affect the equilibrium constant.
65. In which one of the following equilibria, K p  K c ? (12APR_S2)
a) 2 C  s   O 2  g   2 C O  g  b) 2 H I  g   H 2  g   I 2  g 
c) N O 2  g   S O 2  g   N O  g   S O 3  g  d) 2 N O  g   N 2  g   O 2  g 
JEE MAINS 2018
66. Which of the following lines correctly show the temperature dependence of equilibrium constant, K, for an
exothermic reaction?
ln K

B
1
 0, 0  T K 




 C

 D
a) B and C b) C and D c) A and D d) A and B

IONIC EQUILIBRIUM
JEE MAINS 2020
67. Each of solution A and B of 100L containing 4g NaOH and 9.8 g H 2 S O 4 . Find pH of solution which is obtain by
mixing 40L solution of A and 10L solution of B (7JAN_S1)
68. 3 gram of acetic acid is mixed in 250mL of 0.1 M HCl. This mixture is now diluted to 500 mL. 20 mL of this
1
solution is now taken in another container. mL of 5 M NaOH is added to this. Find the pH of this solution.
2
 lo g 3  0 .4 7 7 1, p K a  4 .7 4  (7JAN_S2)
69. Select the correct stoichiometry and its ksp value according to given graphs. (8JAN_S1)

a) X Y , K sp  2  1 0  6 b) X Y 2 , K sp  4  1 0  9 c) X 2 Y , K sp  9  1 0  9 d) X Y 2 , K sp  1  1 0  9
on mixing 300mL, 0 .1 3 4 M P b  N O 3  2  aq  + 1 0 0 m L , 0 .4 M N aC l  aq 
5
70. Ksp of P b C l 2  1 .6  1 0
(9JAN_S1)
a) Q > K s p b) Q  K s p c) Q  K s p d) Relation does not exist
Given Ksp for C r  O H  3 is 6  1 0 then determine  O H   . (Neglect the contribution of OH– ions from H 2 O )
31
71.
(9JAN_S2)
1/ 4
 6 31 
a)  1 8  1 0  b)  1 8  1 0  c)  6  1 0 
1/ 4 1/ 2 1/ 4
31 31 31
M M M d)   10  M
 27 

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72. 20 mL of 0 .1 M H 2 S O 4 solution is added to 30mL of 0 .2 M N H 4 O H solution. The pH of the resultant mixture is
pK b o f N H 4 O H = 4 .7 
(9JAN_S1)
a) 5.2 b) 9.0 c) 5.0 d) 9.4
 
73. For the equilibrium 2 H 2 O H 3 O  OH ; the value of  G at 298K is approximately:
0
(11JAN_S2)
1 1 1 1
a) 1 0 0 k J m o l b)  8 0 k J m o l c) 8 0 k J m o l d)  1 0 0 k J m o l
12
74. If K sp
of A g 2 C O 3 is 8  1 0 , the molar solubility of A g 2 C O 3 in 0 .1 M A g N O 3 is: (12JAN_S2)
12 11 10 13
a) 8  1 0 M b) 8  1 0 M c) 8  1 0 M d) 8  1 0 M
75. If solubility product of Z r3  P O 4  4 is denoted by K s p and its molar solubility is denoted by S, then which of the
following relation between S and K sp
is correct? (8APR_S1)
1/ 6 1/ 7 1/9 1/ 7
 K sp   K sp   K sp   K sp 
a) S    b) S    c) S    d) S   
 144   6912   929   216 
76. In an acid base titration, 0.1M HCl solution was added to the NaOH solution of unknown strength. Which of the
following correctly shows the change of pH of the titration mixture in this experiment? (9APR_S2)

a) B b) A c) C d) D
77. Consider the following statements (10APR_S1)
A) The pH of a mixture containing 400 mL of 0 .1 M H 2 S O 4 and 400 mL of 0 .1 M N a O H will be approximately
1.3
B) Ionic product of water is temperature dependent
5
C) monobasic acid with K a  1 0 has a pH = 5. The degree of dissociation of this acid id 50%
D) The Le Chatelier’s principle is not applicable to common–ion effect
The correct statements are
a) (A), (B) and (D) b) (A), (B) and (C) c) (B) and (C) d) (A) and (B)
78. The pH of a 0.02 M N H 4 C l solution will be [Given K b  N H 4 O H  = 1 0  5 and lo g 2  0 .3 0 1 ] (10APR_S2)
a) 2.65 b) 4.35 c) 4.65 d) 5.35
79. What is the molar solubility of A l  O H  3 in 0 .2 M N a O H solution? Given that, solubility product of
A l  O H   2 .4  1 0
24
3
(12APR_S1)
19 21 22 23
a) 3  1 0 b) 1 2  1 0 c) 3  1 0 d) 1 2  1 0
5
80. The molar solubility of C d  O H  2 is 1 .8 4  1 0 M in water. The expected solubility of C d  O H  2 in a buffer
solution of pH = 12 is (12APR_S2)
9 2 .4 9 9 11 10
a) 1 .8 4  1 0 M b)  10 M c) 6 .2 3  1 0 M d) 2 .4 9  1 0 M
1 .8 4
JEE MAINS 2018

81. Which of the following salt is the most basic in aqueous solution?
a) C H 3 C O O K b) F e C l 3 c) P b  C H 3 C O O  2 d) A l  C N  3
An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct
82.
combination?
Base Acid End Point Base Acid End Point
a) Strong Strong Pinkish red to yellow b) Weak Strong Yellow to pinkish red
c) Strong Strong Pink to colourless d) Weak Strong Colourless to pink

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An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation of H S 
83.
from H 2 S is 1 .0  1 0  7 and that of S 2  from H S  ions is 1 .2  1 0  1 3 then the concentration of S 2  ions in
aqueous solution is
20 21 19 8
a) 3  1 0 b) 6  1 0 c) 5  1 0 d) 5  1 0
2
84. An aqueous solution contains an unknown concentration of B a . When 50mL of a 1M solution of N a 2 S O 4 is
added, B a S O 4 just begins to precipitate. The final volume is 500mL. The solubility product of B a S O 4 is
10 2
1 10 . What is the original concentration of B a ?
9 9 10 9
a) 2  1 0 M b) 1 .1  1 0 M c) 1 .0  1 0 M d) 5  1 0 M

JEE MAINS 2017

85. p K a of a weak acid (HA) and p K b of a weak base (BOH) are 3.2 and 3.4 respectively. The pH of their salt (AB)
solution is
a) 7.2 b) 6.9 c) 7.0 d) 1.0

THERMODYNAMICS
JEE MAINS 2020
86. A l   
 2 B g  (7JAN_S1)
. Find  G  in k c a l 
 U  2 .1 k c a l ,  S  2 0 c a l / k , T  3 0 0 K
87. A gas undergoes expansion according to the following graph. Calculate work done by the gas (8JAN_S1)

88. Temperature of 4 moles of gas increases from 300K to 500K find 'C v ' if  U  5 0 0 0 J . (8JAN_S2)
89. A can reduce BO 2 under which conditions (9JAN_S1)

a)  1 4 0 0 0 C b)  1 4 0 0 0 C c)  1 2 0 0 0 C a n d  1 4 0 0 0 C d)  1 2 0 0 0 C
90. Select the correct option (9JAN_S2)
a) Entropy is function of temperature and also entropy change is function of temperature
b) Entropy is a function of temperature & entropy change is not a function of temperature
c) Entropy is not a function of temperature & entropy change is a function of temperature
d) Both entropy & entropy change are not a function of temperature
91. 0.1 ml of an ideal gas has volume 1 d m 3 in a locked box with friction less piston. The gas is in thermal equilibrium
with excess of 0.5 m aqueous enthylene glycol at its freezing point. If piston is released all of a sudden at 1 atm
then determine the final volume of gas in d m  R  0 .0 8 a tm L m o l  1 K  1 K f  2 .0 L m o la l  1  (9JAN_S2)
3

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92. Consider the reversible isothermal expansion of an ideal gas in a closed system at two different temperatures T 1 and
T2  T1  T2  . The correct graphical depiction of the dependence of work done(w) on the final volume (V) is:
(9JAN_S1)

a) b) c) d)
93. The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is: (Specific
1 1 1 1
heat of water liquid and water vapour are 4.2 kJ K k g and 2 .0 k J K k g ; heat of liquid fusion and
1 1
vapourisation of water are 3 3 4 k J k g and 2 4 9 1 k J k g , respectively). (9JAN_S2)
 lo g 2 7 3  2 .4 3 6 , lo g 3 7 3  2 .5 7 2 , lo g 3 8 3  2 .5 8 3 
1 1 1 1 1 1 1 1
a) 7 .9 0 k J k g K b) 2 .6 4 k J k g K c) 8 .4 9 k J k g K d) 9 .2 6 k J k g K
1 1 1
94. A process has  H  2 0 0 J m o l and  S  4 0 J K m o l . Out of the values given below, choose the minimum
temperature above which the process will be spontaneous: (10JAN_S1)
a) 20K b) 12K c) 5K d) 4K
95. The process with negative entropy change is: (10JAN_S2)
a) Dissociation of C a S O 4  s  to C a O  s  and S O 3  g  b) Sublimation of dry ice
c) Dissolution of iodine in water d) Synthesis of ammonia from N 2 and H 2
3 2
96. An ideal gas undergoes isothermal compression from 5 m to 1 m 3 against a constant external pressure of 4 N m .
Heat released in this process is used to increase the temperature of 1 mole of Al. If molar heat capacity of Al is
1 1
2 4 J m o l K , the temperature of Al increases by (11JAN_S1)
3 2
a) K b) 2 K c) K d) 1 K
2 3
97. Two blocks of the same metal having same mass and at temperature T 1 , and T 2 , respectively, are brought in contact
with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy,  S , for this
process is (11JAN_S1)
 
1
 T  T    T1  T 2 2
2
 T1  T 2   T1  T 2 
ln  
1 2
a) C p ln   b) 2 C p c) 2 C p ln   d) 2 C p ln  
 4 T1T 2   
T1T 2  4 T1T 2   2 T1T 2 
 
98. For the chemical reaction X  Y , the standard reaction Gibbs energy depends on temperature T  in K  as
3
 rG
0
 in kJ m ol
1
  120  T
8
The major component of the reaction mixture at T is: (11JAN_S2)
a) Y if T = 3 0 0 K b) Y if T = 2 8 0 K c) X if T = 3 5 0 K d) X if T = 3 1 5 K
99. The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by
 G  A  B T where A and B are non–zero constants. Which of the following is true about this reaction?
0

(11JAN_S2)
a) Exothermic if B < 0 b) Endothermic if A > 0
c) Endothermic if A < 0 and B > 0 d) Exothermic if A > 0 and B < 0

100. For a diatomic ideal gas in a closed system, which of the following plots does not correctly describe the relation
between various thermodynamic quantities? (12JNAN_S1)

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a) b) c) d)
101. Given: (12JAN_S2)
 i  C  g ra p h ite   O 2  g   
 CO2  g ;  rH
1
 x kJ m ol
0

 i  C  g ra p h ite   O 2  g   
 CO2  g ;  rH
1
 x kJ m ol
0

1
 ii  C  g r a p h ite   O2  g  CO g ;rH
1
  y kJ m ol
0

2
1
 iii  C O  g   O2  g  CO2  g ; rH
1
  z kJ m ol
0

2
Based on the above thermo chemical equations, find out which one of the following algebraic relationship is
correct?
a) x  y  z b) z  x  y c) y  2 z  x d) x  y  z
JEE MAINS 2018
102. The combustion of benzene (I) gives C O 2  g  and H 2 O  l  . Given that heat of combustion of benzene at constant
volume is  3 2 6 3 .9 k J m o l at 2 5 C , heat of combustion (in kJ mol–1) of benzene at constant pressure will be:
1 o

R  8 .3 1 4 J K
1
m ol
1

a) –452.46 b) 3260 c) –3267.6 d) 4152.6

JEE MAINS 2017

103.  U is equal to
a) Isochoric work`b) Isobaric work c) Adiabatic work d) Isothermal work
104. Given C  g ra p h ite   O 2  g   
 CO2  g 
1
rH   3 9 3 .5 k J m o l
o

2 H 2  g   O2  g   
 H 2O  l 
1
rH   2 8 5 .8 k J m o l
0

C O 2  g   2 H 2O  l   
 C H 4  g   2O 2  g 
1
rH   8 9 0 .3 k J m o l
0

rH
0
Based on the above thermochemical equations, the value of at 2 9 8 K for the reaction
C  g r a p h ite   2 H 2  g   
 CH 4  g  will be
1 1 1 1
a)  7 4 .8 k J m o l b)  1 4 4 .0 k J m o l c)  7 4 .8 k J m o l d)  1 4 4 .0 k J m o l
PERIODIC CLASSIFICATION
JEE MAIN 2020

105. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I? (7JAN_S1)
a) –296, –325, –333, –349 b) –333, –349, –325, –296
c) –349, –333, –325, –296 d) –235, –333, –349, –296

106. Atomic radius of Ag is similar to (7JAN_S1)

a) Cu b) Hg c) Au d) Ni

107. Which one of the following amongs each pair will release maximum energy on gaining one electron (A = F, Cl),
(B=S, Se), (C=Li, Na) (7JAN_S2)
a)  A  = C l,  B  = S ,  C  = L i b)  A  = F ,  B  = S e ,  C  = L i
c)  A  = F ,  B  = S e ,  C  = N a d)  A  = C l,  B  = S ,  C  = N a

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108. Correct order of first ionization energy of the following metals Na, Mg, Al, Si in k J m o l  1 respectively are
a) 497, 737, 577, 786 b) 497, 577, 737, 786 c) 786, 739, 577, 497 d) 739, 577, 786, 487 (8JAN_S1)

109. Among the following which will show geometrical isomerism. (8JAN_S2)
+ 
A)  N i  N H 3  5 C l  B)  N i  N H 3  4 C lB r  C)  N i  N H 3  3 C l  D)  N i  N H 3  2  N O 2  2 
a) B, D b) A, B c) A, B & C d) A, B, C & D

JEE MAINS 2019-

110. In general, the properties that decrease and increase down a group in the periodic table, respectively, are
(9JAN_S1)
a) atomic radius and electronegativity b) electron gain enthalpy and electronegativity
c) electronegativity and atomic radius d) electronegativity and electron gain enthalpy

111. Aluminum is usually found in +3 oxidation state. In contrast, thallium exists in +1 and +3 oxidation states. This is
due to (9JAN_S1)
a) inert pair effect b) diagonal relationship c) lattice effect d) lanthanoid contraction

112. When the first electron gain enthalpy   e g H  of oxygen is  1 4 1 k J / m o l , its second electron gain enthalpy is
(9JAN_S2)
a) a more negative value than the first b) almost the same as that of the first
c) negative, but less negative than the first d) a positive value

113. The electronegativity of aluminium is similar to (10JAN_S1)

a) Carbon b) Beryllium c) Boron d) Lithium

114. The 71st electron of an element X with an atomic number of 71 enters into the orbital (10JAN_S2)
a) 6 p b) 4 f c) 5 d d) 6 s

115. The correct order of atomic radii of C, Cs, Al and S is: (11JAN_S1)
a) C < S < A l < C s b) S < C < C s < A l c) S < C < A l < C s d) C < S < C s < A l

116. The correct option with respect to the Pauling electronegativity values of the elements is: (11JAN_S2)
a) Te>Se b) Ga<Ge c) Si<Al d) P>S

117. The relative stability of +1 oxidation state of group 13 elements follows the order (11JAN_S2)
a) A l < G a < T l < In b) T l  In < G a < A l c) G a  A l < In < T l d) A l < G a < In < T l

118. The element with Z = 120 (not yet discovered) will be an/a: (12JAN_S1)
a) Inner–transition metal b) Alkaline earth metal
c) Alkali metal d) Transition metal

119. The size of the iso–electrnic species C l  , A r and C a 2  is affected by: (8APR_S1)
a) azimuthal quantum number of valence shell
b) electron–electron interaction in the outer orbitals
c) principal quantum number of valence shell
d) nuclear charge

120. The IUPAC symbol for the element with atomic number 119 would be (8APR_S2)
a) uue b) une c) unh d) uun

121. The correct statements among I to III regarding group 13 element oxides are, (9APR_S2)
(I) Boron trioxide is acidic
(II) Oxides of aluminium and gallium are amphoteric
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(III) Oxides of indium and thallium are basic
a) (I) and (II) only b) (I), (II) and (III) c) (I) and (III) only d) (II) and (III) only

122. In comparison to born, beryllium has (12APR_S1)

a) Lesser nuclear charge and lesser first ionization enthalpy
b) greater nuclear charge and lesser first ionization enthalpy
c) greater nuclear charge and greater first ionization enthalpy
d) lesser nuclear charge and greater first ionization enthalpy

JEE MAINS 2017

123. The group having isoelectronic species is
a) O 2  , F  , N a  , M g 2  b) O  , F  , N a , M g 
c) O 2  , F  , N a , M g 2  d) O  , F  , N a  , M g 2 
CHEMICAL BOND
JEE MAINS 2020

1  M e th y le th y le n e o x id e    X , P r o d u c t 'X ' w ill b e

ex cess
124. HBr
(7JAN_S1)

a) b) c) d)

125. Decreasing order of dipole moment in C H C l 3 , C C l 4 & C H 4 is (7JAN_S1)

a) C H C l 3 > C C l 4 = C H 4 b) C H C l 3 > C C l 4  C H 4
c) C C l 4 > C H C l 3 > C H 4 d) C C l 4 = C H 4 > C H C l 3

126. Bond order and magnetic nature of C N  are respectively (7JAN_S2)

a) 3, diamagnetic b) 3, paramagnetic c) 2, 5, paramagnetic d) 2.5, diamagnetic

127. Following vanderwaal forces are present in ethyl acetate liquid (8JAN_S1)
a) H–bond, London forces b) dipole–dipole interation, H–bond
c) dipole–dipole interation, London forces d) H–bond, dipole–dipole interation, London forces

128. Correct bond energy order of following is (8JAN_S2)

a) C  C l  C  B r  C  I  C  F b) C  F  C  C l  C  B r  C  I
c) C  F  C  C l  C  B r  C  I d) C  I  C  B r  C  F  C  C l

129. Complex  M L 5  can exhibit trigonal bipyramidal and square pyramidal geometry. Determine total number of
0 0 0
180 ,90 & 120 L- M - L bond angles (8JAN_S2)

130. Which of the following species have one unpaired electron each? (9JAN_S1)
a) O 2 , O 2 b) O 2 , O 2 c) O 2 , O 2 d) 2
O2 ,O2

JEE MAINS 2019

+ 
131. According to molecular orbital theory, which of the following is true with respect to Li2 and Li2 ? (9JAN_S1)
+   
a) L i 2 is unstable and Li2 is stable b) L i 2 is stable and L i 2 is unstable
c) Both are stable d) both are unstable

132. In which of the following processes, the bond order has increased and paramagnetic character has changed to
diamagnetic? (9JAN_S2)
2
a) N O   NO b) N 2   N2 c) O 2   O2 d) O 2  
 O2
+ + +

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 JEE-Main
FIITJEE CHEMISTRY
-ORIGINAL-
133. Two pi and half sigma bonds are present in: (10JAN_S1)
+
a) O +2 b) N 2 c) O 2 d) N 2

2 2 2
134. Among the following molecules/ions, C2 , N 2
,O2 ,O2 . Which one is diamagnetic and has the shortest bond
length? (8APR_S2)
a) O 2 b) N 22  2
c) O 2 2
d) C 2

135. Among the following, the molecule expected to be stabilized by anion formation is: C 2 , O 2 , N O , F2
a) C 2 b) F 2 c) N O d) O 2 (9APR_S1)

136. Among the following species, the diamagnetic molecule is: (9APR_S2)
a) NO b)CO c) B2 d) O2


137. During the change of O 2 to O 2
, the incoming electron goes to the orbital: (10APR_S1)
a)  2 py b)  * 2 p z c)  * 2 p x d)  2 p x

138. The correct statement among the following is: (12APR_S1)

a)  S iH 3  3 N is planar and less basic than  C H 3  3 N
b)  S iH 3  3 N is pyramidal and more basic than  C H 3  3 N
c)  S iH 3  3 N is pyramidal and less basic than  C H 3  3 N
d)  S iH 3  3 N is planar and more basic than  C H 3  3 N

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
139. Total number of Lone pair of electrons in I3 ion is
a) 6 b) 9 c) 12 d) 3

140. According the molecular orbital theory, which of the following will not be a viable molecule?
a) H e 2 b) H 2 c) H 22  d) H e 22 
141. Which of the following compounds contain(s) no covalent bond(s)?
K C l, P H 3 , O 2 , B 2 H 6 , H 2 S O 4

a) K C l, H 2 S O 4 b) KCl c) K C l, B 2 H 6 d) K C l, B 2 H 6 , P H 3
JEE MAINS 2017- CHEMICAL BOND
142. Which of the following species is not paramagnetic?
a) NO b)CO c) O 2 d) B 2
HYDROGEN AND ITS COMPOUNDS
JEE MAINS 2020
143. Which of the following statements are correct? (7JAN_S2)
(I) On decomposition of 2 2 , O 2 gas is released
H O

(II) 2–ethylanthraquinol is used in preparation of H 2 O 2

(III) On heating K C lO 3 , P b  N O 3  2 , N a N O 3 , O 2 gas is released
(IV) In the preparation of sodium peroxoborate, H 2 O 2 is treated with sodium metaborate
a) I, II, IV b) II, III, IV c) I, II, III, IV d) I, II, III

144. Determine total number of neutrons in three isotopes of hydrogen. (8JAN_S2)

a) 1 b) 2 c)3 d) 4

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145. The isotopes of hydrogen are: (9JAN_S1)
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FIITJEE CHEMISTRY
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a) Tritium and protium only b) Protium and deuterium only
c) Protium, deuterium and tritium d) Deuterium and tritium only

146. The temporary hardness of water is due to: (9JAN_S2)

a) N a 2 S O 4 b) N a C l c) C a  H C O 3  2 d) C a C l 2

147. The total number of isotopes of hydrogen and number of radioactive isotopes among them, respectively, are
(10JAN_S1)
a) 3 and 1 b) 3 and 2 c) 2 and 1 d) 2 and 0

148. The chemical nature of hydrogen peroxide is: (10JAN_S1)

a) Oxidising agent in acidic medium, but not in basic medium
b) Reducing agent in basic medium, but not in acidic medium
c) Oxidising and reducing agent in acidic medium, but not in basic medium
d) Oxidising and reducing agent in both acidic and basic medium

149. The correct statements among (A) to (D) regarding H 2 as a fuel are (11JAN_S1)
A) It produces less pollutants than petrol
B) A cylinder of compressed dihydrogen weighs  3 0 times more than a petrol tank producing the same amount of
energy
C) Dihydrogen is stored in tanks of metal alloys like NaNi5
D) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 kJ,
respectively.
a) (B) and (D) only b) (A) and (C) only c) (B), (C) and (D) only d) (A), (B) and (C) only

150. The hardness of a water sample (in terms of equivalents of CaCO3) containing 1 0  3 M C aS O 4 is:
1
(molar mass of C aS O 4 = 136 g m ol ) (12JAN_S1)
a) 10 ppm b) 5 ppm c) 90 ppm d) 100 ppm

1
151. The volume strength of 1 M H 2 O 2 is: (Molar mass of H 2 O 2 = 34 g m ol ) (12JAN_S2)
a) 5.6 b) 16.8 c) 11.35 d) 22.4

152. 100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 g of magnesium bicarbonate. The
hardness of this water sample expressed in terms of equivalents of C a C O 3 is: (Molar mass of calcium bicarbonate
is 1 6 2 g m o l  1 and magnesium bicarbonate is 1 4 6 g m o l  1 ) (8APR_S1)
a) 5, 000 ppm b) 1,000 ppm c) 100 ppm d) 10, 000 ppm
153. The strength of 11.2 volume solution of H 2 O 2 is: [Given that molar mass of H = 1 g m o l  1 and O = 1 6 g m o l  1
(8APR_S2)
a) 13.6% b) 3.4% c) 34% d) 1.7%

154. The number of water molecules(s) not coordinated to copper ion directly in C u S O 4 .5 H 2 O , is (9APR_S1)
a) 2 b) 3 c) 1 d) 4

155. The synonym for water gas when used in the production of methanol is (10APR_S1)
a) natural gas b) fuel gas c) laughing gas d) syn gas

156. The correct statements among (A) to (D) are (10APR_S2)

A) Saline hydrides produce H2 gas when reacted with H2O
B) Reaction of LiAlH4 with BF3 leads to B2H6
C) PH3 and CH4 are electron-rich and electron-precise hydrides, respectively,
D) HF and CH4 are called as molecular hydrides
a) (A), (B), (C) and (D) b) (C) and (D) only c) (A), (C) and (D) only d) (A), (B) and (C) only

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 JEE-Main
FIITJEE CHEMISTRY
-ORIGINAL-
157. The temporary hardness of a water sample is due to compound X. Boiling this sample converts X to compound Y.
X and Y, respectively, are (12APR_S2)
a) M g  H C O 3  2 a n d M g  O H  2 b) C a  H C O 3  2 a n d C a  O H  2
c) M g  H C O 3  2 a n d M g C O 3 d) C a  H C O 3  2 a n d C a O

JEE MAINS 2018

4 3 3
158. Hydrogen perodixe oxidises  F e  C N  6  to  F e  C N  6  in acidic medium but reduces  F e  C N  6  to
4
Fe CN  6  in alkaline medium, the other products formed are respectively

a)  H 2 O + O 2  a n d  H 2 O + O H   b) H 2 O a n d  H 2 O + O 2 
c) H 2 O a n d  H 2 O + O H   d)  H 2 O + O 2  a n d H 2 O

EXCERSICE-1
CHEMISTRY_ANSWERS & SOLUTIONS

1. A 2. B 3. C 4. B 5. C 6. D 7. A 8. C 9. C 10. A
11. D 12. C 13. D 14. C 15. D 16. B 17. D 18. B 19. A 20. A
21. B 22. A 23. D 24. A 25. 04.96 26. 14.00 27. 10.00 28. B 29. C 30. A
31. D 32. A 33. BONUS 34. D 35. A 36. B 37. A 38. D 39. C 40. C
41. B 42. A 43. C 44. 02.13 45. D 46. B 47. A 48. B 49. A 50. A
51. A 52. A 53. -85.00 54. D 55. A 56. B 57. C 58. B 59. D 60. A
61. A 62. B 63. C 64. A 65. A 66. D 67. 10.60 68. 5.22 69. A 70. A
71. A 72. B 73. C 74. C 75. B 76. B 77. B 78. D 79. C 80. D
81. A 82. B 83. A 84. B 85. A 86. -02.70 87. 48 88. 06.25 89. A 90. A
91. 2.176 92. A 93. D 94. C 95. D 96. C 97. A 98. D 99. C 100. B
101. A 102. C 103. C 104. C 105. B 106. C 107. A 108. A 109. A 110. C
111. A 112. D 113. B 114. C 115. A 116. B 117. D 118. B 119. D 120. A
121. B 122. D 123. A 124. B 125. A 126. A 127. C 128. C 129. 20.00 130. C
131. C 132. A 133. D 134. D 135. A 136. B 137. C 138. A 139. B 140. C
141. B 142. B 143. C 144. C 145. C 146. C 147. A 148. D 149. D 150. D
151. C 152. D 153. B 154. C 155. D 156. D 157. A 158. B 159. 160.

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