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1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Used for dyeing of cotton yarn
Uses advised against Not Applicable
Email dewi.karlina@kemindo.com
Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for transport purposes.
Classification according to
regulation (EC) No Specific target organ toxicity - repeated exposure Category 2
1272/2008 [CLP]
Hazard statement(s)
H373 May cause damage to organs through prolonged or repeated exposure.
Supplementary statement(s)
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Not Applicable
3.1.Substances
See 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1.CAS No
2.EC No
%[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP]
3.Index No
4.REACH No
1.482-89-3
2.207-586-9
>=94 c.i. vat blue 1 Specific target organ toxicity - repeated exposure Category 2; H373
3.Not Available
4.Not Available
1.497-19-8
2.207-838-8
0-3 sodium carbonate Eye Irritation Category 2; H319
3.011-005-00-2
4.Not Available
1.471-34-1
2.207-439-9
0-3 calcium carbonate Not Applicable
3.Not Available
4.Not Available
1.7757-82-6
2.231-820-9
0-3 sodium sulfate Not Applicable
3.Not Available
4.Not Available
1.7732-18-5
2.231-791-2
<=2 water Not Applicable
3.Not Available
4.Not Available
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If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
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EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
sodium carbonate Sodium carbonate 12 mg/m3 130 mg/m3 780 mg/m3
calcium carbonate Carbonic acid, calcium salt 45 mg/m3 210 mg/m3 1300 mg/m3
sodium sulfate Sodium sulfate, anhydrous 11 mg/m3 130 mg/m3 650 mg/m3
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Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or national equivalent)
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TOXICITY IRRITATION
Indigo (C.I. Vat Blue 1)
Not Available Not Available
TOXICITY IRRITATION
[2] Eye (rabbit): 100 mg/24h moderate
dermal (rat) LD50: >2000 mg/kg
[2] Eye (rabbit): 100 mg/30s mild
Inhalation (guinea pig) LC50: 0.8 mg/L/2hr
sodium carbonate
[2] Eye (rabbit): 50 mg SEVERE
Inhalation (mouse) LC50: 1.2 mg/L/2hr
[2] Skin (rabbit): 500 mg/24h mild
Inhalation (rat) LC50: 2.3 mg/L/2hr
[2]
Oral (rat) LD50: 2800 mg/kg
TOXICITY IRRITATION
TOXICITY IRRITATION
water
[2] Not Available
Oral (rat) LD50: >90000 mg/kg
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data
extracted from RTECS - Register of Toxic Effect of chemical Substances
Legend: – Data available but does not fill the criteria for classification
– Data required to make classification available
– Data Not Available to make classification
12.1. Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
c.i. vat blue 1 LC50 96 Fish 6.894mg/L 3
c.i. vat blue 1 EC50 48 Crustacea >500mg/L 1
c.i. vat blue 1 EC50 72 Algae or other aquatic plants >0.55mg/L 1
c.i. vat blue 1 EC10 72 Algae or other aquatic plants =0.12mg/L 1
c.i. vat blue 1 NOEC 72 Algae or other aquatic plants =0.07mg/L 1
sodium carbonate LC50 96 Fish 300mg/L 4
sodium carbonate EC50 48 Crustacea =176mg/L 1
sodium carbonate EC50 96 Algae or other aquatic plants 242mg/L 4
sodium carbonate EC50 384 Crustacea 149.200mg/L 3
sodium carbonate NOEC 16 Crustacea 424mg/L 4
calcium carbonate LC50 96 Fish >56000mg/L 4
calcium carbonate EC50 72 Algae or other aquatic plants >14mg/L 2
calcium carbonate NOEC 72 Algae or other aquatic plants 14mg/L 2
sodium sulfate LC50 96 Fish 56mg/L 4
sodium sulfate EC50 48 Crustacea 2564mg/L 1
sodium sulfate EC50 96 Algae or other aquatic plants 105.72278mg/L 3
sodium sulfate EC0 360 Algae or other aquatic plants 4mg/L 1
sodium sulfate NOEC 168 Fish <220mg/L 4
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -
Legend: Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
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Labels Required
Marine Pollutant NO
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Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
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This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : 98/24/EC, 92/85/EC, 94/33/EC, 91/689/EEC, 1999/13/EC, Commission
Regulation (EU) 2015/830, Regulation (EC) No 1272/2008 and their amendments
PREPARATION IS WGK 1
Name WGK Score Source
c.i. vat blue 1 1 W: VwVwS
SODIUM CARBONATE 1 W: VwVwS
calcium carbonate non-hazardous to waters 0 Calculated
sodium sulfate 1 W: VwVwS
WATER non-hazardous to waters 0 Calculated
Other information
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are
Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or
available engineering controls must be considered.
For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices
end of SDS