what

m
I
poymes ·

are macromolecular compound

polymers
Formed from a smaller
repeating unitcalled

as monomers

masscos-lockres
-evarenignmolesion

emotion
⑰
Based on Sorce:

issummaries
artificially modified)
but

are tussified as
Natural polymers
A plant polymers
Animal
- >
polymers
structure
⑰Based on

Linear polymer
A)

B) Branched polymer

C) Cross
linking polymer
⑰1 Based primerisation ses
A) Addition polymerisation
is Formation of Free radical
is chain initialization
iii) chain
propogation
iv] chain tamination

B) condensation polymerisation
(also
called as growth)
step

Ring opening polymerisation

2)
⑭BASED ONMOLECULAR FORCES

Exhibits Elastic property

⑰
EoMeTS:
weak intermolewal forces (vandewaal
ere
eg: BUNars;BuNaN

⑬ FBRES: HIGH TENSICESTRENGHT TO

RESISTANT

BREAKING UNDER TENSION

STRONG MOLECULAR FORCE

OFATTRACTION

②He Bonding, Dipole Dipole Forces)

egi Nylon 6.6. Tevelyne.

②
mmoplastic: Capable of Repeated softening
and
hardening on
moderate
cooling, strong
Forces ofattraction between elastomer

and
fibres.
polyethens, let C
eg: polysing

once hardened they becomes

⑪ #setting:
remolded
infosible,cannot
be
I

bonds (covalentband)
cross
linking
eg: Bakeline, resiners.
 MOMOPOLYMER AND HETERO POLYMER

⑦
Hpolymer: The
polymers which have only one

units called
type repeating
of monomer

are homo polymers

egg polyethene, Nylm 6.

⑬
o polymer polymer : The
polymes which have

unit
two or more
types repeating
of

called as hetero polymer

are

6.6, Buna-s
eg:Nylm

NATURAL RUBBER
namen

Natural Rubber is Isoprene

Monomer of

butadiene
Isoprene: a-metal
1
 pymeric
footnamel pote

,,

Properties
~
ofNatural Rober =

1) Cis isomer ofIsoprene

molecular Forces due to

2) weak
Xander weal

3) Elastic in Nature.

↑onisation Rer:
II
which cross
The process by
a network of
into elastomers is
link, is introduced an

called as vulcunisation Rubber.

of

vulcunization enhances properties like

tensile shrought; stiffness, Elasticity

toughness etc. Natural
of robber.
 ⑭paration of pymers
⑰
Polyethene:
Monomers:
m
there [CHz cHc]
=

is oftwo kinds
polyethene namely
A) Low Density Polythene (LDP)

High Density Polyethene

B) (HDP)

LOW DENSITY POLYETHENE

is
LDP obtained
by polymerisation Ethere
of
under (1000 mm)
high
2000
pressure
-

at 350-570K

fc ck]
-

cHz CH2
= ->
M
Ethene
LPP

Properties DP: Flexible, tough, moisture resistant

melting point1100
poor conductor Electricity;
of

BOTTLES FTC
Yes: PIDES, INSULATION,
CABLE
 DENSITY POLYESHENE
HIGH

and
high densing
Linear close
polymes with

packing.
CHz CH2333-343K
=

6 -
7atm
HDM

is obtained
#01: HDP using Englan -

-
Nalta
cavalyst
zieglar
-
Natra
Catalystis Combination Ticlu +
of
(zHT), A

144-150.
perties of IDP: Nelting pointofHDP is

tensile. Howe
Hard and
highly
resistantto chemicals

Uses:Toys, Bockets, dustins, bottles etc.

#
FIOn· Honomers used: Poly Tetraflour stene
(CFC CE]
=

Peroxide
n(Fc cF2 =
fCE-cFz]n
PTFE
/ TeFlon

Properties Tough. Resistant to heatand

Reagent.
difficult
C -F to break

U↓es: Used in making non-stick cookware, oil seals, Gaskets etc.

 (PAN) ION
Acryl
By
Monomer used: Acrylonifile/vinyl Cyanide
ncHc
= [-

cHz -

CA In
-

ying cyanide
polyacrylonitrile
Used as artificial 1000 and sweaters

A PHERS
MIDE

#on 6:
Hexamethylene diamine
monomersed A)
B) Adipic Acid

numeral 6,6 denotes the carbon

number of
NOTE:The
in reactant.
the
in Carbon compands
atoms present

Linear condensation reaction

Properties:
- polymer;
amide
linkage, high tensile strenght

sheets, bushes, textile Fabrics.

Yes:Used For making
 #ON6: Nonomer: Eaptum:

total call
The numeral 6 representthe m

in monomer.
present

Properties: High tensile

strought, lustrous

oftyre Cards, ropes are

Ises:Manufacturing

AESTER ·

Monomers as Ethylene Glycol

Acid
6) terephtaic

chemicals and
High melting point, resistantto water.

helmets, bottles
wrinkle Free
Fabric, safety
Used For
making
⑩one: tenylene terrycot
cotton:
3
ELITE:

↑mers. Phenol and Formaldeyde

#lamine -

Fodeyde 8
BUNA-5: Buradiene styene)

Also called as "SBR"

HoR:
75% Butadiene
of
+

shyene
25%of

Ulanized with sulfur.

rubber.
Natal
to
superior
ofTypes.
Used in
making

Rubber
⑭ene :

hose
Neoprene is used in
making pipe
cables
jackets, belts, insulator etc

Nok:Resistantto peholeum, oil, hear

#unisation opene
of

NERS
↑DEGRADABLE

PBX
↑omea used
As 3-Hydroxy Butanoic Acid

Pentanoic Acid
3) 3-Hydroxy

Note Ester
linkage [-0]
Non-Aly6:
↑homedi
As Glycina
Acid.
B) amino Capoic

Commercially ImportantPolymers