New Indian Era’s

NIE CLASSES
5th – 8th 9th – 10th Foundation 11th -12th (Sci) JEE MAINS MHT CET NEET

|| IMP Q.|| Chapter-6|| Chemistry-1 || Class 12th

1) Show that time required for 99.9% completion of a first order
reaction is three times the time required for 90 completion.

2) What is Pseudo first order reaction? Derive integrated rate law

equation for zero order reaction.

3) A chemical reaction occurs in the following steps:

(i) NO2(g) + F2(g) → NO2F(g) + F (g) (slow)

(ii) F(g) + NO2(g) → NO2F(g) (fast)

(a) Write the equation of overall reaction.
(b) Write down rate law.
(c) Identify the reaction intermediate.

4) Show that time required for 99.9% completion of a first order

reaction is three times the time required for 90% completion.

5) Identify the molecularity of following elementary reaction:

NO(g) + O3(g)→ NO3(g) + O(g)

6) Define half life of first order reaction. Obtain the expression for half
life and rate constant of the first order reaction.

2.303 𝑅𝑇
7) Write the value of in Nernst equation.
𝐹

8) What is pseudo-first order reaction? Explain with suitable example.

 New Indian Era’s

NIE CLASSES
5th – 8th 9th – 10th Foundation 11th -12th (Sci) JEE MAINS MHT CET NEET

|| IMP Q.|| Chapter-6|| Chemistry-1 || Class 12th

9) Define isomorphism. Derive integrated law expression for first order
reaction.

10) Define instantaneous rate of reaction. Explain pseudo first order

reaction with suitable example.

11) Write the mathematical relation between half life of zero order
reaction and its rate constant.

12) A reaction occurs by the following mechanism:

(i) NO2(g) + F2(g) → NO2F(g) + F (g)

(ii) F(g) + NO2(g) → NO2F(g)

Identify the intermediate and write net reaction.

13) Define elementary reaction.

14) The half life of first order reaction is 6.0 hours. How long it will take
for the concentration of reactant to decrease from 0.8 M to 0.25 M.

15) The half life period of a first order reaction is 6.0 h. Calculate the
rate constant.